Download or read book Structural and magnetic disorder in crystalline materials written by Davide Gambino and published by Linköping University Electronic Press. This book was released on 2019-05-14 with total page 70 pages. Available in PDF, EPUB and Kindle. Book excerpt: Disorder in crystalline materials can take different forms and originate from different sources. In particular, temperature introduces disorder in any kind of material. This can be observed as the appearance of vacant lattice sites in an otherwise perfect crystal, or as a random distribution of different elements on the same lattice in an alloy; at the same time, if the material is magnetic, temperature induces disorder also on the magnetic degrees of freedom. In this thesis, different levels of disorder associated to structure and magnetism are investigated by means of density functional theory and thermodynamic models. I start with diffusion of Ti vacancies in TiN, which is studied by means of nonequilibrium ab initio molecular dynamics using the color diffusion algorithm at different temperatures. The result is an Arrhenius behavior of Ti vacancy jump rates. A method to perform structural relaxations in magnetic materials in their hightemperature paramagnetic phase is then developed based on the disordered local moments approach in order to study vacancies, interstitial atoms, and combinations of defects in paramagnetic bcc Fe and B1 CrN, as well as the mixing enthalpy of bcc Fe1?xCrx random alloys. A correction to the energetics of every system due to the relaxation in the disordered magnetic state is observed in all cases. Not related to temperature and disorder, but very important for an accurate description of magnetic materials, is the choice of the exchange and correlation functional to be employed in the first principles calculations. We have investigated the performance of a recently developed meta-GGA functional, the strongly constrained and appropriately normed (SCAN) functional, in comparison with the more commonly used LDA and PBE on the ferromagnetic elemental solids bcc Fe, fcc Ni, and hcp Co, and SCAN it is found to give negligible improvements, if not a worsening, in the description of these materials. Finally, the coupling between vibrational and magnetic degrees of freedom is discussed by reviewing the literature and proposing an investigation of the influence of vibrations on longitudinal spin fluctuations. These excitations are here studied by means of thermodynamic models based on Landau expansion of the energy in even powers of the magnitude of the local magnetic moments. We find that vibrational and magnetic disorder alter the energy landscapes as a function of moment size also in bcc Fe, which is often considered a Heisenberg system, inducing a more itinerant electron behavior.
Download or read book Handbook of Crystal Structures and Magnetic Properties of Rare Earth Intermetallics written by Andrej Szytula and published by CRC Press. This book was released on 2020-07-09 with total page 294 pages. Available in PDF, EPUB and Kindle. Book excerpt: Rare-earth intermetallics, also known as lanthanide elements, play an important role in the study of magnetic materials and the development of semi- and super-conducting materials. This handbook provides an up-to-date compilation of crystallographic, physical, and magnetic data on rare-earth intermetallic compounds. Over 20 different structure types are described in detail with an emphasis on how crystal structure can affect magnetic properties. Theoretical models for magnetic interactions are described as well as the impact of crystal electric fields on transport properties, magneto crystalline anistropy and hyperfine interactions. This book provides materials scientists, engineers and physicists with all the critical information needed to use rare-earth intermetallics effectively in the development of new materials.
Download or read book Magnetism in Crystalline Materials written by A. P. Cracknell and published by Elsevier. This book was released on 2016-06-06 with total page 284 pages. Available in PDF, EPUB and Kindle. Book excerpt: Magnetism in Crystalline Materials covers the applications of the theory of groups of cambiant symmetry and the physical properties of magnetically ordered crystalline solids. This book is divided into eight chapters; the first of which discusses the macroscopic properties of magnetic crystals. The structures of magnetically ordered crystals are then explained; this topic is followed by discussions on the theory of corepresentations; magnetic phase transitions; and the tensor properties of magnetic crystals. This text also looks into topics on electrons, lattice vibrations, and spin waves. This selection will be valuable to physicists and to others interested in the magnetism of crystalline materials.
Download or read book Diffuse Neutron Scattering from Crystalline Materials written by Victoria M. Nield and published by Oxford University Press. This book was released on 2001 with total page 344 pages. Available in PDF, EPUB and Kindle. Book excerpt: This is the first comprehensive account of diffuse neutron scattering, a unique tool for determining structural disorder in solids. The text takes the reader through theoretical, computational and experimental developments in the subject and describes in detail its application to a number of structural disorder problems. These include the more traditional subjects of substitutional disorder in alloys and orientational disorder in molecular systems as well as the more recent studies of superior and framework materials. Particular emphasis is placed on recent refinement methods for data interpretation and these are compared with established computer simulation techniques and analytical approaches. The book collects disparate themes into one unique volume, which is written as an introduction to the methods for graduate scientist and as a valuable reference or the expert crystallographer who wishes to apply modern interpretative techniques to diffuse scattering data.
Download or read book Engineering of Crystalline Materials Properties written by Juan J. Novoa and published by Springer Science & Business Media. This book was released on 2007-12-14 with total page 520 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume collects the state of the art in molecular materials. It collects the lecture notes of a series of lectures given by some of the best specialists in the field at the 2007 Erice International School of Crystallography, and also a NATO-ASI course. The school first established "where we are" in terms of modeling, design, synthesis and applications of crystalline solids with predefined properties and then defined current and possible futuristic lines of development.
Download or read book Spin Arrangements and Crystal Structure Domains and Micromagnetics written by George T. Rado and published by Academic Press. This book was released on 2013-10-22 with total page 640 pages. Available in PDF, EPUB and Kindle. Book excerpt: Spin Arrangements and Crystal Structure, Domains, and Micromagnetics deals with cooperative phenomena characterized by ordered arrangements of magnetic moments subject to strong mutual interactions. The emphasis is on the ferromagnetism, ferrimagnetism, and antiferromagnetism of magnetically ordered materials such as insulators and metals. Both theoretical and experimental points of view are presented. Comprised of 12 chapters, this volume begins with an introduction to magnetism and crystal structure in nonmetals, followed by an evaluation of exchange interactions from experimental data. Subsequent chapters focus on the theory of neutron scattering by magnetic crystals; spin configuration of ionic structures; spin arrangements in metals; and permanent magnet materials. Fine particles, thin films, and exchange anisotropy are also considered, with particular reference to the effects of finite dimensions and interfaces on the basic properties of ferromagnets. The book also examines micromagnetics; domains and domain walls; the structure and switching of permalloy films; magnetization reversal in nonmetallic ferromagnets; and preparation and crystal synthesis of magnetic oxides. This book will be a useful resource for professionals and students with physics or chemistry backgrounds.
Download or read book Crystalline Electric Field Effects in f Electron Magnetism written by Robert Guertin and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 571 pages. Available in PDF, EPUB and Kindle. Book excerpt: The present conference, the fourth successive on this subject, was organized to commemorate the 75th birthday of Professor Wtodzimierz Trzebiatowski, one of the pioneers in the field of f-electron materials structure, particularly in the magnetism of actinides. This volume contains 64 papers presented at the conference held in Wroctaw, Poland, September 22-25, 1981. Twenty-one were invited talks. About 100 participants from 13 countries attended the meeting during four days of lecture presentation (note these two numbers have been constant for the last two conferences). The conference consisted of sessions devoted to the investigation of crystalline electric fields and structural effects by spectroscopic techniques, neutron diffraction, magnetic, thermodynamic and electrical measurements all over broad temperature, magnetic field and pressure ranges. Materials investigated included rare earth intermetallics, hydrides, diluted systems and actinides, and among them some exhibited singlet ground state behavior. The experimental results were supplemented by theory. It is our pleasure to mention those persons who helped us make the conference successful. The International Advisory Com mittee included W.J.L. Buyers, B.R. Cooper, J.E. Crow, P. Fulde, A. Furrer, T. Kasuya, L. Kowalewski, G.R. Lander, R. Lemaire and D. Wohlleben. We thank them for valuable suggestions concerning invited speakers. We also wish to thank the co-workers of the In stitute for Low Temperature and Structure Research of the Polish Academy of Sciences in Wroclaw, especially A. Baran, M. Grzebyk, K.
Download or read book Elements of Slow Neutron Scattering written by J. M. Carpenter and published by Cambridge University Press. This book was released on 2015-09-24 with total page 539 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides a comprehensive and up-to-date introduction to the fundamental theory and applications of slow-neutron scattering.
Download or read book Ferromagnetic Materials written by R. A. McCurrie and published by Academic Press. This book was released on 1994 with total page 328 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book covers the properties and structure of a wide range of magnetic materials with engineering applications. It discusses ferromagnetic, ferrigmagnetic, and amorphous materials and their role in the two major property groupings of high permeability and permanent-magnet materials. Other groups, including materials suitable for magnetic recording, magnetoelastic transducers, magneto-optical discs and magnetic bubble memories, are also included. The book providesan in-depth discussion of the basic mechanisms which determine magnetic properties, and features a comprehensive view of how the mechanisms of magnetization reversal and coercivity are related to and interpreted in terms of the structure of the various materials at both the atomic and microstructural levels. For ease of location of materials and topics, the chapters are structured with numbered headings. A large amount of information is presented in textual, tabular, and graphical form, and extensive references will direct the reader to the most important or most representative original papers or reviews. The book is aimed at research students in materials science and electrical engineering, and industrial researchers, for whom the concentration on useful materials will be of particular interest. Covers a wide range of ferromagnetic materials, including many permanent magnets currently under development or research Provides a clear interpretation of the observed properties of ferromagnetic materials or magnetic ceramics in terms of crystal and magnetic structure Presents a detailed discussion and interpretation of magnetic properties of 3.2% Si-Fe transformer core alloy Features extensive references, with easy access to specific materials or topics
Download or read book Glassy Metals Magnetic Chemical and Structural Properties written by Ryusuke Hasegawa and published by CRC Press. This book was released on 2018-01-18 with total page 288 pages. Available in PDF, EPUB and Kindle. Book excerpt: Covers: structure of metallic glass alloys; theory of magnetism in noncrystalline solids; electronic structure of metallic glasses; magnetism in transition metal base amorphous alloys; application of metallic glasses in low-frequency magnetic devices; magnetic material properties and applications of metallic glasses in electronic devices; rare-earth transition metal base alloys; corrosion properties of amorphous alloys.
Download or read book Crackling Noise written by Stefano Zapperi and published by Oxford University Press. This book was released on 2022-05-12 with total page 220 pages. Available in PDF, EPUB and Kindle. Book excerpt: The response of materials and the functioning of devices is often associated with noise. In this book, Stefano Zapperi concentrates on a particular type of noise, known as crackling noise, which is characterized by an intermittent series of broadly distributed pulses. While representing a nuisance in many practical applications, crackling noise can also tell us something useful about the microscopic processes ruling the materials behavior. Each crackle in the noise series usually corresponds to a localized impulsive event, an avalanche, occurring inside the material. A distinct statistical feature of crackling noise, and of the underlying avalanche behavior, is the presence of scaling, observed as power-law distributed noise pulses, long-range correlation, and scale free spectra. These are the hallmarks of critical phenomena and phase transitions. This work summarizes the current understanding of crackling noise, reviewing research undertaken in the past 30 years, from the early and influential ideas on self-organized criticality in sandpile models, to more modern studies on disordered systems. Crackling Noise covers the main theoretical models used to investigate avalanche phenomena, describes the statistical tools needed to analyze crackling noise, and provides a detailed discussion of a set of relevant examples of crackling noise in materials science. These include acoustic emission in fracture, strain bursts in amorphous and crystal plasticity, granular avalanches, magnetic noise in ferromagnets and superconductors, and fluid flow in porous media. The book concludes by considering the wider application of these models in the natural sciences.
Download or read book PEROVSKITES AND OTHER FRAMEWORK STRUCTURE CRYSTALLINE MATERIALS written by and published by Collaborating Academics. This book was released on 2021-01-14 with total page 821 pages. Available in PDF, EPUB and Kindle. Book excerpt: Perovskites are among the most famous materials due to their exceptional properties: they present nearly all existing types of interesting properties, in particular as ferroics or multiferroics, they may be insulators, (super)conductors, or semiconductors, magnetoresistant, they are used in numerous devices, they present hundreds of variants and different crystalline phases and phase transitions, and recently appeared as probably the most promising materials for photovoltaics. With a crystal structure characterized by octahedra that share their corners, these materials belong to the wider category of « Framework Structure (FWS) materials » the structure of which is based on units (octahedra, tetrahedra, …) that share some of their corners (or edges) with their neighbours. This particular feature of FWS materials confers to them unique properties. This review volume is constituted of 26 chapters on different aspects, and is divided in two parts, « Fundamental aspects and general properties », and « Elaborated materials and applied properties ». Its main purpose is to attempt to identify the properties common to all members of the vast family of FWS materials, and understand their differences. Besides perovskites, derived compounds as 2D perovskites, Dion-Jacobson, Ruddlesden-Popper, Aurivillius, tungsten-bronzes, and others, are presented, and their preparation and/or properties as single crystals, ceramics, thin films, multilayers, nanomaterials, nanofibers, nanorods, etc, are discussed. We focus on new trends and important recent developments by leaving somewhat aside more classical aspects which can be easily found in older textbooks or review articles. Among most recent applications, this volume focuses on applications related with interactions with other molecules, on photovoltaics, and on memories, with a special attention to perovskite solar cells that have certainly attracted the most attention of researchers in recent years, opening extremely promising routes in photovoltaics. In conclusion, this book presents a collection of texts elucidating various aspects of the relation between structural organization (including dynamical aspects) and singular properties of framework crystals; it proposes a reasonable balance between experimental and theoretical results, and between fundamental aspects and applied properties. This volume can be approached on several levels (each chapter initially assumes that the reader is not a specialist in the subject, and is presented in a pedagogical way) : it is accessible to master or doctoral students, as well as to researchers who want to have informations on recent developments, who will find excellent detailed introductions up to hotsubjects. It may also be used by undergraduate students who should approach given subjects. The volume contains 800 pages written by about 70 authors from different countries, it has an index, and is completed by numerous figures to illustrate the text.
Download or read book Single Crystal Neutron Diffraction from Molecular Materials written by Chick C. Wilson and published by World Scientific. This book was released on 2000 with total page 390 pages. Available in PDF, EPUB and Kindle. Book excerpt: This important book presents a comprehensive account of the techniques & applications of single crystal neutron diffraction in the area of chemical crystallography & molecular structure. Beginning with a brief description of the general principles & the reasons for choosing the technique - the "why" - the book covers the methods for both the production of neutrons & the measurement of their scattering by molecular crystals - the "how" - followed by a detailed survey of past, present & future applications - the "what". The coverage of both steady state & pulsed neutron sources & instrumentation is extensive, while the survey of applications is the most comprehensive yet undertaken. The book endeavours to show why the technique is an essential method for studying areas as diverse as hydrogen bonding & weak interactions, organometallics, supramolecular chemistry & crystal engineering, metal hydrides, charge density & pharmaceuticals. It is an ideal reference source for the research worker interested in using neutron diffraction to study the structure of molecules. Contents: Crystallography & the Importance of Structural Information; Neutron Scattering; Neutron Diffractometers; Review of Applications I: The Accurate Location of Atoms; Review of Applications II: Hydrogen Bonding & Other Intermolecular Interactions; Review of Applications III: Probing Vibrations & Disorder; Impact on Material Properties & Design; The Future: New Instruments, New Sources, New Techniques. Readership: Students & researchers involved in structural science, especially chemical crystallography.
Download or read book EPDIC 7 written by R. Delhez and published by . This book was released on 2001 with total page 396 pages. Available in PDF, EPUB and Kindle. Book excerpt: This is a two-volume set containing the proceedings of the May 2000 conference on European powder diffraction, a non-destructive technique widely applied for the characterization of crystalline materials. Part 1 (54 contributions) covers method development (deconvolution and pattern decomposition, determination of crystal structure and lattice constants, qualitative and quantitative phase analysis, analysis of microstructure and macrostress, and texture and coarse grains); instrumental development and measurement techniques; and synchrotron power, neutron powder, and in-situ (time-resolved) powder diffraction diffraction. Part 2 (80 contributions) addresses the results of applications of various methods to specific classes of materials. such as thin layers, polymers and amorphous materials, metals and alloys, minerals and inorganics, and organic materials. Distributed in the US by Enfield. c. Book News Inc.
Download or read book Polymer Nanocomposites written by Yiu-Wing Mai and published by Woodhead Publishing. This book was released on 2006-02-28 with total page 613 pages. Available in PDF, EPUB and Kindle. Book excerpt: Polymer nanocomposites are polymer matrices reinforced with nano-scale fillers. This new class of composite materials has shown enhanced optical, electrical and dielectric properties. This important book begins by examining the characteristics of the main types of polymer nanocomposites and then reviews their diverse applications. Part one focuses on polymer/nanoparticle composites, their synthesis, optical properties and electrical conductivity. Part two describes the electrical, dielectric and thermal behaviour of polymer/nanoplatelet composites, whilst polymer/nanotube composites are the subject of Part three. The processing and industrial applications of these nanocomposite materials are discussed in Part four, including uses in fuel cells, bioimaging and sensors as well as the manufacture and applications of electrospun polymer nanocomposite fibers, nanostructured transition metal oxides, clay nanofiller/epoxy nanocomposites, hybrid epoxy-silica-rubber nanocomposites and other rubber-based nanocomposites. Polymer nanocomposites: physical properties and applications is a valuable reference tool for both the research community and industry professionals wanting to learn about these materials and their applications in such areas as fuel cell, sensor and biomedical technology. Gives a comprehensive review of polymer nanocomposites and their properties A standard reference on this area Written by distinguished editors and a international team of authors
Download or read book 20 Jahrestagung der Deutschen Gesellschaft f r Kristallographie March 2012 Munich Germany written by and published by Walter de Gruyter GmbH & Co KG. This book was released on 2015-09-25 with total page 132 pages. Available in PDF, EPUB and Kindle. Book excerpt: Zeitschrift für Kristallographie. Supplement Volume 32 presents the complete Abstracts of all contributions to the 20th Annual Conference of the German Crystallographic Society in Munich 2012: - Plenary Talks - Microsymposia - Poster Session Supplement Series of Zeitschrift für Kristallographie publishes Proceedings and Abstracts of international conferences on the interdisciplinary field of crystallography.
Download or read book Neutron Diffraction of Magnetic Materials written by Izyumov and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 349 pages. Available in PDF, EPUB and Kindle. Book excerpt: Detennination of the magnetic structure of magnetic materials is a fundamental problem that can be solved by magnetic neutron diffraction techniques. By magnetic structures we refer to the mutual alignment of the magnetic moments of the atoms in a crystal and their overall alignment relative to the crystallographic axes. Some indirect, tentative data on the magnetic structure of magnetic materials can be obtained from research on their magnetic, mechanical, thermal, and other properties. But only neutron diffraction is a unique direct method of detennining the magnetic structure of a crystal. The magnetic structure of more than one thousand crystals with magnetic order has been studied during 30 years of neutron diffraction research made on reactors in a large number of laboratories in the world. The results of this research work are extensively described in the handbook Magnetic Structures Determined by Neutron Diffraction [176]; in the present book, we will often refer to this handbook. The first extensive theoretical generalization of the principles of magnetic neutron diffraction and the results of research on magnetic structures appeared in the book by Yu. A. Izyumov and R. P. Ozerov Magnetic Neutron Diffraction [24, 134].
