Download or read book Studies on Kinetics and the Mechanism of the Oxidation of Hydrocarbons in the Gas Phase Part I A Brief Literature Survey on the Oxidation Mechanism of Higher Hydrocarbons and on the Low Temperature Oxidation of N heptane Etc written by g Oehlmann (Chemist.) and published by . This book was released on 1965 with total page 24 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Studies on kinetics and the mechanism of the oxidation of hydrocarbons in the gas phase Part 1 A brief literature survey on the oxidation mechanism of higher hydrocarbons and on the low temperature oxidation of n heptane by G Ohlmann and E Leibnitz written by G. Ohlmann and published by . This book was released on 1965 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book The Gas Phase Oxidation of Hydrocarbons written by V. Ya. Shtern and published by Elsevier. This book was released on 2016-07-29 with total page 721 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Gas-Phase Oxidation of Hydrocarbons reviews research on the mechanism of oxidation of paraffins, naphthenes, olefines, and aromatic hydrocarbons and explains in detail the phenomena and theories with significant kinetic equations and graphs. This book first presents a study of the development of research on the gaseous-phase oxidation of hydrocarbons. The non-chain schemes for the oxidation of hydrocarbons, such as hydroxylation, peroxidation, and aldehyde and dehydrogenation schemes, are then discussed. This book also presents experimental investigations and important topics such as oxidation of methane and olefinic hydrocarbons. This selection will be invaluable to students and experts in the field of chemistry and related disciplines.
Download or read book Studies on Kinetics and the Mechanism of the Oxidation of Hydrocarbons in the Gas Phase Part 1 A Brief Literature Survey on the Oxidation Mechanism of Higher Hydrocarbons and on the Low Temperature Oxidation of N heptane written by G. eOhlmann and published by . This book was released on 1965 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Chemical Kinetics of the Gas Phase Combustion of Fuels written by Francis Westley and published by . This book was released on 1976 with total page 148 pages. Available in PDF, EPUB and Kindle. Book excerpt: Work supported by the Office of Standard Reference Data, National Bureau of Standards, Naval Sea Systems Command, Department of the Navy, and Division of Conservation, Research and Technology, Energy Research and Development Administration.
Download or read book Studies on kinetics and the mechanism of the oxidation of hydrocarbons in the gas phase by E Schroder G Ohlmann and E Leibnitz written by E. Schroder and published by . This book was released on 1967 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book The Oxidation of Hydrocarbons in the Liquid Phase written by N. M. Emanuel' and published by Elsevier. This book was released on 2013-11-19 with total page 425 pages. Available in PDF, EPUB and Kindle. Book excerpt: Approx.424 pages
Download or read book General Catalogue of Printed Books written by British Museum. Dept. of Printed Books and published by . This book was released on 1959 with total page 552 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book The gas phase oxidation of hydrocarbons written by Vladimir J. Štern and published by . This book was released on 1964 with total page 710 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Liquid phase Oxidation of Hydrocarbons written by Nikolaĭ Markovich Ėmanuėlʹ and published by . This book was released on 1967 with total page 374 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book The Gas phase Oxidation of Hydrocarbons written by Vladimir I︠A︡kovlevich Shtern and published by . This book was released on 1964 with total page 724 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book The Mechanisms of Pyrolysis Oxidation and Burning of Organic Materials written by Leo Aloysius Wall and published by . This book was released on 1972 with total page 204 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Chapter II written by E. T. Denisov and published by . This book was released on 1983 with total page 34 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book The Low Temperature Liquid Phase Oxidation of Hydrocarbons written by Frank Morton and published by . This book was released on 1955 with total page 33 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Autoxidation of Hydrocarbons and Polyolefins written by Leo Reich and published by . This book was released on 1969 with total page 546 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Predictive Kinetic Modeling of Low temperature Hydrocarbon Oxidation written by Amrit Jalan and published by . This book was released on 2014 with total page 235 pages. Available in PDF, EPUB and Kindle. Book excerpt: Low temperature oxidation in the gas and condensed phases has been the subject of experimental investigations for many decades owing to applications in many areas of practical significance like thermal stability, combustion, atmospheric chemistry and industrial syntheses. Owing to several practical limitations it has proven difficult to understand these processes at a mechanistic level from experiments alone. Developments in scientific computing have opened up computational chemistry and cheminformatics based tools as an attractive option for exploring and elucidating the kinetics of these complex processes through detailed kinetic modeling and requires efforts in three key areas: single reaction kinetics, reaction networks and coupling kinetics with mass/momentum/energy balance models. This thesis presents several contributions employing high-level electronic structure calculations, reaction rate theory, automated kinetic modeling and empirical correlations to further our mechanistic understanding of low-temperature oxidation in the gas and liquid phase. First, an extensible framework for automatic estimation of species thermochemistry in the solution phase is presented and validated. This framework uses the Linear Solvation Energy Relationship (LSER) formalism of Abraham/Mintz and co-workers for high-throughput estimation of [delta]G°solv(T) in over 30 solvents using solute descriptors estimated from group additivity. The performance of scaled particle theory (SPT) expressions for enthalpic-entropic decomposition of [delta]G°solv(T) is also discussed along with the associated computational issues. Second, the importance of solvent effects on free-radical kinetics is explored using tetralin oxidation as a case study. The solvent dependence for the main propagation and termination reactions are determined using the Polarizable Continuum (PCM) family of solvation models. Incorporating these kinetic solvent effects in detailed kinetic models suggest oxidation rates increase with solvent polarity, consistent with experiment. Following this, electronic structure methods and reaction rate theory are used elucidate mechanistic details of new pathways in liquid-phase and atmospheric oxidation. The first of these studies focuses on pathways that establish [gamma]-ketohydroperoxides (KHP), well-known products in low-temperature alkane oxidation, as precursors to acids through a two-step process. Ab initio calculations are used to identify pathways leading from KHP to a cyclic peroxide isomer which decomposes through novel concerted reactions into carbonyl and carboxylic acid products. High-level gas phase rate coefficients are obtained using DFT/WFT methods coupled with VTST/SCT calculations and multi-structural partition functions (QMs-T). Solvent effects are included using continuum dielectric solvation models and the predicted rate coefficients found to be in excellent agreement with experiment lending theoretical support to the 30-year old Korcek hypothesis. Next, insights from the Korcek reaction are extended to atmospheric chemistry where similar cyclic peroxides are formed by reactions of the Criegee Intermediate (*CH2OO*) with double bonds. More specifically, the role of chemical activation in reactions between *CH2OO* and C=O/C=C species is explored using master equation calculations to obtain phenomenological rate coefficients k(T,P). In the case of reactions with C=O, the yield of collisionally stabilized SOZ at atmospheric pressure was found to increase in the order HCHO
Download or read book Subject Index of the Modern Works Added to the British Museum Library written by and published by . This book was released on 1961 with total page 616 pages. Available in PDF, EPUB and Kindle. Book excerpt:
