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Book Synthesis and Reactivity of Some Tungsten Carbene Complexes

Download or read book Synthesis and Reactivity of Some Tungsten Carbene Complexes written by Ruth A. Pickering and published by . This book was released on 1980 with total page 234 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Synthesis and Reactivity of  alpha    beta  unsaturated Carbene Complexes of Chromium and Tungsten

Download or read book Synthesis and Reactivity of alpha beta unsaturated Carbene Complexes of Chromium and Tungsten written by Puttannachetty Madhukar and published by . This book was released on 1989 with total page 638 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Synthesis  Reactivity  and Structures of Organometallic Complexes Containing Multiple Transition metal Carbene Fragments of Chromium and Tungsten

Download or read book Synthesis Reactivity and Structures of Organometallic Complexes Containing Multiple Transition metal Carbene Fragments of Chromium and Tungsten written by Mu-huang Hung and published by . This book was released on 1989 with total page 294 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book The Synthesis and Reactivity of Tungsten  VI  Alkylidynes and Tungsten  IV  Complexes

Download or read book The Synthesis and Reactivity of Tungsten VI Alkylidynes and Tungsten IV Complexes written by Mark L. Listemann and published by . This book was released on 1985 with total page 342 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book The Synthesis and Reactivity of Tungsten Binaphtholate Complexes

Download or read book The Synthesis and Reactivity of Tungsten Binaphtholate Complexes written by Steven D. Dietz and published by . This book was released on 1992 with total page 298 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Organometallic Chemistry

Download or read book Organometallic Chemistry written by E. W. Abel and published by Royal Society of Chemistry. This book was released on 1983 with total page 570 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organometallic chemistry is an interdisciplinary science which continues to grow at a rapid pace. Although there is continued interest in synthetic and structural studies the last decade has seen a growing interest in the potential of organometallic chemistry to provide answers to problems in catalysis synthetic organic chemistry and also in the development of new materials. This Specialist Periodical Report aims to reflect these current interests reviewing progress in theoretical organometallic chemistry, main group chemistry, the lanthanides and all aspects of transition metal chemistry. Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued. The current list of Specialist Periodical Reports can be seen on the inside flap of this volume.

Book Synthesis and Reactivity of Tungsten  VI  Alkylidene and Metallacyclobutane Complexes

Download or read book Synthesis and Reactivity of Tungsten VI Alkylidene and Metallacyclobutane Complexes written by Jerald Feldman and published by . This book was released on 1989 with total page 384 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book The Synthesis and Reactivity of Methylidyne and Hydride Complexes of Tungsten

Download or read book The Synthesis and Reactivity of Methylidyne and Hydride Complexes of Tungsten written by Steven J. Holmes and published by . This book was released on 1983 with total page 358 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Metal Carbenes in Organic Synthesis

Download or read book Metal Carbenes in Organic Synthesis written by Florencio Zaragoza Dörwald and published by John Wiley & Sons. This book was released on 2008-09-26 with total page 290 pages. Available in PDF, EPUB and Kindle. Book excerpt: There are hardly more versatile compounds in organic synthesis than carbene complexes. The rapid development of new synthetic methods involving carbene complexes - stereoselective cyclopropanation, carbonyl olefination, olefin metathesis, etc. - reveals the value and high potential of these compounds. Their application ranges from the synthesis of fine chemicals to polymer production. This comprehensive, well structured handbook presents the fundamental principles and the recent advances in carbene complex chemistry. Arranged according to structure and reactivity, all relevant classes of carbene complexes, their generation, and application in organic synthesis are discussed in detail. Critically selected, up-to-date references and valuable experimental procedures await the reader. Every chemist searching for a concise introduction and reference work for carbene complex chemistry will welcome this practical guide. "...this concise presentation of all the aspects of the use of carbene complexes in synthesis will help provide the impetus for even more rapid developments in this field of research." R. H. Grubbs (Caltech)

Book Fischer and N heterocyclic Carbene Complexes of Tungsten 0

Download or read book Fischer and N heterocyclic Carbene Complexes of Tungsten 0 written by René Pretorius and published by . This book was released on 2012 with total page 248 pages. Available in PDF, EPUB and Kindle. Book excerpt: The synthesis of novel Fischer and N-heterocyclic tungsten(0) carbene complexes was endeavoured in this study and resulted in the synthesis, isolation and characterisation of eighteen new complexes. Sixteen novel Fischer carbene complexes were synthesised. In these complexes, both carbene ligand substituents were varied. Ethoxy as well as amino heteroatom substituents were used. Heteroaryl compounds thiophene and furan were employed as the second substituents on the carbene ligand. Complexes with combinations of these different substituents were synthesised and investigated to assess the influence the various substituents of the carbene ligand may have on the carbene complex itself. In addition, the metal ligand sphere was altered by substitution of one or two carbonyl ligands for either an amine or a phosphine ligand/s. These substitutions resulted in the formation of metal pentacarbonyl, metal tetracarbonyl as well as metal tricarbonyl systems. The complexes were successfully characterised by means of NMR and IR spectroscopy, and in selected cases X-ray diffraction and mass spectrometry. Synthesis of N-heterocyclic carbene complexes derived from isopropyl and mesityl imidazolium chlorides was attempted. The products were obtained in crude form, but could not be isolated due to decomposition during purification. Two novel decomposition products, which point towards a unique decomposition route, were isolated. Theoretical models of both the novel Fischer carbene complexes and the N-heterocyclic carbene complexes were calculated. This allowed for identification of infrared modes observed in experimental data. Furthermore, the HOMO and LUMO distributions and the HOMO-LUMO energy gaps were calculated, along with electrostatic potential maps. In all the Fischer carbene complexes the HOMOs were located on the metal centre and the LUMOs on the carbene ligand. In contrast, the HOMO and the LUMO were both located on the metal centre for the N-heterocyclic carbenes. The HOMO-LUMO energy gap decreased as follows: NHC complexes > Amino Fischer carbene complexes > Ethoxy Fischer carbene complexes Lastly, in all the complexes studied, the electrostatic potential maps indicated that the highest amount of electron density was found on the carbonyl ligands of these complexes. Both experimental and theoretical data indicated marked differences in the various classes of compounds, suggesting that these complexes would not only have different reactivities but also be suited to different applications. Experimental studies on reactivity and applications are thus future avenues of study which are made available from these results.

Book Energy Research Abstracts

Download or read book Energy Research Abstracts written by and published by . This book was released on 1981 with total page 1740 pages. Available in PDF, EPUB and Kindle. Book excerpt: