EBookClubs

Read Books & Download eBooks Full Online

EBookClubs

Read Books & Download eBooks Full Online

Book Synthesis  Characterization and Application of Pd Pt Bimetallic Nanoparticles and Carbon Nanotubes Supported Nanocomposites

Download or read book Synthesis Characterization and Application of Pd Pt Bimetallic Nanoparticles and Carbon Nanotubes Supported Nanocomposites written by Guoqiang Ren and published by . This book was released on 2007 with total page 116 pages. Available in PDF, EPUB and Kindle. Book excerpt: "A study on the synthesis of Pd-Pt alloy nanoparticles and composition evolution of the alloys was reported. The synthesis followed a hot organometallic route, with Pd and Pt acetylacetonate as the metal precursors and trioctylphosphine as the solvent. The size of the Pd-Pt nanoparticles narrowed down with time and reached a final size of 3.5 nm in about 10 min. The alloy compositions evolved with time and reached the preset Pd to Pt ratio of precursors in 120 min. An atomic exchange process between the Pt-TOP complex and the Pd atoms at the nanoparticle surface was proposed to elucidate this synthesis process"--Abstract, leaf iv.

Book Nanotechnology in Catalysis Volumes 1 and 2

Download or read book Nanotechnology in Catalysis Volumes 1 and 2 written by Bing Zhou and published by Springer Science & Business Media. This book was released on 2003-12-31 with total page 416 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is mainly based on the first and second symposia on Nanotechnology in Catalysis held in 2001 and 2002, but it also includes several contributions not presented in the symposia to round out the scope of the subject. The contents are the most up to date developments made by researchers all over the world in the catalysis field in this fascinating nanotechnology era. It reflects some of the frontier areas of nanoscience and nanotechnology in fabricating and characterizing catalysts and carrying out studies to prove their superior selectivity and activity. The field of application of nanotechnology for the development of catalysts for green chemistry is likely to grow rapidly during the next decade. This book hopes to contribute to the evolution of nanotechnology in that direction.

Book Inorganic Nanoparticles

Download or read book Inorganic Nanoparticles written by Claudia Altavilla and published by CRC Press. This book was released on 2017-12-19 with total page 885 pages. Available in PDF, EPUB and Kindle. Book excerpt: Among the various nanomaterials, inorganic nanoparticles are extremely important in modern technologies. They can be easily and cheaply synthesized and mass produced, and for this reason, they can also be more readily integrated into applications. Inorganic Nanoparticles: Synthesis, Applications, and Perspectives presents an overview of these special materials and explores the myriad ways in which they are used. It addresses a wide range of topics, including: Application of nanoparticles in magnetic storage media Use of metal and oxide nanoparticles to improve performance of oxide thin films as conducting media in commercial gas and vapor sensors Advances in semiconductors for light-emitting devices and other areas related to the energy sector, such as solar energy and energy storage devices (fuel cells, rechargeable batteries, etc.) The expanding role of nanosized particles in the field of catalysis, art conservation, and biomedicine The book’s contributors address the growing global interest in the application of inorganic nanoparticles in various technological sectors. Discussing advances in materials, device fabrication, and large-scale production—all of which are urgently required to reduce global energy demands—they cover innovations in areas such as solid-state lighting, detailing how it still offers higher efficiency but higher costs, compared to conventional lighting. They also address the impact of nanotechnology in the biomedical field, focusing on topics such as quantum dots for bioimaging, nanoparticle-based cancer therapy, drug delivery, antibacterial agents, and more. Fills the informational gap on the wide range of applications for inorganic nanoparticles in areas including biomedicine, electronics, storage media, conservation of cultural heritage, optics, textiles, and cosmetics Assembling work from an array of experts at the top of their respective fields, this book delivers a useful analysis of the vast scope of existing and potential applications for inorganic nanoparticles. Versatile as either a professional research resource or textbook, this effective tool elucidates fundamentals and current advances associated with design, characterization, and application development of this promising and ever-evolving device.

Book Synthesis and Characterization of Carbon Nanotube Supported Nanoparticles for Catalysis

Download or read book Synthesis and Characterization of Carbon Nanotube Supported Nanoparticles for Catalysis written by Ganesh Vijayaraghavan and published by . This book was released on 2007 with total page 300 pages. Available in PDF, EPUB and Kindle. Book excerpt: This dissertation describes the synthesis and characterization of nitrogen doped carbon nanotube (NCNT) supported nanoparticles for catalysis, specifically, the cathodic oxygen reduction reaction (ORR) in fuel cells. Strategies for synthesis of mono- and bimetallic nanoparticle catalysts through dendrimer based templating techniques and with the aid of metal organic chemical vapor deposition (MOCVD) precursors and efficient assembly protocols of the catalysts with the NCNTs are discussed in detail. Physicochemical properties of the NCNTs and NCNT supported catalysts were characterized using a host of tools including scanning electron microscopy, transmission electron microscopy, Raman spectroscopy, x-ray photoelectron spectroscopy (XPS), thermo gravimetric analysis, BET surface area and pore size analysis and electrochemical techniques including cyclic voltammetry, chronocoulometry, chronoamperometry and rotating disk electrode voltammetry. Chapter 1 serves as a general introduction and provides a brief overview of challenges associated with the synthesis, characterization and utilization of graphitic carbons and graphitic carbon supported catalysts in heterogeneous catalysis. Chapter 2 provides an overview of the synthesis and characterization of systematically doped iron and nickel catalyzed NCNTs in an effort to understand the effect of nitrogen doping on ORR. Chapter 3 describes the use of NCNTs as supports for dendrimer templated nanoparticle catalysts for ORR. A facile synthetic strategy for the immersion based loading of catalysts onto NCNTs by spontaneous adsorption to achieve specific catalyst loadings is explored. Chapter 4 details the loading of monodisperse Pt, Pd and PtPd catalysts on the as synthesized NCNTs using MOCVD precursors. The MOCVD route offers promise for direct dispersion and activation of ORR catalysts on NCNT supports and eliminates a host of problems associated with traditional solvent based catalyst preparation schemes. Chapter 5 details future directions on a few topics of interest including efficient electrodeposition strategies for preparing NCNT supported catalysts, studies on PtCu catalysts for ORR and finally prospects of using NCNT supported catalysts in fuel cell applications.

Book Bimetallic Nanoparticles

    Book Details:
  • Author : Alexandra Marcela Landry
  • Publisher :
  • Release : 2016
  • ISBN :
  • Pages : 92 pages

Download or read book Bimetallic Nanoparticles written by Alexandra Marcela Landry and published by . This book was released on 2016 with total page 92 pages. Available in PDF, EPUB and Kindle. Book excerpt: Bimetallic nanoparticles can lead to catalysts with improved turnover rates and selectivities, but many synthetic protocols, such as impregnation or precipitation, typically form particles of non-uniform size and composition. Colloidal methods may be able to improve their uniformity, but often require reagents that poison catalytic surfaces (ex. S, B, P). Such compositional non-uniformity and ubiquitous impurities have prevented rigorous conclusions about the consequences of alloying on reactivity and selectivity. Herein, we describe a sequential galvanic displacement-reduction (GDR) colloidal synthesis method using precursors containing only C, H, O, and N, that leads to bimetallic AuPt and PtPd nanoparticles narrowly distributed in size and composition. Au3+ or Pt4+ precursors were added to monometallic Pt or Pd clusters, respectively, whose surface atoms are thermodynamically driven to reduce and deposit the solvated cations onto cluster surfaces due to the lower reduction potentials (E0) of the seed metal relative to the precursor cations (E0Au> E0Pt> E0Pd); oxidized Pt and Pd surface atoms subsequently return to cluster surfaces upon reduction by the solvent, a reductant (ethanol or ethylene glycol, respectively). Such methods have been previously used to synthesize AuPd clusters from Pd seed clusters. TEM micrographs confirm that initial seed cluster sizes increase monotonically with increasing Au3+ or Pt4+ content, with final bimetallic cluster dispersity values near unity indicating a narrow size distribution. UV visible spectroscopy of AuPt cluster suspensions show no plasmon resonance features characteristic of Au nano-sized surfaces, indicating the presence of Pt atoms at bimetallic surfaces, as expected for GDR processes. Elemental analysis by EDS confirmed the formation of strictly bimetallic particles with the mean composition of the synthesis mixture. The GDR model requires that bimetallic growth be proportional to the initial seed surface area, with the number of precursor atoms deposited per surface metal atom of the seed constant and independent of seed metal size. Elemental analysis using EDS supports this hypothesis for thermodynamically favorable alloys such as PtPd and AuPd, but not for AuPt, an unfavorable alloy. These differences appear to reflect the segregation of metals within AuPt clusters during synthesis, placing the metal with the lower surface energy, Au, at cluster surfaces, and decreasing the availability of Pt0 surface atoms for GDR. Consequently, autocatalytic Au3+ reduction on Au0 sites becomes a competitive Au3+ reduction pathway during the synthesis of AuPt clusters. Polymers such as polyvinylpyrrolidone (PVP)--which bind to metal surfaces during synthesis via charge-transfer interactions--were required in colloidal suspensions to prevent particle agglomeration in solution, but must be removed prior to catalysis. We show that after depositing clusters on SiO2, PVP can be removed from particle surfaces by post-synthetic treatments at mild temperatures (d"423 K) in reductants such as H2 and/or EtOH without significant particle agglomerations. Reductants compete with the polymer at the metal surface, thus breaking the polymer-metal bond. The absence of surface residues was confirmed by the similar cluster sizes derived from O2 chemisorption and TEM measurements. Larger cluster sizes and surfaces that chemisorb oxygen more weakly--such as Pt relative to Pd--were found to facilitate the removal of PVP from metal particles due to weaker metal-polymer bonds. The model catalytic materials prepared in this study are of both fundamental and practical interest to probe the effects of alloying. Using AuPd and AuPt, we investigate the consequences of alloying with Au on the reactivity of catalyst surfaces saturated with either chemisorbed CO* (CO oxidation) or O* (H2 oxidation) that bind strongly to Pt and Pd surfaces and inhibit rates. Singleton Pt-CO* bond energies, reflected in vibrational CO* stretches, were decoupled from dipole-dipole coupling effects using isotopic dilution methods, and were shown to decrease with increasing catalyst Au content. Despite lower CO* binding energies, CO oxidation turnover rates (normalized per metal surface atom) on AuPt catalysts decreased with increasing Au content. These results show that CO oxidation rates depend weakly on CO* binding energy--consistent with the reported structed insensivity of this reaction--and that Au acts primarily as an inert diluent of the active Pt ensembles required for catalysis. In contrast, H2 oxidation turnover rates (normalized per metal surface atom) on AuPt and AuPd catalysts increase with increasing Au content (up to 11 % at. Au content on AuPt and up to 67 % at. Au content on AuPd), indicating that the reactivity of O* saturated surfaces is more sensitive to changes in adsorbate binding energy than surfaces saturated in CO*, consisted with the reported structure sensitivity of reactions on O* saturated surfaces. Reconstruction of CO* adlayers is facile due to highly mobile CO* molecules, thus allowing CO* adlayers to access configurations that help mitigate strong CO* binding and introduce vacancies. O* adlayers, meanwhile, are more strongly bound to Pt and Pd metal surfaces and less mobile. H2 oxidation rates thus depend more strongly on adsorbate binding energy than CO oxidation rates.

Book Nanomaterials for Direct Alcohol Fuel Cells

Download or read book Nanomaterials for Direct Alcohol Fuel Cells written by Fatih Şen and published by Elsevier. This book was released on 2021-08-25 with total page 556 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nanomaterials for Direct Alcohol Fuel Cells explains nanomaterials and nanocomposites as well as the characterization, manufacturing, and design of alcohol fuel cell applications. The advantages of direct alcohol fuel cells (DAFCs) are significant for reliable and long-lasting portable power sources used in devices such as mobile phones and computers. Even though substantial improvements have been made in DAFC systems over the last decade, more effort is needed to commercialize DAFCs by producing durable, low-cost, and smaller-sized devices. Nanomaterials have an important role to play in achieving this aim. The use of nanotechnology in DAFCs is vital due to their role in the synthesis of nanocatalysts within the manufacturing process. Lately, nanocatalysts containing carbon such as graphene, carbon nanotubes, and carbon nanocoils have also attracted much attention. When compared to traditional materials, carbon-based materials have unique advantages, such as high corrosion resistance, better electrical conductivity, and less catalyst poisoning. This book also covers different aspects of nanocomposites fabrication, including their preparation, design, and characterization techniques for their fuel cell applications. This book is an important reference source for materials scientists, engineers, energy scientists, and electrochemists who are seeking to improve their understanding of how nanomaterials are being used to enhance the efficiency and lower the cost of DAFCs. - Shows how nanomaterials are being used for the design and manufacture of DAFCs - Explores how nanotechnology is being used to enhance the synthesis and catalysis processes to create the next generation of fuel cells - Assesses the major challenges of producing nanomaterial-based DAFCs on an industrial scale

Book Carbon based Composites and Nanocomposites

Download or read book Carbon based Composites and Nanocomposites written by Jeyaseelan Aravind and published by Walter de Gruyter GmbH & Co KG. This book was released on 2024-08-06 with total page 220 pages. Available in PDF, EPUB and Kindle. Book excerpt: Explore the dynamic world of carbon-based composites and nanocomposites, where innovation intersects with environmental consciousness. This expansive volume delves into the multifaceted role of carbon composites in combating pollution, from the versatility of activated carbon in adsorbing emerging contaminants to the strategic application of carbon-polymer composites for environmental challenges. Discover the effectiveness of activated carbon in adsorbing emerging contaminants and the strategic use of carbon-polymer composites in addressing environmental challenges. Gain insights into the transformative potential of biochar and the synergistic interplay of carbon and metal nanoparticle composites, carbon nanotubes, and nano-fibers in water purification and sustainable environmental applications.

Book Sustainable Polymer Composites and Nanocomposites

Download or read book Sustainable Polymer Composites and Nanocomposites written by Inamuddin and published by Springer. This book was released on 2019-02-01 with total page 1424 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents emerging economical and environmentally friendly polymer composites that are free of the side effects observed in traditional composites. It focuses on eco-friendly composite materials using granulated cork, a by-product of the cork industry; cellulose pulp from the recycling of paper residues; hemp fibers; and a range of other environmentally friendly materials procured from various sources. The book presents the manufacturing methods, properties and characterization techniques of these eco-friendly composites. The respective chapters address classical and recent aspects of eco-friendly polymer composites and their chemistry, along with practical applications in the biomedical, pharmaceutical, automotive and other sectors. Topics addressed include the fundamentals, processing, properties, practicality, drawbacks and advantages of eco-friendly polymer composites. Featuring contributions by experts in the field with a variety of backgrounds and specialties, the book will appeal to researchers and students in the fields of materials science and environmental science. Moreover, it fills the gap between research work in the laboratory and practical applications in related industries.

Book Nanocatalysts

    Book Details:
  • Author : Indrajit Sinha
  • Publisher : BoD – Books on Demand
  • Release : 2019-07-31
  • ISBN : 1789841593
  • Pages : 170 pages

Download or read book Nanocatalysts written by Indrajit Sinha and published by BoD – Books on Demand. This book was released on 2019-07-31 with total page 170 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nanocatalysis is a topical area of research that has huge potential. It attempts to merge the advantages of heterogeneous and homogeneous catalysis. The collection of articles in this book treats the topics of specificity, activity, reusability, and stability of the catalyst and presents a compilation of articles that focuses on different aspects of these issues.

Book Nanoalloys

Download or read book Nanoalloys written by Florent Calvo and published by Newnes. This book was released on 2013-03-12 with total page 433 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nanoalloys: From Fundamentals to Emergent Applications presents and discusses the major topics related to nanoalloys at a time when the literature on the subject remains scarce. Particular attention is paid to experimental and theoretical aspects under the form of broad reviews covering the most recent developments. The book is organized into 11 chapters covering the most fundamental aspects of nanoalloys related to their synthesis and characterization, as well as their theoretical study. Aspects related to their thermodynamics and kinetics are covered as well. The coverage then moves to more specific topics, including optics, magnetism and catalysis, and finally to biomedical applications and the technologically relevant issue of self-assembly.With no current single reference source on the subject, the work is invaluable for researchers as the nanoscience field moves swiftly to full monetization. - Encapsulates physical science of structure, properties, size, composition and ordering at nanoscale, aiding synthesis of experimentation and modelling - Multi-expert and interdisciplinary perspectives on growth, synthesis and characterization of bimetallic clusters and particulates supports expansion of your current research activity into applications - Synthesizes concepts and draws links between fundamental metallurgy and cutting edge nanoscience, aiding interdisciplinary research activity

Book Nanoparticles in Catalysis

Download or read book Nanoparticles in Catalysis written by Karine Philippot and published by John Wiley & Sons. This book was released on 2021-06-28 with total page 384 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nanoparticles in Catalysis Discover an essential overview of recent advances and trends in nanoparticle catalysis Catalysis in the presence of metal nanoparticles is an important and rapidly developing research field at the frontier of homogeneous and heterogeneous catalysis. In Nanoparticles in Catalysis, accomplished chemists and authors Karine Philippot and Alain Roucoux deliver a comprehensive guide to the key aspects of nanoparticle catalysis, ranging from synthesis, activation methodology, characterization, and theoretical modeling, to application in important catalytic reactions, like hydrogen production and biomass conversion. The book offers readers a review of modern and efficient tools for the synthesis of nanoparticles in solution or onto supports. It emphasizes the application of metal nanoparticles in important catalytic reactions and includes chapters on activation methodology and supported nanoclusters. Written by an international team of leading voices in the field, Nanoparticles in Catalysis is an indispensable resource for researchers and professionals in academia and industry alike. Readers will also benefit from the inclusion of: A thorough introduction to New Trends in the Design of Metal Nanoparticles and Derived Nanomaterials for Catalysis An exploration of Dynamic Catalysis and the Interface Between Molecular and Heterogeneous Catalysts A practical discussion of Metal Nanoparticles in Water: A Relevant Toolbox for Green Catalysis Organometallic Metal Nanoparticles for Catalysis A concise treatment of the opportunities and challenges of CO2 Hydrogenation to Oxygenated Chemicals Over Supported Nanoparticle Catalysts Perfect for catalytic, organic, inorganic, and physical chemists, Nanoparticles in Catalysis will also earn a place in the libraries of chemists working with organometallics and materials scientists seeking a one-stop resource with expert knowledge on the synthesis and characterization of nanoparticle catalysis.

Book Nano and Bio Based Technologies for Wastewater Treatment

Download or read book Nano and Bio Based Technologies for Wastewater Treatment written by Elvis Fosso-Kankeu and published by John Wiley & Sons. This book was released on 2019-05-21 with total page 382 pages. Available in PDF, EPUB and Kindle. Book excerpt: Presents recent challenges related to new forms of pollution from industries and discusses adequate state-of-the-art technologies capable to remediate such forms of pollution. Over the past few decades the boom in the industrial sector has contributed to the release in the environment of pollutants that have no regulatory status and which may have significant impact on the health of humans and animals. These pollutants also referred to as "emerging pollutants", are mostly aromatic compounds which derive from excretion of pharmaceutical, industrial effluents and municipal discharge. It is recurrent these days to find water treatment plants which no longer produce water that fits the purpose of domestic consumption based on newly established guidelines. This situation has prompted water authorities and researchers to develop tools for proper prediction and control of the dispersion of pollutants in the environment to ensure that appropriate measures are taken to prevent the occurrence of outbreaks due to sudden load of these pollutants in the water system. The chapters in this book cover a wide range of nano and bio-based techniques that have been designed for the real time detection of emerging contaminants in environmental water sources, geochemical models that are continuously improved for the prediction of inorganic contaminants migration from the mine solid wastes into ground and surface waters. Remediation strategies are also discussed and include effective techniques based on nanotechnology, advanced membrane filtration, oxidative and bio-degradation processes using various types of nanocatalysts, biocatalysts or supporting polymer matrices which are under advanced investigations for their implementation at large scale for the removal of recalcitrant pollutants from polluted water. Nano and Bio-Based Technologies for Wastewater Treatment: Prediction and Control Tools for the Dispersion of Pollutants in the Environment is divided is two sections. The first section covers the occurrence of emerging pollutants in environmental water while the second section covers state-of-the-art research on the removal of emerging pollutants from water using sustainable technologies. A total of 13 chapters addressing various topics related to the two sections are essentially based on recent developments in the respective field which could have a significant impact on the enhancement of the performance of wastewater treatment plants around the world, and especially in developing countries where access to clean and safe water remains a daily challenge.

Book Synthesis of Carbon Nanotube supported Catalytic Nanoparticles and Their Applications in Catalysis

Download or read book Synthesis of Carbon Nanotube supported Catalytic Nanoparticles and Their Applications in Catalysis written by Horng-Bin Pan and published by . This book was released on 2011 with total page 338 pages. Available in PDF, EPUB and Kindle. Book excerpt: Fine Rh nanoparticles can be deposited uniformly on surfaces of carboxylate functionalized MWNTs using the one-pot sonochemical method. The CNT-supported Rh nanoparticles show remarkably high catalytic active and are reusable for hydrogenation of arenes at room temperature. Complete ring saturation of polycyclic aromatic hydrocarbons (PAHs) can be achieved under mild hydrogenation conditions using the MWNTs catalyst that can not be done by commercially available Rh nanocatalysts (Rh- Escat 3401 ). This technique also provides a simple and rapid way of making Rh nanoparticles of different size, which allows us to study particle size effects on catalysis. Furthermore, we extended the sonochemical method to synthesize well-dispersed Pt-Rh alloy bimetallic nanoparticles on sidewalls of CNTs and studied the potentially improved activity (synergistic effect) for room temperature catalytic hydrogenation of neat benzene, neat alkylbenzenes, and PAHs.

Book Plasma Syntheses of Carbon Nanotube Supported Pt Pd Nanoparticles supported by National Natural Science Foundation of China  Nos  11305218  11575253   the Youth Innovation Promotion Association of the Chinese Academy of Sciences  No  2015262   the CASHIPS Director s Fund  No  YZJJ201505  and Anhui Provincial Natural Science Foundation for Distinguished Young Scholars of China  No  1608085J03

Download or read book Plasma Syntheses of Carbon Nanotube Supported Pt Pd Nanoparticles supported by National Natural Science Foundation of China Nos 11305218 11575253 the Youth Innovation Promotion Association of the Chinese Academy of Sciences No 2015262 the CASHIPS Director s Fund No YZJJ201505 and Anhui Provincial Natural Science Foundation for Distinguished Young Scholars of China No 1608085J03 written by and published by . This book was released on 2016 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Abstract: It is reported that the highly dispersed Pt nanoparticles on carbon nanotubes can be synthesized under mild conditions by in situ plasma treatment. The carbon nanotube was pretreated by O2 plasma to transform into oxide carbon nanotubes (O-CNTs), and then it was mixed with the precursors (the mixture of H2 PtCl6 and PdCl6 ). After that, the O-CNTs and the precursors were simultaneously treated by H2 plasma. The precursors were transformed into Pt-Pd nanoparticles (NPs) and the O-CNTs transformed into CNT. The synthesized CNT-based Pt-Pd nanoparticles were characterized by scanning electron microscopy, transmission electron microscopy, X-ray diffraction and X-ray photoelectron spectroscopy. All the analysis showed that the Pt-Pd nanoparticles were deposited on CNT as a form of face-centered cubical structure.

Book Synthesis and Characterization of Carbon Nanotube Supported Platinum and Titanium Dioxide Nanoparticles

Download or read book Synthesis and Characterization of Carbon Nanotube Supported Platinum and Titanium Dioxide Nanoparticles written by Qianqian Liu and published by . This book was released on 2011 with total page 122 pages. Available in PDF, EPUB and Kindle. Book excerpt: Platinum (Pt) supported on single-walled carbon nanotube (SWCNT) is one of the most efficient catalysts for methanol electroxidation. However, there is lack of a facile and environmental method to synthesize Pt nanoparticles on SWCNT. In the first section, I investigated a novel method to synthesize Pt nanoparticles on SWCNT using DNA molecules as dispersing agent for nanotube uniformly suspended in aqueous solutions and templates for the synthesis of Pt nanoparticles. The morphology of DNA molecules and Pt nanoparticles and their distributions along SWCNT were studied with the use of a number of electron microscopy and microanalysis techniques; electrocatalytic activities of Pt nanoparticles for methanol oxidations were characterized using cyclic voltammetry and A.C. impedance spectroscopy; and interactions among SWCNT, DNA molecules, and Pt nanoparticles were characterized by UV-visible spectroscopy. As a result, I found DNA molecules affect the synthesis of Pt nanoparticles around SWCNT and electrocatalytic activity of Pt nanoparticles supported on SWCNT for methanol oxidations. In the second section, I investigated two approaches for synthesizing carbon nanotube (CNT) coated with TiO2 nanoparticles for solar cell applications. One method used titanium sulfate (Ti (SO4)2) as a reaction precursor, and a second method employed titanium isopropoxide (Ti (OCH (CH3)2)4) as a reaction precursor. My experimental results indicate that without surface functionalization of CNT, nanotube coated with sensitizing TiO2 nanoparticles could be obtained through the selection of desirable precursors and reaction parameters-using Ti (OCH (CH3)2)4 as a reaction precursor.

Book Controlled Synthesis of Pt Ni Bimetallic Catalysts and Study of Their Catalytic Properties

Download or read book Controlled Synthesis of Pt Ni Bimetallic Catalysts and Study of Their Catalytic Properties written by Yuen Wu and published by Springer. This book was released on 2016-05-14 with total page 119 pages. Available in PDF, EPUB and Kindle. Book excerpt: This thesis focuses on the controlled synthesis of Pt–Ni bimetallic nanoparticles and the study of their catalytic properties. It discusses in detail the nucleation mechanism and the growth process of bimetallic systems, which is vital for a deeper understanding of the design of bimetallic catalysts. The author presents four pioneering studies: (1) syntheses of water-soluble octahedral, truncated octahedral, and cubic Pt–Ni nanocrystals and the study of their structure-activity relationship in model hydrogenation reactions; (2) a strategy for designing a concave Pt–Ni alloy using controllable chemical etching; (3) defect-dominated shape recovery of nanocrystals, which is a new synthesis strategy for trimetallic catalysts; (4) a sophisticated construction of Au islands on Pt−Ni, which is an ideal trimetallic nanoframe catalyst. This thesis inspires researchers working in materials, catalysis as well as other interdisciplinary areas.

Book Handbook of Nanoelectrochemistry

Download or read book Handbook of Nanoelectrochemistry written by Mahmood Aliofkhazraei and published by Springer. This book was released on 2015-11-03 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: This edited book is devoted to different electrochemical aspects of nano materials. This comprehensive reference text is basically divided in 3 parts: electrochemical synthesis routes for nanosized materials, electrochemical properties of nano materials and electrochemical characterization methods for nanostructures. The Handbook is a reference work to chemists and materials scientists interested in the nano aspects of electrochemistry. The chapters are written by a number of international experts in the field and the content will assist members of both electrochemical and materials communities to keep abreast of developments in the field.