Download or read book Temperature dependence of gas sorption and transport properties in glassy polymers written by Lora Marlene Costello and published by . This book was released on 1994 with total page 450 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Gas Transport in Glassy Polymers written by Maria Grazia De Angelis and published by MDPI. This book was released on 2021-04-22 with total page 256 pages. Available in PDF, EPUB and Kindle. Book excerpt: This Special Issue of Membranes focuses on several new aspects of fluid transport in glassy polymers, with application in relevant membrane separations such as gas purification, VOC removal and CO2 capture. In particular, the focus lies on novel experimental techniques, and detailed characterization of specific phenomena like polar and multicomponent interactions during transport. The properties of novel materials, such as mixed matrix membranes based on glassy polymers and different selective fillers, are also presented. A critical review of existing modeling approaches to describe the sorption and transport in glassy polymers suitable for membrane separations is provided, including both macroscopic and atomistic models, and relying both on the standard solution–diffusion process and on the facilitated transport mechanism.

Download or read book SPE ANTEC 1997 Proceedings written by Spe and published by CRC Press. This book was released on 1997-04-22 with total page 1504 pages. Available in PDF, EPUB and Kindle. Book excerpt: First published in 1997. Routledge is an imprint of Taylor & Francis, an informa company.

Download or read book Polymeric Gas Separation Membranes written by D.R. Paul and published by CRC Press. This book was released on 2018-05-04 with total page 635 pages. Available in PDF, EPUB and Kindle. Book excerpt: Polymeric Gas Separation Membranes is an outstanding reference devoted to discussing the separation of gases by membranes. An international team of contributors examines the latest findings of membrane science and practical applications and explores the complete spectrum of relevant topics from fundamentals of gas sorption and diffusion in polymers to vapor separation from air. They also compare membrane processes with other separation technologies. This essential book will be valuable to all practitioners and students in membrane science and technology.

Download or read book Wenduine Harendijke written by and published by . This book was released on with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Diffusion in Polymers written by John Crank and published by . This book was released on 1968 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Structure and Properties of Glassy Polymers written by Martin R. Tant and published by . This book was released on 1998 with total page 486 pages. Available in PDF, EPUB and Kindle. Book excerpt: In twenty-nine chapters by leading authorities, Structure and Properties of Glassy Polymers provides readers with comprehensive coverage of basic and applied research on glass polymers as well as a wealth of information on current topics such as molecular modeling, characterization, polymer glasses in confined spaces, and conducting glass polymers. The characterization techniques presented include temperature-modulated differential scanning calorimetry, dielectric loss spectroscopy, photochemical hole burning, positron annihilation lifetime spectroscopy, and transient current generation.

Download or read book Sorption and Transport of Gases in Glassy Polymers written by William John Koros and published by . This book was released on 1977 with total page 506 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Membrane Materials for Gas and Separation written by Yuri Yampolskii and published by John Wiley & Sons. This book was released on 2017-03-20 with total page 122 pages. Available in PDF, EPUB and Kindle. Book excerpt: Si containing polymers have been instrumental in the development of membrane gas separation practices since the early 1970s. Their function is to provide a selective barrier for different molecular species, where selection takes place either on the basis of size or on the basis of physical interactions or both. Combines membrane science, organosilicon chemistry, polymer science, materials science, and physical chemistry Only book to consider polymerization chemistry and synthesis of Si-containing polymers (both glassy and rubbery), and their role as membrane materials Membrane operations present environmental benefits such as reduced waste, and recovered/recycled valuable raw materials that are currently lost to fuel or to flares

Download or read book Permeability of Plastic Films and Coatings written by Harold Hopfenberg and published by Springer Science & Business Media. This book was released on 2013-11-21 with total page 480 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Sorption and Transport of Gases and Vapors in Glassy Polymers written by Vinit Saxena and published by . This book was released on 1981 with total page 276 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Transport Properties of Polymeric Membranes written by Sabu Thomas and published by Elsevier. This book was released on 2017-11-20 with total page 726 pages. Available in PDF, EPUB and Kindle. Book excerpt: Transport Properties of Polymeric Membranes is an edited collection of papers that covers, in depth, many of the recent technical research accomplishments in transport characteristics through polymers and their applications. Using the transport through polymer membranes method leads to high separation efficiency, low running costs, and simple operating procedures compared to conventional separation methods. This book provides grounding in fundamentals and applications to give you all the information you need on using this method. This book discusses the different types of polymer, their blends, composites, nanocomposites and their applications in the field of liquid, gas and vapor transport. Some topics of note include modern trends and applications of polymer nanocomposites in solvent, vapor and gas transport; fundamentals and measurement techniques for gas and vapor transport in polymers; and transport properties of hydrogels. This handpicked selection of topics, and the combined expertise of contributors from global industry, academia, government and private research organizations, make this book an outstanding reference for anyone involved in the field of polymer membranes. Presents current trends in the field of transport of liquid, gas and vapor through various polymeric systems Features case studies focused on industrial applications of membrane technology, along with fundamentals of transport and materials Helps readers quickly look up a particular technique to learn key points, capabilities and drawbacks

Download or read book Fundamentals of Gas Sorption and Transport in Thermally Rearranged Polyimides written by Zachary Pace Smith and published by . This book was released on 2014 with total page 824 pages. Available in PDF, EPUB and Kindle. Book excerpt: Thermally rearranged polymers are formed from the solid-state thermal reaction of polyimides and polyamides that contain reactive groups ortho position to their diamine. These polymers have shown outstanding transport properties for gas separation applications. The thrust of this work is to critically examine the chemical and morphological structure of these polymers and to identify the fundamental contributions of gas sorption to permeability. To accomplish this goal, a series of TR polymers and TR polymer precursors have been synthesized and investigated for transport properties. As a function of conversion, diffusivity increases more dramatically than sorption, which explains the outstanding permeabilities observed for these samples. Modifications to the polymer backbone structure, which can be achieved by adding rigid functional groups such as hexafluoroisopropylidene-functional linking groups, can further be used to improve permeabilities. The precursor used to form TR polymers has dramatic effects on the final polymer transport properties. Despite having nearly identical polymer structure, TR polymers formed from polyamide precursors have lower combinations of permeability and selectivity than TR polymers formed from polyimide precursors. In addition to structure-property studies with TR polymers, this thesis also present comparisons of permeability, diffusivity, and sorption of sparingly soluble gases (i.e., hydrogen and helium) for hydrocarbon-based polymer, highly fluorinated polymers, perfluoropolymers, and a silicon-based polymer. An explanation for the unique transport properties of perfluoropolymers is presented from the standpoint of the solution-diffusion model, whereby perfluoropolymers have uniquely different solubility selectivities than hydrocarbon-based polymers. Additionally, a large database of sorption, diffusion, and permeability coefficients is used to determine the contributions of free volume on solubility selectivity in polymers.

Download or read book Impact of Humidity and Polymer Blending on the Gas Transport Properties of Polybenzimidazoles written by Joshua David Moon and published by . This book was released on 2019 with total page 556 pages. Available in PDF, EPUB and Kindle. Book excerpt: Polybenzimidazoles (PBIs) are attractive polymers for gas separation membranes due to their high chemical and thermal stability and rigid, size-selective molecular structures. Opportunities exist for using PBIs for high temperature H2/CO2 separation, among other separations, where significant amounts of water are often present. However, PBIs are uniquely hydrophilic glassy polymers, and the impact of humidity on PBI gas transport properties is not well understood. Highly sorbing penetrants like water are often considered to affect molecular transport in polymers through phenomena such as competitive sorption, antiplasticization, and plasticization, but greater fundamental understanding is needed to relate these phenomena to other key concepts in polymer transport like free volume. Additionally, opportunities exist to improve low PBI gas permeabilities through material modification. This study investigates fundamentals of water sorption, dilation, and diffusion in PBIs to develop a systematic understanding of how water uptake affects molecular transport in hydrophilic glassy polymers. Water vapor sorption and swelling in PBIs were experimentally measured, which enabled direct evaluation of polymer free volume changes arising from water uptake. Gas transport properties were measured across a range of humidities using a custom experimental apparatus and correlated with humidity-induced free volume changes. This analysis enabled unique insight into the tradeoff between competitive sorption, antiplasticization, and plasticization effects of water sorption on PBI transport properties. Similar analysis could be used to investigate fundamentals of mixed penetrant sorption and diffusion in other polymers. Finally, a method of improving PBI gas separation properties by blending PBIs with a more permeable polymer was investigated. Commercial PBI was blended with an ortho-functional polyimide capable of undergoing thermal rearrangement at high temperatures. Films of PBI blended with a small fraction of polyimide exhibited matrix-droplet morphologies that enabled synergistic combination of PBI and polyimide gas separation properties. Heat treatment caused thermal rearrangement of the polyimide phase, increasing blend H2 permeabilities, while also increasing structural order in the PBI phase, increasing blend H2/CO2 selectivities. The net result of heat treatment was simultaneous improvement in both H2 permeability and H2/CO2 selectivity at ambient temperatures, surpassing the 2008 H2/CO2 upper bound

Download or read book Sorption and transport properties of compatible polymer blends written by Paolo Masi and published by . This book was released on 1980 with total page 264 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Materials Science of Membranes for Gas and Vapor Separation written by Benny Freeman and published by John Wiley & Sons. This book was released on 2006-05-12 with total page 466 pages. Available in PDF, EPUB and Kindle. Book excerpt: Materials Science of Membranes for Gas and Vapor Separation is a one-stop reference for the latest advances in membrane-based separation and technology. Put together by an international team of contributors and academia, the book focuses on the advances in both theoretical and experimental materials science and engineering, as well as progress in membrane technology. Special attention is given to comparing polymer and inorganic/organic separation and other emerging applications such as sensors. This book aims to give a balanced treatment of the subject area, allowing the reader an excellent overall perspective of new theoretical results that can be applied to advanced materials, as well as the separation of polymers. The contributions will provide a compact source of relevant and timely information and will be of interest to government, industrial and academic polymer chemists, chemical engineers and materials scientists, as well as an ideal introduction to students.

Download or read book Nano Enhanced and Nanostructured Polymer Based Membranes for Energy Applications written by Maria Giovanna Buonomenna and published by Woodhead Publishing. This book was released on 2022-01-22 with total page 426 pages. Available in PDF, EPUB and Kindle. Book excerpt: There is a growing need for better membranes in several emerging application fields especially those related to energy conversion and storage as well as to water treatment and recycling. Processability, is an important functional property, often ignored, especially in the early discovery phase for new materials, but it should be one of the most important properties, that needs to be considered in the development of better membrane materials. Useful membrane materials have to be capable of being formed into thin membranes, in particular for membrane gas separation, water treatment and desalination, and then packaged, into large area membrane modules. All gas separation membranes that are in current commercial use are based on polymers, which are solution-processable. This book intends to deal with composite, in most cases hybrid polymer-based membranes for three separate application fields: energy conversion, energy storage and water treatment and recovery. Each chapter will explain clearly the various membrane processes then go on to discuss in detail the corresponding advanced membranes used. The logic that lies behind this is that you have to understand the process in order to develop new high-performance membranes. By taking this approach, the author aims to overcome the disconnection that currently exists between membrane materials scientists and industrial process engineers. Discusses interdisciplinary content by a single author, approaching synthesis and development of materials from the perspective of their processability Describes the novel aspects of membrane science that is related to energy storage, conversion and wastewater treatment Presents an emphasis on scientific results which have an impact on real applications in terms of renewable and clean energy challenges