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Book Chiral Transition Metal Complexes Containing Phosphines

Download or read book Chiral Transition Metal Complexes Containing Phosphines written by Darlene Grace D'Alliessi and published by . This book was released on 2003 with total page 314 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Synthesis and Characterization of Bis phosphine Complexes with Transition Metals

Download or read book Synthesis and Characterization of Bis phosphine Complexes with Transition Metals written by Alicia L. McDaniel and published by . This book was released on 2009 with total page 136 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Phosphorus III Ligands in Homogeneous Catalysis

Download or read book Phosphorus III Ligands in Homogeneous Catalysis written by Paul C. J. Kamer and published by John Wiley & Sons. This book was released on 2012-05-09 with total page 673 pages. Available in PDF, EPUB and Kindle. Book excerpt: Over the last 60 years the increasing knowledge of transition metal chemistry has resulted in an enormous advance of homogeneous catalysis as an essential tool in both academic and industrial fields. Remarkably, phosphorus(III) donor ligands have played an important role in several of the acknowledged catalytic reactions. The positive effects of phosphine ligands in transition metal homogeneous catalysis have contributed largely to the evolution of the field into an indispensable tool in organic synthesis and the industrial production of chemicals. This book aims to address the design and synthesis of a comprehensive compilation of P(III) ligands for homogeneous catalysis. It not only focuses on the well-known traditional ligands that have been explored by catalysis researchers, but also includes promising ligand types that have traditionally been ignored mainly because of their challenging synthesis. Topics covered include ligand effects in homogeneous catalysis and rational catalyst design, P-stereogenic ligands, calixarenes, supramolecular approaches, solid phase synthesis, biological approaches, and solubility and separation. Ligand families covered in this book include phosphine, diphosphine, phosphite, diphosphite, phosphoramidite, phosphonite, phosphinite, phosphole, phosphinine, phosphinidenene, phosphaalkenes, phosphaalkynes, P-chiral ligands, and cage ligands. Each ligand class is accompanied by detailed and reliable synthetic procedures. Often the rate limiting step in the application of ligands in catalysis is the synthesis of the ligands themselves, which can often be very challenging and time consuming. This book will provide helpful advice as to the accessibility of ligands as well as their synthesis, thereby allowing researchers to make a more informed choice. Phosphorus(III) Ligands in Homogeneous Catalysis: Design and Synthesis is an essential overview of this important class of catalysts for academic and industrial researchers working in catalyst development, organometallic and synthetic chemistry.

Book I Synthesis Characterization and Reactivity of Platinum II Metal Complexes of Phosphorus containing Mesocycles II Bifunctional Phosphines as Reagents in Carbon Tetrachloride promoted Chlorination Reactions

Download or read book I Synthesis Characterization and Reactivity of Platinum II Metal Complexes of Phosphorus containing Mesocycles II Bifunctional Phosphines as Reagents in Carbon Tetrachloride promoted Chlorination Reactions written by Susan Deborah Toto and published by . This book was released on 1989 with total page 504 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Transition metal Complexes Containing Phosphorus Ligands

Download or read book Transition metal Complexes Containing Phosphorus Ligands written by Stephen D. Robinson and published by . This book was released on 1972 with total page 5 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book 31P and 13C NMR of Transition Metal Phosphine Complexes

Download or read book 31P and 13C NMR of Transition Metal Phosphine Complexes written by P. S. Pregosin and published by Springer. This book was released on 1979 with total page 176 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Synthesis Characterization and Reactivity of Platinum 0 tetraphosphion Complexes and Group VIII Metal Phosphine Complexes Coordinated to Alkoxide and Hydroxide Ligands

Download or read book Synthesis Characterization and Reactivity of Platinum 0 tetraphosphion Complexes and Group VIII Metal Phosphine Complexes Coordinated to Alkoxide and Hydroxide Ligands written by Lisa Marie Green and published by . This book was released on 1987 with total page 502 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Synthesis Characterization and Reactivity of Low Valent Technetium Phosphine Complexes

Download or read book Synthesis Characterization and Reactivity of Low Valent Technetium Phosphine Complexes written by Evan Freiberg and published by . This book was released on 2001 with total page 446 pages. Available in PDF, EPUB and Kindle. Book excerpt: Chapter 1. The chemistry of the metal-metal multiply bonded Tc2(II, II) core has been investigated with bis(diphenylphosphino)methane (dppm). The parent complex, Tc2Cl4(dppm)2, has been prepared from the reaction of Tc2C14(PEt3)4 with dppm. The reactivity of Tc2Cl4(dppm)2 with tert-butyl isocyanide has been studied and a neutral 1:1 adduct, Tc2Cl4(dppm)2CNBut, a cationic 1:2 adduct, [Tc2Cl3(dppm)4(CNBut)2](PF6), and a [mu]-iminyl complex, [Tc2Cl3(dppm)2(CNBut)2CNHBul(PF6), have been prepared. The parent compound and its reaction products have been characterized via a combination of spectroscopic techniques and single crystal X-ray crystallography. The metal-metal bonded ditechnetium bis(dppm) motif is retained in the reaction products. Chapter 2. The reduction of ammonium pertechnetate with bis(diphenylphosphino)methane (dppm), and with diphenyl-2-pyridyl phosphine (Ph2Ppy), has been investigated. The neutral Tc(II) complex, TcCl2(dppm)2, has been isolated from the reaction of (NH4)[TcO4] with excess dppm in refluxing EtOH/HCl. Chemical oxidation with ferricinium hexafluorophosphate results in formation of the cationic Tc(III) analogue, [TcCl2(dppm)2](PF6). The dppm ligands adopt the chelating bonding mode in both complexes, resulting in strained four member metallocycles. With excess PhPpy, the reduction of (NH4)[TcO4] in refluxing EtOH/HCl yields a complex with one chelating Ph2Ppy ligand and one unidentate Ph2Ppy ligand, TcCl3(Ph2Ppy-P, N)(Ph2Ppy-P).

Book Transition metal Complexes of Ferrocenyl Phosphine

Download or read book Transition metal Complexes of Ferrocenyl Phosphine written by Julian Rodger Frederic Pritzwald-Stegmann and published by . This book was released on 2013 with total page 109 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Synthesis Characterization and Reactions of Tertiary Phosphine Complexes of Cobalt Derivatives of Nitrogen Oxides

Download or read book Synthesis Characterization and Reactions of Tertiary Phosphine Complexes of Cobalt Derivatives of Nitrogen Oxides written by Clemente Diogenes Vallenilla and published by . This book was released on 1985 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: