Download or read book Chemistry and Structures of Some Polynuclear Metal Carbonyl Complexes written by Glenn Richard Wilkes and published by . This book was released on 1965 with total page 356 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book A Textbook of Inorganic Chemistry Volume 1 written by Mandeep Dalal and published by Dalal Institute. This book was released on 2017-01-01 with total page 482 pages. Available in PDF, EPUB and Kindle. Book excerpt: An advanced-level textbook of inorganic chemistry for the graduate (B.Sc) and postgraduate (M.Sc) students of Indian and foreign universities. This book is a part of four volume series, entitled "A Textbook of Inorganic Chemistry – Volume I, II, III, IV". CONTENTS: Chapter 1. Stereochemistry and Bonding in Main Group Compounds: VSEPR theory; dπ -pπ bonds; Bent rule and energetic of hybridization. Chapter 2. Metal-Ligand Equilibria in Solution: Stepwise and overall formation constants and their interactions; Trends in stepwise constants; Factors affecting stability of metal complexes with reference to the nature of metal ion and ligand; Chelate effect and its thermodynamic origin; Determination of binary formation constants by pH-metry and spectrophotometry. Chapter 3. Reaction Mechanism of Transition Metal Complexes – I: Inert and labile complexes; Mechanisms for ligand replacement reactions; Formation of complexes from aquo ions; Ligand displacement reactions in octahedral complexes- acid hydrolysis, base hydrolysis; Racemization of tris chelate complexes; Electrophilic attack on ligands. Chapter 4. Reaction Mechanism of Transition Metal Complexes – II: Mechanism of ligand displacement reactions in square planar complexes; The trans effect; Theories of trans effect; Mechanism of electron transfer reactions – types; outer sphere electron transfer mechanism and inner sphere electron transfer mechanism; Electron exchange. Chapter 5. Isopoly and Heteropoly Acids and Salts: Isopoly and Heteropoly acids and salts of Mo and W: structures of isopoly and heteropoly anions. Chapter 6. Crystal Structures: Structures of some binary and ternary compounds such as fluorite, antifluorite, rutile, antirutile, crystobalite, layer lattices- CdI2, BiI3; ReO3, Mn2O3, corundum, pervoskite, Ilmenite and Calcite. Chapter 7. Metal-Ligand Bonding: Limitation of crystal field theory; Molecular orbital theory: octahedral, tetrahedral or square planar complexes; π-bonding and molecular orbital theory. Chapter 8. Electronic Spectra of Transition Metal Complexes: Spectroscopic ground states, Correlation and spin-orbit coupling in free ions for Ist series of transition metals; Orgel and Tanabe-Sugano diagrams for transition metal complexes (d1 – d9 states); Calculation of Dq, B and β parameters; Effect of distortion on the d-orbital energy levels; Structural evidence from electronic spectrum; John-Tellar effect; Spectrochemical and nephalauxetic series; Charge transfer spectra; Electronic spectra of molecular addition compounds. Chapter 9. Magantic Properties of Transition Metal Complexes: Elementary theory of magneto - chemistry; Guoy’s method for determination of magnetic susceptibility; Calculation of magnetic moments; Magnetic properties of free ions; Orbital contribution, effect of ligand-field; Application of magneto-chemistry in structure determination; Magnetic exchange coupling and spin state cross over. Chapter 10. Metal Clusters: Structure and bonding in higher boranes; Wade’s rules; Carboranes; Metal carbonyl clusters - low nuclearity carbonyl clusters; Total electron count (TEC). Chapter 11. Metal-π Complexes: Metal carbonyls: structure and bonding; Vibrational spectra of metal carbonyls for bonding and structure elucidation; Important reactions of metal carbonyls; Preparation, bonding, structure and important reactions of transition metal nitrosyl, dinitrogen and dioxygen complexes; Tertiary phosphine as ligand.
Download or read book Organometallic Chemistry written by E W Abel and published by Royal Society of Chemistry. This book was released on 2007-10-31 with total page 522 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organometallic chemistry is an interdisciplinary science which continues to grow at a rapid pace. Although there is continued interest in synthetic and structural studies the last decade has seen a growing interest in the potential of organometallic chemistry to provide answers to problems in catalysis synthetic organic chemistry and also in the development of new materials. This Specialist Periodical Report aims to reflect these current interests reviewing progress in theoretical organometallic chemistry, main group chemistry, the lanthanides and all aspects of transition metal chemistry. Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued. The current list of Specialist Periodical Reports can be seen on the inside flap of this volume.
Download or read book Summaries of Projects Completed written by National Science Foundation (U.S.) and published by . This book was released on with total page 1108 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Advances in Organometallic Chemistry written by and published by Academic Press. This book was released on 1980-07-21 with total page 365 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advances in Organometallic Chemistry
Download or read book Energy Research Abstracts written by and published by . This book was released on 1992-03 with total page 358 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Structure and Reactivity of Modified Zeolites written by V.B. Kazansky and published by Elsevier. This book was released on 2009-06-05 with total page 389 pages. Available in PDF, EPUB and Kindle. Book excerpt: Structure and Reactivity of Modified Zeolites
Download or read book Structural Studies of Several Organometallic Complexes Containing Sulfur of Phorus written by Judith Margaret Coleman and published by . This book was released on 1966 with total page 192 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Zeolites Science and Technology written by Fernando Ramôa Ribeiro and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 698 pages. Available in PDF, EPUB and Kindle. Book excerpt: Zeolites have been the focus of intensive activity and growth in applications over the past 25 years in ion exchange, in adsorp tion and in catalytic process technology. Beginning with the syn thetic zeolites A,X and Y, continuing into the emerging ZSM series, and including selected natural zeolites, applications span the range from large-scale purification and separation to such major petroleum and petrochemical processes as catalytic cracking and aromatics alkylation. The future promises several new areas of signiciant use as our energy resource base is expanded. As a result, a NATO Advanced Study Institute on Zeolites was held in Alcabideche, Portugal, May 1-12, 1983. Its purpose was to summarize the state-of-the-art in zeolite science and technology, with particular emphasis on recent developments. This summary is intended to complement presentations of the latest research results at the 1983 International Zeolites Association meeting in .Reno, Nevada - USA. Both the fundamentals concepts and industrial applications are addressed in the lectures of the Institute. Individual chapters cover historical development, structure, crystallography and synthesis techniques. Basic principles of adsorption, diffusion, ion exchange and acidity are reviewed. A section on catalysis addresses shape selectivity, transition metals, bifunctional catalysis and "methanol to-gasoline". Included in the section on industrial applications are chapters on reactor and adsorber design, catalytic cracking, xylene and n -paraffins isomerization, as well as ion exchange and adsorption.
Download or read book Landmarks in Organo Transition Metal Chemistry written by Helmut Werner and published by Springer Science & Business Media. This book was released on 2008-12-16 with total page 361 pages. Available in PDF, EPUB and Kindle. Book excerpt: Since the discovery of ferrocene and the sandwich-type complexes, the development of organometallic chemistry took its course like an avalanche and became one of the scientific success stories of the second half of the twentieth century. Based on this development, the traditional boundaries between inorganic and organic chemistry gradually disappeared and a rebirth of the nowadays highly important field of homogeneous catalysis occurred. It is fair to say that despite the fact that the key discovery, which sparked it all off, was made more than 50 years ago, organometallic chemistry remains a young and lively discipline.
Download or read book Bibliography of Mass Spectroscopy Literature for 1970 written by and published by . This book was released on 1972 with total page 900 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Focus on Organometallic Chemistry Research written by Marin A. Cato and published by Nova Publishers. This book was released on 2005 with total page 218 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organometallic chemistry is based on the reactions and use of a class of compounds (R-M) that contain a covalent bond between carbon and metal. They are prepared either by direct reaction of the metal with an organic compound or by replacement of a metal from another organometallic substance. Research in organometallic chemistry is also conducted in the areas of cluster synthesis, main-group derivatives in unusual oxidation states, organometallic polymers, unstable organometallic compounds and intermediates in matrices, structure determination of organometallic compounds in the solid state [X-ray diffraction] and gaseous states [electron diffraction], and mechanisms of reactions of transient silylenes and related species. In addition to the traditional metals and semimetals, elements such as selenium, lithium and magnesium are considered to form organometallic compounds, e.g. organomagnesium compounds MeMgI, iodo(methyl)magnesium and diethylmagnesium which are Grignard reagents an organo-lithium compound BuLi butyllithium. Organometallic compounds often find practical use as catalysts, the processing of petroleum products and the production of organic polymers.
Download or read book Organometallic Chemistry written by Edward William Abel and published by Royal Society of Chemistry. This book was released on 1978 with total page 512 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Basic Organometallic Chemistry written by Ionel Haiduc and published by Walter de Gruyter. This book was released on 2011-06-01 with total page 517 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Current Research in Britain written by and published by . This book was released on 1990 with total page 526 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Organometallic Chemistry written by Edward W. Abel and published by Royal Society of Chemistry. This book was released on 1985 with total page 510 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organometallic chemistry is an interdisciplinary science which continues to grow at a rapid pace. Although there is continued interest in synthetic and structural studies the last decade has seen a growing interest in the potential of organometallic chemistry to provide answers to problems in catalysis synthetic organic chemistry and also in the development of new materials. This Specialist Periodical Report aims to reflect these current interests reviewing progress in theoretical organometallic chemistry, main group chemistry, the lanthanides and all aspects of transition metal chemistry. Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued. The current list of Specialist Periodical Reports can be seen on the inside flap of this volume.
Download or read book REARRANGEMENTS AND CHEMISTRY OF GROUP ELEMENTS English Edition Chemistry Book Paper II written by Dr. Renu Agarwal and published by Thakur Publication Private Limited. This book was released on 2023-11-01 with total page 328 pages. Available in PDF, EPUB and Kindle. Book excerpt: REARRANGEMENTS AND CHEMISTRY OF GROUP ELEMENTS e-Book in English Language for B.Sc 5th Semester UP State Universities By Thakur publication.
