Download or read book Synthesis and Optical Characterization of Iv vi Semiconductor Nanocrystals written by Ariel Kigel and published by . This book was released on 2009 with total page 103 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Semiconductor and Metal Nanocrystals written by Victor I. Klimov and published by CRC Press. This book was released on 2003-11-07 with total page 505 pages. Available in PDF, EPUB and Kindle. Book excerpt: The vast technological potential of nanocrystalline materials, as well as current intense interest in the physics and chemistry of nanoscale phenomena, has led to explosive growth in research on semiconductor nanocrystals, also known as nanocrystal quantum dots, and metal nanoparticles. Semiconductor and Metal Nanocrystals addresses current topics impacting the field including synthesis and assembly of nanocrystals, theory and spectroscopy of interband and intraband optical transitions, single-nanocrystal optical and tunneling spectroscopies, electrical transport in nanocrystal assemblies, and physical and engineering aspects of nanocrystal-based devices. Written by experts who have contributed pioneering research, this reference comprises key advances in the field of semiconductor nanocrystal quantum dots and metal nanoparticles over the past several years. Focusing specifically on nanocrystals generated through chemical techniques, Semiconductor and Metal Nanocrystals Merges investigative frontiers in physics, chemistry, and engineering Documents advances in nanocrystal synthesis and assembly Explores the theory of electronic excitations in nanoscale particles Presents comprehensive information on optical spectroscopy of interband and intraband optical transitions Reviews data on single-nanocrystal optical and tunneling spectroscopies Weighs controversies related to carrier relaxation dynamics in ultrasmall nanoparticles Discusses charge carrier transport in nanocrystal assemblies Provides examples of lasing and photovoltaic nanocrystal-based devices Semiconductor and Metal Nanocrystals is a must read for scientists, engineers, and upper-level undergraduate and graduate students interested in the physics and chemistry of nanoscale semiconductor and metal particles, as well as general nanoscale science.
Download or read book Nanocrystals written by Sudheer Neralla and published by BoD – Books on Demand. This book was released on 2012-08-29 with total page 214 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nanocrystals research has been an area of significant interest lately, due to the wide variety of potential applications in semiconductor, optical and biomedical fields. This book consists of a collection of research work on nanocrystals processing and characterization of their structural, optical, electronic, magnetic and mechanical properties. Various methods for nanocrystals synthesis are discussed in the book. Size-dependent properties such as quantum confinement, superparamagnetism have been observed in semiconductor and magnetic nanoparticles. Nanocrystals incorporated into different material systems have proven to possess improved properties. A review of the exciting outcomes nanoparticles study has provided indicates further accomplishments in the near future.
Download or read book Semiconductor Nanocrystal Quantum Dots written by Andrey Rogach and published by Springer Science & Business Media. This book was released on 2008-09-02 with total page 374 pages. Available in PDF, EPUB and Kindle. Book excerpt: This is the first book to specifically focus on semiconductor nanocrystals, and address their synthesis and assembly, optical properties and spectroscopy, and potential areas of nanocrystal-based devices. The enormous potential of nanoscience to impact on industrial output is now clear. Over the next two decades, much of the science will transfer into new products and processes. One emerging area where this challenge will be very successfully met is the field of semiconductor nanocrystals. Also known as colloidal quantum dots, their unique properties have attracted much attention in the last twenty years.
Download or read book Semiconductor Nanocrystals written by Alexander L. Efros and published by Springer Science & Business Media. This book was released on 2013-06-29 with total page 277 pages. Available in PDF, EPUB and Kindle. Book excerpt: A physics book that covers the optical properties of quantum-confined semiconductor nanostructures from both the theoretical and experimental points of view together with technological applications. Topics to be reviewed include quantum confinement effects in semiconductors, optical adsorption and emission properties of group IV, III-V, II-VI semiconductors, deep-etched and self assembled quantum dots, nanoclusters, and laser applications in optoelectronics.
Download or read book Synthesis Optical and Electronic Properties of Group IV Semiconductor Nanocrystals written by Kirill V. Shcheglov and published by . This book was released on 1997 with total page 194 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Colloidal Semiconductor Nanocrystals Synthesis Properties and Applications written by Vladimir Lesnyak and published by Frontiers Media SA. This book was released on 2020-01-06 with total page 110 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Semiconductor Nanocrystals and Metal Nanoparticles written by Tupei Chen and published by CRC Press. This book was released on 2016-10-14 with total page 526 pages. Available in PDF, EPUB and Kindle. Book excerpt: Semiconductor nanocrystals and metal nanoparticles are the building blocks of the next generation of electronic, optoelectronic, and photonic devices. Covering this rapidly developing and interdisciplinary field, the book examines in detail the physical properties and device applications of semiconductor nanocrystals and metal nanoparticles. It begins with a review of the synthesis and characterization of various semiconductor nanocrystals and metal nanoparticles and goes on to discuss in detail their optical, light emission, and electrical properties. It then illustrates some exciting applications of nanoelectronic devices (memristors and single-electron devices) and optoelectronic devices (UV detectors, quantum dot lasers, and solar cells), as well as other applications (gas sensors and metallic nanopastes for power electronics packaging). Focuses on a new class of materials that exhibit fascinating physical properties and have many exciting device applications. Presents an overview of synthesis strategies and characterization techniques for various semiconductor nanocrystal and metal nanoparticles. Examines in detail the optical/optoelectronic properties, light emission properties, and electrical properties of semiconductor nanocrystals and metal nanoparticles. Reviews applications in nanoelectronic devices, optoelectronic devices, and photonic devices.
Download or read book Colloidal Synthesis of I III VI Semiconductor Nanocrystals and Study of Their Optical Properties written by Ankita Bora and published by . This book was released on 2023 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Nanocrystal Quantum Dots written by Victor I. Klimov and published by CRC Press. This book was released on 2017-12-19 with total page 485 pages. Available in PDF, EPUB and Kindle. Book excerpt: A review of recent advancements in colloidal nanocrystals and quantum-confined nanostructures, Nanocrystal Quantum Dots is the second edition of Semiconductor and Metal Nanocrystals: Synthesis and Electronic and Optical Properties, originally published in 2003. This new title reflects the book’s altered focus on semiconductor nanocrystals. Gathering contributions from leading researchers, this book contains new chapters on carrier multiplication (generation of multiexcitons by single photons), doping of semiconductor nanocrystals, and applications of nanocrystals in biology. Other updates include: New insights regarding the underlying mechanisms supporting colloidal nanocrystal growth A revised general overview of multiexciton phenomena, including spectral and dynamical signatures of multiexcitons in transient absorption and photoluminescence Analysis of nanocrystal-specific features of multiexciton recombination A review of the status of new field of carrier multiplication Expanded coverage of theory, covering the regime of high-charge densities New results on quantum dots of lead chalcogenides, with a focus studies of carrier multiplication and the latest results regarding Schottky junction solar cells Presents useful examples to illustrate applications of nanocrystals in biological labeling, imaging, and diagnostics The book also includes a review of recent progress made in biological applications of colloidal nanocrystals, as well as a comparative analysis of the advantages and limitations of techniques for preparing biocompatible quantum dots. The authors summarize the latest developments in the synthesis and understanding of magnetically doped semiconductor nanocrystals, and they present a detailed discussion of issues related to the synthesis, magneto-optics, and photoluminescence of doped colloidal nanocrystals as well. A valuable addition to the pantheon of literature in the field of nanoscience, this book presents pioneering research from experts whose work has led to the numerous advances of the past several years.
Download or read book Optical Properties of Semiconductor Nanocrystals written by S. V. Gaponenko and published by Cambridge University Press. This book was released on 1998-10-28 with total page 263 pages. Available in PDF, EPUB and Kindle. Book excerpt: Examines the optical properties of low-dimensional semiconductor structures, a hot research area - for graduate students and researchers.
Download or read book Synthesis and Characterization of III V Semiconductor Nanocrystals written by Andrew Antranik Guzelian and published by . This book was released on 1996 with total page 440 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Optical Properties of Semiconductor Nanostructures written by Marcin L. Sadowski and published by Springer Science & Business Media. This book was released on 2000-06-30 with total page 470 pages. Available in PDF, EPUB and Kindle. Book excerpt: Optical methods for investigating semiconductors and the theoretical description of optical processes have always been an important part of semiconductor physics. Only the emphasis placed on different materials changes with time. Here, a large number of papers are devoted to quantum dots, presenting the theory, spectroscopic investigation and methods of producing such structures. Another major part of the book reflects the growing interest in diluted semiconductors and II-IV nanosystems in general. There are also discussions of the fascinating field of photonic crystals. `Classical' low dimensional systems, such as GsAs/GaAlAs quantum wells and heterostructures, still make up a significant part of the results presented, and they also serve as model systems for new phenomena. New materials are being sought, and new experimental techniques are coming on stream, in particular the combination of different spectroscopic modalities.
Download or read book Colloidal Synthesis and Photophysical Characterization of Group IV Alloy and Group IV V Semiconductors written by Venkatesham Tallapally and published by . This book was released on 2018 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Nanomaterials, typically less than 100 nm size in any direction have gained noteworthy interest from scientific community owing to their significantly different and often improved physical properties compared to their bulk counterparts. Semiconductor nanoparticles (NPs) are of great interest to study their tunable optical properties, primarily as a function of size and shape. Accordingly, there has been a lot of attention paid to synthesize discrete semiconducting nanoparticles, of where Group III-V and II-VI materials have been studied extensively. In contrast, Group IV and Group IV-V based nanocrystals as earth abundant and less-non-toxic semiconductors have not been studied thoroughly. From the class of Group IV, Ge1-xSnxalloys are prime candidates for the fabrication of Si-compatible applications in the field of electronic and photonic devices, transistors, and charge storage devices. In addition, Ge1-xSnx alloys are potentials candidates for bio-sensing applications as alternative to toxic materials. Tin phosphides, a class of Group IV-V materials with their promising applications in thermoelectric, photocatalytic, and charge storage devices. However, both aforementioned semiconductors have not been studied thoroughly for their full potential in visible (Vis) to near infrared (NIR) optoelectronic applications. In this dissertation research, we have successfully developed unique synthetic strategies to produce Ge1-xSnxalloy quantum dots (QDs) and tin phosphide (Sn3P4, SnP, and Sn4P3) nanoparticles with tunable physical properties and crystal structures for potential applications in IR technologies. Low-cost, less-non-toxic, and abundantly-produced Ge1-xSnxalloys are an interesting class of narrow energy-gap semiconductors that received noteworthy interest in optical technologies. Admixing of Îł-Sn into Ge results in an indirect-to-direct bandgap crossover significantly improving light absorption and emission relative to indirect-gap Ge. However, the narrow energy-gaps reported for bulk Ge1-xSnxalloys have become a major impediment for their widespread application in optoelectronics. Herein, we report the first colloidal synthesis of Ge1-xSnxalloy quantum dots (QDs) with narrow size dispersity (3.3±0.5 -- 5.9±0.8 nm), wide range of Sn compositions (0--20.6%), and composition-tunable energy-gaps and near infrared (IR) photoluminescence (PL). The structural analysis of alloy QDs indicates linear expansion of cubic Ge lattice with increasing Sn, suggesting the formation of strain-free nanoalloys. The successful incorporation of Îł-Sn into crystalline Ge has been confirmed by electron microscopy, which suggests the homogeneous solid solution behavior of QDs. The quantum confinement effects have resulted in energy gaps that are significantly blue-shifted from bulk Ge for Ge1-xSnxalloy QDs with composition-tunable absorption onsets (1.72±0.84 eV for x=1.5--20.6%) and PL peaks (1.62--1.31 eV for x=1.5--5.6%). Time-resolved PL (TRPL) spectroscopy revealed microsecond and nanosecond timescale decays at 15 K and 295 K, respectively owing to radiative recombination of dark and bright excitons as well as the interplay of surface traps and core electronic states. Realization of low-to-non-toxic and silicon-compatible Ge1-xSnxQDs with composition-tunable near IR PL allows the unprecedented expansion of direct-gap Group IV semiconductors to a wide range of biomedical and advanced technological studies. Tin phosphides are a class of materials that received noteworthy interest in photocatalysis, charge storage and thermoelectric devices. Dual stable oxidation states of tin (Sn2+ and Sn4+) enable tin phosphides to exhibit different stoichiometries and crystal phases. However, the synthesis of such nanostructures with control over morphology and crystal structure has proven a challenging task. Herein, we report the first colloidal synthesis of size, shape, and phase controlled, narrowly disperse rhombohedral Sn4P3, hexagonal SnP, and amorphous tin phosphide nanoparticles (NPs) displaying tunable morphologies and size dependent physical properties. The control over NP morphology and crystal phase was achieved by tuning the nucleation/growth temperature, molar ratio of Sn/P, and incorporation of additional coordinating solvents (alkylphosphines). The absorption spectra of smaller NPs exhibit size-dependent blue shifts in energy gaps (0.88--1.38 eV) compared to the theoretical value of bulk Sn3P4 (0.83 eV), consistent with quantum confinement effects. The amorphous NPs adopt rhombohedral Sn4P3 and hexagonal SnP crystal structures at 180 and 250 ̊C, respectively. Structural and surface analysis indicates consistent bond energies for phosphorus across different crystal phases, whereas the rhombohedral Sn4P3 NPs demonstrate Sn oxidation states distinctive from those of the hexagonal and amorphous NPs owing to complex chemical structure. All phases exhibit N(1s) and ʋ(N-H) energies suggestive of alkylamine surface functionalization and are devoid of tetragonal Sn impurities.
Download or read book Brieven van N N geschreven aan Isaac Belinfante 1814 1892 written by Isaac Belinfante and published by . This book was released on 1820 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Semiconductor Nanocrystals written by Xudong Wang and published by . This book was released on 2020 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: The study in this dissertation mainly focused on semiconductor nanocrystals ranging from controllable synthesis of II-VI quantum dots in both organic phase and aqueous phase, to their optical property and potential environmental impact. Besides, our study of fluorescent nanomaterials was extended from semiconductor nanocrystals to another system, carbon dots. In the first project, an unconventional method to induce anisotropic growth of CdS arms on CdSe/CdS seeds was developed to form nanotetrapods. Our control experiments suggested the key role of CdS shell thickness of CdSe/CdS seeds and concentration of precursor for CdS growth in the growth of nanotetrapods. Our results show that the branching came from a zinc blende phase formation at the slow growing end of c-axis of wurtzite CdSe/CdS seeds due to the enrichment of stacking fault. The second work focused on the study of blinking properties of CdSe/CdS core/shell QDs with various morphology, surface capping ligands, and shell growth chemistry. Outstanding blinking suppression has been observed with hexagonal pyramid and bipyramid QDs, especially the bipyramid QDs. Besides, there are more off-state events observed with QDs coated with hydrophilic ligands, while the quantum yield was slightly decreased after ligand exchange reaction. Additionally, QDs prepared with the newly developed shell growth chemistry have been observed with lower on time fraction and an effect of core size on the blinking properties. The third work focused on the study on how Hg interacts with nanoparticles using aqueous CdSe nanoparticles capped with l-cysteine as a model system. The fluorescent nature of CdSe nanoparticles allows us to study the interaction of Hg ion with CdSe nanoparticles via photoluminescence spectra and photoluminescence decay. Results of ICP-MS measurements of CdSe NPs and the separated solution obtained after addition of Hg ions excluded the cation exchange of Cd2+ by Hg2+ except at very high Hg to Cd ratio. XPS further suggested that the Hg was bound to the amine and carboxylate group of l-cysteine capping agent on the nanoparticle surface. The fourth project is an experimental study of fluorescent carbon nanodots on their photoluminescence response to external electric field. Fluorescent carbon dots were synthesized using procedures modified from oil phase synthesis of QDs with citric acid as the reactants. The carbon nanodots showed remarkable excitation dependent emission properties. After encapsulated in artificial lipid bilayers, the carbon dots showed competitive sensitivity of voltage compared to the most used commercial membrane potential sensing dyes, which indicates great potential of carbon dots as alternative voltage sensing probes.
Download or read book Group IV Semiconductor Nanostructures Volume 832 written by Materials Research Society. Meeting and published by . This book was released on 2005-05-24 with total page 440 pages. Available in PDF, EPUB and Kindle. Book excerpt: Broad interest and steady progress in the area of Group-IV (Si:Ge:C) semiconductor nanostructures, including quantum dots, wires and wells, has produced a new class of functional materials and devices with characteristic dimensions less than 50nm. This volume brings together scientists from different disciplines to discuss fabrication and characterization techniques and optical and transport properties, as well as applications of Group-IV semiconductor nanostructures. Fields such as photonic systems, nanocrystal memories, light-emitting and THz devices, nanowire-based interconnections and transistors are addressed. Topics include: nanoscale silicon-based photonic systems; Si/SiGe/SiN heterostructures and devices; Si/SiGe quantum cascade laser for terahertz; three-dimensional Si/SiGe nanostructures; Si nanocrystals and porous Si- light-emitting properties; Si nanocrystals and porous Si - other properties; Group-IV semiconductor nanowires; and rare-earth-doped Group-IV semiconductor nanostructures.
