Download or read book Surfactant enhanced Remediation of Hydrocarbon Contamination written by Timothy J. McHale and published by . This book was released on 1995 with total page 186 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Surfactant enhanced Electrokinetic Remediation of Hydrocarbon contaminated Soils written by Steven P. Thomas and published by . This book was released on 1996 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Concern over soil and groundwater contamination has created a demand for new and efficient remediation technologies. Surfactant-enhanced electrokinetic remediation is an innovative technique which has the potential to remove hydrocarbons from contaminated clay soils faster and more efficiently than conventional remediation methods. The main objectives of this research were to (1) evaluate the efficiency of using surfactant-enhanced electrokinetic remediation to remove hydrocarbons from contaminated soil columns in the laboratory; (2) identify the effect of various physical and chemical factors on the performance of electrokinetic remediation; and (3) develop equations to model surfactant-enhanced electrokinetic remediation. Research was also conducted on expanding and improving the analytical methods using the relatively new solid-phase microextraction technique for the determination of hydrocarbon concentration in water. The soil column experiments indicate surfactant-enhanced electrokinetic remediation with sodium dodecylsulfate (SDS) is dominated by electrophoretic transport of micelles. The application of a surfactant increased the current through the soil which led to increased electrolysis of water. Pore fluid flow was also significantly greater in clay columns with an applied voltage potential gradient... Surfactant-enhanced electrokinetic remediation was modelled by adapting the classical advection-dispersion-retardation equation to include a modified retardation factor and electrokinetic effects. The model results were highly dependent on the input parameters chosen. Modelling results indicate that electrophoretic transport of hydrocarbons in SDS micelles is the dominant factor influencing transport during surfactant-enhanced electrokinetic remediation. In order to utilize electroosmotic flow, the voltage potential gradient should be greater than 1 V/cm. Surfactant-enhanced electrokinetic remediation is still an emerging technology and a greater understanding of the factors involved is necessary before decontamination can be confidently applied in the field. However, this research significantly adds to the knowledge of surfactant-enhanced electrokinetic remediation.
Download or read book Design and Optimization of Surfactant Based Enhanced Remediation of Bunker C Fuel Oil Contaminated Soil written by Abdulrazaq Zubair and published by . This book was released on 2015 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Soil pollution, particularly by petroleum compounds is a very important global issue. It is typically a result of improper storage and disposal, historic careless spills, accidental spills, and leaks from tanks. This environmental damage can result in wide spread groundwater and surface water contamination, and limit soil use for agricultural purposes. There are a large number of brownfield sites across Canada. These are sites that have been previously used for industrial and commercial activities and have been contaminated with hazardous wastes. Newfoundland and Labrador (NL) in particular, has numerous sites due to a legacy of fuel oil use for power generation at abandoned, old and emerging mining fields. Data from the federal contaminated site inventory indicate that on federal owned sites in NL, there are over 3000 m3 of oil-contaminated soil. It has therefore become necessary to develop remediation technologies that are economically and technically feasible, environmentally friendly, fast, and applicable in a wide range of physical settings. A wide range of technologies have been developed over the past few decades for the remediation of contaminated sites. Some of these processes have been found to be successful in removing only a specific group of contaminants from the soil. As a result, combinations of different approaches are usually adopted for more effective remediation thereby leading to more expensive remedial operations. Surfactant-enhanced remediation technology, otherwise known as soil washing has proven to be an effective method to remove a mixture of contaminants such as heavy metals, petroleum compounds, volatile organic compounds, pesticides and herbicides as well as other hazardous and non-degradable substances from contaminated soils. Surfactant remediation relies on the ability of surfactant formulations to remove both organic and inorganic contaminants from soil and sediments by desorbing them from the solid to liquid phase. The technology removes contaminants via two mechanisms; one occurs below the Critical micelle concentration (CMC) of the surfactants known as mobilization mechanism, and the other above the CMC known as solubilization mechanism. However, this technology has not been widely reported for the remediation of Bunker C fuel oil, a complex and recalcitrant petroleum compound that is persistent in the environment and extensively reported to be resistant to chemical and biological degradation, and therefore difficult to remediate. This research presents an assessment of the performance of soil washing technology for the remediation of Bunker C contaminated oil from weathered contaminated soil using patented surfactant formulations. Weathered soil are known to be more difficult to remediate than freshly contaminated soil hence, the study used weathered soil in order to be certain of the effects of soil washing on Bunker C removal. Specific research objectives include: (1) determining the micellar properties (Surface Tension and CMC) of the patented surfactants, (2) development of a reliable analytical method for the analysis of (heavy) petroleum hydrocarbons in soil, (3) evaluation of the parameters that govern the implementation of soil washing and an assessment of their effects on the washing of weathered Bunker C oil from contaminated soil at surfactants concentrations below the CMC (mobilization mechanism) using the multivariate experimental and statistical approach, (4) determination of the optimum conditions (optimization) for the removal of Bunker C oil with the tested surfactants. The research, in the course of analysing the Total Petroleum Hydrocarbon in the soil using the Canada-Wide Standard (CWS) for Petroleum Hydrocarbon in soil is used for the analysis of petroleum hydrocarbon compounds found considerable variability and inconsistencies in the results. This could be due, in part, to the different gas chromatography (GC) conditions, soil properties, as well as and other steps involved in the method. These differences impacts the determination of the effectiveness of remediation at hydrocarbon-contaminated sites. The thesis therefore, developed validated the analytical method for the quantitative analysis of TPH in (contaminated) soil. The newly developed method was successfully applied for a faster and more reliable analysis of TPH of Bunker C oil in contaminated soil. It is expected that this research will lay a road map for further studies on the application, optimization and development of a treatment system protocol for the use of soil washing for Bunker C remediation. It should be noted that although Bunker C is the contaminant, the hydrocarbon composition of Bunker C makes it a good surrogate for other heavy oils.
Download or read book Biosurfactants for a Sustainable Future written by Hemen Sarma and published by John Wiley & Sons. This book was released on 2021-04-19 with total page 556 pages. Available in PDF, EPUB and Kindle. Book excerpt: Biosurfactants for a Sustainable Future Explore the state-of-the-art in biosurfactant technology and its applications in environmental remediation, biomedicine, and biotechnology Biosurfactants for a Sustainable Future explores recent developments in biosurfactants and their use in a variety of cutting-edge applications. The book opens a window on the rapid development of microbiology by explaining how microbes and their products are used in advanced medical technology and in the sustainable remediation of emerging environmental contaminants. The book emphasizes the different techniques that are used for the production of biosurfactants from microorganisms and their characterization. Various aspects of biosurfactants, including structural characteristics, developments, production, bio-economics and their sustainable use in the environment and biomedicine, are addressed, and the book also presents metagenomic strategies to facilitate the discovery of novel biosurfactants producing microorganisms. Readers will benefit from the inclusion of: A thorough introduction to the state-of-the-art in biosurfactant technology, techniques, and applications An exploration of biosurfactant enhanced remediation of sediments contaminated with organics and inorganics A discussion of perspectives for biomedical and biotechnological applications of biosurfactants A review of the antiviral, antimicrobial, and antibiofilm potential of biosurfactants against multi-drug-resistant pathogens. An examination of biosurfactant-inspired control of methicillin-resistant Staphylococcus aureus Perfect for academic researchers and scientists working in the petrochemical industry, pharmaceutical industry, and in the agroindustry, Biosurfactants for a Sustainable Future will also earn a place in the libraries of scientists working in environmental biotechnology, environmental science, and biomedical engineering.
Download or read book Hydrocarbon Contaminated Soils written by Paul T. Kostecki and published by CRC Press. This book was released on 1992-09-01 with total page 894 pages. Available in PDF, EPUB and Kindle. Book excerpt: Hydrocarbon Contaminated Soils, Volume II presents all of the important topics of hydrocarbon contaminated soils from the perspectives of scientific theory, regulatory application, and analysis and site assessment. These topics include an analysis of pollutants, soil physics and environmental fate; remediation techniques; health effects; regulations; and case histories. The book also includes a special section on petroleum contamination in groundwater and soils. Hydrocarbon Contaminated Soils, Volume II will interest anyone who works with contaminated soils, ground water, and underground storage tanks. It will also be an excellent reference for regulatory personnel and environmental consultants at all levels.
Download or read book Soil Contamination written by Marcelo Larramendy and published by BoD – Books on Demand. This book was released on 2016-12-21 with total page 358 pages. Available in PDF, EPUB and Kindle. Book excerpt: This edited book, Soil Contamination - Current Consequences and Further Solutions, is intended to provide an overview on the different environmental consequences of our anthropogenic activities, which has introduced a large number of xenobiotics that the soil cannot, or can only slower, decompose or degrade. We hope that this book will continue to meet the expectations and needs of all interested in diverse fields with expertise in soil science, health, toxicology, and other disciplines who contribute and share their findings to take this area forward for future investigations.
Download or read book Surfactant enhanced DNAPL Remediation written by David A. Sabatini and published by . This book was released on 1996 with total page 18 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Parameterization of Modeling Subsurface Hydrocarbon Contamination and Biosurfactant Enhanced Remediation Processes written by Zelin Li and published by . This book was released on 2016 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Subsurface hydrocarbon contamination caused by accidental spills or operational leakages of petroleum products is a global environmental concern. In order to cost-effectively and eco-friendly recover the contaminated sites, biosurfactant enhanced aquifer remediation (BSEAR) technologies have become a popular subject in both research and practice. However, the inherent uncertainties and complexities of the subsurface systems make it challenging in numerical simulation of the hydrocarbon transport and fate as well as remediation processes. Efforts in developing more efficient and robust parameterization approaches for such modeling purpose, therefore, are highly desired. This research aims to help fill the gap by developing a novel hybrid stochastic - design of experiment aided parameterization (HSDP) method for modeling BSEAR processes. The method was developed and tested based on an integrated physical and numerical modeling system comprised of a set of intermediate scale flow cells (ISFCs) and a numerical simulator named BioF&T 3D. Generally, the HSDP method was performed by: 1) building the design of experiment (DOE) models based on screened parameters and defined responses, which could reflect the goodness of fit between observed and simulated data; 2) identifying the and interactions among parameters and their significance; 3) optimizing the DOE predicted responses; 4) introducing stochastic data within reduced intervals based on the optimized parameters; 5) running Monte Carlo simulation to find the optimal responses with the corresponding combinations of parameters. The flow cell tests proved that the HSDP method could improve both efficiency and robustness of modeling parameterization and significantly reduce the computational demand without compromising the effectiveness in quantifying parameter interactions and uncertainties. Furthermore, a specific lab synthetized surfactin was applied in this study. The effect of dissolution enhancement was observed from parallel flow cell experiments especially during the first 12 hours following the initial hydrocarbon release. The HSDP method was demonstrated to be capable of advancing BioF&T 3D, which lacks the capacity of simulating surfactant. By incorporating the HSDP method, the BSEAR processes were effectively simulated with a satisfactory overall goodness of fit (R2 = 0.76, 0.81, 0.83, and 0.81 for benzene, toluene, ethylbenzene, and xylene, respectively). The enhanced dissolution effect was also reflected in the modeling parameterization by increasing the first 12 hours hydrocarbon loading ratio (12LR) compared to non-biosurfactant processes. This research developed a new parameterization method HSDP, which is capable of revealing interactions of parameters, as well as quantifying their uncertainties, in a robust and efficient manner. Also, using this method, this study initiated the attempts to advance simpler numerical models in simulating complicated BSEAR processes, which is particularly attractive for the potential applications in practice.
Download or read book Surfactant Enhanced Biodegradation of Petroleum Hydrocarbons in Oily Sludge written by Xiaoxi Zhang and published by . This book was released on 2010 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Bioremediation has been recognized as an effective method to treat petroleum hydrocarbon pollutants. However, the biodegradation of crude oil contaminated sludge could be a time-consuming and low-efficiency process. One of the reasons is that petroleum hydrocarbons in the sludge are unavailable for utilization by microorganisms. Surfactants have the potential to increase the bioavailability of such pollutants due to their capability of reducing the surface and interfacial tension and increasing the solubility of hydrocarbons in water. In this study, the production of biological surfactants during sludge bioremediation was observed using surface tension measurement method, and this would provide valuable information for developing an effective bioremediation process. The addition of two different chemical surfactants (Igepal CO-630 and Cedephos FA-600) and a biosurfactant (Rhamnolipids) were tested using a laboratory respirometer, and the effects of such surfactants on the biodegradation of total petroleum hydrocarbons (TPH) in the oil refinery sludge were investigated. All surfactants were found to be effective for improving microbial growth at low concentration. Igepal CO-630 at 400 mg/kg, Cedephos FA-600 at 400 mg/kg and Rhamnolipids at 200 mg/kg were found most effective in improving the reduction of TPH (C10-C50) compared to the control sample without any addition of surfactants. Better oxygen availability to soils contaminated with hydrocarbon sludge enhances both microbial growth and TPH reduction in the samples when surfactant concentrations were optimized. --P.i.
Download or read book Surfactant enhanced Subsurface Remediation written by David A. Sabatini and published by . This book was released on 1995 with total page 320 pages. Available in PDF, EPUB and Kindle. Book excerpt: Provides a timely and thorough review of surfactant-based remediation technologies. Covers fundamental mechanistic studies to scale-up and process modeling and full-scale field implementation studies. Summarizes the technical, economic, and sociopolitical issues affecting widespread implementation of these technologies. Includes contributions from academic and industrial researchers as well as regulatory personnel.
Download or read book Effect of Cationic Surfactant CTAB in the Electrokinetic Remediation of Diesel contaminated Soils written by and published by . This book was released on 1998 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Effect of Cationic Surfactant CTAB in the Electrokinetic Remediation of Diesel contaminated Soils written by Yuwei Qian and published by . This book was released on 1998 with total page 316 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Biosurfactant Enhanced Remediation of a Mixed Contaminated Soil written by Clementina Oghenekevwe Okoro and published by . This book was released on 2006 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Surfactant Enhanced Remediation of Residual Organic Contaminants written by Barbara Krebs-Yuill and published by . This book was released on 1995 with total page 208 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Biosurfactants written by Ramkrishna Sen and published by Springer Science & Business Media. This book was released on 2010-12-31 with total page 356 pages. Available in PDF, EPUB and Kindle. Book excerpt: The microbial world has given us many surprises including microbes that grow under extremely harsh conditions (122C at 40 MPa), novel metabolisms such as the uranium and perchlorate reduction, and novel chemicals that can be used to control diseases. We continually face new and difficult problems such as the need to transition to more carbon-neutral energy sources and to find eco-friendly chemicals and to find new drugs to treat disease. Will it be possible to tap into the seemingly limitless potential of microbial activity to solve our current and future problems?The answer to this question is probably yes. We are already looking to the microbial world to provide new energy sources, green chemicals to replace those made from petroleum, and new drugs to fight disease. To help us along these paths, we are deciphering how microorganisms interact with each other. We know that microbial populations interact and communicate with each other. The language that microbes use is chemical where small molecules are exchanged among different microbial cells. Sometimes, these chemicals suppress activities of competitors and could be used as antibiotics or may have other therapeutic uses. Other times, the chemicals stimulate complex responses in microbial populations such as fruiting body or biofilm formation. By understanding the conversation that microbes are having among themselves, e. g.
Download or read book In Situ Chemical Oxidation for Groundwater Remediation written by Robert L. Siegrist and published by Springer Science & Business Media. This book was released on 2011-02-25 with total page 715 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume provides comprehensive up-to-date descriptions of the principles and practices of in situ chemical oxidation (ISCO) for groundwater remediation based on a decade of intensive research, development, and demonstrations, and lessons learned from commercial field applications.
Download or read book Groundwater and Soil Cleanup written by National Research Council and published by National Academies Press. This book was released on 1999-11-21 with total page 301 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents a comprehensive, up-to-date review of technologies for cleaning up contaminants in groundwater and soil. It provides a special focus on three classes of contaminants that have proven very difficult to treat once released to the subsurface: metals, radionuclides, and dense nonaqueous-phase liquids such as chlorinated solvents. Groundwater and Soil Cleanup was commissioned by the Department of Energy (DOE) as part of its program to clean up contamination in the nuclear weapons production complex. In addition to a review of remediation technologies, the book describes new trends in regulation of contaminated sites and assesses DOE's program for developing new subsurface cleanup technologies.
