Download or read book The Catalytic Activity of Metal Oxides on Thermal Decomposition Reactions written by Eli S. Freeman and published by . This book was released on 1967 with total page 142 pages. Available in PDF, EPUB and Kindle. Book excerpt: The effects of a selected series of solid metal oxides on the catalysis of the thermal decomposition of potassium chlorate and potassium perchlorate were investigated. The kinetics and rate parameters of the catalyzed decomposition reactions were studied and compared to the rate parameters observed in the absence of the solid oxides. Two oxides were selected for more precisely correlating the relationships between the electronic defect structure of the oxides and their catalytic behavior. The oxides investigated from this point of view were: ferric oxide and magnesium oxide. These oxides were doped with selected altervalent cation impurities, and heat treated at temperatures ranging from 700 to 1000 degrees C in oxygen and inert gas environment in order to introduce electronic defects. In addition, changes in catalytic activity in relationship to electronic changes as a result of exposure to Cobalt (60) gamma rays were investigated. The changes in semiconducting properties were studied and the results correlated with the changes in catalytic activity. A mechanism of decomposition of potassium chlorate is discussed as well as a proposed mechanism for the interaction of sulfur and potassium chlorate. (Author).
Download or read book Metal Oxide Catalysis 2 Volume Set written by S. David Jackson and published by John Wiley & Sons. This book was released on 2008-11-24 with total page 916 pages. Available in PDF, EPUB and Kindle. Book excerpt: With its two-volume structure, this handbook and ready reference allows for comprehensive coverage of both characterization and applications, while uniform editing throughout ensures that the structure remains consistent. The result is an up-to-date review of metal oxides in catalysis. The first volume covers a range of techniques that are used to characterize oxides, with each chapter written by an expert in the field. Volume 2 goes on to cover the use of metal oxides in catalytic reactions. For all chemists and engineers working in the field of heterogeneous catalysis.
Download or read book Photopromoted and Thermal Decomposition of Nitric Oxide by Metal Oxides written by and published by . This book was released on 1992 with total page 40 pages. Available in PDF, EPUB and Kindle. Book excerpt: This technical report summarizes research on decomposition of NOx by photopromoted and thermal solid-catalyzed decomposition of NO. Typical catalysts incorporated one or more metal oxides. Photopromotion of catalytic activity was observed with several catalysts. Nearly complete thermal decomposition of NO was achieved by several catalysts in the absence of O2. However, no combination of catalyst and conditions achieved satisfactory rates of decomposition of NO in the presence of target concentrations (>10 percent) of O2.
Download or read book Metal Oxides in Heterogeneous Catalysis written by Jacques C. Vedrine and published by Elsevier. This book was released on 2018-01-11 with total page 620 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal Oxides in Heterogeneous Catalysis is an overview of the past, present and future of heterogeneous catalysis using metal oxides catalysts. The book presents the historical, theoretical, and practical aspects of metal oxide-based heterogeneous catalysis. Metal Oxides in Heterogeneous Catalysis deals with fundamental information on heterogeneous catalysis, including reaction mechanisms and kinetics approaches.There is also a focus on the classification of metal oxides used as catalysts, preparation methods and touches on zeolites, mesoporous materials and Metal-organic frameworks (MOFs) in catalysis. It will touch on acid or base-type reactions, selective (partial) and total oxidation reactions, and enzymatic type reactions The book also touches heavily on the biomass applications of metal oxide catalysts and environmentally related/depollution reactions such as COVs elimination, DeNOx, and DeSOx. Finally, the book also deals with future trends and prospects in metal oxide-based heterogeneous catalysis. Presents case studies in each chapter that provide a focus on the industrial applications Includes fundamentals, key theories and practical applications of metal oxide-based heterogeneous catalysis in one comprehensive resource Edited, and contributed, by leading experts who provide perspectives on synthesis, characterization and applications
Download or read book Metal Oxides written by J.L.G. Fierro and published by CRC Press. This book was released on 2005-08-24 with total page 808 pages. Available in PDF, EPUB and Kindle. Book excerpt: The chemistry of metals has traditionally been more understood than that of its oxides. As catalytic applications continue to grow in a variety of disciplines, Metal Oxides: Chemistry and Applications offers a timely account of transition-metal oxides (TMO), one of the most important classes of metal oxides, in the context of catalysis. The
Download or read book Technical Abstract Bulletin written by Defense Documentation Center (U.S.) and published by . This book was released on 1967 with total page 784 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Heterogeneous Catalytic Redox Reactions written by Vladislav Sadykov and published by Walter de Gruyter GmbH & Co KG. This book was released on 2019-10-21 with total page 255 pages. Available in PDF, EPUB and Kindle. Book excerpt: The current book brings together cutting-edge research in the area of heterogeneous catalytic redox processes. The first part of the book covers the catalytic properties of transition metal oxides and the techniques for catalysts preparation, such as mechanochemistry, plasmochemistry, hydrothermal treatment, etc. Further the authors focus on mechanisms of heterogeneous redox reactions followed by the overview of industrial applications.
Download or read book On the Catalytic Activity of Certain Metals and Metallic Oxides written by Harvey Day Royce and published by . This book was released on 1924 with total page 100 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book The Influence of Surface Structure on the Catalytic Activity of Alumina Supported Transition Metal Oxides written by Paul Worn Park and published by . This book was released on 1996 with total page 430 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Heterogeneous Catalysis of Mixed Oxides written by M. Misono and published by Newnes. This book was released on 2013-02-28 with total page 193 pages. Available in PDF, EPUB and Kindle. Book excerpt: Mixed oxides are the most widely used catalyst materials for industrial catalytic processes. The principal objective of this book is to describe systematically the mixed oxide catalysts, from their fundamentals through their practical applications. After describing concisely general items concerning mixed oxide and mixed oxide catalysts, two important mixed oxide catalyst materials, namely, heteropolyacids and perovskites, are taken as typical examples and discussed in detail. These two materials have several advantages: 1. They are, respectively, typical examples of salts of oxoacids and double oxide, that is, the two main categories of mixed oxides in solid state chemistry. 2. Both exhibit excellent catalytic performance in nearly crystalline state and are used in several industrial applications. 3. They have studied for many years. In addition, metal oxides functioning as a catalyst support (carrier) are included. Although the supports are very important in practical applications, and tremendous progress has been made in the past decades, few systematic reviews exist. It is notable that heteropolyacids and perovskite exhibit unique performance when used as a support. Fundamental catalytic science and technology and solid state chemistry necessary is presented for the proper understanding of mixed oxide catalysts as well as for R&D. For the latter, the concept of design of practical catalysts is very important. This is considered throughout the book. Systematically describes design principles of mixed oxide catalysts Shows how catalysis and solid-state chemistry of metal oxides are inter-related Covers all useful basic concepts of mixed oxide catalysis
Download or read book THE CATALYSIS OF THERMAL DECOMPOSITION AND BURNING REACTIONS OF FUEL OXIDANT COMPOSITIONS written by and published by . This book was released on 1968 with total page 73 pages. Available in PDF, EPUB and Kindle. Book excerpt: The effects of defect structure and doping of potassium chlorate on its chemical reactivity with respect to its propagative reactions with sulfur was investigated. The preparation of doped single crystals of potassium chlorate was continued during the entire program. The crops of single crystals were analyzed for their dopant contents. The influence of doping on the thermal decomposition of potassium chlorate was investigated by DTA and TGA. The effect of potassium chloride and perchlorate as an intermediate reaction product on the thermal decomposition of potassium chlorate was studied. These experiments are necessary for establishing the basis for evaluating the reactivity of potassium chlorate with sulfur. Electrical conductivity studies were initiated to correlate electronic defect structure with the reactivity behavior of potassium chlorate. Low temperature isothermal investigations were conducted to evaluate possible reaction mechanisms. The effect of irradiation and mechanical shock on the decomposition of potassium chlorate was probed. The combustion reaction of mixtures of sulfur with doped potassium chlorate and of mixtures with selected metal oxides was investigated.
Download or read book Metal Oxides and Related Solids for Electrocatalytic Water Splitting written by Junlei Qi and published by Elsevier. This book was released on 2022-05-16 with total page 404 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal Oxides and Related Solids for Electrocatalytic Water Splitting reviews the fundamentals and strategies needed to design and fabricate metal oxide-based electrocatalysts. After an introduction to the key properties of transition metal oxides, materials engineering methods to optimize the performance of metal-oxide based electrocatalysts are discussed. Strategies reviewed include defect engineering, interface engineering and doping engineering. Other sections cover important categories of metal-oxide (and related solids) based catalysts, including layered hydroxides, metal chalcogenides, metal phosphides, metal nitrides, metal borides, and more. Each chapter introduces important properties and material design strategies, including composite and morphology design. There is also an emphasis on cost-effective materials design and fabrication for optimized performance for electrocatalytic water splitting applications. Lastly, the book touches on recently developed in-situ characterization methods applied to observe and control the material synthesis process. Introduces metal oxide-based materials for electrocatalytic water splitting applications, including their key properties, synthesis, design and fabrication strategies Reviews the most relevant materials design strategies, including defect engineering, interface engineering, and doping engineering Discusses the pros and cons of metal oxide-based materials for water splitting applications to aid in materials selection
Download or read book Metal Nanoparticles for Catalysis written by Franklin Tao and published by Royal Society of Chemistry. This book was released on 2014-06-12 with total page 285 pages. Available in PDF, EPUB and Kindle. Book excerpt: Catalysis is a central topic in chemical transformation and energy conversion. Thanks to the spectacular achievements of colloidal chemistry and the synthesis of nanomaterials over the last two decades, there have also been significant advances in nanoparticle catalysis. Catalysis on different metal nanostructures with well-defined structures and composition has been extensively studied. Metal nanocrystals synthesized with colloidal chemistry exhibit different catalytic performances in contrast to metal nanoparticles prepared with impregnation or deposition precipitation. Additionally, theoretical approaches in predicting catalysis performance and understanding catalytic mechanism on these metal nanocatalysts have made significant progress. Metal Nanoparticles for Catalysis is a comprehensive text on catalysis on Nanoparticles, looking at both their synthesis and applications. Chapter topics include nanoreactor catalysis; Pd nanoparticles in C-C coupling reactions; metal salt-based gold nanocatalysts; theoretical insights into metal nanocatalysts; and nanoparticle mediated clock reaction. This book bridges the gap between nanomaterials synthesis and characterization, and catalysis. As such, this text will be a valuable resource for postgraduate students and researchers in these exciting fields.
Download or read book Solid Propellant Chemistry Combustion and Motor Interior Ballistics 1999 written by Vigor Yang and published by AIAA. This book was released on 2000 with total page 1038 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book The Catalytic Activity of Transition Metal Oxides in Hydrogenation and Related Reactions written by D. Nicholls and published by . This book was released on 1965 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Alkoxo and Aryloxo Derivatives of Metals written by Don Bradley and published by Elsevier. This book was released on 2001-02-22 with total page 717 pages. Available in PDF, EPUB and Kindle. Book excerpt: Alkoxo and Aryloxo Derivatives of Metals gives a comprehensive account of the chemistry of metal alkoxides and metal aryloxides, including their industrial applications such as microelectronics, ceramics, nonlinear optical materials, high-temperature superconductors, specialized glasses, and other advanced novel materials. It is an invaluable reference source book. The book is an updated edition of Metal Alkoxides, published by Academic Press in 1978, with additional coverage of metal aryloxides. It reflects the enormous growth in interest in this field in recent years. Alkoxo and aryloxo derivatives are organic compounds with metals for useful industrial purposes. Alkoxo and Aryloxo Derivatives of Metals will appeal to a wide-ranging audience, including university researchers and chemistry graduate students in industrial laboratories concerned with microelectronics, ceramics, glasses and other advanced novel materials; any laboratories doing research on nonlinear optical materials, high-temperature superconductors, ceramic materials, and specialized glasses. It can also serve as a supplementary text for final year courses in advanced inorganic chemistry, e.g., metallo-organic chemistry.
Download or read book Volatile Organic Compound Removal written by Hongqing Ren and published by Elsevier. This book was released on 2024-08-30 with total page 366 pages. Available in PDF, EPUB and Kindle. Book excerpt: Volatile Organic Compound Removal: Technologies and Functional Materials for VOC Removal details technologies and materials for the removal of volatile organic compounds (VOCs) from polluted air, covering not only the fundamental mechanisms, processes, and designs of the latest VOC abatement technologies, but also the characteristics and applications of advanced functional materials for VOC removal. The first half of this book centers on VOC abatement technologies including catalytic degradation, thermal oxidation, membrane separation, adsorption, absorption, and condensation, whereas the second half focuses on the applications of functional materials, especially novel nanomaterials, in VOC removal. Volatile Organic Compound Removal: Technologies and Functional Materials for VOC Removal is unique in covering both the fundamental mechanisms and practical applications of VOC abatement technologies, as well as focusing on the preparation, characterization, and application of novel functional materials for VOC removal. Details both the technologies and the functional materials possible for use in destructive and non-destructive removal of VOCs Covers both sustainability-related issues and nanotechnology applications for VOC removal Includes detailed case studies in appropriate chapters
