Download or read book Structural and Synthetic Studies on Homo and Heterogeneous Transition Metal Carbonyl Cluster written by S. L. Cook and published by . This book was released on 1985 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Structural and Synthetic Studies on Homo and Heterogeneous Transition Metal Carbonyl Cluster Species written by Stephen Leonard Cook and published by . This book was released on 1985 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Transition Metal Carbonyl Cluster Chemistry written by Paul J. Dyson and published by CRC Press. This book was released on 2018-10-03 with total page 180 pages. Available in PDF, EPUB and Kindle. Book excerpt: Transition metal carbonyl clusters (TMCCs) continue to inspire great interest in chemical research, as much for their fascinating structures as for potential industrial applications conferred by their unique properties. This highly accessible book introduces the bonding, structure, spectroscopic properties, and characterization of clusters, and then explores their synthesis, reactivity, reaction mechanisms and use in organic synthesis and catalysis. Transition Metal Carbonyl Cluster Chemistry describes models and rules that correlate cluster structure with electron count, which are then applied in worked examples. Subsequent chapters explain how bonding relates to molecular structure, demonstrate the use of spectroscopic techniques such as NMR, IR and MS in cluster chemistry, and outline the factors contributing to the stability, dynamics and reactivity of clusters. The second part of this book discusses the synthesis and applications of TMCCs. It emphasizes the differences between the reactivities of clusters vs. mononuclear metal complexes, contingent to the availability of multiple-bonding sites and heterosite reactivity. The final chapters discuss reactions in which clusters act as homogeneous catalysts; including discussion on the use of solid and biphasic liquid-liquid supported clusters in heterogeneous catalysts. A useful reference for those commencing further research or post-graduate study on metal carbonyl clusters and advanced organometallic chemistry, this book is also a cornerstone addition to academic and libraries as well as private collections.

Download or read book Cluster Chemistry written by Guillermo Gonzalez-Moraga and published by Springer Science & Business Media. This book was released on 2013-11-09 with total page 310 pages. Available in PDF, EPUB and Kindle. Book excerpt: Cluster chemistry is one of the recent, exciting areas of Inorganic Chemistry. The occurence of molecular clusters, like fullerene C60, constitutes a fundamental feature midway between the chemistry of isolated chemical compounds and that of the elements. Main features of the Cluster Chemistry of both main group and transition metal elements are treated in this book. The author highlights aspects releated to the synthesis, the structure, the special bonding and the reactivity of these species. The book is written as a textbook for senior undergraduate and postgraduate students. References in tables andillustrations permit the reader to reach relevant original information. Professor Gonzalez-Moraga fills a demand for a publication appropriate for dissemination and specially for teaching this exciting subject. From the Contents: Current Concepts in Modern Chemistry - Transition Metal Cluster Chemistry - Main Group-Transition Metal Mixed Clusters - Cluster Compounds of the Main Group Elements - Synthetic Analogues of the Active Sites of Iron-Sulfur Proteins.

Download or read book Synthetic Structural and Electrochemical Studies of Some Transition Metal Carbonyl and Nitrosyl Complexes written by Robert Bertram English and published by . This book was released on 1977* with total page 410 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Late Transition Metal Carboryne Complexes written by Zaozao Qiu and published by Springer Science & Business Media. This book was released on 2012-01-05 with total page 143 pages. Available in PDF, EPUB and Kindle. Book excerpt: Zaozao Qiu shows in this thesis that transition metals can mediate or catalyze the cycloaddition or coupling reactions of carboryne with alkynes or alkenes to afford benzocarboranes, alkenylcarboranes or dihydrobenzocarboranes. These results represent powerful strategies to assemble useful complex molecules from very simple precursors in a single operation. Carboranes have many applications in medicine. However, their unique structures make derivatization difficult and the limited efficient synthetic methods to obtain functional carborane materials have restricted applications of carboranes within a narrow scope. This work breaks a new ground in metal-carboryne chemistry and will have a significant impact on synthetic, cluster and materials chemistry.

Download or read book Metal Clusters in Chemistry written by Pierre Braunstein and published by Wiley-VCH. This book was released on 2000-01-11 with total page 708 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal cluster chemistry is at the cutting edge between molecular and solid-state chemistry and has therefore had a great impact on the researchers working on organic, coordination, and solid-state chemistry, catalysis, physics, and materials science. The development of new sophisticated synthetic techniques has led to enormous progress in the synthesis of this diverse class of compounds. The number of clusters is growing rapidly, since the possible variations in the metal and ligand sphere are numerous. Modern bonding theories, such as the isolobal principle, have allowed a better understanding of the structures and properties of metal clusters, and thus paved the way for the usage of these versatile materials. Catalysis and nanomaterials are just two of the very promising application-oriented fields. Seventy six contributions, written by world experts in this research field, provide extensive coverage of different aspects of cluster chemistry, ranging from synthesis, structure determination, and dynamics to applications. Up-to-date information, including an impressive collection of structural data and illustrations, extensive coverage of the most important publications of the last decade, and many more features make this three-volume set a complete single-source guide for all researchers working in the area of cluster chemistry.

Download or read book The Interface of Main Group and Transition Metal Cluster Chemistry written by Kenton H. Whitmire and published by . This book was released on 1988 with total page 110 pages. Available in PDF, EPUB and Kindle. Book excerpt: This special issue reviews the literature concerning cluster complexes which contain both main group element and transition metal vertices. Synthetic methods and general reactivity patterns are summarized. Emphasis is placed on structural comparisons of cluster geometries for a wide variety of element combinations. Relationships between these mixed clusters and the main group element clusters known as Zintl ions are discussed.

Download or read book Ligated Transition Metal Clusters in Solid state Chemistry written by Jean-François Halet and published by Springer Nature. This book was released on 2019-08-29 with total page 201 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume dedicated to the memory of Marcel Sergent who was a leader in this field for many years, addresses past achievements and recent developments in this vibrant area of research. Large classes of ligated transition metal clusters are produced either exclusively or most reliably by means of high-temperature solid-state reactions. Among them, the Chevrel-Sergent phases and related materials have generated enormous interest since their discovery in 1971. Today, these materials and their numerous derivatives still constitute a vivid area of research finding some applications not only in superconductivity, but also in catalysis, optics or thermoelectricity to mention a few.

Download or read book Synthesis of Transition Metal Carbonyl Clusters with Phosphine Ligands written by and published by . This book was released on with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The chemistry of transition metal chalcogenide polynuclear clusters is a rapidly expanding area. The increasing interest is due to the search for structural models and precursors of extended inorganic solids with novel electronic, magnetic and optical properties. Our interest for the synthesis of a variety of transition - etal clusters is due to their use as a model and precursors for materials and catalyst. Synthesis and study of a variety of ligand substituted iron carbonyl cluster has been carried out to understand the reactivity features and structural variety. The main focus has been on the transition metal clusters containing chalcogens which act as bridges between different metal fragments and are helpful in cluster growth reactions and maintains the cluster integrity. A synthetic strategy has been developed to prepare a mixed metal cluster when a dichloromethane solution of [Fe3Y2(CO)6], Y=S, Se, Te and ML4 (M=Pd, L=PPh3) was reacted at room temperature in presence of trimethylamine-N-oxide. Substitution reaction of carbonyl groups by triphenylphosphine and bis(diphenylphosphino)methane ligands results in the formation of different types of trinuclear clusters. Homo metallic cluster as well mixed metal clusters with phosphine ligands has been synthesized by a room temperature reaction and characterized by FTIR, proton and 31P NMR spectroscopy. Some of the transition metal cluster contains chelating phosphine ligands which stabilizes the cluster integrity.

Download or read book Synthetic Structural and Catalytic Studies of Metal Carbonyl Clusters of Group VIII written by A. G. Jones and published by . This book was released on 1986 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Structural Synthetic And Kinetic Studies Of Some Transition Metal Carbonyl Dimers And Trimers written by David John Robinson and published by . This book was released on 1984 with total page 366 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Structural Studies of Metalation Products written by Ben Terrell Huie and published by . This book was released on 1976 with total page 618 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Transition Metal Carbonyl Hydride Cluster Complexes written by Mark Allen Andrews and published by . This book was released on 1977 with total page 584 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Studies in Synthetic Organometallic Chemistry written by Joseph Salvatore Merola and published by . This book was released on 1978 with total page 508 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Synthetic and Structural Aspects of Some Transition Metal Clusters written by M. d J. d S. C. Rosales Hoz and published by . This book was released on 1982 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Studies in Transition Metal Chemistry written by Allen Capron Sievert and published by . This book was released on 1980 with total page 496 pages. Available in PDF, EPUB and Kindle. Book excerpt: