Download or read book Th Thorium written by David Brown and published by Springer Science & Business Media. This book was released on 2013-06-29 with total page 170 pages. Available in PDF, EPUB and Kindle. Book excerpt: The present volume, Thorium C5, deals with the compounds of thorium and sulfur, selenium, tellurium, and boron, as well as with oxoacid compounds of the three chalcogen elements. Thorium borates have already been treated in Thorium C2. In contrast to the corresponding compounds of uranium the thorium sulfides, etc. , do not show any nuclear or other technological application; they are only of academic interest, despite some very interest ing electronic properties, especially of the 1 : 1 compounds. The thorium-sulfur and the thorium boron systems in particular were studied in detail, so that we have a clear picture of them, whereas there are still a lot of open questions in the systems Th-Se and Th-Te - not very different from other metal chalcogenide systems. Thorium sulfates are of some technological importance because they are formed in solution during recovery of thorium from monazite by sulfuric acid leaching. The very detailed and critical treatment of the chemical and physical properties of the compounds discussed also enables us to find gaps still remaining in our knowledge and thus to initiate new research in this field. I want to thank the two authors, Dr. Horst Wedemeyer (Karlsruhe) and Dr. David Brown (Harwell), for their excellent contributions, the "Literaturabteilung" of the Karlsruhe Nuclear Research Center for its help in providing reports and other documents difficult to procure, as well as the staff of the Gmelin-Institute, especially to Dr. K. -C.
Download or read book Th Thorium written by Kenneth W. Bagnall and published by Springer Science & Business Media. This book was released on 2013-12-12 with total page 177 pages. Available in PDF, EPUB and Kindle. Book excerpt: The present volume of the Gmelin thorium series describes the solid thorium-carbon compounds with the exception of the carbides and coordination compounds of the type 4 ThAn· X B, where B is a neutral ligand. The complex equilibria of the Th + ion with C-containing complexing agents are treated in the ThD1 volume. A first look into this volume demonstrates that a very large number of ThlV complexes has 4 been prepared. This may be explained by the fact that the Th + ion is the largest tetravalent ion of the periodic table. Therefore, the preparation of complexes with, e. g. , multidentate ligands can give a well-established picture of the coordination number as a function of charge and ionic radius. However, there are very few modern and updated comprehensive treatments of such data. Many compounds described in this volume are characterized by no other means than analytical composition and IR spectra (whereby IR spectra of organic ThlV salts mostly give information only on the ligand). Besides thorium carbonate and carbonato complexes, which are relevant for the environmental behaviour of this radioactive element and some organic complexes like oxalates, which are used in the field of analytical and separation chemistry nearly all other compounds described here are practically only of scientific interest. On the other hand in order to have scientifically reliable data, a very large part of these compounds needs further investigation and characterization.
Download or read book Th Thorium written by R. Benz and published by Springer Science & Business Media. This book was released on 2013-11-11 with total page 141 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume C 3, as a part of the Gmelin "Thorium" Handbook, Series C, describes the thorium-nitrogen compounds. Included are compounds both of technological importance like the nitrides and the nitrates and those of merely scientific interest, such as amides and related compounds. However, due to the decreasing technical importance of the nuclear thorium fuel cycle, especially with the advanced fuels like the nitride ThN, in recent years, the thorium compounds with nitrogen have been investigated much less extensively than the correspond ing uranium compounds. In order to have the data for the Th-N-X systems accumulated in one specific volume, the decision was made to publish this volume without incorporating other Th systems. ThN is the compound with the lowest N :Th ratio. In addition to its (former) nuclear interest due to its thermal and radiation stability, it has many very interesting physicochemical properties. Thorium nitrate, the other well-investigated compound, is of importance because it is (in the form of an adduct with tri-n-butylphosphate) the extracted compound when burnt-up thorium fuels are reprocessed. Despite the wealth of accumulated data on the chemical and physicochemical properties of the compounds discussed, the knowledge of the compounds and of the systems is far from satisfactory - it must be deepened and improved in further studies. I would like to thank the competent authors for their critical contributions as well as the Gmelin-Institute for the excellent cooperation provided, especially Prof. Dr. Fluck and Dr. Keim, the editor-in-chief of this volume.
