Download or read book Synthetic Multidentate Macrocyclic Compounds written by Reed Izatt and published by Elsevier. This book was released on 2012-12-02 with total page 335 pages. Available in PDF, EPUB and Kindle. Book excerpt: Synthetic Multidentate Macrocyclic Compounds attempts to bring together selected chapters in which the authors discuss in depth investigations in important areas of macrocycle research. The chapters deal mainly with macrocyclic compounds (saturated polyethers and their derivatives), and macrobicyclic compounds (cryptates). The book contains six chapters and opens with a first-hand account of the initial synthesis of the cyclic polyethers. This is followed by separate chapters on the synthesis of cyclic polyethers, polyether amines, and polyether sulfides; the synthesis of multidentate compounds; and the structure of synthetic macrocyclic compounds and their cation complexes. Subsequent chapters deal with the rates of reactions and the mechanism by which synthetic macrocyclic ligands complex substrates in solution; and commercial applications of the synthetic macrocyclic ligands. This book is primarily aimed at researchers and students in organic, physical, analytical, and inorganic chemistry, and in chemical engineering. However, it will also be of interest to many in the areas of biology, biochemistry, and physiology. Extensive literature references are found in each chapter.
Download or read book Template Synthesis of Macrocyclic Compounds written by N. V. Gerbeleu and published by John Wiley & Sons. This book was released on 2008-07-11 with total page 574 pages. Available in PDF, EPUB and Kindle. Book excerpt: The synthesis of macrocycles is an art in itself. Template-controlled synthesis provides elegant access to fascinating macrocyclic structures. Polyazamacrocycles, crown ethers, cryptands, rotaxanes, knots -- the range of macrocyclic compounds is as broad as their potential application as molecular switches, in ion exchange, electron transfer or catalysis. This book provides authoritative information on all aspects of template-controlled macrocyclizations. It covers in depth the current state of research on template processes - novel synthetic techniques and mechanistic approaches. The critical discussion of the diverse synthetic routes includes the detailed characterization of the broad variety of macrocyclic products. References to applications of macrocyclic compounds and over 1,500 citations make this handbook an indispensable tool for chemists in academia and industry. Researchers in organic and supramolecular chemistry, biotechnology, and inorganic chemistry will find inspiration for the design, synthesis, and myriad uses of new synthetic macrocycles.
Download or read book Cation Binding by Macrocycles written by Inoue and published by Routledge. This book was released on 2018-10-03 with total page 768 pages. Available in PDF, EPUB and Kindle. Book excerpt: This reference details the theory and application of cation complexation, including the design and synthesis of various cyclic systems, these materials' use as transport systems, in complexation and selectivity studies by macrocyclic systems, and methodologies for understanding these phenomena. In a
Download or read book Host Guest Complex Chemistry Macrocycles written by F. Vögtle and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 421 pages. Available in PDF, EPUB and Kindle. Book excerpt: The scientific and practical interest in coronands (crown ethers), cryptands, podands as complexing agents for cations as well as for anions and neutral low molecular species is undeniable 1,2). The chemistry of crown compounds is steadily increasing. About 250 original papers dealing with crown chemistry appeared only in 1980. New molecules· with crown ether properties are constantly synthesized and new applications discov,?red. Owing to lack of space, only a small number of the original publications is men tioned here. Thus, in the literature compilation only some, but relevant works are selected for each chapter. Whenever possible, reference is made to reviews or review-like articles alone by means of which origin,al works can be consulted. The reviews given under ref. 1) are considered to be the most relevant. The formulae presented in the figures should be understood as representative structures outlining a specific field. 2 Classification of Oligo-/Multidentate Neutral Ligands and of their Complexes Today, a distinction is made between the classical ring oligoethers (crown ethers) and monocyclic coronands, oligocyclic spherical cryptands and the acyclic podands with respect to topological aspects 3). This classification and the topology are illustrated in Fig. 1, each figure representing the minimum number of donor atoms and chain segments characteristic of each class of compounds. Multidentate mono cyclic ligands with any type of donor atoms are called coronands ("crown compounds"), while the term crown ether should be reserved for cyclic oligoethers exclusively containing oxygen as donor atom.
Download or read book Synthetic Coordination and Organometallic Chemistry written by Alexander D. Garnovskii and published by CRC Press. This book was released on 2003-04-25 with total page 568 pages. Available in PDF, EPUB and Kindle. Book excerpt: This reference describes standard and nonstandard coordination modes of ligands in complexes, the intricacies of polyhedron-programmed and regioselective synthesis, and the controlled creation of coordination compounds such as molecular and hn-p-complexes, chelates, and homo- and hetero-nuclear compounds. It offers a clear and concise review of modern synthetic techniques of metal complexes as well as lesser known gas- and solid-phase synthesis, electrosynthesis, and microwave and ultrasonic treatment of the reaction system. The authors pay special attention to o-hydroxyazomethines and their S-, Se-containing analogues, b-diketones, and quinines, among others, and examine the immediate interaction of ligands and metal salts or carbonyls.
Download or read book Liquid Membranes written by Takeo Araki and published by CRC Press. This book was released on 1990-05-09 with total page 234 pages. Available in PDF, EPUB and Kindle. Book excerpt: This interesting work extensively describes newer applications of liquid membrane systems which contain molecular and/or ion recognizing carrier compounds and the related characteristic membrane materials. This volume focuses on the current knowledge about chemistry, biology and related technology of liquid membranes. It reviews the most recent advances in design and characteristics of synthetic liquid membrane transport. Additionally, this fascinating reference discusses up-to-date topics in the analytical and separation science, plus biomimetic membrane technology. Because this book is presented in a compact, understandable format, readers can start from biological cell membranes, then net aspects of host-guest chemistry for effective recognition of ions and molecules, followed by its application for artificial sensors-such as neuro-systems, functionalized new detergents, mechanochemical systems, and separation chemistry. This publication is ideal for graduate-level students and will stimulate university and industry researchers.
Download or read book Nobel Laureates in Chemistry 1901 1992 written by James K. Laylin and published by Chemical Heritage Foundation. This book was released on 1993-10-30 with total page 820 pages. Available in PDF, EPUB and Kindle. Book excerpt: Through new perspectives from a mix of original monographs, biographies, autobiographical memoirs, edited collections of essays and documentary sources, translations, classic reprints, and pictorial volumes, this series will document the individuals, ideas, institutions, and innovations that have created the modern chemcial sciences.
Download or read book Oligomer Technology and Applications written by Uglea and published by CRC Press. This book was released on 1998-01-05 with total page 530 pages. Available in PDF, EPUB and Kindle. Book excerpt: Details laboratory and industrial synthesis and applications of oligomers-suggesting practical solutions to the on-the-job problems as well as exploring processing devices and techniques for industrial-scale production of new oligomer types.
Download or read book Bioenergetics and Thermodynamics Model Systems written by A. Braibanti and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 471 pages. Available in PDF, EPUB and Kindle. Book excerpt: Proceedings of the NATO Advanced Study Institute, Tabiano, Parma, Italy, May 21-June 1, 1979
Download or read book Topics in Stereochemistry written by Ernest L. Eliel and published by John Wiley & Sons. This book was released on 2009-09-17 with total page 320 pages. Available in PDF, EPUB and Kindle. Book excerpt: This seminal series, first edited by Ernest Eliel, responsible for some of the major advances in stereochemistry and the winner of the ACS Priestley Medal in 1996, provides coverage of the major developments of the field of stereochemistry. The scope of this series is broadly defined to encompass all fields of chemical and biological sciences that are founded on molecular and supramolecular interactions. Insofar as chemical, physical, and biological properties are determined by molecular shape and structure, the importance of stereochemistry is fundamental to and consequential for all natural sciences. Topics in Stereochemistry serves as a multidisciplinary series that enriches all of chemistry. Aimed at advanced students, university professors and teachers as well as researchers in pharmaceutical, agricultural, biotechnological, polymer, materials, and fine chemical industries, Topics in Stereochemistry publishes definitive and scholarly reviews in stereochemistry and has long been recognized as the gold standard reference work in this field. Covering the effect of chirality on all aspects of molecular interaction from the fundamental physical chemical properties of molecules and their molecular physics to the application of chirality in new areas such as its applications in materials science, Topics in Stereochemistry explores a wide variety of properties, both physical and chemical of isomers with a view to their applications in a number of disciplines from biochemistry to materials science.
Download or read book CRC Handbook of Organic Analytical Reagents Second Edition written by Kuang Lu Cheng and published by CRC Press. This book was released on 1992-09-25 with total page 628 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Handbook of Organic Analytical Reagents, 2nd Edition, is an indispensable source book of physico-chemical properties, preparation, and analytical applications of the most commonly used organic reagents. Updated from the 1st Edition, this volume includes data on 40 new reagents (such as ultra-high sensitive azo dyes, fluorescent calcium indicators, and chromogenic crown ethers and porphyrin reagents), a new Reagent Index listing reagents according to the elements to be assayed, and completely updated references. Each entry contains information on synonyms, sources and methods of synthesis, analytical applications, complexation reactions and the properties of complexes, purification and purity of the reagent, and other regeants with a related structure. The Handbook of Organic Analytical Reagents, 2nd Edition, is an invaluable bench-side reference for professional analytical chemists and graduate students.
Download or read book CRC Handbook of Organic Analytical Reagents written by Kuang Lu Cheng and published by Routledge. This book was released on 2017-09-29 with total page 625 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Handbook of Organic Analytical Reagents, 2nd Edition, is an indispensable source book of physico-chemical properties, preparation, and analytical applications of the most commonly used organic reagents. Updated from the 1st Edition, this volume includes data on 40 new reagents (such as ultra-high sensitive azo dyes, fluorescent calcium indicators, and chromogenic crown ethers and porphyrin reagents), a new Reagent Index listing reagents according to the elements to be assayed, and completely updated references. Each entry contains information on synonyms, sources and methods of synthesis, analytical applications, complexation reactions and the properties of complexes, purification and purity of the reagent, and other regeants with a related structure. The Handbook of Organic Analytical Reagents, 2nd Edition, is an invaluable bench-side reference for professional analytical chemists and graduate students.
Download or read book An Annotated Bibliography of Compiled Thermodynamic Data Sources for Biochemical and Aqueous Systems 1930 to 1975 written by George Thomson Armstrong and published by . This book was released on 1976 with total page 72 pages. Available in PDF, EPUB and Kindle. Book excerpt: 101 selected references to books and journal articles. Also includes some foreign-language titles. Alphabetical arrangement by primary authors. Each entry gives bibliographical information and annotation. Author, subject indexes.
Download or read book NBS Special Publication written by and published by . This book was released on 1976 with total page 780 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book N4 Macrocyclic Metal Complexes written by J.H. Zagal and published by Springer Science & Business Media. This book was released on 2006-07-19 with total page 828 pages. Available in PDF, EPUB and Kindle. Book excerpt: In response to significant developments in sensor science and technology, this book offers insight into the various extended applications and developments of N4 macrocycle complexes in biomimetic electrocatalysis. Covers chemical properties of electrocatalysts, use of specific species, and analytical applications.
Download or read book Coordination Chemistry of Macrocyclic Compounds written by Gordon Melson and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 676 pages. Available in PDF, EPUB and Kindle. Book excerpt: Chemists have been aware of the existence of coordination compounds con taining organic macrocyclic ligands since the first part of this century ; however, only during the past few years have they expanded research into the chemistry of these compounds. The expansion was initiated in the early 1960s by the synthesis and characterization of compounds containing some new macrocyclic ligands. The synthesis of compounds which may serve as model systems for some natural products containing large rings as ligands provided the main goal for the early expansion of research effort; indeed, a recurrent theme behind much of the reported chemistry has been the analogy between synthetic macrocyclic compounds and many natural-product systems. More recently, the emphases of reported research have ranged over the whole spectrum of chemistry, and the number of publications that discuss macrocyclic chemistry has increased at a dramatic rate. The completed research has been reported in a variety of journals throughout the world but there has been no previous attempt to bring the major developments together under one cover. This book, therefore, attempts to satisfy the need for a single source in which there is both a collection and a correlation of information concerning the coordination chemistry of macrocyclic compounds. The chapters in this book discuss various aspects of macrocyclic chemistry, and while these chapters as a whole constitute an in-depth survey of the state-of the-art of the field, each chapter is written as a complete unit.
Download or read book Chemical Sensors written by T. E. Edmonds and published by Springer Science & Business Media. This book was released on 2013-03-14 with total page 332 pages. Available in PDF, EPUB and Kindle. Book excerpt: At the beginning of this book, and in the absence of guidance from IUPAC, it is appropriate to clarify the term 'chemical sensor'. A chemical sensor may be defined as a simple-to-use, robust device that is capable of reliable quantitative or qualitative recognition of atomic, molecular or ionic species. It is hard to imagine a field of applied chemistry in which a significant impact could not be made by such a device. Undoubtedly, it is this potential that has fuelled the contemporary preoccupation with chemical sensors. An unfortunate side-effect of this otherwise welcome interest is the use of the term 'chemical sensor' to add the chemical equivalent of a 'High-Tech gloss' to a rather ordinary device, publication, conference or research group. This loose usage of terminology is responsible in part for the ambiguity that surrounds many chemists' concepts of the form and function of chemical sensors. Further ambiguity arises from the extravagant claims that have been made for some sensors, and the impression that has been given of much 'verging-on-a-breakthrough' research. The research chemist engaged in sensor development should be mindful of the fact that the ultimate target for these devices is the real world, and that a successful laboratory device operating under well-defined conditions and careful calibration does not constitute a chemical sensor. Research into chemical sensors is not a recent phenomenon; it has been under way for over 80 years.
