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Book Synthesis and Spectroscopic Investigation on Thiophene Containing Monomers and Polymers

Download or read book Synthesis and Spectroscopic Investigation on Thiophene Containing Monomers and Polymers written by Kobkul Sudsuansri and published by . This book was released on 1991 with total page 266 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Sulfur Containing Polymers

Download or read book Sulfur Containing Polymers written by Xing-Hong Zhang and published by John Wiley & Sons. This book was released on 2021-03-23 with total page 482 pages. Available in PDF, EPUB and Kindle. Book excerpt: A must-have resource to the booming field of sulfur-containing polymers Sulfur-Containing Polymers is a state-of-the-art text that offers a synthesis of the various sulfur-containing polymers from low-cost sulfur resources such as elemental sulfur, carbon disulfide (CS2), carbonyl sulfide (COS) and mercaptan. With contributions from noted experts on the topic, the book presents an in-depth understanding of the mechanisms related to the synthesis of sulfur-containing polymers. The book also includes a review of the various types of sulfur-containing polymers, such as: poly(thioester)s, poly(thioether)s and poly(thiocarbonate)s and poly(thiourethane)s with linear or hyperbranched (dendrimer) architectures. The expert authors provide the fundamentals on the structure-property relationship and applications of sulfur-containing polymers. Designed to be beneficial for both research and application-oriented chemists and engineers, the book contains the most recent research and developments of sulfur-containing polymers. This important book: Offers the first comprehensive handbook on the topic Contains state-of-the-art research on synthesis of sulfur containing polymers from low-cost sulfur-containing compounds Examines the synthesis, mechanism, structure properties, and applications of various types of sulful-containing polymers Includes contributions from well-known experts Written for polymer chemists, materials scientists, chemists in industry, biochemists, and chemical engineers, Sulfur-Containing Polymers offers a groundbreaking text to the field with inforamtion on the most recent research.

Book Synthesis and Characterization of Polythiophene Derivatives

Download or read book Synthesis and Characterization of Polythiophene Derivatives written by Xin Chen and published by ProQuest. This book was released on 2007 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: In Chapter 1, the history of conducting polymers, especially polythiophene and its derivatives, was briefly reviewed. Different approaches of structural modifications to afford small bandgap polythiophene derivatives were discussed. The emergence of metal-containing polymers (metallopolymers) as functional materials has attracted tremendous attention around the world. Introduction of metals into thiophene-based oligomers and polymers, whether the backbone or the side chain of the pi-conjugated framework, the electronic, optical, or magnetic properties of the material are expected to be significantly affected by metals through various mechanisms. Synthesis methods to prepare poly(thienylene vinylene) were also briefly reviewed in this chapter. In Chapter 2, the motivations and objectives were briefly discussed. Two structurally similar compounds, thieno[3,4-d]-1,3-dithiole-2-thione and thieno[3,4-d]-1,3-dithiol-2-one are the starting point of this project due to their unique carbondithiolate structures, which may lead to metal-dithiolate coordinated oligomers or/and polymers, or polymers crosslinked by DTTTF units. For the preparation of monomers, six types of reactions were systematically studied with focus on thieno[3,4-d]-1,3-dithiol-2-one to prepare different direvatives. Different halogenated compounds, Mannich bases, chloromethylated compounds, a number of nucleophilic substituted derivatives and a DTTTF analogue from chloromethylated compounds were successful synthesized. All products were fully characterized through 1H and 13C-NMR, FT-IR, ESI-TOF high resolution mass spectroscopy. The halogenated products were prepared through halogensuccinimides or other halogenation reagents such as Br2, I2. These halogenated compounds may be candidates to prepare homopolymer and/or copolymers bearing carbondithiolate structures by cross-coupling reactions. 4,6-Bis(chloromethyl) thieno[3,4- d]-1,3-dithiol-2-one and its nucleophilic derivatives may be good monomers for the two-step precursor polymerization to achieve fully conjugated poly(thienylene vinylene) derivatives and even metallopolymers with metal-dithiolate coordinations. Attempted polymerization reactions to homopolymers and copolymers through directly C-C coupling, such as transitional metal catalyzed cross-coupling, Stille reaction, and Ullman reaction, et al. were discussed in the beginning of Chapter 3. Base-promoted and acid-promoted polymerizations were attempted to afford soluble precursor polymers with carbondithiolate structures. However, all the symmetrical thiophene derivatives did not successfully yield processable precursor polymers; asymmetrical monomers generated some possibilities for future study. Synthesis of thiophene-based oligomers, such as dimmers (dithienyl compounds), trimers (trithienyl compounds), and heptamers were also explored in chapter 3, followed by preparation of thiophene-based copolymers through Wittig-Horner reactions. Properties of oligomers, especially trimers were well characterized by NMR, FT-IR, and ESI-TOF. Several conjugated DTTTF derivatives from trimers were prepared by the triethyl phosphite cross-coupling method. These conjugated DTTTF compounds posses some unique properties. They are stable in solid forms, but may be doped in solution forms. The copolymers were characterized by elemental analysis, and FT-IR. UV-Vis spectra of copolymers show their bandgap values are aroud 1.87eV (UV edge calculation). In the Experimental chapter, all reaction conditions of preparation of new annulated thiophene derivatives and oligomers were documented in details. Physical and spectroscopic properties of these new compounds were also presented in this chapter. Key words. polythiophene, oligomer, conjugation, synthesis, characterization, DTTTF, metallopolymer.

Book ACS Directory of Graduate Research 1993

Download or read book ACS Directory of Graduate Research 1993 written by American Chemical Society. Committee on Professional Training and published by . This book was released on 1993 with total page 1700 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Dissertation Abstracts International

Download or read book Dissertation Abstracts International written by and published by . This book was released on 2008 with total page 994 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Scientific and Technical Aerospace Reports

Download or read book Scientific and Technical Aerospace Reports written by and published by . This book was released on 1992 with total page 1572 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Synthesis of Thiophene containing Oligomers and Polymers

Download or read book Synthesis of Thiophene containing Oligomers and Polymers written by James Paul Parakka and published by . This book was released on 1995 with total page 318 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Sulfur Compounds   Advances in Research and Application  2013 Edition

Download or read book Sulfur Compounds Advances in Research and Application 2013 Edition written by and published by ScholarlyEditions. This book was released on 2013-06-21 with total page 701 pages. Available in PDF, EPUB and Kindle. Book excerpt: Sulfur Compounds—Advances in Research and Application: 2013 Edition is a ScholarlyEditions™ book that delivers timely, authoritative, and comprehensive information about Hydrogen Sulfide. The editors have built Sulfur Compounds—Advances in Research and Application: 2013 Edition on the vast information databases of ScholarlyNews.™ You can expect the information about Hydrogen Sulfide in this book to be deeper than what you can access anywhere else, as well as consistently reliable, authoritative, informed, and relevant. The content of Sulfur Compounds—Advances in Research and Application: 2013 Edition has been produced by the world’s leading scientists, engineers, analysts, research institutions, and companies. All of the content is from peer-reviewed sources, and all of it is written, assembled, and edited by the editors at ScholarlyEditions™ and available exclusively from us. You now have a source you can cite with authority, confidence, and credibility. More information is available at http://www.ScholarlyEditions.com/.

Book Handbook of Thiophene Based Materials

Download or read book Handbook of Thiophene Based Materials written by Igor F. Perepichka and published by John Wiley & Sons. This book was released on 2009-07-17 with total page 910 pages. Available in PDF, EPUB and Kindle. Book excerpt: This essential resource consists of a series of critical reviews written by leading scientists, summarising the progress in the field of conjugated thiophene materials. It is an application-oriented book, giving a chemists’ point of view on the state-of-art and perspectives of the field. While presenting a comprehensive coverage of thiophene-based materials and related applications, the aim is to show how the rational molecular design of materials can bring a new breadth to known device applications or even aid the development of novel application concepts. The main topics covered include synthetic methodologies to thiophene-based materials (including the chemistry of thiophene, preparation of oligomers and polymerisation approaches) and the structure and physical properties of oligo- and polythiophenes (discussion of structural effects on electronic and optical properties). Part of the book is devoted to the optical and semiconducting properties of conjugated thiophene materials for electronics and photonics, and the role of thiophene-based materials in nanotechnology.

Book Textile Technology Digest

Download or read book Textile Technology Digest written by and published by . This book was released on 2002 with total page 752 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book American Doctoral Dissertations

Download or read book American Doctoral Dissertations written by and published by . This book was released on 2002 with total page 776 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Polymer Synthesis

Download or read book Polymer Synthesis written by and published by Springer Science & Business Media. This book was released on 2004-10-08 with total page 228 pages. Available in PDF, EPUB and Kindle. Book excerpt: 1. T. Takata, N. Kihara, Y. Furusho: Polyrotaxanes and Polycatenanes: Recent Advances in Syntheses and Applications of Polymers Comprising of Interlocked Structures.- 2. M. Suginome, Y. Ito: Transition Metal-Mediated Polymerization of Isocyanides.- 3. K. Osakada, D. Takeuchi: Coordination Polymerization of Dienes, Allenes and Methylenecycloalkanes.

Book Handbook of Conducting Polymers  2 Volume Set

Download or read book Handbook of Conducting Polymers 2 Volume Set written by Terje A. Skotheim and published by CRC Press. This book was released on 2007-01-16 with total page 1692 pages. Available in PDF, EPUB and Kindle. Book excerpt: Learn how recent advances are fueling new possibilities in textiles, optics, electronics, and biomedicine! As the field of conjugated, electrically conducting, and electroactive polymers has grown, the Handbook of Conducting Polymers has been there to document and celebrate these changes along the way. Now split into two vo

Book Handbook of Advanced Electronic and Photonic Materials and Devices  Ten Volume Set

Download or read book Handbook of Advanced Electronic and Photonic Materials and Devices Ten Volume Set written by Hari Singh Nalwa and published by Academic Press. This book was released on 2000-10-09 with total page 383 pages. Available in PDF, EPUB and Kindle. Book excerpt: Vol. 1: Semiconductors;Vol. 2: Semiconductors Devices;Vol. 3: High-Tc Superconductors and Organic Conductors; Vol. 4: Ferroelectrics and Dielectrics; Vol. 5: Chalcogenide Glasses and Sol-Gel Materials; Vol. 6 Nanostructured Materials; Vol. 7: Liquid Crystals, Display and Laser Materials; Vol. 8: Conducting Polymers; Vol. 9: Nonlinear Optical Materials; Volume 10: Light-Emitting Diodes, Lithium Batteries and Polymer Devices

Book Conjugated Polymers

Download or read book Conjugated Polymers written by Terje A. Skotheim and published by CRC Press. This book was released on 2006-12-26 with total page 1030 pages. Available in PDF, EPUB and Kindle. Book excerpt: Many significant fundamental concepts and practical applications have developed since the publication of the best-selling second edition of the Handbook of Conducting Polymers. Now divided into two books, the third edition continues to retain the excellent expertise of the editors and world-renowned contributors while providing superior coverage of