Download or read book SuperFuel written by Richard Martin and published by St. Martin's Press. This book was released on 2012-05-08 with total page 273 pages. Available in PDF, EPUB and Kindle. Book excerpt: A riveting look at how an alternative source of energy is revoluntionising nuclear power, promising a safe and clean future for millions, and why thorium was sidelined at the height of the Cold War In this groundbreaking account of an energy revolution in the making, award-winning science writer Richard Martin introduces us to thorium, a radioactive element and alternative nuclear fuel that is far safer, cleaner, and more abundant than uranium. At the dawn of the Atomic Age, thorium and uranium seemed to be in close competition as the fuel of the future. Uranium, with its ability to undergo fission and produce explosive material for atomic weapons, won out over its more pacific sister element, relegating thorium to the dustbin of science. Now, as we grapple with the perils of nuclear energy and rogue atomic weapons, and mankind confronts the specter of global climate change, thorium is re-emerging as the overlooked energy source as a small group of activists and outsiders is working, with the help of Silicon Valley investors, to build a thorium-power industry. In the first book mainstream book to tackle these issues, Superfuel is a story of rediscovery of a long lost technology that has the power to transform the world's future, and the story of the pacifists, who were sidelined in favour of atomic weapon hawks, but who can wean us off our fossil-fuel addiction and avert the risk of nuclear meltdown for ever.
Download or read book Th Thorium Supplement Volume C 8 written by Michael Bickel and published by Springer Science & Business Media. This book was released on 2013-04-17 with total page 324 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume comprises the compounds of thorium with the 4th main group elements silicon and germanium and all 5th main group elements except nitrogen. On the subject of ternary and polynary compounds containing oxygen, only those compounds with phosphorus are included (e.g., phosphates, hypophosphates, or phosphinates). Similar compounds of the other ele ments like silicates, arsenates, etc. were already treated in "Thorium" Suppl. Vol. C 2, 1976. Most of the compounds in the different systems treated in this volume are of scientific interest because of their special physical and chemical properties. On the other hand, there are also many compounds wh ich are of specific technological interest, mainly in the nuclear field. Refractory compounds like ThSi or ThP have potential interest as nuclear fuel for special reactors due to their physical properties like good heat conductivity and their chemical stability, e.g., against the corrosion of cladding alloys for nuclear fuel elements. Due to the present situation in the further development of the thorium nuclear fuel cycle, their large potential has not yet been fully investigated. For most of the binary and ternary phases in these systems, we presently have good knowledge about the preparation of the compounds and their physical and chemical properties. But nevertheless, there are still a lot of open questions concerning phase equilibria, solid solutions, and homogeneity of some of the phases described in this volume.
Download or read book Thorium written by Renae Jamison and published by Nova Science Pub Incorporated. This book was released on 2014-01-01 with total page 178 pages. Available in PDF, EPUB and Kindle. Book excerpt: Thorium (Th) is the first element in the Actinide series having atomic number 90. It is a radioactive element. Thorium oxides can be used as nuclear fuels, although this application is quite limited compared with uranium oxide materials. In contrast to the well-known properties of bulk thorium oxides, thorium oxide molecules are much less understood. This book discusses the chemical properties, uses and environmental effects of thorium. Topics discussed include the products of laser ablated thorium atom reactions with small molecules; soil profile thorium and uranium concentration distributions in southeastern Missouri soils; influences of coal-fired power plants on the thorium levels in soils and on radioactive hazards for the population; behavior of Th-isotopes along the pigment TiO2 industrial production process; some features of the Th presence in the poços de Caldas alkaline massif, Brazil; geological and geophysical implications for western Australia; hermophysical and thermodynamic properties of oxygen-containing compounds of thorium; and unique role of thorium in closed (Th-U-Pu)-fuel cycle due to the involvement of hybrid fusion-fission reactors to generate advanced (231Pa+232U+233U)-fuel.
Download or read book Health Risks of Radon and Other Internally Deposited Alpha Emitters written by National Research Council and published by National Academies Press. This book was released on 1988-02-01 with total page 623 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book describes hazards from radon progeny and other alpha-emitters that humans may inhale or ingest from their environment. In their analysis, the authors summarize in one document clinical and epidemiological evidence, the results of animal studies, research on alpha-particle damage at the cellular level, metabolic pathways for internal alpha-emitters, dosimetry and microdosimetry of radionuclides deposited in specific tissues, and the chemical toxicity of some low-specific-activity alpha-emitters. Techniques for estimating the risks to humans posed by radon and other internally deposited alpha-emitters are offered, along with a discussion of formulas, models, methods, and the level of uncertainty inherent in the risk estimates.
Download or read book Th Thorium written by Reiner Ditz and published by Springer Science & Business Media. This book was released on 2013-06-29 with total page 406 pages. Available in PDF, EPUB and Kindle. Book excerpt: In connection with the recent treatment of radium and the actinides, the Gmelin Institute is carrying out the description of thorium and its compounds. The Supplement Volumes A 2, A 3, A 4, and A 5 with the history, isotopes, uses, the recovery of thorium and general properties of thorium atom and ions, the thermodynamics of its compounds and solutions, spectroscopic data and analytical chemistry, biological behavior, health protection and safety control have already been published. The Supplement Volumes C 1, C 2 and C 3 describing the compounds with the noble gases, hydrogen, oxygen compounds and nitrogen compounds are also available; also have been published Supplement Volumes C 5 and C 7 describing the compounds with sulfur, selenium, tellurium, and boron, carbonates, thiocynates, alkoxides, and carboxylates. The Supplement Volumes D 1, D 2, and D 3 describing the properties of thorium ions in solution and the solvent extraction of thorium as well as Supplement Volume E describing the coordination compounds also have been published. The present volume begins, in a summary fashion, with a description of the natural occurrence of the element Th. Especially stressed are those facts that are most important in understanding its geological distribution on Earth (as, e.g., mode of occurrence and distribution among minerals) and its behavior in minerals (as, e.g., mode of occurrence and distribution among minerals) and its behavior in minerals (as, e.g., diadochy and metamictization of minerals). Attached is a tabulation of the highest reported Th or ThO2 content in minerals that normally (by their crystal-chemical formula) do not contain Th. The main part of the present volume describes the minerals of Th. As can be seen from the crystal-chemical formulas, there are, in addition to a few minerals containing Th as the sole cation, a number of minerals that contain Th as an additional cation or as a diadochic element. In the case of diadochic substitution the mineral may represent a Th-rich end member of a solid-solution series and, therefore, is described as a separate Th mineral, or may only sporadically contain higher amounts of Th (no mineral description is given). The mineral descriptions, in this volume including oxides, carbonates and phosphates/siliconphosphates of Th, comprise the following topics: occurence; chemistry; crystal form and structure; optical and other physical properties; and chemical and thermal behavior. The silicates of Th and the deposits of Th will be described in the volume "Thorium" Suppl. Vol. A 1b, that also contains a mineral index for both volumes.
Download or read book Th Thorium written by Robert G. Behrens and published by Springer Science & Business Media. This book was released on 2013-06-29 with total page 263 pages. Available in PDF, EPUB and Kindle. Book excerpt: The present volume describes the general properties of the thorium atom and ions, the thermodynamics of its compounds and solutions, the behavior of solutions and solid com pounds under the influence of its own radiation as well as an external radiation field, and spectroscopic data in great detail. The different chapters are of special interest to scientists who work in these fields, and also in the corresponding fields of other elements. In some special fields there exists a detailed knowledge of this radioelement whereas in other fields, such as M6Bbauer spectra, lower oxidation states, or radiation stability, there are large gaps. Due to the fact that the significance 23 of thorium as a breeder fuel ( 2"fh to be converted to fissile 233U after thermal neutron capture) has decreased within the last decade, the behavior of thorium is not as yet so thoroughly investigated as the heavier radioactive element uranium. Many of these data, however, are not only of academic interest, e.g., the knowledge of atomic spectra is needed for some analytical methods, especially in the trace concentration region. Due to the noble gaS-like electronic configuration of the tetravalent ion, there are no absorption bands in the visible region so that in general spectra and data are very scarce. This volume is a very detailed and critically reviewed compilation, written by experts from the Federal Republic of Germany, Belgium, and the United States.
Download or read book Thorium Energy for the Future written by A.K. Nayak and published by Springer. This book was released on 2019-01-30 with total page 546 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book comprises selected proceedings of the ThEC15 conference. The book presents research findings on various facets of thorium energy, including exploration and mining, thermo-physical and chemical properties of fuels, reactor physics, challenges in fuel fabrication, thorium fuel cycles, thermal hydraulics and safety, material challenges, irradiation experiences, and issues and challenges for the design of advanced thorium fueled reactors. Thorium is more abundant than uranium and has the potential to provide energy to the world for centuries if used in a closed fuel cycle. As such, technologies for using thorium for power generation in nuclear reactors are being developed worldwide. Since there is a strong global thrust towards designing nuclear reactors with thorium-based fuel, this book will be of particular interest to nuclear scientists, reactor designers, regulators, academics and policymakers.
Download or read book Molten Salt Reactors and Thorium Energy written by Thomas James Dolan and published by Elsevier. This book was released on 2024-01-25 with total page 1068 pages. Available in PDF, EPUB and Kindle. Book excerpt: Molten Salt Reactors and Thorium Energy, Second Edition is a fully updated comprehensive reference on the latest advances in MSR research and technology. Building on the successful first edition, Tom Dolan and the team of experts have fully updated the content to reflect the impressive advances from the last 5 years, ensuring this book continues to be the go-to reference on the topic. This new edition covers progress made in MSR design, details innovative experiments, and includes molten salt data, corrosion studies and deployment plans. The successful case studies section of the first edition have been removed, expanded, and fully updated, and are now published in a companion title called Global Case Studies on Molten Salt Reactors. Readers will gain a deep understanding of the advantages and challenges of MSR development and thorium fuel use, as well as step-by-step guidance on the latest in MSR reactor design. Each chapter provides a clear introduction, covers technical issues and includes examples and conclusions, while promoting the sustainability benefits throughout. A fully updated comprehensive handbook on Molten Salt Reactors and Thorium Energy, written by a team of global experts Covers MSR applications, technical issues, reactor types and reactor designs Includes 3 brand new chapters which reflect the latest advances in research and technology since the first edition published Presents case studies on molten salt reactors which aid in the transition to net zero by providing abundant clean, safe energy to complement wind and solar powe
Download or read book Thorium written by Robert Hargraves and published by Createspace Independent Publishing Platform. This book was released on 2012 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Thorium energy can help check CO2 and global warming, cut deadly air pollution, provide inexhaustible energy, and increase human prosperity. Our world is beset by global warming, pollution, resource conflicts, and energy poverty. Millions die from coal plant emissions. We war over mideast oil. Food supplies from sea and land are threatened. Developing nations' growth exacerbates the crises. Few nations will adopt carbon taxes or energy policies against their economic self-interests to reduce global CO2 emissions. Energy cheaper than coal will dissuade all nations from burning coal. Innovative thorium energy uses economic persuasion to end the pollution, to provide energy and prosperity to developing nations, and to create energy security for all people for all time. "This book presents a lucid explanation of the workings of thorium-based reactors. It is must reading for anyone interested in our energy future." Leon Cooper, Brown University physicist and 1972 Nobel laureate for superconductivity "As our energy future is essential I can strongly recommend the book for everybody interested in this most significant topic." George Olah, 1994 Nobel laureate for carbon chemistry
Download or read book Gmelin Handbook of Inorganic Chemistry written by Gmelin-Institut für anorganische Chemie and published by . This book was released on 1990 with total page 286 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Th Thorium written by Robert G. Behrens and published by Springer. This book was released on 1989-06-30 with total page 249 pages. Available in PDF, EPUB and Kindle. Book excerpt: The present volume describes the general properties of the thorium atom and ions, the thermodynamics of its compounds and solutions, the behavior of solutions and solid com pounds under the influence of its own radiation as well as an external radiation field, and spectroscopic data in great detail. The different chapters are of special interest to scientists who work in these fields, and also in the corresponding fields of other elements. In some special fields there exists a detailed knowledge of this radioelement whereas in other fields, such as M6Bbauer spectra, lower oxidation states, or radiation stability, there are large gaps. Due to the fact that the significance 23 of thorium as a breeder fuel ( 2"fh to be converted to fissile 233U after thermal neutron capture) has decreased within the last decade, the behavior of thorium is not as yet so thoroughly investigated as the heavier radioactive element uranium. Many of these data, however, are not only of academic interest, e.g., the knowledge of atomic spectra is needed for some analytical methods, especially in the trace concentration region. Due to the noble gaS-like electronic configuration of the tetravalent ion, there are no absorption bands in the visible region so that in general spectra and data are very scarce. This volume is a very detailed and critically reviewed compilation, written by experts from the Federal Republic of Germany, Belgium, and the United States.
Download or read book Thorium Energy for the World written by Jean-Pierre Revol and published by Springer. This book was released on 2016-04-05 with total page 442 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Thorium Energy Conference (ThEC13) gathered some of the world’s leading experts on thorium technologies to review the possibility of destroying nuclear waste in the short term, and replacing the uranium fuel cycle in nuclear systems with the thorium fuel cycle in the long term. The latter would provide abundant, reliable and safe energy with no CO2 production, no air pollution, and minimal waste production. The participants, representatives of 30 countries, included Carlo Rubbia, Nobel Prize Laureate in physics and inventor of the Energy Amplifier; Jack Steinberger, Nobel Prize Laureate in physics; Hans Blix, former Director General of the International Atomic Energy Agency (IAEA); Rolf Heuer, Director General of CERN; Pascal Couchepin, former President of the Swiss Confederation; and Claude Haegi, President of the FEDRE, to name just a few. The ThEC13 proceedings are a source of reference on the use of thorium for energy generation. They offer detailed technical reviews of the status of thorium energy technologies, from basic R&D to industrial developments. They also describe how thorium can be used in critical reactors and in subcritical accelerator-driven systems (ADS), answering the important questions: – Why is thorium so attractive and what is the role of innovation, in particular in the nuclear energy domain? – What are the national and international R&D programs on thorium technologies and how are they progressing? ThEC13 was organized jointly by the international Thorium Energy Committee (iThEC), an association based in Geneva, and the International Thorium Energy Organisation (IThEO). It was held in the Globe of Science and Innovation at the European Organization for Nuclear Research (CERN), Geneva, Switzerland, in October 2013.
Download or read book Chemistry of Thorium in Aqueous Solutions written by A. J. Fry and published by . This book was released on 1949 with total page 24 pages. Available in PDF, EPUB and Kindle. Book excerpt: