Download or read book Synthesis and Physicochemical Characterization of Large Nickel carbonyl arsinidene Clusters and a Novel Au6Ni12 Carbonyl Cluster written by Alison Jane Whoolery and published by . This book was released on 1993 with total page 508 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Dissertation Abstracts International written by and published by . This book was released on 1994 with total page 744 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Transition Metal Carbonyl Cluster Chemistry written by Paul J. Dyson and published by CRC Press. This book was released on 2018-10-03 with total page 180 pages. Available in PDF, EPUB and Kindle. Book excerpt: Transition metal carbonyl clusters (TMCCs) continue to inspire great interest in chemical research, as much for their fascinating structures as for potential industrial applications conferred by their unique properties. This highly accessible book introduces the bonding, structure, spectroscopic properties, and characterization of clusters, and then explores their synthesis, reactivity, reaction mechanisms and use in organic synthesis and catalysis. Transition Metal Carbonyl Cluster Chemistry describes models and rules that correlate cluster structure with electron count, which are then applied in worked examples. Subsequent chapters explain how bonding relates to molecular structure, demonstrate the use of spectroscopic techniques such as NMR, IR and MS in cluster chemistry, and outline the factors contributing to the stability, dynamics and reactivity of clusters. The second part of this book discusses the synthesis and applications of TMCCs. It emphasizes the differences between the reactivities of clusters vs. mononuclear metal complexes, contingent to the availability of multiple-bonding sites and heterosite reactivity. The final chapters discuss reactions in which clusters act as homogeneous catalysts; including discussion on the use of solid and biphasic liquid-liquid supported clusters in heterogeneous catalysts. A useful reference for those commencing further research or post-graduate study on metal carbonyl clusters and advanced organometallic chemistry, this book is also a cornerstone addition to academic and libraries as well as private collections.
Download or read book Metal metal Bonded Carbonyl Dimers and Clusters written by Catherine E. Housecroft and published by . This book was released on 2007 with total page 93 pages. Available in PDF, EPUB and Kindle. Book excerpt: This text is designed in part as a companion volume to the Primer Cluster molecules of the p-block elements. Metal-metal bonded carbonyl dimers and clusters deals with the synthesis, structure, bonding, and reactivity of J-block metal carbonyl compounds and derivatives containing hydride, phosphine, phosphite, and organic ligands as well as clusters containing both transition metal and main group fragments. Like most areas of chemistry, this is a large one and this text is only intended to be an introduction to the field; the reader is guided to several more advanced texts and literature reviews for more in-depth explorations of metal carbonyl dimer and cluster chemistry.
Download or read book Carbonylation written by H.M. Colquhoun and published by Springer Science & Business Media. This book was released on 1991-05-31 with total page 314 pages. Available in PDF, EPUB and Kindle. Book excerpt: Describes and recommends catalytic carbonylation as a general tool in synthetic organic chemistry, dealing exclusively with laboratory scale reactions involving the interconversion of carbon monoxide and organic carbonyl compounds. Most of the reactions discussed involve catalytic formation of carbonyl compounds, but also considered are those requiring stoichiometric quantities of transition metal, and those that eliminate an organic carbonyl group as carbon monoxide. Annotation copyrighted by Book News, Inc., Portland, OR
