Download or read book Phosphorus III Ligands in Homogeneous Catalysis written by Paul C. J. Kamer and published by John Wiley & Sons. This book was released on 2012-05-09 with total page 673 pages. Available in PDF, EPUB and Kindle. Book excerpt: Over the last 60 years the increasing knowledge of transition metal chemistry has resulted in an enormous advance of homogeneous catalysis as an essential tool in both academic and industrial fields. Remarkably, phosphorus(III) donor ligands have played an important role in several of the acknowledged catalytic reactions. The positive effects of phosphine ligands in transition metal homogeneous catalysis have contributed largely to the evolution of the field into an indispensable tool in organic synthesis and the industrial production of chemicals. This book aims to address the design and synthesis of a comprehensive compilation of P(III) ligands for homogeneous catalysis. It not only focuses on the well-known traditional ligands that have been explored by catalysis researchers, but also includes promising ligand types that have traditionally been ignored mainly because of their challenging synthesis. Topics covered include ligand effects in homogeneous catalysis and rational catalyst design, P-stereogenic ligands, calixarenes, supramolecular approaches, solid phase synthesis, biological approaches, and solubility and separation. Ligand families covered in this book include phosphine, diphosphine, phosphite, diphosphite, phosphoramidite, phosphonite, phosphinite, phosphole, phosphinine, phosphinidenene, phosphaalkenes, phosphaalkynes, P-chiral ligands, and cage ligands. Each ligand class is accompanied by detailed and reliable synthetic procedures. Often the rate limiting step in the application of ligands in catalysis is the synthesis of the ligands themselves, which can often be very challenging and time consuming. This book will provide helpful advice as to the accessibility of ligands as well as their synthesis, thereby allowing researchers to make a more informed choice. Phosphorus(III) Ligands in Homogeneous Catalysis: Design and Synthesis is an essential overview of this important class of catalysts for academic and industrial researchers working in catalyst development, organometallic and synthetic chemistry.

Download or read book The Chemistry of Ruthenium Rhodium Palladium Osmium Iridium and Platinum written by Stanley E. Livingstone and published by Elsevier. This book was released on 2017-01-31 with total page 225 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Chemistry of Ruthenium, Rhodium, Palladium, Osmium, Iridium and Platinum

Download or read book NMR in Organometallic Chemistry written by Paul S. Pregosin and published by John Wiley & Sons. This book was released on 2013-07-26 with total page 409 pages. Available in PDF, EPUB and Kindle. Book excerpt: The first and ultimate guide for anyone working in transition organometallic chemistry and related fields, providing the background and practical guidance on how to efficiently work with routine research problems in NMR. The book adopts a problem-solving approach with many examples taken from recent literature to show readers how to interpret the data. Perfect for PhD students, postdocs and other newcomers in organometallic and inorganic chemistry, as well as for organic chemists involved in transition metal catalysis.

Download or read book Homonuclear and Heteronuclear Complexes Containing Bifunctional Phosphine Ligands with Emphasis on 2 6 bis diphenylphosphino pyridine written by Fred Edwin Wood and published by . This book was released on 1984 with total page 526 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book 31P and 13C NMR of Transition Metal Phosphine Complexes written by Paul S. Pregosin and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 164 pages. Available in PDF, EPUB and Kindle. Book excerpt: For almost a quarter of a century the words "nuclear magnetic reso nance" were synonymous with proton I,leasurements. During this period the literature abounded with a seemingly infinite variety of 1H NHR studies concerned primarily with carbon chemistry. Occasionally a "novel" nucleus was studied and, even in those early days, the poten- 13 14 31 19 tial offered by C, N, P and F was clearly recognized. Despite the allure, the technical difficulties involved in measuring some of these nuclei were far from trivial. Small magnetic moments and low natural abundance in combination with spin-spin coupling from other nuclei, mostly protons, resulted in a signal-to-noise problem whose severity effectively excluded the study of metal complexes with unfa vorable solubility characteristics. The first important breakthrough came with the advent of broad band 1H-decoupling. For example, the featureless broad 31p resonance associated with the commonly used ligand triphenyl phosphine is converted to a sharp, more readily ob served singlet when wide-band decoupling is employed (see Fig. 1). Despite this improvement investigation of more interesting molecules, such as catalytically active complexes was forced to await the devel opment of Fourier Transform methods since only with relatively rapid signal averaging methods could sufficient signal-to-noise ratios be achieved.

Download or read book Phosphorus Compounds written by Maurizio Peruzzini and published by Springer Science & Business Media. This book was released on 2011-06-10 with total page 477 pages. Available in PDF, EPUB and Kindle. Book excerpt: Each chapter of Phosphorus Compounds: Advanced Tools in Catalysis and Material Sciences have been carefully selected by the editors in order to represent a state-of-the-art overview of how phosphorus chemistry can provide solutions in various fields of applications. The editors have assembled an international array of world-renowned scientists and each chapter is written by experts in the fields of synthetic chemistry, homogeneous catalysis, dendrimers, theoretical calculations, materials science, and medicinal chemistry with a special focus on the chemistry of phosphorus compounds. Phosphorus Compounds: Advanced Tools in Catalysis and Material Sciences is of interest to a general readership ranging from advanced university course students to experts in academia and industry.

Download or read book Organometallic Chemistry of Five Membered Heterocycles written by Alexander Sadimenko and published by Elsevier. This book was released on 2019-10-16 with total page 792 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organometallic Chemistry of Five-Membered Heterocycles explores the synthesis, coordination modes, reactivity of coordinated five-membered monoheterocycles, and organometallic complexes of their numerous derivatives, including chelating ligands, oligomers, and macrocycles. Beginning with the introduction of organometallic compounds, this book dives deep into the reactivity of coordinated five-membered monoheterocycles and the derivatives of fundamental ligands. This book is an ideal reference for researchers working in organometallic, heterocyclic, materials, or organic chemistry, and catalysis. The readers will gain a comprehensive understanding of modern synthetic methods, reactivity trends of heteroaromatic ligands, and the methods of modern materials construction.

Download or read book Supercritical Fluid Technology in Materials Science and Engineering written by Ya-Ping Sun and published by CRC Press. This book was released on 2002-03-26 with total page 595 pages. Available in PDF, EPUB and Kindle. Book excerpt: This title analyzes the chemical reactions, structures and fundamental properties of supercritical fluid systems for the production of new compounds, nanomaterials, fibers, and films. It compiles contemporary research and technological advances for increased selectivity and reduced waste in chemical, industrial, pharmaceutical, and biomedical applications. Topics include fluid dynamics, catalysis, hydrothermal synthesis, surfactants, conducting polymers, crystal growth, and other aspects and applications of supercritical fluids.

Download or read book Bibliography of Mass Spectroscopy Literature for 1970 written by and published by . This book was released on 1972 with total page 900 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Annual Reports on NMR Spectroscopy written by and published by Academic Press. This book was released on 2022-08-31 with total page 266 pages. Available in PDF, EPUB and Kindle. Book excerpt: Annual Reports on NMR Spectroscopy, Volume 107, the latest release in a series that has established itself as a premier resource for both specialists and non-specialists interested in new techniques and applications pertaining to NMR spectroscopy, includes a variety of updated chapters covering NMR Diffusion Studies, Recent Advances in Understanding of Nucleus Contributions to NMR Nuclear Shieldings, and more. - Serves as the premier resource for learning new techniques and applications in NMR spectroscopy - Provides a key reference for chemists and physicists using NMR spectroscopy to study the structure and dynamics of molecules - Covers all aspects of molecular science, including MRI (Magnetic Resonance Imaging)

Download or read book Comprehensive Handbook on Hydrosilylation written by B. Marciniec and published by Elsevier. This book was released on 2013-10-22 with total page 767 pages. Available in PDF, EPUB and Kindle. Book excerpt: This handbook provides an up-to-date account of hydrosilylation reactions and the directions in which synthetic and mechanistic studies as well as practical applications of these processes are proceeding. The book consists of two parts: the first is descriptive, presenting the catalytic, mechanistic, structural and synthetic aspects of hydrosilylation, as well as its application in organic and organosilicon chemistry. The second part, presented in tabular form sets out encyclopedic information concerning reaction conditions taken from more than 2000 papers and patents in the period 1965 - 1990.

Download or read book Comprehensive Coordination Chemistry II written by J. A. McCleverty and published by Newnes. This book was released on 2003-12-03 with total page 11845 pages. Available in PDF, EPUB and Kindle. Book excerpt: Comprehensive Coordination Chemistry II (CCC II) is the sequel to what has become a classic in the field, Comprehensive Coordination Chemistry, published in 1987. CCC II builds on the first and surveys new developments authoritatively in over 200 newly comissioned chapters, with an emphasis on current trends in biology, materials science and other areas of contemporary scientific interest.

Download or read book Official Gazette of the United States Patent and Trademark Office written by and published by . This book was released on 1993 with total page 656 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Heteronuclear Metal Metal Bonds written by R.D. Adams and published by Elsevier. This book was released on 2004-09-16 with total page 458 pages. Available in PDF, EPUB and Kindle. Book excerpt: The number of organometallic compounds containing heteronuclear metal-metal bonds has grown tremendously in the last ten years. Also known as cluster compounds, these compounds have been found to exhibit a rich diversity of molecular structures and reactivities. Descriptions of the structures and transformations of the complexes are central features. Separate chapters have been prepared for compounds containing bonds between transition metals and the metals of the copper and zinc subgroups. Unlike COMC, this volume contains an entire chapter devoted to studies of heteronuclear metal compounds in catalysis.

Download or read book Technical Abstract Bulletin written by and published by . This book was released on with total page 912 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Organo Transition Metal Compounds and Related Aspects of Homogeneous Catalysis written by B. L. Shaw and published by Elsevier. This book was released on 2016-06-06 with total page 231 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organo-Transition Metal Compounds and Related Aspects of Homogeneous Catalysis covers compounds that possess carbon atoms bonded to metal and to other carbon atoms. The order in which the substances appear in the book is based on the number of carbon atoms it have. The first section is about the alkyl, aryl, ethynyl, acyl, and carbene complexes. The second section deals with olefin and chelating diolefin complexes and complexes formed from acetylene. The following section covers the p-allylic complexes. The structures, stability, and bonding of alkyl and aryl complexes are fully covered. The magnetic moments and electronic spectra are discussed in detail.The fourth section discusses the conjugated diolefinic complexes that contain butadiene or cyclobutadiene. The rest of the book focuses on cyclopentadienyls, arene complexes, tropylium complexes, and complexes formed from cyclo-octatetraene or azulene. The book will be a useful tool for chemists, chemical engineers, and students and researchers in the field of chemistry.

Download or read book Radically Different A Themed Issue in Honor of Professor Bernd Giese on the Occasion of His 80th Birthday written by Katharina M. Fromm and published by MDPI. This book was released on 2020-12-02 with total page 284 pages. Available in PDF, EPUB and Kindle. Book excerpt: This Special Issue came together thanks to contributions from friends and colleagues of Prof. Bernd Giese on behalf of his 80th birthday on 2 June 2020. Reflecting on the varied interests of Bernd in all areas of chemistry, this issue contains work, including historical work, on inorganic coordination chemistry, nanomaterials, theory, and organic and radical chemistry—Bernd’s core expertise. It is wonderful that so many different publications came together from all over the world, as both review articles and original contributions, making this Special Issue worthwhile reading.