Download or read book The Characterization of Phenol formaldehyde Resin Adhesive as Related to Effectiveness in Wood Adhesion written by Chung-Yun Hse and published by . This book was released on 1973 with total page 254 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Preparation and Characterization of Formaldehyde Free Wood Adhesives from Oil Palm Elaeis guineensis Fronds Lignin Penerbit USM written by Mohd. Hazwan Hussin and published by Penerbit USM. This book was released on with total page 87 pages. Available in PDF, EPUB and Kindle. Book excerpt: Phenol formaldehyde (PF) is one of the widely used wood adhesives in the wood industry. The raw materials in the production of phenol formaldehyde resin are petroleum-derived and formaldehyde-based materials which corresponds to public health issues, environmental problems and non-economical costing. In recent years, the increasing price of petrochemical due to energy shortage and environmental problems such as global warming and climate change as results from the burning of fossil fuels have been brought to great public attention. Public health issues related to the emission of formaldehyde-based adhesives in most buildings and constructions, have also been given notice. Thus, lignin phenol glyoxal (LPG) wood adhesives have been formulated by partially replacing phenol with Kraft and organosolv lignins at varying weight percentages. Results showed that 50 % organosolv LPG (OLPG) resin may cure as a stronger, natural, green, cost-effective and sustainable wood adhesive to replace PF resin in the wood industry.

Download or read book Adhesives for Wood and Lignocellulosic Materials written by R. N. Kumar and published by John Wiley & Sons. This book was released on 2019-07-16 with total page 450 pages. Available in PDF, EPUB and Kindle. Book excerpt: A unique and ground-breaking book from two leading specialists on adhesion and adhesives for wood and lignocellulosic materials The book is a comprehensive treatment covering a wide range of subjects uniquely available in a single source for the first time. A material science approach has been adopted in dealing with wood adhesion and adhesives. The approach of the authors is to bring out hierarchical cellular and porous characteristics of wood with polymeric cell wall structure, along with the associated non-cell wall extractives, which greatly influence the interaction of wood substrate with polymeric adhesives in a very unique manner not existent in the case of other adherends. Environmental aspects, in particular formaldehyde emission from adhesive bonded wood products, has been included. A significant feature of the book is the inclusion of polymeric matrix materials for wood polymer composites.

Download or read book Characterization of PF PVAC Hybrid Adhesive wood Interaction and Its Effect on Wood Strand Composites Performance written by Yang Cao and published by . This book was released on 2010 with total page 108 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Bio based Wood Adhesives written by Zhongqi He and published by CRC Press. This book was released on 2017-05-25 with total page 366 pages. Available in PDF, EPUB and Kindle. Book excerpt: Adhesive bonding plays an increasing role in the forest product industry and is a key factor for efficiently utilizing timber and other lignocellulosic resources. As synthetic wood adhesives are mostly derived from depleting petrochemical resources and have caused increasing environmental concern, natural product and byproduct-derived adhesives have attracted much attention in the last decades. Although adhesives made from plant and animal sources have been in existence since ancient times, increased knowledge of their chemistry and improved technical formulation of their preparation are still needed to promote their broader industrial applications. The primary goals of this book are to (1) synthesize the fundamental knowledge and latest research on bio-based adhesives from a remarkable range of natural products and byproducts, (2) identify need areas and provide directions of future bio-based adhesive research, and (3) help integrating research findings in practical adhesive application for maximal benefits. This book covers information on a variety of natural products and byproducts and the latest research on formulation, testing and improvement of the relevant adhesives in fifteen chapters written by an international group of accomplished contributors. This book will serve as a valuable reference source for university faculty, graduate students, research scientists, agricultural and wood engineers, international organization advocators and government agency regulators who work and deal with enhanced utilization of agricultural and forest products and byproducts.

Download or read book Wood Industry Abstracts written by and published by . This book was released on 1975 with total page 788 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Wood Adhesives written by A. Pizzi and published by Routledge. This book was released on 2018-10-08 with total page 432 pages. Available in PDF, EPUB and Kindle. Book excerpt: The perfect companion to the highly acclaimed Volume 1 of Wood Adhesives,Volume 2 presents stimulating discussions on technically and economically importantadhesives for wood bonding-covering their preparation and formulation, as well astechniques and suggestions for their application.Like its companion book, Wood Adhesives, Volume 2 provides up-to-date informationand analysis of new technologies and recent breakthroughs ... gives insightinto the relationship between adhesive chemistry and technical application . . . anddiscusses present and future trends likely to have considerable impact on the field.Elaborating upon general overviews presented in Volume 1, Wood Adhesives,Volume 2 includes a chapter on protein adhesives ... fills the gap on the chemistryof polyvinyl acetate wood adhesives ... contains a detailed discussion of formaldehydeemission ... and much more.A complementary and much needed follow-up to Volume 1, Wood Adhesives,Volume 2 is essential reading for wood technologists; adhesives and physicalchemists; forest products researchers; polymer scientists; chemical, mechanical, process,and civil engineers who must choose and apply wood adhesives; and advancedundergraduate and graduate students in the above disciplines.

Download or read book Bondability of modified wood written by Alireza Bastani and published by Cuvillier Verlag. This book was released on 2016-06-30 with total page 152 pages. Available in PDF, EPUB and Kindle. Book excerpt: This study investigates the bonding properties of modified wood by considering three different aspects: water related characteristics, mechanical performance and optical (fluorescence microscopy and X-ray micro-computed tomography) observation of adhesive penetration into modified wood structure. In recent years, the new wood modifications have become more commercially available in the market for both exterior and interior applications due to improved properties that modification can bring to the wood e.g. the improved biological durability, dimensional stability, hardness and weathering resistance of the wood as well as the environmentally friendly nature of the wood modification processes (Militz and Hill 2005). Besides these advantages, modification can affect some technological aspects of the wood such as its bonding performance. For example, it can alter the strength of adhesion as a result of changes in chemical, physical and structural characteristics of the wood. For example, the less polar and less porous modified wood surfaces can result in reduced adhesion due to formation of less free OH groups for bonding leading to poorer adhesive wetting of the wood surface and weaker chemical bonds between the two adherents (Hunt et al. 2007). As modified wood becomes a more demanded material for different applications, there is a need to study its bonding performance where the challenge is to bond different modified materials as their physical and chemical characteristics are substantially changed by modification. In this thesis, measurements of capillary water uptake, contact angle and surface energy were used to determine the water related properties and hydrophobic behavior of furfurylated (FA40 and FA70, which represent 65 and 75 % WPGs) and N-methylol melamine (NMM) (10, 20 and 30%) modified Scots pine and thermally treated Scots pine and beech (modified through an industrial scale vacuum press dewatering method at 195 and 210 °C). The capillary water uptake results indicated a considerable reduction of water uptake for all modifications in all directions both after short (24 h) and long contact times (168, 336 h). Contact angle measurement data revealed an increased hydrophobicity of modified wood. However, some exceptions were observed, mainly for thermally treated wood. Modifications provided radial and tangential surfaces with a non-polar character. Penetration of adhesives into the wood structure plays an important role in the production of glued wood-based panels and products by affecting the bond quality (Frihart 2005, Kamke and Lee 2007). The gross penetration of emulsion polymer isocyanate (EPI), polyurethane (PU) and polyvinyl acetate (PVAc) adhesives into modified wood, both with and without pressure, were determined by using fluorescence microscopy based on measurements of effective (EP) and maximum penetration (MP). Without application of pressure, the EP of EPI adhesive reduced after NMM modification and furfurylation (FA70) and also PU adhesive after NMM modification while the EP of PVAc adhesive increased into furfurylated and NMM modified (10 and 20%) wood. For thermally treated Scots pine, increasing the treatment temperature improved EP of all adhesives. Among used adhesives, PU penetrated much deeper into thermally treated wood for both treatment temperatures. Comparison of penetration of adhesive with and without pressure revealed that with the exception of EP of PU and EPI adhesives into NMM-modified wood and PVAc into thermally treated beech at 195°C, application of pressure led to rather different results as compared to the EP data when no pressure was applied. Visual observation and analysis of fluorescence microscopy photomicrographs provided more detailed information on modality of penetration. Due to the large and deep penetration of PU adhesive into thermally treated Scots pine observed in both studies (with and without pressure), the 3D pattern of penetration of this adhesive was obtained by X-ray micro- computed tomography indicating the pathways which were used by this adhesive for penetration. In another study, the bonding shear strength of the same modified wood materials glued with the same adhesives was also investigated. For all adhesives used, the shear strength significantly reduced after furfurylation and NMM modification of Scots pine samples, mainly due to the brittle nature of the wood after modification rather to the failure of the bondline. Bonding strength of both Scots pine and beech was also negatively affected by thermal modification and the bondline was found to be the weakest link in thermally modified wood. The EP of adhesives and the bondline thickness did not relate to the shear strength of all modified wood materials. It was indicated that the lower shear strength of modified wood could be attributed to other factors, such as the decreased chemical bonding or mechanical interlocking of adhesives, and the reduced strength of brittle modified wood substrate. The effect of two important bonding variables, wood moisture content and open assembly time on penetration of PU adhesive into thermally modified wood (195 and 210 °C) was also studied. The equilibrium moisture content (EMC) level of 8.6% was found to be the optimum for an effective penetration of PU adhesive in thermally modified Scots pine treated at 195°C. In most of the cases, penetration of PU adhesive did not change significantly by increasing the open assembly time, which suggested using a shorter open assembly time of 15 min than 30 min for bonding of thermally modified Scots pine with PU adhesive, in order to save time and reducing the production costs. For samples treated at both treatment temperatures and after shorter open assembly time, the highest MP values observed at moderate EMC levels of 8.6 and 8.2% and the lowest at the higher EMC levels of 13.2 and 12.5%. In another study, the effect of phenol formaldehyde (PF) treatment on bonding performance of beech glued with PVAc and phenol resorcinol formaldehyde (PRF) adhesives was also investigated. The results of both dry and wet conditions indicated higher shear strength for samples bonded with PRF than PVAc. With the exception of 25% PF treated wood bonded with PVAc, the PF modified wood can be glued with both adhesives satisfactorily under dry condition, while under wet condition only the 25% PF modified samples bonded with PRF provided acceptable bonding. For both adhesive systems, PF modification caused a reduction of adhesive penetration into wood structure, especially in the case of higher load treatment. The development of bonding strength of modified birch veneers glued with hot curing phenol formaldehyde (PF) adhesive was investigated in different pressing (20 s , 160s) and open assembly times (20s , 10 min). Generally, the bonding strength improved by extending the pressing time. In 20 s pressing, increasing assembly time did not change the bonding strength in most of the cases while at 160 s pressing, prolongation of assembly time developed a better bonding for controls, NMM modified and thermally treated veneers at 180°C. The combination of 10 min assembly time and 160 s pressing time provided the highest bonding strength for controls, NMM modified and thermally treated veneers at 180°C while furfurylated samples achieved the highest values in 20 s assembly and 160 s pressing times. In general, modification affected negatively the bonding performance of the veneers, especially for furfurylated and NMM modified samples. In General, the overall results obtained in this thesis showed that modified wood has lower bonding ability and performance than unmodified wood as result of the decreased water related properties, less penetration of adhesive into wood structure and decreased bonding strength after modification. However, the increased dimensional stability and low water uptake of modified wood might lead to better performance in long term.

