Download or read book Spectroelectrochemical Studies of Some Platinum II and Palladium II Polypyridyl Complexes written by Susan Marie Rhodes and published by . This book was released on 1994 with total page 142 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Synthesis Characterization and Redox Studies of Platinum and Palladium Complexes with Mer coordinating Ligands written by Seher Kuyuldar Tastan and published by . This book was released on 2009 with total page 206 pages. Available in PDF, EPUB and Kindle. Book excerpt: Synthetic, structural, spectroscopic, and redox studies of platinum(II) and palladium(II) compounds with mer-coordinating ligands have been undertaken in an effort to better understand the role of the metal and the ligands in controlling d^6/d^8 electron-transfer reactions. A series of Pd(pip2NCN)X (pip2NCNH=1,3-bis(piperdylmethyl)benzene) and [Pd(pip2NNN)X]X (X=Cl, Br, I) (pip2NNN=2,6- bis(piperdyl-methyl)pyridine) complexes are reported. Electronic spectra are consistent with stabilization of ligand-to-metal-charge-transfer states as the ancillary ligand is varied along the ClBr
Download or read book The Chemistry of Platinum and Palladium with Particular Reference to Complexes of the Elements written by F. R. Hartley and published by . This book was released on 1973 with total page 570 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Synthetic and Spectroscopic Studies of Palladium II and Platinum II Dithioacid Complexes written by Margaret C. Cornock and published by . This book was released on 1977 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Synthesis and Emission Studies of Polypyridyl Complexes of Platinum II written by Jan-André Gertenbach and published by . This book was released on 2000 with total page 426 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Spectroscopic and Kinetic Studies of Tetragonal Planar Complexes of Platinum II and Palladium II written by David Gordon Cooper and published by c1976.. This book was released on 1976 with total page 526 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Spectroscopic and Kinetic Studies of Tetragonal Planar Complexes of Platinum II and Palladium II written by David Gordon Cooper and published by . This book was released on 1976 with total page 526 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Platinum II and Palladium II Complexes of Some Phosphine nitrile Ligands written by David A. Blinn and published by . This book was released on 1976 with total page 106 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book LUMINESCENT PALLADIUM II PL written by Pui-Keong Chow and published by Open Dissertation Press. This book was released on 2017-01-26 with total page 502 pages. Available in PDF, EPUB and Kindle. Book excerpt: This dissertation, "Luminescent Palladium(II) and Platinum(II) Complexes With Tridentate Monoanionic and Tetradentate Dianionic Cyclometallated Ligands: Structures, Photophysical Properties and Material Application" by Pui-keong, Chow, 周沛強, was obtained from The University of Hong Kong (Pokfulam, Hong Kong) and is being sold pursuant to Creative Commons: Attribution 3.0 Hong Kong License. The content of this dissertation has not been altered in any way. We have altered the formatting in order to facilitate the ease of printing and reading of the dissertation. All rights not granted by the above license are retained by the author. Abstract: Four structural isomers of platinum(II) complexes with C-deprotonated R-C DEGREESN DEGREESN-R' cyclometallated ligands (R-C DEGREESN DEGREESN-R' = -extended 6-aryl-2,2'-bipyridine derivatives containing 2-naphthyl, 3-isoquinolinyl, 1-isoquinolinyl or 2-quinolinyl moieties) have been synthesized with their photophysical properties investigated. The one bearing a 3-isoquinolinyl moiety shows the highest emission quantum yield among the four and hence has been extensively modified to give a series of complexes with different ancillary ligands (chloride, iodide, phenoxide, or acetylide). Most of these complexes show vibronic emission (max = 515-644 nm) with high emission quantum yield (up to unity) in degassed CH2Cl2; one of them has been used for OLED fabrication and shows a maximum EQE of 8.15 % with current efficiency of 25 cd A-1. The photocatalytic properties of these derivative complexes for oxidative tertiary amine functionalization have also been examined. Several highly robust and emissive platinum(II) complexes supported by two types of tetradentate O DEGREESN DEGREESC DEGREESN ligand systems (Φem up to 0.99; Td up to 520 ℃) have been synthesized and show different emission energies (λmax = 482-561 nm). Most of them exhibit excimeric emission in solution state at room temperature which are dependent on the modifications on the tetradentate O DEGREESN DEGREESC DEGREESN ligands. DFT/TDDFT calculations reveal that the metal complex showing the most intense excimeric emission possesses an excimeric excited state with a localized structure, which is unusual for these classes of platinum(II) complexes. Based on this finding, WOLED (ηL(max) = 71.0 cd/A, ηp(max) = 55.8 lm/W, ηExt = 16.5 %, CIE = 0.33, 0.42, CRI = 77) and WPLED (ηL(max) = 17.0 cd/A, ηp(max) = 9.1 lm/W, ηExt = 9.7 %, CIE = 0.43, 0.45, CRI = 78) based on this complex have been fabricated with high efficiency achieved. Palladium(II) complexes containing C-deprotonated R-C DEGREESN DEGREESN-R' cyclometallated and pentafluorophenylacetylide ligands exhibit phosphorescence in both solid state and fluid solutions at room temperature with some of them exhibiting aggregation-induced emission (AIE). These complexes have been applied as photosensitizers in light-induced oxidative functionalization of secondary and tertiary benzylic amines as well as in light-induced hydrogen production, with a maximum of 175 turnovers for hydrogen produced. Palladium(II) complexes containing two types of tetradentate dianionic O DEGREESN DEGREESC DEGREESN ligand systems (Systems 1 and 2) have been prepared and show constrasting photophyical properties. A full scale time-resolved spectroscopic analysis has been done on some of these complexes and a platinum(II) analogue. These complexes are found to have similar excited state decay pathway( 〖S_1〗 DEGREESi→〖S_1〗 DEGREESf→T) with ΦISC of about unity. The emission efficiency of System 2 complexes is superior to that of System 1 complexes, which is ascribed to the suppression of excited state distortion on the basis of the results of DFT calculations. A lower radiative decay rate of System 2 palladium(II) complexes relative to the platinum(II) analogue has been found, which could be due to their lower spin-orbit coupling constant. One of the palladium(II) complexes ha
Download or read book Photophysical Studies of Silver I Platinum II Palladium II and Nickel II Complexes and Their Use in Electronic Devices written by and published by . This book was released on 2007 with total page 153 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Synthesis and Isomerization Studies of New Palladium II and Platinum II Alkyly Complexes written by David Glenn Garza and published by . This book was released on 1992 with total page 234 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Synthesis and Structural Analysis of Some Pi allylic Complexes of Palladium II and Platinum II written by Wai-Ling Anna Cordelia Chan and published by . This book was released on 1970 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Higher Oxidation State Organopalladium and Platinum Chemistry written by Allan J. Canty and published by Springer Science & Business Media. This book was released on 2011-02-27 with total page 195 pages. Available in PDF, EPUB and Kindle. Book excerpt: Kyle A. Grice, Margaret L. Scheuermann and Karen I. Goldberg: Five-Coordinate Platinum(IV) Complexes.- Jay A. Labinger and John E. Bercaw: The Role of Higher Oxidation State Species in Platinum-Mediated C-H Bond Activation and Functionalization.- Joy M. Racowski and Melanie S. Sanford: Carbon-Heteroatom Bond-Forming Reductive Elimination from Palladium(IV) Complexes.- Helena C. Malinakova: Palladium(IV) Complexes as Intermediates in Catalytic and Stoichiometric Cascade Sequences Providing Complex Carbocycles and Heterocycles.- Allan J. Canty and Manab Sharma: h1-Alkynyl Chemistry for the Higher Oxidation States of Palladium and Platinum.- David C. Powers and Tobias Ritter: Palladium(III) in Synthesis and Catalysis.- Marc-Etienne Moret: Organometallic Platinum(II) and Palladium(II) Complexes as Donor Ligands for Lewis-Acidic d10 and s2 Centers.
Download or read book Synthetic and Kinetic Studies of Some Platinum II Complexes written by Henry Alexander Raethel and published by . This book was released on 1969 with total page 380 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Design and Synthesis of Luminescent Metal Polypyridyl Complexes of Platinum ii Ruthenium ii and Osmium ii for Chemosensing and Biological Studies written by Wing-Suen Tang and published by . This book was released on 2017-01-27 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Preparative and Spectroscopic Studies of Some Platinum and Palladium Complexes written by D. A. Duddell and published by . This book was released on 1967 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Self assembly of Two and Three dimensional Palladium II and Platinum II Macrocyclic Complexes written by Jun Fan and published by . This book was released on 1999 with total page 830 pages. Available in PDF, EPUB and Kindle. Book excerpt:
