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Book Synthesis and Structure of Platinum and Palladium Tertiary Phosphine Complexes

Download or read book Synthesis and Structure of Platinum and Palladium Tertiary Phosphine Complexes written by Matthew D. Sargent and published by . This book was released on 1997 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Synthesis and Reactivity of Nickel Palladium and Platinum Phosphine Complexes with Hydridoamido Hydridophenoxo and Dithiooxalato Ligands

Download or read book Synthesis and Reactivity of Nickel Palladium and Platinum Phosphine Complexes with Hydridoamido Hydridophenoxo and Dithiooxalato Ligands written by Robert L. Cowan and published by . This book was released on 1989 with total page 358 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Tertiary Phosphine Complexes of Platinum ii and Palladium ii

Download or read book Tertiary Phosphine Complexes of Platinum ii and Palladium ii written by Richard Lee Keiter and published by . This book was released on 1967 with total page 212 pages. Available in PDF, EPUB and Kindle. Book excerpt: The results are reported of research which was undertaken (1) to determine the chemical shifts of cis and trans isomers of platinum(II) complexes in hope of gaining information about pi-bonding in the Pt-P bond, and to extend this study to palladium(II); (2) to determine trends which may exist within a series of ligands for the purpose of developing expressions that would enable calculation of chemical shifts for complexes; (3) to expand the knowledge of the chemistry of tertiary phosphine complexes of platinum(II) and palladium(II); and (4) to determine phosphorus-phosphorus coupling constants by preparing a complex of a chelating diphosphine (R2PCH2CH2PR'2) or by preparing a complex containing two different phosphines.

Book The Synthesis of Four Palladium II Tertiary Phosphine Complexes

Download or read book The Synthesis of Four Palladium II Tertiary Phosphine Complexes written by Michael Orchowski and published by . This book was released on 2000 with total page 60 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Proton and Phosphorus 31 NMR Studies of Tertiary Phosphine Complexes of Palladium and Platinum

Download or read book Proton and Phosphorus 31 NMR Studies of Tertiary Phosphine Complexes of Palladium and Platinum written by Catherine T. Hunt and published by . This book was released on 1981 with total page 380 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Design and Synthesis of Metal Phosphine Complexes of Palladium ii and Gold i with Various Receptor Ligands for Ion Controlled Or Photoresponsive Host Guest Chemistry

Download or read book Design and Synthesis of Metal Phosphine Complexes of Palladium ii and Gold i with Various Receptor Ligands for Ion Controlled Or Photoresponsive Host Guest Chemistry written by Hau-San Tang and published by Open Dissertation Press. This book was released on 2017-01-27 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: This dissertation, "Design and Synthesis of Metal Phosphine Complexes of Palladium(II) and Gold(I) With Various Receptor Ligands for Ion-controlled or Photoresponsive Host-guest Chemistry" by Hau-san, Tang, 鄧巧珊, was obtained from The University of Hong Kong (Pokfulam, Hong Kong) and is being sold pursuant to Creative Commons: Attribution 3.0 Hong Kong License. The content of this dissertation has not been altered in any way. We have altered the formatting in order to facilitate the ease of printing and reading of the dissertation. All rights not granted by the above license are retained by the author. Abstract: Abstract of thesis entitled DESIGN AND SYNTHESIS OF METAL PHOSPHINE COMPLEXES OF PALLADIUM(II) AND GOLD(I) WITH VARIOUS RECEPTOR LIGANDS FOR ION-CONTROLLED OR PHOTORESPONSIVE HOST-GUEST CHEMISTRY Submitted by Tang Hau San for the Degree of Doctor of Philosophy at The University of Hong Kong in August 2006 A series of palladium(II) phosphine complexes containing different receptor sites, [Pd(PPh R) Cl] [R = C H NHCOCH, C H N(CH )COCH, 2 2 2 6 4 3 6 4 3 3 C HNHCONHPh, C HNHCOPyr and C H NHCO(CH )Pyr] have been 6 4 6 4 6 4 2 3 prepared. Two X-ray crystal structures have been determined, in which one of the crystal structures showed hydrogen bonding interactions between the amide protons and the Cl ions with distances of ca. 2.466 A. The photophysical properties of these complexes have been studied and their emission origins were elucidated. The binding properties of the complexes towards anions have 1 31 been studied by H NMR, P NMR, UV-vis and emission spectrophotometry, in which drastic changes in the ratio of trans to cis isomers upon addition of 31 anions were observed in the P NMR titration studies. The present ion-induced conformational change involving a trans-cis isomerization of the square-planar palladium(II) complex via the binding of anions to amide or urea functionalities through hydrogen bonding interactions represents a new class of ion-controlled switching devices based on transition metal systems. A series of gold(I) alkynyl phosphine complexes containing azobenzene or stilbene functionalities, [{Au(PPh )} (C≡C-L-C≡C)] and [Au (P DEGREESP) (C≡C-L- 3 2 4 2 C≡C) ] [L = C H -N=N-C H or C H -CH=CH-C H; P DEGREESP = dppm, dcpm, 2 6 4 6 4 6 4 6 4 Ph PN(C H F-p)PPh, Ph PN( Pr)PPh, Ph PN(C H )PPh] have been 2 6 4 2 2 2 2 14 29 2 synthesized and characterized. The X-ray crystal structure of [Au (dppm) (C≡C- 4 2 L-C≡C) ] revealed that the two azobenzene ligands in the tetranuclear complex adopted a trans disposition with the presence of short intramolecular Au Au contacts. The azobenzene-containing gold(I) complexes showed emissions both in dichloromethane solution at room temperature and in 77 K glass, which were assigned as a metal-perturbed intraligand (IL) origin mainly derived from the π-π*(C≡C) states with some mixing of a π-π* character of the azo unit. On the other hand, the emissive origin of the stilbene-containing gold(I) complexes was assigned as derived from the π-π* excited state of the stilbene moiety with some mixing of the alkynyl units, and probably mixed with σ(Au-P) → π*(C≡C) excited state in the solid states. The photoisomerization properties of the dinuclear and tetranuclear complexes have been studied, in which a tetranuclear macrocyclic gold(I) alkynyl phosphine complex was demonstrated to function as a dual input molecular logic with photoswitching behaviour that could be controlled by addition or removal of silver(I). In addition, several gold(I) complexes with different crown ether pendants including the mercapto-azacrown ether-containing complexes, [Au (P DEGREESP)(S-A15C5) ] [P DEGREESP = dppm, dcpm] and the mononuclear gold(I) alkynyl 2 2 complexes, [Au(PPh )(C≡CR)] [R = B15C5, B15S5], and dinuclear gold(I) complexes with oligo(ethylene oxide) linkages, [{(Ph P)

Book Higher Oxidation State Organopalladium and Platinum Chemistry

Download or read book Higher Oxidation State Organopalladium and Platinum Chemistry written by Allan J. Canty and published by Springer. This book was released on 2011-02-25 with total page 195 pages. Available in PDF, EPUB and Kindle. Book excerpt: Kyle A. Grice, Margaret L. Scheuermann and Karen I. Goldberg: Five-Coordinate Platinum(IV) Complexes.- Jay A. Labinger and John E. Bercaw: The Role of Higher Oxidation State Species in Platinum-Mediated C-H Bond Activation and Functionalization.- Joy M. Racowski and Melanie S. Sanford: Carbon-Heteroatom Bond-Forming Reductive Elimination from Palladium(IV) Complexes.- Helena C. Malinakova: Palladium(IV) Complexes as Intermediates in Catalytic and Stoichiometric Cascade Sequences Providing Complex Carbocycles and Heterocycles.- Allan J. Canty and Manab Sharma: h1-Alkynyl Chemistry for the Higher Oxidation States of Palladium and Platinum.- David C. Powers and Tobias Ritter: Palladium(III) in Synthesis and Catalysis.- Marc-Etienne Moret: Organometallic Platinum(II) and Palladium(II) Complexes as Donor Ligands for Lewis-Acidic d10 and s2 Centers.

Book The Synthesis and Chemistry of Platinum II Hydroxo and Hydroxycarbonyl Complexes Containing Tertiary Phosphine Ligands

Download or read book The Synthesis and Chemistry of Platinum II Hydroxo and Hydroxycarbonyl Complexes Containing Tertiary Phosphine Ligands written by Jin Hong and published by . This book was released on 1990 with total page 436 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Synthesis and Characterisation of Ortho metallated Platinum Complexes Containing Tertiary Phosphine and Arsine Donor Ligands

Download or read book Synthesis and Characterisation of Ortho metallated Platinum Complexes Containing Tertiary Phosphine and Arsine Donor Ligands written by Steven H. Privér and published by . This book was released on 2004 with total page 424 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Hybrid Tertiary Phosphine secondary Amide and Amine Ligands

Download or read book Hybrid Tertiary Phosphine secondary Amide and Amine Ligands written by David Hedden and published by . This book was released on 1985 with total page 330 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Synthesis and Testing of Palladium and Platinum Phosphine Complexes with Potential Mitochondrial Targeting Anti cancer Properties

Download or read book Synthesis and Testing of Palladium and Platinum Phosphine Complexes with Potential Mitochondrial Targeting Anti cancer Properties written by Patricia Wanjiru Gitari and published by . This book was released on 2007 with total page 432 pages. Available in PDF, EPUB and Kindle. Book excerpt: