Download or read book A Textbook of Inorganic Chemistry Volume 1 written by Mandeep Dalal and published by Dalal Institute. This book was released on 2017-01-01 with total page 482 pages. Available in PDF, EPUB and Kindle. Book excerpt: An advanced-level textbook of inorganic chemistry for the graduate (B.Sc) and postgraduate (M.Sc) students of Indian and foreign universities. This book is a part of four volume series, entitled "A Textbook of Inorganic Chemistry – Volume I, II, III, IV". CONTENTS: Chapter 1. Stereochemistry and Bonding in Main Group Compounds: VSEPR theory; dπ -pπ bonds; Bent rule and energetic of hybridization. Chapter 2. Metal-Ligand Equilibria in Solution: Stepwise and overall formation constants and their interactions; Trends in stepwise constants; Factors affecting stability of metal complexes with reference to the nature of metal ion and ligand; Chelate effect and its thermodynamic origin; Determination of binary formation constants by pH-metry and spectrophotometry. Chapter 3. Reaction Mechanism of Transition Metal Complexes – I: Inert and labile complexes; Mechanisms for ligand replacement reactions; Formation of complexes from aquo ions; Ligand displacement reactions in octahedral complexes- acid hydrolysis, base hydrolysis; Racemization of tris chelate complexes; Electrophilic attack on ligands. Chapter 4. Reaction Mechanism of Transition Metal Complexes – II: Mechanism of ligand displacement reactions in square planar complexes; The trans effect; Theories of trans effect; Mechanism of electron transfer reactions – types; outer sphere electron transfer mechanism and inner sphere electron transfer mechanism; Electron exchange. Chapter 5. Isopoly and Heteropoly Acids and Salts: Isopoly and Heteropoly acids and salts of Mo and W: structures of isopoly and heteropoly anions. Chapter 6. Crystal Structures: Structures of some binary and ternary compounds such as fluorite, antifluorite, rutile, antirutile, crystobalite, layer lattices- CdI2, BiI3; ReO3, Mn2O3, corundum, pervoskite, Ilmenite and Calcite. Chapter 7. Metal-Ligand Bonding: Limitation of crystal field theory; Molecular orbital theory: octahedral, tetrahedral or square planar complexes; π-bonding and molecular orbital theory. Chapter 8. Electronic Spectra of Transition Metal Complexes: Spectroscopic ground states, Correlation and spin-orbit coupling in free ions for Ist series of transition metals; Orgel and Tanabe-Sugano diagrams for transition metal complexes (d1 – d9 states); Calculation of Dq, B and β parameters; Effect of distortion on the d-orbital energy levels; Structural evidence from electronic spectrum; John-Tellar effect; Spectrochemical and nephalauxetic series; Charge transfer spectra; Electronic spectra of molecular addition compounds. Chapter 9. Magantic Properties of Transition Metal Complexes: Elementary theory of magneto - chemistry; Guoy’s method for determination of magnetic susceptibility; Calculation of magnetic moments; Magnetic properties of free ions; Orbital contribution, effect of ligand-field; Application of magneto-chemistry in structure determination; Magnetic exchange coupling and spin state cross over. Chapter 10. Metal Clusters: Structure and bonding in higher boranes; Wade’s rules; Carboranes; Metal carbonyl clusters - low nuclearity carbonyl clusters; Total electron count (TEC). Chapter 11. Metal-π Complexes: Metal carbonyls: structure and bonding; Vibrational spectra of metal carbonyls for bonding and structure elucidation; Important reactions of metal carbonyls; Preparation, bonding, structure and important reactions of transition metal nitrosyl, dinitrogen and dioxygen complexes; Tertiary phosphine as ligand.

Download or read book Journal written by American Chemical Society and published by . This book was released on 2001 with total page 1320 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Transition Metal Dinitrogen Complexes written by Yoshiaki Nishibayashi and published by John Wiley & Sons. This book was released on 2019-05-06 with total page 496 pages. Available in PDF, EPUB and Kindle. Book excerpt: A comprehensive book that explores nitrogen fixation by using transition metal-dinitrogen complexes Nitrogen fixation is one of the most prominent fields of research in chemistry. This book puts the focus on the development of catalytic ammonia formation from nitrogen gas under ambient reaction conditions that has been recently repowered by some research groups. With contributions from noted experts in the field, Transition Metal-Dinitrogen Complexes offers an important guide and comprehensive resource to the most recent research and developments on the topic of nitrogen fixation by using transition metal-dinitrogen. The book is filled with the information needed to understand the synthesis of transition metal-dinitrogen complexes and their reactivity. This important book: -Offers a resource for understanding nitrogen fixation chemistry that is essential for explosives, pharmaceuticals, dyes, and all forms of life -Includes the information needed for anyone interested in the field of nitrogen fixation by using transition metal-dinitrogen complexes -Contains state-of-the-art research on synthesis of transition metal-dinitrogen complexes and their reactivity in nitrogen fixation -Incorporates contributions from well-known specialists and experts with an editor who is an innovator in the field of dinitrogen chemistry Written for chemists and scientists with an interest in nitrogen fixation, Transition Metal-Dinitrogen Complexes is a must-have resource to the burgeoning field of nitrogen fixation by using transition metal-dinitrogen complexes.

Download or read book Study of Di and Polynuclear Metal Complexes written by Antonius Franciscus Maria Josephus van der Ploeg and published by . This book was released on 1981* with total page 180 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Comprehensive Organic Synthesis written by Barry M. Trost and published by Elsevier. This book was released on 1991 with total page 1174 pages. Available in PDF, EPUB and Kindle. Book excerpt: Volume 8.

Download or read book Molecular Metal Metal Bonds written by Stephen T. Liddle and published by John Wiley & Sons. This book was released on 2016-03-16 with total page 592 pages. Available in PDF, EPUB and Kindle. Book excerpt: Systematically covering all the latest developments in the field, this is a comprehensive and handy introduction to metal-metal bonding. The chapters follow a uniform, coherent structure for a clear overview, allowing readers easy access to the information. The text covers such topics as synthesis, properties, structures, notable features, reactivity and examples of applications of the most important compounds in each group with metal-metal bonding throughout the periodic table. With its general remarks at the beginning of each chapter, this is a must-have reference for all molecular inorganic chemists, including PhD students and postdocs, as well as more experienced researchers.

Download or read book Inorganic Chemistry of the Transition Elements Volume 6 written by Brian Frederick Gilbert Johnson and published by Royal Society of Chemistry. This book was released on 1978 with total page 520 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Bioinorganic Chemistry written by Ivano Bertini and published by . This book was released on 1994 with total page 648 pages. Available in PDF, EPUB and Kindle. Book excerpt: Written by major contributors to the field, Bioinorganic Chemistry provides students with an introduction and overview of the subject and gives them the background required to read and follow the current research literature.

Download or read book Highly Efficient OLEDs written by Hartmut Yersin and published by John Wiley & Sons. This book was released on 2019-01-04 with total page 604 pages. Available in PDF, EPUB and Kindle. Book excerpt: Dieses Fachbuch eines Pioniers in diesem schnell wachsenden Fachbereich fasst die jüngsten Erkenntnisse zur Optimierung von OLEDs zusammen. Die Theorie wird ausführlich beschrieben, ebenso verschiedene organische und anorganische emittierende Materialien, Display- und Lichtanwendungen.

Download or read book Progress in Inorganic Chemistry Volume 29 written by Stephen J. Lippard and published by John Wiley & Sons. This book was released on 2009-09-17 with total page 412 pages. Available in PDF, EPUB and Kindle. Book excerpt: This comprehensive series of volumes on inorganic chemistry provides inorganic chemists with a forum for critical, authoritative evaluations of advances in every area of the discipline. Every volume reports recent progress with a significant, up-to-date selection of papers by internationally recognized researchers, complemented by detailed discussions and complete documentation. Each volume features a complete subject index and the series includes a cumulative index as well.

Download or read book Progress in Inorganic Chemistry Volume 46 written by Kenneth D. Karlin and published by John Wiley & Sons. This book was released on 2009-09-17 with total page 498 pages. Available in PDF, EPUB and Kindle. Book excerpt: Capturing today's scientific imagination...PROGRESS in InorganicChemistry Nowhere is creative scientific talent busier than in the world ofinorganic chemistry experimentation. And the traditional forum forexchanging innovative research has been the respected Progress inInorganic Chemistry series. With contributions from internationallyrenowned chemists, this latest volume offers an in-depth,far-ranging examination of the changing face of the field,providing a tantalizing glimpse of the emerging state of thescience. CONTENTS OF VOLUME 46 * Anion Binding and Recognition by Inorganic Based Receptors (PaulD. Beer and David K. Smith) * Copper (I), Lithium and Magnesium Thiolate Complexes: An Overviewwith Due Mention of Selenolate and Tellurolate Analogues andRelated Silver (I) and Gold (I) Species (Maurits D. Janssen, DavidM. Grove, and Gerard van Koten) * The Role of the Pyrazolate Ligand in Building PolynuclearTransition Metal Systems (Girolamo La Monica and G. AttilloArdizzoia) * Recent Trends in Metal Alkoxide Chemistry (Ram C. Mehrotra andAnirudh Singh). "This series is distinguished not only by its scope and breadth,but also by the depth and quality of the reviews." --Journal of theAmerican Chemical Society. "This series is a valuable addition to the library of thepracticing research chemist, and is a good starting point forstudents wishing to understand modern inorganic chemistry."--Canadian Chemical News. "[This series] has won a deservedly honored place on the bookshelfof the chemist attempting to keep afloat in the torrent of originalpapers on inorganic chemistry." --Chemistry in Britain.

Download or read book Organometallic Chemistry Research Perspectives written by Richard P. Irwin and published by Nova Publishers. This book was released on 2007 with total page 324 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organometallic chemistry is based on the reactions and use of a class of compounds (R-M) that contain a covalent bond between carbon and metal. They are prepared either by direct reaction of the metal with an organic compound or by replacement of a metal from another organometallic substance. This book presents research in this field.

Download or read book Reduction written by Barry M. Trost and published by Elsevier. This book was released on 1992-09-08 with total page 1166 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume contains 37 chapters on methods for reducing functional groups, organized into four main parts. (i) Reduction of C=X systems, where X is an electronegative heteroatom, divided into 14 chapters based on the degree of reduction, the oxidation level of the C=X substrate, and on the nature of the reagent. (ii) Reduction of X=Y systems, divided into three chapters, covering the reduction of such groups as nitro, azo, and the various kinds of P=O and S=O groups. (iii) Reduction of C=C and C≡C, divided into 12 chapters based on the method of reduction, with aromatic, heteroaromatic, and conjugated systems treated separately, and including an extensive discussion of hydrometallation. (iv) Reduction of single bonds, C-X to C-H, in eight chapters, including the hydrogenolysis of the various kinds of C-X bonds, the reduction of epoxides, and the reduction of vinyl derivatives to alkenes. Each chapter includes a discussion of chemoselectivity, regioselectivity, and stereoselectivity, wherever it is appropriate, and most include advice on the reagent of choice, and the mechanistic basis of the various methods of reduction. In short, it is, within the space available, as near to a comprehensive account of reduction in organic chemistry as one could hope for.

Download or read book Advances in Organometallic Chemistry written by and published by Academic Press. This book was released on 1999-10-14 with total page 390 pages. Available in PDF, EPUB and Kindle. Book excerpt: A widely-acclaimed serial, Advances in Organometallic Chemistry contains authoritative reviews that address all aspects of organometallic chemistry, a field which has expanded enormously since the publication of Volume 1 in 1964. Almost all branches of chemistry and material science now interface with organometallic chemistry--the study of compounds containing carbon-metal bonds. Organometallic compounds range from species which are so reactive that they only have a transient existence at ambient temperatures to species which are thermally very stable. Organometallics are used extensively in the synthesis of compounds on both large and small scales. Industrial processes involving plastics, polymers, electronic materials, and pharmaceuticals all depend on advancements in organometallic chemistry.

Download or read book Comprehensive Organometallic Chemistry II written by Richard J. Puddephatt and published by Elsevier. This book was released on 1995 with total page 670 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Comprehensive Organometallic Chemistry II Volume 14 written by Edward W. Abel and published by Elsevier. This book was released on 2002-09-10 with total page 399 pages. Available in PDF, EPUB and Kindle. Book excerpt: Since the publication Comprehensive Organometallic Chemistry in 1982, studies on the chemistry of molecules with carbon-metal bonds have continued to expand rapidly. This is due to many factors, ranging from the sheer intellectual challenge and excitement provided by the continuing production of novel results, which demand new ideas, through to the successful application of organometallic species in organic syntheses, the generation of living catalysts for polymerization, and the synthesis of precursors for materials employed in the electronic and ceramic industries. These factors led to the publication of the updated Comprehensive Organometallic Chemistry II. The original work serves as a basis for new volumes, focusing on organometallic chemistry reported since 1982, with reference back to the original work when necessary. For ease of use the new volumes maintain the same general structure as employed previously but reflect the changes in substance and direction the field has undergone in the last ten years. This book will serve as a pivotal reference point for new work and will function to generate new ideas and perceptions for the continued advance of what will surely continue as a vibrant area of chemistry.

Download or read book Inorganic Chemistry of the Transition Elements written by B F G Johnson and published by Royal Society of Chemistry. This book was released on 2007-10-31 with total page 520 pages. Available in PDF, EPUB and Kindle. Book excerpt: Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued. The current list of Specialist Periodical Reports can be seen on the inside flap of this volume.