Download or read book Spin Dynamics in Radical Pairs written by Alan Lewis and published by Springer. This book was released on 2018-09-12 with total page 167 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book sheds new light on the dynamical behaviour of electron spins in molecules containing two unpaired electrons (i.e. a radical pair). The quantum dynamics of these spins are made complicated by the interaction between the electrons and the many nuclear spins of the molecule; they are intractable using analytical techniques, and a naïve numerical diagonalization is not remotely possible using current computational resources. Hence, this book presents a new method for obtaining the exact quantum-mechanical dynamics of radical pairs with a modest number of nuclear spins. Readers will learn how a calculation that would take 13 years using conventional wavepacket propagation can now be done in 1 day, and will also discover a new semiclassical method for approximating the dynamics in the presence of many nuclear spins. The new methods covered in this book are shown to provide significant insights into three topical and diverse areas: charge recombination in molecular wires (which can be used in artificially mimicking photosynthesis), magnetoelectroluminescence in organic light-emitting diodes, and avian magnetoreception (how birds sense the Earth’s magnetic field in order to navigate).
Download or read book Introduction to Dynamic Spin Chemistry written by Hisaharu Hayashi and published by World Scientific. This book was released on 2004 with total page 272 pages. Available in PDF, EPUB and Kindle. Book excerpt: Readership: Graduate students, researchers and industrialists in chemistry, physics and biology.
Download or read book Carbon Centered Free Radicals and Radical Cations written by Malcolm D. Forbes and published by John Wiley & Sons. This book was released on 2010-01-22 with total page 300 pages. Available in PDF, EPUB and Kindle. Book excerpt: Covers the most advanced computational and experimental methods for studying carbon-centered radical intermediates With its focus on the chemistry of carbon-centered radicals and radical cations, this book helps readers fully exploit the synthetic utility of these intermediates in order to prepare fine chemicals and pharmaceutical products. Moreover, it helps readers better understand their role in complex atmospheric reactions and biological systems. Thoroughly up to date, the book highlights the most advanced computational and experimental methods available for studying and using these critically important intermediates. Carbon-Centered Free Radicals and Radical Cations begins with a short history of the field of free radical chemistry, and then covers: A discussion of the relevant theory Mechanistic chemistry, with an emphasis on synthetic utility Molecular structure and mechanism, focusing on computational methods Spectroscopic investigations of radical structure and kinetics, including demonstrations of spin chemistry techniques such as CIDNP and magnetic field effects Free radical chemistry in macromolecules Each chapter, written by one or more leading experts, explains difficult concepts clearly and concisely, with references to facilitate further investigation of individual topics. The authors were selected in order to provide insight into a broad range of topics, including small molecule synthesis, polymer degradation, computational chemistry as well as highly detailed experimental work in the solid, liquid, and gaseous states. This volume is essential for students or researchers interested in building their understanding of the role of carbon-centered radical intermediates in complex systems and how they may be used to develop a broad range of useful products.
Download or read book Introduction To Dynamic Spin Chemistry Magnetic Field Effects On Chemical And Biochemical Reactions written by Hisaharu Hayashi and published by World Scientific Publishing Company. This book was released on 2004-03-08 with total page 267 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents a detailed account of one of the most mysterious problems in science — whether ordinary magnetic fields can exert an appreciable influence on chemical and biochemical reactions. The first aim of the book is to introduce this research, through theoretical and dynamic spin chemistry, to graduate students and researchers, by means of detailed theoretical and experimental descriptions. The second aim is to review typical recent investigations, which will stimulate new interest and applications in the 21st century. Because dynamic spin chemistry is based on established science, it is expected to provide a guide for all situations in which radicals, radical pairs, and higher spin species occur, including the effects of environmental electromagnetic fields on the human body.
Download or read book Principles of Electron Spin Resonance written by Neil Manning Atherton and published by Prentice Hall. This book was released on 1993 with total page 622 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Introduction to Frustrated Magnetism written by Claudine Lacroix and published by Springer Science & Business Media. This book was released on 2011-01-12 with total page 682 pages. Available in PDF, EPUB and Kindle. Book excerpt: The field of highly frustrated magnetism has developed considerably and expanded over the last 15 years. Issuing from canonical geometric frustration of interactions, it now extends over other aspects with many degrees of freedom such as magneto-elastic couplings, orbital degrees of freedom, dilution effects, and electron doping. Its is thus shown here that the concept of frustration impacts on many other fields in physics than magnetism. This book represents a state-of-the-art review aimed at a broad audience with tutorial chapters and more topical ones, encompassing solid-state chemistry, experimental and theoretical physics.
Download or read book The Physics of Polarized Targets written by Tapio O. Niinikoski and published by Cambridge University Press. This book was released on 2020-01-16 with total page 535 pages. Available in PDF, EPUB and Kindle. Book excerpt: Explains what spin is and how spins are polarized to study elementary particles, nuclei, atoms and molecular structures.
Download or read book World Scientific Reference On Spin In Organics In 4 Volumes written by Zeev Valy Vardeny and published by World Scientific. This book was released on 2017-12-27 with total page 1364 pages. Available in PDF, EPUB and Kindle. Book excerpt: This reference work on Spin in Organics contains four volumes dedicated to spin injection, spin transport, spin pumping, organic magnetic field effect, and molecular spintronics. The field of Organic Spintronics has accelerated and matured in the last dozen years with the realization of an organic spin-valve (in 2004) and magneto-resistance and magneto-electroluminescence in organic optoelectronic devices (2006).The book series is comprehensive in that it summarizes all aspects of Organic Spintronics to date. The first two volumes deal with spin injection, spin transport, spin manipulation and spin pumping into organic semiconductors. The main device that is thoroughly discussed here is the organic spin-valve, where spinterface states at the interface between the organic semiconductor and the ferromagnetic (FM) electrode has been the focus of many chapters. An interesting emerging subject is the role of chirality in the organic layer of the device. A relatively new method of achieving spin aligned carriers in organic semiconductors is spin pumping, where magnons in the FM substrate generate spin aligned carriers in the organic layer at the FM/organic interface.The third volume deals mainly with magnetic field effect in organic devices. Several spin-mixture processes that lead to magnetic field effect in devices and films are thoroughly discussed, such as hyperfine interaction, direct spin-orbit coupling, indirect spin-orbit coupling via Δg, triplet-triplet annihilation, and thermal spin alignment. The similarity between the magnetic field effect obtained in optoelectronic devices based on organic semiconductors and the novel hybrid organic-inorganic semiconductors is also a subject of intense interest. The fourth volume deals with spin in molecular films and devices. It includes thorough discussion of spin exchange interaction that leads to organic ferromagnets, as well as manifestation of various spin interactions in thin molecular films and devices.
Download or read book Organic Spintronics written by Zeev Valy Vardeny and published by CRC Press. This book was released on 2010-04-09 with total page 354 pages. Available in PDF, EPUB and Kindle. Book excerpt: Major development efforts in organic materials research has grown for an array of applications. Organic spintronics, in particular, has flourished in the area of organic magneto-transport. Reflecting the main avenues of advancement in this arena, this volume explores spin injection and manipulation in organic spin valves, the magnetic field effect in organic light-emitting diodes (OLEDs), the spin transport effect in relation to spin manipulation, organic magnets as spin injection electrodes in organic spintronics devices, the coherent control of spins in organic devices using the technique of electronically detected magnetic resonance, and the possibility of using organic spin valves as sensors.
Download or read book Bioengineering and Biophysical Aspects of Electromagnetic Fields written by Ben Greenebaum and published by CRC Press. This book was released on 2018-10-03 with total page 626 pages. Available in PDF, EPUB and Kindle. Book excerpt: Bioengineering and Biophysical Aspects of Electromagnetic Fields primarily contains discussions on the physics, engineering, and chemical aspects of electromagnetic (EM) fields at both the molecular level and larger scales, and investigates their interactions with biological systems. The first volume of the bestselling and newly updated Handbook of Biological Effects of Electromagnetic Fields, Third Edition, this book adds material describing recent theoretical developments, as well as new data on material properties and interactions with weak and strong static magnetic fields. Newly separated and expanded chapters describe the external and internal electromagnetic environments of organisms and recent developments in the use of RF fields for imaging. Bioengineering and Biophysical Aspects of Electromagnetic Fields provides an accessible overview of the current understanding on the scientific underpinnings of these interactions, as well as a partial introduction to experiments on the interactions themselves.
Download or read book Electron Spin Echo Envelope Modulation ESEEM Spectroscopy written by Sergei A. Dikanov and published by CRC Press. This book was released on 2024-11-01 with total page 430 pages. Available in PDF, EPUB and Kindle. Book excerpt: The first volume devoted entirely to Electron Spin Echo Envelope Modulation (ESEEM) Spectroscopy This valuable book provides an introduction and broad survey of topics in ESEEM spectroscopy, including the theory, instrumentation, peculiarities of ESE experiments, and analysis of experimental data with particular emphasis on orientationally disordered systems. Applications of ESEEM spectroscopy to study chemically and biologically important paramagnetic centers in single crystals, amorphous solids, and powders are discussed as well. Electron Spin Echo Envelope Modulation (ESEEM) Spectroscopy will benefit specialists in magnetic resonance spectroscopy, physicists, chemists, and biologists who use magnetic resonance in their research.
Download or read book Simulation Studies of Recombination Kinetics and Spin Dynamics in Radiation Chemistry written by Amit Agarwal and published by Springer Science & Business. This book was released on 2014-04-23 with total page 354 pages. Available in PDF, EPUB and Kindle. Book excerpt: Amit Agarwal’s thesis reports a substantial contribution to the microscopic simulation of radiation chemical reactions. In his research Agarwal extends existing models to further understand scavenging, spin and relaxation effects. This research has advanced the development of both the Monte Carlo Random Flights and the Independent Reaction Times (IRT) simulation tools. Particular highlights are the extension of these tools to include both the spin-exchange interaction and spin relaxation, both of which are influential in radiolytic systems where many reactions are spin-controlled. In addition, the study has led to the discovery of a novel correlation of the scavenging rate with the recombination time in low permittivity solvents. This finding goes against existing assumptions underlying the theory of diffusion kinetics while still being accommodated in the IRT method which demonstrates the power of this unconventional approach. The work in this thesis can be applied to a wide number of fields including the nuclear industry, medicine, food treatment, polymer curing, the preparation of nano-colloids, power generation and waste disposal.
Download or read book Recent Advances In Density Functional Methods Part I written by Delano Pun Chong and published by World Scientific. This book was released on 1995-11-30 with total page 427 pages. Available in PDF, EPUB and Kindle. Book excerpt: Of all the different areas in computational chemistry, density functional theory (DFT) enjoys the most rapid development. Even at the level of the local density approximation (LDA), which is computationally less demanding, DFT can usually provide better answers than Hartree-Fock formalism for large systems such as clusters and solids. For atoms and molecules, the results from DFT often rival those obtained by ab initio quantum chemistry, partly because larger basis sets can be used. Such encouraging results have in turn stimulated workers to further investigate the formal theory as well as the computational methodology of DFT.This volume contains ten contributions from active workers in DFT, covering topics from basic principles to methodology to applications. In the Foreword, Prof Walter Kohn gives his perspective on the recent advances in DFT. Because DFT is being developed in so many different directions, no single volume can provide a complete review of DFT. However, this volume will help both beginners and experimentalists to read the growing DFT literature more easily.
Download or read book Foundations of Modern EPR written by Gareth R. Eaton and published by World Scientific. This book was released on 1998 with total page 836 pages. Available in PDF, EPUB and Kindle. Book excerpt: Since its inception 50 years ago, electron paramagnetic resonance (EPR, also called ESR or EMR) has become a major tool in diverse fields ranging from biology and chemistry to solid state physics and materials science. This important book includes personal descriptions of early experiments by pioneers who laid the foundations for the field, perspectives on the state of the art, and glimpses of future opportunities. It presents a broad view of the foundations of EPR and its applications, and will therefore appeal to scientists in many fields. Even the expert will find here history not previously recorded and provocative views of future directions.
Download or read book Field cycling NMR Relaxometry written by Rainer Kimmich and published by Royal Society of Chemistry. This book was released on 2018-10-11 with total page 590 pages. Available in PDF, EPUB and Kindle. Book excerpt: Field-cycling NMR relaxometry is evolving into a methodology of widespread interest with recent technological developments resulting in powerful and versatile commercial instruments. Polymers, liquid crystals, biomaterials, porous media, tissue, cement and many other materials of practical importance can be studied using this technique. This book summarises the expertise of leading scientists in the area and the editor is well placed, after four decades of working in this field, to ensure a broad ranging and high quality title. Starting with an overview of the basic principles of the technique and the scope of its use, the content then develops to look at theory, instrumentation, practical limitations and applications in different systems. Newcomers to the field will find this book invaluable for successful use of the technique. Researchers already in academic and industrial settings, interested in molecular dynamics and magnetic resonance, will discover an important addition to the literature.
Download or read book Advanced EPR written by A.J. Hoff and published by Elsevier. This book was released on 2012-12-02 with total page 943 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advanced EPR: Applications in Biology and Biochemistry provides an up-to-date survey of existing EPR techniques and their applications in biology and biochemistry, and also provides a wealth of ideas for future developments in instrumentation and theory. The material is broadly organized into four parts. In the first part (chapters 1 to 6) pulsed EPR is discussed in detail. The second part (chapters 7 to 12) provides detailed discussions of a number of novel and experimental methods. The third part comprises seven chapters on double-resonance techniques, five on ENDOR and two on optically- and reaction yield-detected resonance. The final part is devoted to a thorough discussion of a number of new developments in the application of EPR to various biological and biochemical problems. Advanced EPR will interest biophysicists, physical biochemists, EPR spectroscopists and others who will value the extensive treatment of pulsed EPR techniques, the discussion of new developments in EPR instrumentation, and the integration of theory and experimental details as applied to problems in biology and biochemistry.
Download or read book Magnetic Orientation in Animals written by Roswitha Wiltschko and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 311 pages. Available in PDF, EPUB and Kindle. Book excerpt: Biological effects of magnetic fields have been studied in many animals and plants. The magnetic fields were of a wide intensity range and, as alternating fields, of a wide frequency range and of a variety of impulse shapes. Effects on the cellular level, on bio chemical processes, growth and development, interactions with physiology, sensory input, reflexes and rhythm control, to name just a few, have been reported. Numerous magnetically induced changes in behavior have also been described. Recently, the amount of literature covering biological effects of magnetic fields has been rapidly increasing. By now it has grown to such an extent that it can no longer be covered in one volume. Most reviews specialize and focus on particular aspects and/or types of fields or effects. For example, the book edited by MARET et al. (1986) gives an overview on biological effects of steady magnetic fields, MISAKIAN et al. (1993) reviewed those of extremely low frequency magnetic fields, focusing on in vitro effects. BERN HARD (1992) reported on 'electromagnetic smog' in view of pos sible effects on human health and well-being, and a series of papers edited by AMEMIYA (1994) summarizes Japanese research on effects of electromagnetic fields ranging from extern ely low to ultra-high frequencies. TENFORDE (1979) and ADEY (1981) sum marized and discussed tissue interactions, REITER (1993a) neu roendocrine and neurochemical changes associated with various kinds of electromagnetic fields. The book edited by KIRSCHVINK et al.