Download or read book Handbook of Adhesive Technology Revised and Expanded written by Antonio Pizzi and published by CRC Press. This book was released on 2003-08-06 with total page 1060 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Handbook of Adhesive Technology, Second Edition exceeds the ambition of its bestselling forerunner by reexamining the mechanisms driving adhesion, categories of adhesives, techniques for bond formation and evaluation, and major industrial applications. Integrating modern technological innovations into adhesive preparation and application, this greatly expanded and updated edition comprises a total of 26 different adhesive groupings, including three new classes. The second edition features ten new chapters, a 40-page list of resources on adhesives, and abundant figures, tables, equations.

Download or read book Investigation of the Wood phenol formaldehyde Adhesive Interphase Morphology written by and published by . This book was released on 2002 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: This work addresses the morphology of the wood/ Phenol-Formaldehyde (PF) adhesive interphase using yellow-poplar. In this case, morphology refers to the scale or dimension of adhesive penetration into wood. The objective is to develop methods for revealing ever smaller levels of wood/resin morphology. Dynamic techniques that are commonly utilized in polymer blend studies are investigated as potential methods for probing the wood/ adhesive interphase morphology. These are Dynamic Mechanical Analysis (DMA) and solid state NMR using CP/MAS. PF resin molecular weight is manipulated to promote or inhibit resin penetration in wood, using a very low or a very high molecular weight PF resin. With DMA, the influence of PF resin on wood softening is investigated. It is first demonstrated that the cooperativity analysis according to the Ngai coupling model of relaxation successfully applies to the in-situ lignin glass transition of yellow-poplar and spruce woods. No significant difference in intermolecular coupling is detected between the two woods. It is then demonstrated that combining simple DMA measurements with the cooperativity analysis yields ample sensitivity to the interphase morphology. From simple DMA temperature scans, a low molecular weight PF (PF-Low) does not influence lignin glass transition temperature. However, the Ngai coupling model of relaxation indicates that intermolecular coupling is enhanced with the low molecular weight PF. This behavior is ascribed to the low molecular weight PF penetrating lignin on a nanometer scale and polymerizing in-situ. On the other hand, a high molecular weight resin with a broad distribution of olecular weights (PF-High) lowers lignin glass transition temperature dramatically. This plasticizing effect is ascribed to a small fraction of the PF resin being low enough in molecular weight to penetrate lignin on a nanoscale, but being too dispersed for forming a crosslinked network.

Download or read book Progress in Adhesion and Adhesives Volume 4 written by K. L. Mittal and published by John Wiley & Sons. This book was released on 2019-07-01 with total page 463 pages. Available in PDF, EPUB and Kindle. Book excerpt: A solid collection of interdisciplinary review articles on the latest developments in adhesion science and adhesives technology With the ever-increasing amount of research being published, it is a Herculean task to be fully conversant with the latest research developments in any field, and the arena of adhesion and adhesives is no exception. Thus, topical review articles provide an alternate and very efficient way to stay abreast of the state-of-the-art in many subjects representing the field of adhesion science and adhesives. Based on the success of the preceding volumes in this series "Progress in Adhesion and Adhesives"), the present volume comprises 9 review articles published in Volume 6 (2018) of Reviews of Adhesion and Adhesives. The subject of these reviews fall into the following general areas: 1. Adhesion to wood and wood bonds 2. Adhesive joints 3. Adhesion in microelectronic packaging 4. Surface modification 5. Contact angle, wettability and surface free energy. The topics covered include: Adhesion phenomena in microelectronic packaging; adhesives for wood and lignocellulosic materials; adhesion to wood and lignocellulosic materials; adhesively bonded lap joints having bi-adhesive and modulus-graded bondlines; adhesion between compounded elastomers; applications of contact angle measurements in pharmaceuticals and foods; oxygen or ammonia plasma treatment of polyolefin surfaces; surface free energy determination of powders and particles; wood bonds; and dispersion adhesion forces between macroscopic objects.

Download or read book Handbook of Wood Chemistry and Wood Composites written by Roger M. Rowell and published by CRC Press. This book was released on 2005-02-18 with total page 505 pages. Available in PDF, EPUB and Kindle. Book excerpt: The degradable nature of high-performance, wood-based materials is an attractive advantage when considering environmental factors such as sustainability, recycling, and energy/resource conservation. The Handbook of Wood Chemistry and Wood Composites provides an excellent guide to the latest concepts and technologies in wood chemistry and bio-based composites. The book analyzes the chemical composition and physical properties of wood cellulose and its response to natural processes of degradation. It describes safe and effective chemical modifications to strengthen wood against biological, chemical, and mechanical degradation without using toxic, leachable, or corrosive chemicals. Expert researchers provide insightful analyses of the types of chemical modifications applied to polymer cell walls in wood, emphasizing the mechanisms of reaction involved and resulting changes in performance properties. These include modifications that increase water repellency, fire retardancy, and resistance to ultraviolet light, heat, moisture, mold, and other biological organisms. The text also explores modifications that increase mechanical strength, such as lumen fill, monomer polymer penetration, and plasticization. The Handbook of Wood Chemistry and Wood Composites concludes with the latest applications, such as adhesives, geotextiles, and sorbents, and future trends in the use of wood-based composites in terms of sustainable agriculture, biodegradability and recycling, and economics. Incorporating over 30 years of teaching experience, the esteemed editor of this handbook is well-attuned to educational demands as well as industry standards and research trends.

Download or read book Characterization of the Cellulosic Cell Wall written by Douglas D. Stokke and published by John Wiley & Sons. This book was released on 2008-02-28 with total page 296 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume brings together a broad array of scientific expertise to focus on the characterization and utilization of cellulosic materials. Researchers from Austria, Germany, Sweden, Japan, New Zealand, Australia, and the U.S. explore many facets of the plant cell wall, from its fundamental structure and its manipulation via molecular biology to its application in composite materials. Exciting applications of near infrared spectroscopy, x-ray diffraction, confocal microscopy, and molecular coupling as a viscoelastic probe provide new insights into the ultrastructure and properties of cellulosic materials.

Download or read book Phenolic Resins A Century of Progress written by Louis Pilato and published by Springer Science & Business Media. This book was released on 2010-03-10 with total page 543 pages. Available in PDF, EPUB and Kindle. Book excerpt: The legacy of Leo Hendrik Baekeland and his development of phenol formal- hyde resins are recognized as the cornerstone of the Plastics Industry in the early twentieth century, and phenolic resins continue to ?ourish after a century of robust growth. On July 13, 1907, Baekeland ?led his “heat and pressure” patent related to the processing of phenol formaldehyde resins and identi?ed their unique utility in a plethora of applications. The year 2010 marks the Centennial Year of the prod- tion of phenolic resins by Leo Baekeland. In 1910, Baekeland formed Bakelite GmbH and launched the manufacture of phenolic resins in Erkner in May 1910. In October 1910, General Bakelite began producing resins in Perth Amboy, New Jersey. Lastly, Baekeland collaborated with Dr. Takamine to manufacture phenolic resins in Japan in 1911. These events were instrumental in establishing the Plastics Industry and in tracing the identity to the brilliance of Dr. Leo Baekeland. Phenolic resins remain as a versatile resin system featuring either a stable, thermoplastic novolak composition that cures with a latent source of formaldehyde (hexa) or a heat reactive and perishable resole composition that cures thermally or under acidic or special basic conditions. Phenolic resins are a very large volume resin system with a worldwide volume in excess of 5 million tons/year, and its growth is related to the gross national product (GNP) growth rate globally.

Download or read book Adhesives Technology Handbook written by Sina Ebnesajjad and published by William Andrew. This book was released on 2014-11-26 with total page 437 pages. Available in PDF, EPUB and Kindle. Book excerpt: Covering a wide range of industrial applications across sectors including medical applications, automotive/aerospace, packaging, electronics, and consumer goods, this book provides a complete guide to the selection of adhesives, methods of use, industrial applications, and the fundamentals of adhesion. Dr Ebnesajjad examines the selection of adhesives and adhesion methods and challenges for all major groups of substrate including plastics (thermosets and thermoplastics), elastomers, metals, ceramics and composite materials. His practical guidance covers joint design and durability, application methods, test methods and troubleshooting techniques. The science and technology of adhesion, and the principles of adhesive bonding are explained in a way that enhances the reader's understanding of the fundamentals that underpin the successful use and design of adhesives. The third edition has been updated throughout to include recent developments in the industry, with new sections covering technological advances such as nanotechnology, micro adhesion systems, and the replacement of toxic chromate technology. Provides practitioners of adhesion technology with a complete guide to bonding materials successfully Covers the whole range of commonly used substrates including plastics, metals, elastomers and ceramics, explaining basic principles and describing common materials and application techniques Introduces the range of commercially available adhesives and the selection process alongside the science and technology of adhesion

Download or read book Development of Biobased Phenolic Adhesives for Engineered Wood Products written by Somayyeh Kalami and published by . This book was released on 2018 with total page 84 pages. Available in PDF, EPUB and Kindle. Book excerpt: Phenolic adhesives are widely used in the production of engineered wood products due to their exceptional moisture and thermal resistance, chemical stability, and bonding strength. The phenolic adhesive is currently produced through condensation polymerization of two fossil fuel-derived compounds: phenol and formaldehyde. However, due to fluctuations in the price of phenol and formaldehyde with the price of oil, environmental and health issues associated with using these compounds, there is a strong interest in finding alternative renewables feedstocks. Lignin is a natural polyphenolic compound with excellent potential to substitute phenol in phenolic adhesive formulations. Lignin is produced as byproducts during pulp and bioethanol processes. On the other hand, biobased aldehydes such as glyoxal have recently gained a lot of attention for replacing the toxic formaldehyde in production of environmentally friendly wood products. In this study, a wide range of lignin samples from different resources (hardwood, softwood, wheat straw, and corn stover), and isolated via various processes (kraft, organosolv, soda, sulfite, and enzymatic hydrolysis), were used to formulate 100% lignin-based phenolic adhesives. In a separate work, formaldehyde-free phenolic adhesives were also developed using either glyoxal or gossypol (a dialdehyde from cotton seed) in combination with phenol. Chemical, physical, and thermal properties of lignin samples and developed phenolic resins and adhesive were measured using advanced analytical techniques and appropriate ASTM standard test methods.Based on two-way ANOVA analysis results of shear strength data, a biorefinery corn stover lignin that had the highest p-hydroxyphenyl and p-coumaric acid content was the most suitable lignin for replacing 100% of phenol in phenolic adhesive formulation. In addition, the developed lignin-based adhesive (formulated with biorefinery corn stover lignin) showed similar dry and wet adhesion strengths as that of commercially formulated phenol resorcinol formaldehyde (PRF) adhesive. On weight basis, the formaldehyde consumption in the developed lignin-based adhesive was 50% lower than the formaldehyde used in phenol formaldehyde (PF) resin. Moreover, two formaldehyde-free formulated adhesives using glyoxal and gossypol (renewable feedstocks) had very similar physico-chemical properties to phenol formaldehyde adhesive.

Download or read book Dissertation Abstracts International written by and published by . This book was released on 2003 with total page 674 pages. Available in PDF, EPUB and Kindle. Book excerpt: