Download or read book Sulfonation and Related Reactions written by Everett Eddy Gilbert and published by . This book was released on 1965 with total page 552 pages. Available in PDF, EPUB and Kindle. Book excerpt: No general work on the organic derivatives of sulfur trioxide has appeared since the publication of C.M. Suter's basic treatise The Organic Chemistry of Sulfur, which covered the literature through 1941. This book represents an effort to overcome this need The author's approach has been selective, rather than all-inclusive, with the general objective of supplying background information of possible value to the laboratory chemist. Recent trends have been emphasized. Chief among these is the recognition that, although the conventional rules of aromatic orientation are followed under kinetically controlled conditions during sulfonation with sulfuric acid or oleum, these rules are not always followed under conditions that are thermodynamically controlled. This effect is made possible by the reversible nature of the sulfonation reaction, a characteristic which has enough other implications to warrant consideration in a sweparate chapter. Another effect noted increasingly in all aspects of sulfonate preparation, as well as in desulfonation, is the importance of steric requirements. Many examples are noted of the steric assistance or hindrance to be expected in reactions involving moieties as large as sulfur trioxide or sulfite ion. Emphasis is also placed upon recent studies involving the reactions of sulfur trioxide itself, and its various adducts with organic compounds. An effort is made in appropriate cases to bring together isolated facts into possibly meaningful form in such a way as to indicate trends or generalizations.
Download or read book SULFONATION AND RELATED REACTIONS written by EE. GILBERT and published by . This book was released on 1977 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Sulfonation of ketones and related reactions written by Wayne Lloyd St. John and published by . This book was released on 1951 with total page 106 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Mechanistic Studies on the Sulfonation of the Xylenes and on Some Related Reactions written by Arend Jan Prinsen and published by . This book was released on 1968 with total page 88 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book The Sulfonation of Benzene written by Adelbert William Harvey and published by . This book was released on 1922 with total page 24 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Sulphonation Technology in the Detergent Industry written by W. Herman de Groot and published by Springer Science & Business Media. This book was released on 2013-03-14 with total page 300 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is about Sulph(on)ation Technology in its technical entirety, aiming at superiority in final product quality, raw material utilisation, sustained plant reliability and safety, minimisation of liquid effluent and gaseous emissions; it is about the total quality of the operation. It will be of value to engineers and chemists who are, or will be, involved in the practical daily operation of sulphonation plants or R&D activities. The book can also be used as a tool for the teacher in preparing fmal year projects in a chemical engineering curriculum. The book covers sulphonation of alkylbenzenes, primary alcohols, alcohol ethers, alpha-olefIns and fatty acid methyl esters, with a strong emphasis on the sulphur-based S~/air sulphonation technology. The first part deals with raw material specifications, hazards, storage, handling and physical properties. In the following section the process chemistry is discussed, indicating main chemical reactions, undesired parallel and consecutive reactions, exothermal heat effects and all other process chemistry data that are relevant for process selection and equipment design. The section about the actual process equipment from the various plant equipment suppliers (Ballestra, Chemithon, Mazzoni, Meccaniche Modeme and Lion Corp.) takes into account the chemical reaction engineering aspects derived from the sulphonation technology processing chemistry. Product quality, product storage and handling, product safety and physical properties are the contents of the next section. The effluent handling and exhaust gas treatment of the SOiair sulphonation technology are further discussed in detail.
Download or read book Advances in Sulphonation Techniques written by Navin G. Ashar and published by Springer. This book was released on 2015-10-10 with total page 98 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents a complete, in-depth analysis for on the impact of liquid sulfur dioxide and liquid sulfur trioxide to carry out complex and difficult sulfonations, as well as manufacture of sulfuric acid with a CAPEX requirement of less than half, an area requirement less than one-third, and no emission of sulfur dioxide. The processes described in this volume represents an innovative approach relevant to the current manufacturing processes of sulfuric acid, sulfamic acid, para toluene sulfonic acid and other sulfonated product.
Download or read book Chlorosulfonic Acid written by Richard James William Cremlyn and published by Royal Society of Chemistry. This book was released on 2002 with total page 344 pages. Available in PDF, EPUB and Kindle. Book excerpt: Since its discovery in 1854, chlorosulfonic acid has demonstrated that it is a truly versatile reagent. It is widely used as a sulfonating and chlorosulfonating agent, particularly of organic compounds, and it provides useful synthetic intermediates for many branches of industry. This book provides a detailed, up to date account of the reactions of chlorosulfonic acid with aliphatic, aromatic and heterocyclic compounds; reactions with elements and inorganic compounds are also discussed, along with the use of the reagent as a powerful acid catalyst, and halogenation and dehydrating agent. Finally, the commercial uses and manufacture of chlorosulfonic acid are reviewed. The detailed coverage in this book, coupled with the many references to recent work, will ensure that it is welcomed as a reference by synthetic chemists in, for example, the pharmaceutical, agrochemical, plastic and detergent industries. Researchers and their students in academia will also find it a valuable addition to their bookshelves.
Download or read book Aromatic Sulfonation and Related Reactions written by P. J. Oldershaw and published by . This book was released on 1971 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book March s Advanced Organic Chemistry written by Michael B. Smith and published by John Wiley & Sons. This book was released on 2007-01-29 with total page 2379 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Sixth Edition of a classic in organic chemistry continues its tradition of excellence Now in its sixth edition, March's Advanced Organic Chemistry remains the gold standard in organic chemistry. Throughout its six editions, students and chemists from around the world have relied on it as an essential resource for planning and executing synthetic reactions. The Sixth Edition brings the text completely current with the most recent organic reactions. In addition, the references have been updated to enable readers to find the latest primary and review literature with ease. New features include: More than 25,000 references to the literature to facilitate further research Revised mechanisms, where required, that explain concepts in clear modern terms Revisions and updates to each chapter to bring them all fully up to date with the latest reactions and discoveries A revised Appendix B to facilitate correlating chapter sections with synthetic transformations
Download or read book Chlorosulfonic Acid written by R J Cremlyn and published by Royal Society of Chemistry. This book was released on 2007-10-31 with total page 324 pages. Available in PDF, EPUB and Kindle. Book excerpt: Since its discovery in 1854, chlorosulfonic acid has demonstrated that it is a truly versatile reagent. It is widely used as a sulfonating and chlorosulfonating agent, particularly of organic compounds, and it provides useful synthetic intermediates for many branches of industry. This book provides a detailed, up to date account of the reactions of chlorosulfonic acid with aliphatic, aromatic and heterocyclic compounds; reactions with elements and inorganic compounds are also discussed, along with the use of the reagent as a powerful acid catalyst, and halogenation and dehydrating agent. Finally, the commercial uses and manufacture of chlorosulfonic acid are reviewed. The detailed coverage in this book, coupled with the many references to recent work, will ensure that it is welcomed as a reference by synthetic chemists in, for example, the pharmaceutical, agrochemical, plastic and detergent industries. Researchers and their students in academia will also find it a valuable addition to their bookshelves.
Download or read book Kinetics of Sulfonation Reactions written by Gerald Alfred Ratcliff and published by . This book was released on 1954 with total page 280 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Practical Process Research and Development written by Neal G. Anderson and published by Academic Press. This book was released on 2012-05-23 with total page 489 pages. Available in PDF, EPUB and Kindle. Book excerpt: Designed to provide a comprehensive, step-by-step approach to organic process research and development in the pharmaceutical, fine chemical, and agricultural chemical industries, this book describes the steps taken, following synthesis and evaluation, to bring key compounds to market in a cost-effective manner. It describes hands-on, step-by-step, approaches to solving process development problems, including route, reagent, and solvent selection; optimising catalytic reactions; chiral syntheses; and "green chemistry." Second Edition highlights:• Reflects the current thinking in chemical process R&D for small molecules• Retains similar structure and orientation to the first edition. • Contains approx. 85% new material• Primarily new examples (work-up and prospective considerations for pilot plant and manufacturing scale-up)• Some new/expanded topics (e.g. green chemistry, genotoxins, enzymatic processes)• Replaces the first edition, although the first edition contains useful older examples that readers may refer to Provides insights into generating rugged, practical, cost-effective processes for the chemical preparation of "small molecules" Breaks down process optimization into route, reagent and solvent selection, development of reaction conditions, workup, crystallizations and more Presents guidelines for implementing and troubleshooting processes
Download or read book Chemical Reaction in Condensed Phase written by Gennadiĭ Efremovich Zaikov and published by Nova Publishers. This book was released on 2006 with total page 282 pages. Available in PDF, EPUB and Kindle. Book excerpt: Chemical Reactions in Condensed Phase - The Quantitative Level
Download or read book Reactions Involved in the Sulfonation of Heat Treated Abietic Acid written by Torsten Hasselstrom and published by . This book was released on 1938 with total page 2 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Mechanistic Aspects in Aromatic Sulfonation and Desulfonation written by Hans Cerfontain and published by . This book was released on 1968 with total page 344 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Handbook of Detergents Part F written by Uri Zoller and published by CRC Press. This book was released on 2008-11-20 with total page 624 pages. Available in PDF, EPUB and Kindle. Book excerpt: This sixth part of the multi-volume Handbook of Detergents focuses on the production of surfactants, builders and other key components of detergent formulations, including the various multi-dimensional aspects and implications on detergent formulations and applications domestically, institutionally, in industry and agriculture, with all the environ
