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Book Sulfur Compounds In Hydrocarbon Pyrolysis

Download or read book Sulfur Compounds In Hydrocarbon Pyrolysis written by M. Bajus and published by Taylor & Francis. This book was released on 1989 with total page 84 pages. Available in PDF, EPUB and Kindle. Book excerpt: First published in 1989. Routledge is an imprint of Taylor & Francis, an informa company.

Book Identification of Sulfur Compounds in Petroleum

Download or read book Identification of Sulfur Compounds in Petroleum written by and published by . This book was released on 1966 with total page 28 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Geochemistry of Sulfur in Fossil Fuels

Download or read book Geochemistry of Sulfur in Fossil Fuels written by Wilson L. Orr and published by . This book was released on 1990 with total page 728 pages. Available in PDF, EPUB and Kindle. Book excerpt: Here is the first volume to examine sulfur in fossil fuels from a geochemical perspective. It begins with six introductory chapters that present an overview of the material, historical background, and summaries of the present state of knowledge. Subsequent chapters cover: case studies of specific sedimentary environments; characterization of sulfur in selected coals and petroleums by various methods and techniques; and the major advances in understanding geochemistry at the molecular level. This important volume fills a significant gap in the technical literature and updates the understanding of the chemical processes in geological environments giving rise to sulfur fossil fuels.

Book Chemistry of Organic Sulfur Compounds in Petroleum and Petroleum Products

Download or read book Chemistry of Organic Sulfur Compounds in Petroleum and Petroleum Products written by Nauchnai︠a︡ sessii︠a︡ po khimii sera- i azot-organicheskikh soedineniĭ, soderzhashchikhsi︠a︡ v nefti︠a︡kh i nefteproduktakh and published by . This book was released on 1963 with total page 220 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Sulfur Compounds   Advances in Research and Application  2013 Edition

Download or read book Sulfur Compounds Advances in Research and Application 2013 Edition written by and published by ScholarlyEditions. This book was released on 2013-06-21 with total page 701 pages. Available in PDF, EPUB and Kindle. Book excerpt: Sulfur Compounds—Advances in Research and Application: 2013 Edition is a ScholarlyEditions™ book that delivers timely, authoritative, and comprehensive information about Hydrogen Sulfide. The editors have built Sulfur Compounds—Advances in Research and Application: 2013 Edition on the vast information databases of ScholarlyNews.™ You can expect the information about Hydrogen Sulfide in this book to be deeper than what you can access anywhere else, as well as consistently reliable, authoritative, informed, and relevant. The content of Sulfur Compounds—Advances in Research and Application: 2013 Edition has been produced by the world’s leading scientists, engineers, analysts, research institutions, and companies. All of the content is from peer-reviewed sources, and all of it is written, assembled, and edited by the editors at ScholarlyEditions™ and available exclusively from us. You now have a source you can cite with authority, confidence, and credibility. More information is available at http://www.ScholarlyEditions.com/.

Book Predicting Organosulfur Chemistry in Fuel Sources

Download or read book Predicting Organosulfur Chemistry in Fuel Sources written by Caleb Andrew Class and published by . This book was released on 2015 with total page 152 pages. Available in PDF, EPUB and Kindle. Book excerpt: Desulfurization of fossil fuels with supercritical water (SCW) has been the topic of many studies over the past few decades. This process does not require the use of any catalyst, eliminates the need for a hydrogen feed, and minimizes coke formation. Previous research has shown that it has the potential to be a viable commercial process, and recent experimental studies have proven that water acts as one hydrogen source for sulfur removal in this process. However, the exact desulfurization mechanism is largely unknown, as are many other reaction mechanisms involving sulfur compounds. Recent work has greatly expanded our ability to build comprehensive reaction mechanisms automatically for the decomposition of organic sulfur compounds using the automated Reaction Mechanism Generator (RMG). This thesis presents the implementation of this and other tools to investigate chemical processes relevant to our use of fuel sources containing sulfur compounds, and it shows some steps that have been taken to improve our predictions for these mechanisms and those that will be generated in the future. Previous investigations had focused on the pyrolysis of small sulfur compounds containing less than six heavy atoms, so RMG is first used to study the pyrolysis of t-butyl sulfide. A detailed reaction mechanism is then presented for the SCW desulfurization of hexyl sulfide. Comprehensive kinetic mechanisms for these larger molecules are likely to include thousands of reactions, so RMG builds this model in a systematic and unbiased way using a database of ab initio data. This database is expanded with potentially relevant thermochemical and kinetic parameters using transition state theory and quantum chemical calculations at the CBS-QB3 and CCSD(T)-F12 levels of theory. With these data, as well as previously calculated rates for hydrocarbon and sulfur kinetics, RMG is used to build a reaction mechanism for the conversion of hexyl sulfide to hydrogen sulfide, pentane, and carbon monoxide in the presence of SCW. This mechanism is validated with results from batch and flow reactor experiments, and predictions are accurate within a factor of two for reactant and major product concentrations. Analysis of the proposed mechanism shows that the molecular addition of water to the carbonsulfur double-bond in hexanethial is a key step in the SCW process, as this not only leads to the desulfurization of the compound, but also prevents the thioaldehyde from undergoing addition reactions with other hydrocarbons in a process that could eventually form coke. Thus, this work not only has implications in the SCW desulfurization process, but in the overall crude oil upgrading process as well. The calculated kinetic and thermochemical parameters are used to generate predictive reaction mechanisms for other processes relevant in fuel chemistry, such as the geological formation of oil and gas from kerogen. This not only allows us to model experimental work investigating the effect sulfur compounds have on the oil-to-gas process, but we also explore how these effects differ at geological conditions and timescales. And as the possible applications of RMG grow, the need for accurate parameters in mechanism generation become even more critical. A thermochemical database is generated for a wide variety of sulfur compounds using the highaccuracy CCSD(T)-F12/cc-pVTZ-F12 method, and this provides a basis for the investigation of organosulfur chemistry with tighter uncertainty.

Book Crude Oil Fouling

Download or read book Crude Oil Fouling written by Francesco Coletti and published by Gulf Professional Publishing. This book was released on 2014-11-20 with total page 385 pages. Available in PDF, EPUB and Kindle. Book excerpt: With production from unconventional rigs continuing to escalate and refineries grappling with the challenges of shale and heavier oil feedstocks, petroleum engineers and refinery managers must ensure that equipment used with today’s crude oil is protected from fouling deposits Crude Oil Fouling addresses this overarching challenge for the petroleum community with clear explanations on what causes fouling, current models and new approaches to evaluate and study the formation of deposits, and how today’s models could be applied from lab experiment to onsite field usability for not just the refinery, but for the rig, platform, or pipeline. Crude Oil Fouling is a must-have reference for every petroleum engineer’s library that gives the basic framework needed to analyze, model, and integrate the best fouling strategies and operations for crude oil systems. Defines the most critical variables and events that cause fouling Explains the consequences of fouling and its impact on operations, safety, and economics Provides the technical models available to better predict and eliminate the potential for fouling in any crude system

Book Chemistry of Organic Sulfur Compounds in Petroleum and Petroleum Products

Download or read book Chemistry of Organic Sulfur Compounds in Petroleum and Petroleum Products written by Akademii︠a︡ nauk SSSR. Bashkirskiĭ filial and published by . This book was released on 1963 with total page 222 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Pyrolysis and Gasification

Download or read book Pyrolysis and Gasification written by G.L. Ferrero and published by Springer. This book was released on 1989-12-31 with total page 704 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book The Chemical Thermodynamic Properties of Hydrocarbons and Related Substances

Download or read book The Chemical Thermodynamic Properties of Hydrocarbons and Related Substances written by M. Zaki El-Sabban and published by . This book was released on 1970 with total page 568 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Organosulfur Antioxidants in Hydrocarbon Oils

Download or read book Organosulfur Antioxidants in Hydrocarbon Oils written by D. N. Harpp and published by CRC Press. This book was released on 1985 with total page 44 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Pyrolysis  Theory and Industrial Practice

Download or read book Pyrolysis Theory and Industrial Practice written by Lyle Frederick Albright and published by . This book was released on 1983 with total page 512 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book The Pyrolysis of Carbon Compounds

Download or read book The Pyrolysis of Carbon Compounds written by Charles Dewitt Hurd and published by . This book was released on 2013-01 with total page 810 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Small  Oxygenated Sulfur Compounds

Download or read book Small Oxygenated Sulfur Compounds written by Aaron J. Frank and published by . This book was released on 2000 with total page 514 pages. Available in PDF, EPUB and Kindle. Book excerpt: