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Book Synthesis and Characterization of Cu II  Cu I  Mixed Valence Complexes

Download or read book Synthesis and Characterization of Cu II Cu I Mixed Valence Complexes written by Hansani T. Lekam Wasam Liyanage and published by . This book was released on 2017 with total page 122 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Synthesis and Characterization of Thiolate bridged Multicopper Complexes

Download or read book Synthesis and Characterization of Thiolate bridged Multicopper Complexes written by Robert Paul Houser and published by . This book was released on 1996 with total page 408 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Synthesis and Reactivity of Copper i  Amidinate Complexes

Download or read book Synthesis and Reactivity of Copper i Amidinate Complexes written by Andrew C. Lane and published by . This book was released on 2015 with total page 87 pages. Available in PDF, EPUB and Kindle. Book excerpt: Group 11 transition metals are used daily throughout our bodies and as additives in many common products. One biological function of copper, a group 11 metal, is its use in the Cu A site of cytochrome c oxidase, an enzyme found in the last step of cellular respiration. To model this active site, three formamidinate ligands have been examined: 2,6-dimethylphenyl, 2,6- diisopropylphenyl, and 2,4,6-trimethylphenyl. The synthesis and structural characterization of these dinuclear Cu(I) complexes is described as well as their redox chemistry with I 2 to afford complexes of mixed-valence which is the normal resting state of the Cu A site. Using EPR spectroscopy and DFT calculations on the iodine oxidized products, different electronic structures base d on the formamidinate was found. Additionally, insertion of CS 2 into the copper-nitrogen bonds of the copper(I) formamidinate complexes produces tetra- and hexanuclear clusters based on the steric properties of the ligand

Book Synthesis and Characterization of Copper  II  Complexes with 1 4 7 10 tetrabenzyl 1 4 7 10 tetraazacyclododecane

Download or read book Synthesis and Characterization of Copper II Complexes with 1 4 7 10 tetrabenzyl 1 4 7 10 tetraazacyclododecane written by Mary Christine Styka and published by . This book was released on 1974 with total page 126 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Synthesis and Characterization of Some Mixed Ligand Complexes of Copper  II  Containing Ortho Substituted Azo Dyes

Download or read book Synthesis and Characterization of Some Mixed Ligand Complexes of Copper II Containing Ortho Substituted Azo Dyes written by Carl James Doumit and published by . This book was released on 1973 with total page 278 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Synthesis and Characterization of Some Copper  II  Complexes with Ligands Formed with 14 membered Ring Amine Ligands

Download or read book Synthesis and Characterization of Some Copper II Complexes with Ligands Formed with 14 membered Ring Amine Ligands written by Scott Jackson Dantley and published by . This book was released on 1995 with total page 130 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Part One  Synthesis and Characterization of Copper Complexes of Alkyl Thiolates and Detailed Ligand to Metal Charge Transfer  LMCT  Spectra of Cu II  and Ni II    N2S2 Complexes

Download or read book Part One Synthesis and Characterization of Copper Complexes of Alkyl Thiolates and Detailed Ligand to Metal Charge Transfer LMCT Spectra of Cu II and Ni II N2S2 Complexes written by Elizabeth K. John and published by . This book was released on 1987 with total page 344 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Synthesis and Original Reactivity of Copper and Gold Complexes

Download or read book Synthesis and Original Reactivity of Copper and Gold Complexes written by Maximilian Joost and published by Springer. This book was released on 2015-06-13 with total page 244 pages. Available in PDF, EPUB and Kindle. Book excerpt: This thesis addresses the coordination chemistry and reactivity of copper and gold complexes with a focus on the elucidation of (i) the metal-mediated activation of σ-bonds and (ii) the migratory insertion reaction. Both processes are of considerable importance in organometallic chemistry, but remain elusive for Cu and Au complexes. In this work, the author contributes significant advances: The first σ-SiH complexes of copper are experimentally and computationally characterized, yielding valuable insights into σ-bond activation processes for copper. Evidence for a highly unusual migratory syn insertion of unsaturated organic molecules into the gold-silicon bond of silylgold (I) complexes is provided and the corresponding mechanism identified. The intermolecular oxidative addition of σ-SiSi, σ-CC and σ-CX (X=halogen) bonds with molecular gold (I) complexes is studied in detail, effectively demonstrating that this reaction, usually considered to be impossible for gold, is actually highly favored, provided an adequate ligand is employed. The use of small-bite angle bis (phosphine) gold (I) complexes allows for the first time the oxidative addition of σ-CC and σ-CX bonds for gold (I). These results shed light on an unexpected reactivity pattern of gold complexes and may point the way to 2-electron redox transformations mediated by this metal, opening up new perspectives in gold catalysis.

Book Studies of Copper  II   Aminoacidato  Complexes  Synthesis and Characterization

Download or read book Studies of Copper II Aminoacidato Complexes Synthesis and Characterization written by Tyler A. Knowles and published by . This book was released on 2000 with total page 68 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Synthesis and Characterization of Dicoumarol Based Cu Complexes

Download or read book Synthesis and Characterization of Dicoumarol Based Cu Complexes written by Hitesh R. Dholariya and published by LAP Lambert Academic Publishing. This book was released on 2014-11-28 with total page 68 pages. Available in PDF, EPUB and Kindle. Book excerpt: Our prime objective is to prepare a series of copper complex compounds which possess enhance biological activity by introducing 4-hydroxycoumarins and fluoroquinolones segments together. In the present article, we have synthesized twelve novel ligands and their Cu (II) complexes. We have focused much on antimicrobial activity, antioxidant and antitubarcular activity. Results from antimicrobial activity revealed that Cu (II) complexes were found biologically active as compared to its ligands. Few of the complexes have been found more potent antimicrobial agent against gram positive bacteria. Results obtained from the in vitro anti-tubercular activity of all Cu (II) complexes indicated that, few compounds have been found more potent than that of standard drugs Ethambutol and Streptomycin. One compound has been emerged as the promising anti-tubercular member due to better activity as compared to Streptomycin. In vitro antioxidant activity of all the complexes exposed moderate to good ferric reducing power. One of the compounds showed good anti oxidant power.

Book Synthesis and Characterization of Copper I  Polycarbonyl Complexes

Download or read book Synthesis and Characterization of Copper I Polycarbonyl Complexes written by John Wesley Hammel and published by . This book was released on 1998 with total page 176 pages. Available in PDF, EPUB and Kindle. Book excerpt: