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Book Synthesis and Characterization of Bent shaped Liquid Crystal

Download or read book Synthesis and Characterization of Bent shaped Liquid Crystal written by Kala a/p Shanku Pillay and published by . This book was released on 2006 with total page 100 pages. Available in PDF, EPUB and Kindle. Book excerpt: The field of liquid crystal is relatively new area of chemistry, and therefore generates a large frontier of research. The ability of being able to produce high resolution display screens for use in televisions or laptop computers with a very low power consumption, has revolutionised the technological market for this product. As a result of the success of the knowledge already known about liquid crystals and their properties, and their as yet unexplored potential, it is not suprising that there is an extremely large amount of research into the area. In relation to this, in this project, a five ring bent-shaped liquid crystal, which is relatively new compound in liquid crystalline phase, was synthesized using several organic synthesis methods, such as, Diazonium coupling reaction, Williamson ether synthesis, hydrolysis and reaction with resorcinol. The compounds synthesized were characterized through FTIR analysis, melting point, and its physical apperances. Other than that, the percent yield for each compound also have been calculated. The compound synthesized in first step, ethyl4-4-(hydroxyphenylazo)benzoate was a red color solid with melting point at 235 C and the percent yield was 52.07%. In second step 3.542 grams of Ethyl-4-(4-hexadecanoxyphenylazo)benzoate which orange in color with melting point of 135 C was obtained. The percent yield from the reaction was 42.11%. The third compound synthesized was yellow color solid with melting point of 280-290 C and the final compound was 1,3-Phenelyne bis[4-(4-hexadecanoxyphenylazo)benzoate], a pale yellow color solid with melting point at range of 130-135 C was obtained.

Book Bent Shaped Liquid Crystals

Download or read book Bent Shaped Liquid Crystals written by Hideo Takezoe and published by CRC Press. This book was released on 2017-07-20 with total page 290 pages. Available in PDF, EPUB and Kindle. Book excerpt: Bent-Shaped Liquid Crystals: Structures and Physical Properties provides insight into the latest developments in the research on liquid crystals formed by bent-shaped mesogens. After a historical introduction, the expert authors discuss different kinds of mesophase structures formed by bent-shaped molecules. This book devotes the majority of its pages to physical properties such as polar switching, optics and non-linear optics, and behavior in restricted geometries. However, as chemistry is often highly relevant to the emergence of new phases, particularly with reflection symmetry breaking, it also involves a broad spectrum of interesting chemistry viewpoints.

Book Synthesis and Characterization of Bent shaped Liquid Crystal with Azobenzene Having Phenylbenzoate Linkage

Download or read book Synthesis and Characterization of Bent shaped Liquid Crystal with Azobenzene Having Phenylbenzoate Linkage written by Indhumathi Sivanesan and published by . This book was released on 2008 with total page 91 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Design of Liquid Crystal Dimers and Trimers

Download or read book Design of Liquid Crystal Dimers and Trimers written by Maria Gabriela Tamba and published by . This book was released on 2014 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Thermotropic liquid crystals; bent-core mesogens; calamitic mesogens; oligomers; chirality; anti(ferroelectricity); polar mesophases; dark-conglomerate-phases; electro-optic switching; X-ray scattering

Book The Synthesis and Properties of Achiral and Chiral Bent core Liquid Crystals

Download or read book The Synthesis and Properties of Achiral and Chiral Bent core Liquid Crystals written by Kenneth Matthew Fergusson and published by . This book was released on 2008 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The area of liquid crystals has received substantial research effort over the last century, particularly when the beneficial applications such as Liquid Crystal Displays (LCDs) were realised and developed. For the majority of this time, it has been considered that a linear molecular shape is required in order to generate a mesomorphic phase. It was therefore of particular interest and excitement when, in 1996, it was shown that a 'banana-shaped' molecular architecture could exhibit a new class of liquid crystalline phase. Additionally it was found that these new mesophases exhibited chiral domains, leading to electrooptical switching properties, despite the constituent molecules being achiral. Unsurprisingly, these observations have led to a vast frontier of research in the area of 'banana-shaped' and 'bentcore' systems over the past decade and many interesting properties relating to such systems have been reported. The work contained within this thesis investigates two areas of bent-core liquid crystals. Firstly, the introduction of fluoro-substituents to the bent-core of an achiral banana-shaped system has been assessed, in terms of both position, and number of substituents. The resultant mesomorphic properties of these compounds have shown that there is a very delicate boundary between banana, and 'conventional' mesomorphism, relating to subtle changes in molecular structure. Appropriately positioned fluoro-substituents upon the bent-core generate a more linear conformation, facilitating the generation of nematic phases. Possible reasoning for this observation has been discussed. Secondly, the effect of introducing a bent-core to a conventional calamitic structure, and the addition of fluoro-substituents, has been examined. Whilst a variation of this nature to the majority of calamitic molecular structures would have a severely detrimental effect upon the resultant mesophase morphology, it has been shown that this is not always the case and indeed the addition of fluoro-substituents is shown to enhance the mesomorphic stability of the smectic A phase.

Book Liquid Crystal Dimers

    Book Details:
  • Author : Sandeep Kumar
  • Publisher : Cambridge University Press
  • Release : 2017-03-06
  • ISBN : 1316870901
  • Pages : 248 pages

Download or read book Liquid Crystal Dimers written by Sandeep Kumar and published by Cambridge University Press. This book was released on 2017-03-06 with total page 248 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book covers in-depth discussion of design principles, synthesis and thermal behavior of all types of liquid crystal (LC) dimers. The text presents recent advances in the field of LC dimers consisting of different mesogenic units such as calamitic, discotic and bent-core molecules. It starts with a chapter on the introduction of liquid crystal dimers, including their odd-even behavior, basic classification of dimers and common mesophases in dimers. The text shows how the molecular architectures are being used to develop new materials to study a range of interesting phenomena such as the biaxial nematic phase containing rod-like and disc-like mesogenic units. Finally, the text presents perspectives related to technological relevance of these dimers such as dopants in LC display mixtures exhibiting faster relaxation time, strong flexoelectric coupling and others to effect control over the properties of these materials.

Book Physical Characterization of Smectic Liquid Crystals Formed by Bent Shaped Molecules

Download or read book Physical Characterization of Smectic Liquid Crystals Formed by Bent Shaped Molecules written by Alexey B. Eremin and published by . This book was released on 2003 with total page 272 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Development and Characterization of Blue Phases Made from Bent core Liquid Crystals

Download or read book Development and Characterization of Blue Phases Made from Bent core Liquid Crystals written by Stefanie Taushanoff and published by . This book was released on 2011 with total page 130 pages. Available in PDF, EPUB and Kindle. Book excerpt: Blue phases (BP) are phases of chiral liquid crystals formed by lattices of double-twist cylinders with corresponding lattices of disclination lines. The conditions under which such an arrangement is energetically favorable generally occur in only a narrow band of temperature ranges, commonly less than 2C. Several methods have been devised to expand this range, notably polymer stabilization or nanoparticle stabilization. In addition, there is interest in using unconventionally shaped liquid crystals to form blue phases as molecular biaxiality is expected to help stabilize the phase. Here, we explore the potential of bent-core liquid crystals in creating stable blue phase materials with broad temperature ranges. It is known that the presence of achiral bent-core molecules in a chiral nematic material can induce blue phases where none were previously observed, and that liquid crystal dimers with a flexible center can create broad-temperature blue phases. Here we develop broad-temperature blue phase materials using bent-core nematic liquid crystals and chiral dopants, resulting in the first known example of a broad-range BPIII. Additional methods of phase stabilization are utilized in an attempt to increase the temperature range of the phase to encompass room temperatures.

Book Synthesis Bent Shaped Liquid Crystal Having Polymerizable Monomers

Download or read book Synthesis Bent Shaped Liquid Crystal Having Polymerizable Monomers written by Nur Atiqah binti Abdullah and published by . This book was released on 2010 with total page 64 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Bent core Liquid Crystals

Download or read book Bent core Liquid Crystals written by Hideo Takezoe and published by CRC Press. This book was released on 2015-12-26 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides insight into the latest developments in the research on liquid crystals formed by bent-core mesogens. After a short historical introduction, the authors discuss different kinds of mesophase structures formed by bent-core molecules. A majority of this book is devoted to physical properties such as elasticity, optics and non-linear optics, and behavior in restricted geometries. As chemistry is often relevant to the emergence of new phases, particularly with chiral symmetry breaking, chemistry viewpoints are broadly involved in this book.

Book Advances in Liquid Crystals

Download or read book Advances in Liquid Crystals written by Yuan Ming Huang and published by Trans Tech Publications Ltd. This book was released on 2010-01-12 with total page 620 pages. Available in PDF, EPUB and Kindle. Book excerpt: Volume is indexed by Thomson Reuters CPCI-S (WoS). Liquid crystals are substances that have properties which are intermediate between those of a conventional liquid and those of a solid crystal. This special collection comprises peer-reviewed papers that are concerned with all aspects of liquid crystal science and technology. The volume consists of five parts: plenary lectures, the molecular design and synthesis of liquid crystals, the characterization of liquid crystals, the applications of liquid crystals, and the emerging technologies and materials relevant to information display.