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Book Syntheses  Characterization and Photophysics of Polynuclear Copper  I  and Silver  I  Complexes Containing Monoynyl  Diynyl and Chalcogen Type Ligands

Download or read book Syntheses Characterization and Photophysics of Polynuclear Copper I and Silver I Complexes Containing Monoynyl Diynyl and Chalcogen Type Ligands written by 林智豪 and published by . This book was released on 2017-01-27 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: This dissertation, "Syntheses, Characterization and Photophysics of Polynuclear Copper (I) and Silver (I) Complexes Containing Monoynyl, Diynyl and Chalcogen-type Ligands" by 林智豪, Chi-ho, Aaron, Lam, was obtained from The University of Hong Kong (Pokfulam, Hong Kong) and is being sold pursuant to Creative Commons: Attribution 3.0 Hong Kong License. The content of this dissertation has not been altered in any way. We have altered the formatting in order to facilitate the ease of printing and reading of the dissertation. All rights not granted by the above license are retained by the author. DOI: 10.5353/th_b3124043 Subjects: Copper compounds - Synthesis Silver compounds - Synthesis Ligands

Book Syntheses  Characterization and Photophysics of Polynuclear Copper  I  and Silver  I  Complexes Containing Monoynyl  Diynyl and Chalcogen type Ligands

Download or read book Syntheses Characterization and Photophysics of Polynuclear Copper I and Silver I Complexes Containing Monoynyl Diynyl and Chalcogen type Ligands written by Chi-ho Lam (Aaron) and published by . This book was released on 2000 with total page 558 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Syntheses and Photophysics of Luminescent Polynuclear Coinage Metal Complexes with Chalcogen and Pnictogen

Download or read book Syntheses and Photophysics of Luminescent Polynuclear Coinage Metal Complexes with Chalcogen and Pnictogen written by 鄭重展 and published by . This book was released on 2017-01-27 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: This dissertation, "Syntheses and Photophysics of Luminescent Polynuclear Coinage Metal Complexes With Chalcogen and Pnictogen: Containing Bridging Ligands" by 鄭重展, Chung-chin, Cheng, was obtained from The University of Hong Kong (Pokfulam, Hong Kong) and is being sold pursuant to Creative Commons: Attribution 3.0 Hong Kong License. The content of this dissertation has not been altered in any way. We have altered the formatting in order to facilitate the ease of printing and reading of the dissertation. All rights not granted by the above license are retained by the author. DOI: 10.5353/th_b3124153 Subjects: Silver compounds - Synthesis Copper compounds - Synthesis Gold compounds - Synthesis Ligands Photochemistry

Book Synthesis  Structure and Photophysical and Photochemical Properties of Polynuclear Copper  1   Silver  1  and Gold  1  Complexes

Download or read book Synthesis Structure and Photophysical and Photochemical Properties of Polynuclear Copper 1 Silver 1 and Gold 1 Complexes written by Dan Li and published by Open Dissertation Press. This book was released on 2017-01-27 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: This dissertation, "Synthesis, Structure and Photophysical and Photochemical Properties of Polynuclear Copper (1), Silver (1) and Gold (1) Complexes" by 李丹, Dan, Li, was obtained from The University of Hong Kong (Pokfulam, Hong Kong) and is being sold pursuant to Creative Commons: Attribution 3.0 Hong Kong License. The content of this dissertation has not been altered in any way. We have altered the formatting in order to facilitate the ease of printing and reading of the dissertation. All rights not granted by the above license are retained by the author. DOI: 10.5353/th_b3123312 Subjects: Copper Silver Gold Photochemistry

Book SYNTHESES PHOTOPHYSICS   PHOTO

Download or read book SYNTHESES PHOTOPHYSICS PHOTO written by 李維傑 and published by Open Dissertation Press. This book was released on 2017-01-27 with total page 260 pages. Available in PDF, EPUB and Kindle. Book excerpt: This dissertation, "Syntheses, Photophysics and Photochemistry of Polynuclear D10 Complexes of Copper(I) and Gold(I)" by 李維傑, Wai-kit, Lee, was obtained from The University of Hong Kong (Pokfulam, Hong Kong) and is being sold pursuant to Creative Commons: Attribution 3.0 Hong Kong License. The content of this dissertation has not been altered in any way. We have altered the formatting in order to facilitate the ease of printing and reading of the dissertation. All rights not granted by the above license are retained by the author. DOI: 10.5353/th_b3123426 Subjects: Copper compounds - Synthesis Gold compounds - Synthesis Photochemistry

Book SYNTHESES   PHOTOPHYSICS OF LU

Download or read book SYNTHESES PHOTOPHYSICS OF LU written by Man-Chung Wong and published by Open Dissertation Press. This book was released on 2017-01-27 with total page 282 pages. Available in PDF, EPUB and Kindle. Book excerpt: This dissertation, "Syntheses and Photophysics of Luminescent Mono- and Dinuclear Rhenium Complexes Containing Functional Ligands" by Man-chung, Wong, 黃文忠, was obtained from The University of Hong Kong (Pokfulam, Hong Kong) and is being sold pursuant to Creative Commons: Attribution 3.0 Hong Kong License. The content of this dissertation has not been altered in any way. We have altered the formatting in order to facilitate the ease of printing and reading of the dissertation. All rights not granted by the above license are retained by the author. Abstract: Abstract of thesis entitled "SYNTHESES AND PHOTOPHYSICS OF LUMINESCENT MONO- AND DINUCLEAR RHENIUM COMPLEXES CONTAINING FUNCTIONAL LIGANDS" Submitted by Wong Man Chung for the degree of Doctor of Philosophy at The University of Hong Kong ABSTRACT With the growing interest in the exploration of inorganic/ organometallic sensing materials, a series of mononuclear rhenium(I) and rhenium(V) and dinuclear rhenium(I) (DIC-18-C-6)Cl], complexes with crown ether pendants of formula [Re(CO) [{Re(CO) Cl}(DDIC)], [Re(CO)(DIC-S)Cl], [Re(CO)(DIC-3S)Cl], [Re(CO) (DIC- 3 2 3 3 3 Se)Cl], [Re(CO) (DPPZC)Cl] and [Re (PPh ) (C≡C-benzo-15-crown-5) ] have been 3 3 2 2 synthesized. The photophysical, electrochemical and cation-binding properties of these systems have been studied. The structure of [Re(CO) (DIC-Se)Cl] has been established by X-ray crystallography. The electronic absorption energies of the rhenium(I) complexes were found to be sensitive to the presence of metal cations. The stability constants of [Re(CO)(DIC-18-C-6)Cl] and [{Re(CO) Cl}(DDIC)] for alkali and 3 3 2 alkaline-earth metal cations have been determined by UV-visible spectrophotometry. The complexes [Re(CO)(DIC-S)Cl], [Re(CO)(DIC-3S)Cl] and [Re(CO) (DIC-Se)Cl] 3 3 3 showed a downfield shift of methylene protons adjacent to the sulphur or selenium atom on the crown ether moiety upon addition of silver ion in deuterated acetonitrile. Their stability constants for silver ion have also been determined by UV-visible and H NMR spectroscopies. Direct evidences for the formation of the inclusion species between the crown ether-containing rhenium(V) complex [Re (PPh ) (C≡C-benzo-15-crown-5) ] and 3 2 2 lithium or sodium ions were obtained from electrospray ionization-mass spectrometry. A series of mononuclear and dinuclear rhenium(I) complexes with thiolate and selenolate ligands, [Re(CO) (N-N)(S-C H -X-p)] and [{Re(CO) (N-N)} (μ-S-C H -X- 3 6 4 3 2 6 4] t p)], have been synthesized (N-N = bpy, Me -bpy, Bu -bpy, phen; X = CH, OCH, 2 2 3 3 C(CH ), Cl, F). Unsymmetrical dinuclear rhenium(I) thiolate complexes have been 3 3 prepared by utilizing the mononuclear complexes as precursors. Their electrochemical properties have also been studied. The photophysical behaviour of the dinuclear complexes has been studied. Attempts to investigate the photophysical behaviour of the mononuclear counterparts were unsuccessful owing to their low photo-stability. The crystal structures of the complexes [Re(CO) (phen)(SC H -OCH -p)], [Re(CO) ( Bu - 3 6 4 3 3 2 bpy)(SePh)], [{Re(CO) (bpy)} (μ-SC H -CH -p)]OTf, [Re(CO) (phen)(μ-SC H -OMe- 3 2 6 4 3 3 6 4 p)Re(CO) (bpy)]OTf and [Re(CO) (Me -bpy)(μ-SC H -Me-p)Re(CO) (NO -phen)]OTf 3 3 2 6 4 3 2 have also been determined. Besides, a series of luminescent rhenium(I) acetylide complexes with diimine ligands, [Re(CO) (N-N)(C≡C-R)] (N-N = bpy, Me -bpy, phen, NO -phen; R = Ph, C H - 3 2 2 6 4 Cl-p, C H -C H -p, C H -C≡CH-p, C H -N=N-C H -OC H, EEME), have been 6 4 8 17 6 4 6 4 6 4 12 25 synthesized and their photophysical and electrochemical properties studied. The X-ray crystal structure of [Re(CO) (bpy)(C≡C-Ph)] has been determined. An unsymmetrical dinuclear complex, [(bpy)(CO) Re-C≡C-C H -C≡C-C≡C-C H -C≡C-Re(CO) ( Bu -bpy)] 3 6 4 6 4 3 2 has been prepared by

Book Syntheses and Characterization of Copper Chalcogen Complexes

Download or read book Syntheses and Characterization of Copper Chalcogen Complexes written by Miriam Wern and published by . This book was released on 2018 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Synthesis  Spectroscopic Properties  Magnetic Properties and Crystal Structures of Polynuclear Copper II  Complexes Containing the Oxyanion bridged Ligands

Download or read book Synthesis Spectroscopic Properties Magnetic Properties and Crystal Structures of Polynuclear Copper II Complexes Containing the Oxyanion bridged Ligands written by and published by . This book was released on 2006 with total page 194 pages. Available in PDF, EPUB and Kindle. Book excerpt: