Download or read book Solvothermal Synthesis and Characterization of Lower Group 14 and Transition Metal Based Extended Materials written by and published by . This book was released on 2005 with total page 382 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Dissertation Abstracts International written by and published by . This book was released on 2005 with total page 842 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Synthesis Characterization and Reactivity of Some Low coordinate Low oxidation State Heavier Main Group 14 Element Species written by Madison Louis McCrea-Hendrick and published by . This book was released on 2018 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: This dissertation describes the synthesis, characterization and reactivity of some low-coordinate, low-oxidation state heavier main group 13 and 14 element species. Chapter 2 describes the reactivity of the heavier main group 13 element digallene, (GaAr[superscript iPr4])2, (Ar[superscript iPr4] = -C6H3-2,6-(C6H3-2,6-[superscript i]Pr2)2) with group 6 transition metal hexacarbonyls under photoirradiation to form the bis(gallanediyl) complexes, trans-bis(GaAr[superscript iPr4])2M(CO)4 (M = Cr, Mo, or W). The mechanism of formation of these products was investigated both computationally and experimentally. A postulated intermediate in their formation is the monogallanediyl complex, Ga(Ar[superscript iPr4])Mo(CO)5 which was synthesized by the reaction (GaAr[superscript iPr4])2 with two equivalents Mo(CO)5NMe3. (GaAr[superscript iPr4])2 was also reacted at 25°C with Co2(CO)8 to give Ga(Ar[superscript iPr4])Co2(CO)7, in which the gallanediyl fragment is bound to each cobalt atom in a bridging fashion. Chapter 3 is an extension of the work in Chapter 2 to the reactions of the heavier main group 14 element dimetallynes, (EAr[superscript iPr4])2 (E = Ge or Sn), with group 6 transition metal hexacarbonyls under photoirradiative conditions. These reactions afforded the products {Ar[superscript iPr4]EM(CO)4}2 (E = Ge or Sn; M = Cr, Mo, or W) which featured rhomboid E2M2 cores with Ar[superscript iPr4]E units bridging transition metal tetracarbonyl fragments, M(CO)4. Chapter 4 describes the reactions of the aryl tin(II) hydrides {Ar[superscript iPr6]Sn([mu]-H)}2 (Ar[superscript iPr6] = C6H3-2,6-(C6H2-2,4,6-[superscript i]Pr6)2) and {Ar[superscript iPr4]Sn([mu]-H)}2 with phenyl acetylene and diphenyl acetylene. The reactions with diphenyl acetylene affords simple insertion of the Sn-H bond into a [pi]-bond of the alkyne to yield the products ArSnC(Ph)C(H)Ph (Ar = Ar[superscript iPr6] or Ar[superscript iPr4]). In contrast, the reaction of {ArSn([mu]-H)}2 with phenyl acetylene affords different products that are connected with the presence (Ar[superscript iPr6]) or absence (Ar[superscript iPr4]) of an isopropyl group at the remote para position of the flanking aryl rings of the terphenyl substituent. When {Ar[superscript iPr6]Sn([mu]-H)}2 is reacted with phenyl acetylene the product Ar[superscript iPr6](H)SnC(H)C(Ph)Sn(H)Ar[superscript iPr6] containing a 1,2-distannacyclobut-3-ene moiety is obtained as a colorless solid. In contrast, the reaction of {Ar[superscript iPr4]Sn([mu]-H)}2 with phenyl acetylene affords a red product of formula Ar[superscript iPr4]SnC(H)C(Ph)Sn(H)2Ar[superscript iPr4] with the tin atoms having different oxidation states of +2 and +4 as determined by solution 119Sn NMR spectroscopy. Chapter 5 describes the synthesis and characterization of the most sterically congested tetrylenes currently known: E(Ar[superscript iPr6])2 (E = Ge, Sn, or Pb). Computational studies of these tetrylenes and E(Ar[superscript Me6])2 (Ar[superscript Me6] = C6H3-2,6-(C6H2-2,4,6-Me3)2) and E(Ar[superscript iPr4])2 were also performed with and without dispersion corrections to evaluate the contribution of London dispersion force effects on the C[subscript ipso]-E-C[subscript ipso] interligand angle.
Download or read book Modern Inorganic Synthetic Chemistry written by Ruren Xu and published by Elsevier. This book was released on 2017-02-11 with total page 810 pages. Available in PDF, EPUB and Kindle. Book excerpt: Modern Inorganic Synthetic Chemistry, Second Edition captures, in five distinct sections, the latest advancements in inorganic synthetic chemistry, providing materials chemists, chemical engineers, and materials scientists with a valuable reference source to help them advance their research efforts and achieve breakthroughs. Section one includes six chapters centering on synthetic chemistry under specific conditions, such as high-temperature, low-temperature and cryogenic, hydrothermal and solvothermal, high-pressure, photochemical and fusion conditions. Section two focuses on the synthesis and related chemistry problems of highly distinct categories of inorganic compounds, including superheavy elements, coordination compounds and coordination polymers, cluster compounds, organometallic compounds, inorganic polymers, and nonstoichiometric compounds. Section three elaborates on the synthetic chemistry of five important classes of inorganic functional materials, namely, ordered porous materials, carbon materials, advanced ceramic materials, host-guest materials, and hierarchically structured materials. Section four consists of four chapters where the synthesis of functional inorganic aggregates is discussed, giving special attention to the growth of single crystals, assembly of nanomaterials, and preparation of amorphous materials and membranes. The new edition's biggest highlight is Section five where the frontier in inorganic synthetic chemistry is reviewed by focusing on biomimetic synthesis and rationally designed synthesis. - Focuses on the chemistry of inorganic synthesis, assembly, and organization of wide-ranging inorganic systems - Covers all major methodologies of inorganic synthesis - Provides state-of-the-art synthetic methods - Includes real examples in the organization of complex inorganic functional materials - Contains more than 4000 references that are all highly reflective of the latest advancement in inorganic synthetic chemistry - Presents a comprehensive coverage of the key issues involved in modern inorganic synthetic chemistry as written by experts in the field
Download or read book Nanocatalysts written by Indrajit Sinha and published by BoD – Books on Demand. This book was released on 2019-07-31 with total page 170 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nanocatalysis is a topical area of research that has huge potential. It attempts to merge the advantages of heterogeneous and homogeneous catalysis. The collection of articles in this book treats the topics of specificity, activity, reusability, and stability of the catalyst and presents a compilation of articles that focuses on different aspects of these issues.
Download or read book Introduction to Reticular Chemistry written by Omar M. Yaghi and published by John Wiley & Sons. This book was released on 2019-03-22 with total page 684 pages. Available in PDF, EPUB and Kindle. Book excerpt: A concise introduction to the chemistry and design principles behind important metal-organic frameworks and related porous materials Reticular chemistry has been applied to synthesize new classes of porous materials that are successfully used for myraid applications in areas such as gas separation, catalysis, energy, and electronics. Introduction to Reticular Chemistry gives an unique overview of the principles of the chemistry behind metal-organic frameworks (MOFs), covalent organic frameworks (COFs), and zeolitic imidazolate frameworks (ZIFs). Written by one of the pioneers in the field, this book covers all important aspects of reticular chemistry, including design and synthesis, properties and characterization, as well as current and future applications Designed to be an accessible resource, the book is written in an easy-to-understand style. It includes an extensive bibliography, and offers figures and videos of crystal structures that are available as an electronic supplement. Introduction to Reticular Chemistry: -Describes the underlying principles and design elements for the synthesis of important metal-organic frameworks (MOFs) and related materials -Discusses both real-life and future applications in various fields, such as clean energy and water adsorption -Offers all graphic material on a companion website -Provides first-hand knowledge by Omar Yaghi, one of the pioneers in the field, and his team. Aimed at graduate students in chemistry, structural chemists, inorganic chemists, organic chemists, catalytic chemists, and others, Introduction to Reticular Chemistry is a groundbreaking book that explores the chemistry principles and applications of MOFs, COFs, and ZIFs.
Download or read book Functionalization of Graphene written by Vasilios Georgakilas and published by John Wiley & Sons. This book was released on 2014-04-03 with total page 507 pages. Available in PDF, EPUB and Kindle. Book excerpt: All set to become the standard reference on the topic, this book covers the most important procedures for chemical functionalization, making it an indispensable resource for all chemists, physicists, materials scientists and engineers entering or already working in the field. Expert authors share their knowledge on a wide range of different functional groups, including organic functional groups, hydrogen, halogen, nanoparticles and polymers.
Download or read book Materials for Lithium Ion Batteries written by Christian Julien and published by Springer Science & Business Media. This book was released on 2000-10-31 with total page 658 pages. Available in PDF, EPUB and Kindle. Book excerpt: A lithium-ion battery comprises essentially three components: two intercalation compounds as positive and negative electrodes, separated by an ionic-electronic electrolyte. Each component is discussed in sufficient detail to give the practising engineer an understanding of the subject, providing guidance on the selection of suitable materials in actual applications. Each topic covered is written by an expert, reflecting many years of experience in research and applications. Each topic is provided with an extensive list of references, allowing easy access to further information. Readership: Research students and engineers seeking an expert review. Graduate courses in electrical drives can also be designed around the book by selecting sections for discussion. The coverage and treatment make the book indispensable for the lithium battery community.
Download or read book Handbook of Nanoparticles written by Mahmood Aliofkhazraei and published by Springer. This book was released on 2015-08-07 with total page 2000 pages. Available in PDF, EPUB and Kindle. Book excerpt: This Handbook covers all aspects of Nanoparticles, from their preparation to their practical application. The chapters present different ways to synthesize nanometer particles, as well as their functionalization and other surface treatments to allow them to a practical use. Several industrial applications of such nanometer particles are also covered in this Handbook. It is a complete reference for those working with Nanotechnology at the lab level, from students to professionals.
Download or read book Metal Organic Framework Materials written by Leonard R. MacGillivray and published by John Wiley & Sons. This book was released on 2014-09-19 with total page 1210 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal-Organic Frameworks (MOFs) are crystalline compounds consisting of rigid organic molecules held together and organized by metal ions or clusters. Special interests in these materials arise from the fact that many are highly porous and can be used for storage of small molecules, for example H2 or CO2. Consequently, the materials are ideal candidates for a wide range of applications including gas storage, separation technologies and catalysis. Potential applications include the storage of hydrogen for fuel-cell cars, and the removal and storage of carbon dioxide in sustainable technical processes. MOFs offer the inorganic chemist and materials scientist a wide range of new synthetic possibilities and open the doors to new and exciting basic research. Metal-Organic Frameworks Materials provides a solid basis for the understanding of MOFs and insights into new inorganic materials structures and properties. The volume also reflects progress that has been made in recent years, presenting a wide range of new applications including state-of-the art developments in the promising technology for alternative fuels. The comprehensive volume investigates structures, symmetry, supramolecular chemistry, surface engineering, recognition, properties, and reactions. The content from this book will be added online to the Encyclopedia of Inorganic and Bioinorganic Chemistry: http://www.wileyonlinelibrary.com/ref/eibc
Download or read book Chemistry of Zeolites and Related Porous Materials written by Ruren Xu and published by John Wiley & Sons. This book was released on 2009-05-29 with total page 616 pages. Available in PDF, EPUB and Kindle. Book excerpt: Widely used in adsorption, catalysis and ion exchange, the family of molecular sieves such as zeolites has been greatly extended and many advances have recently been achieved in the field of molecular sieves synthesis and related porous materials. Chemistry of Zeolites and Related Porous Materials focuses on the synthetic and structural chemistry of the major types of molecular sieves. It offers a systematic introduction to and an in-depth discussion of microporous, mesoporous, and macroporous materials and also includes metal-organic frameworks. Provides focused coverage of the key aspects of molecular sieves Features two frontier subjects: molecular engineering and host-guest advanced materials Comprehensively covers both theory and application with particular emphasis on industrial uses This book is essential reading for researches in the chemical and materials industries and research institutions. The book is also indispensable for researches and engineers in R&D (for catalysis) divisions of companies in petroleum refining and the petrochemical and fine chemical industries.
Download or read book Chemical Abstracts written by and published by . This book was released on 2002 with total page 2540 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Zeolite Synthesis written by Mario L. Occelli and published by . This book was released on 1989 with total page 672 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume is a complete progress report on the various aspects of zeolite synthesis on a molecular level. It provides many examples that illustrate how zeolites can be crystallized and what the important parameters are that control crystallization. Forty-two chapters cover such topics as: crystallization techniques; gel chemistry; crystal size and morphology; the role of organic compounds; and novel synthesis procedures. It offers a complete review of zeolite synthesis as well as the latest finding in this important field. Contains benchmark contributions from many notable pioneers in the field, including R.M. Barrer, H. Robson, and Robert Milton.
Download or read book Two dimensional Materials written by Pramoda Kumar Nayak and published by BoD – Books on Demand. This book was released on 2016-08-31 with total page 282 pages. Available in PDF, EPUB and Kindle. Book excerpt: There are only a few discoveries and new technologies in materials science that have the potential to dramatically alter and revolutionize our material world. Discovery of two-dimensional (2D) materials, the thinnest form of materials to ever occur in nature, is one of them. After isolation of graphene from graphite in 2004, a whole other class of atomically thin materials, dominated by surface effects and showing completely unexpected and extraordinary properties, has been created. This book provides a comprehensive view and state-of-the-art knowledge about 2D materials such as graphene, hexagonal boron nitride (h-BN), transition metal dichalcogenides (TMD) and so on. It consists of 11 chapters contributed by a team of experts in this exciting field and provides latest synthesis techniques of 2D materials, characterization and their potential applications in energy conservation, electronics, optoelectronics and biotechnology.
Download or read book Verified Synthesis of Zeolitic Materials written by H. Robson and published by Gulf Professional Publishing. This book was released on 2001-06-26 with total page 288 pages. Available in PDF, EPUB and Kindle. Book excerpt: Zeolite synthesis is an active field of research. As long as this continues, new phases will be discovered and new techniques for preparing existing phases will appear. This edition of Verified Synthesis of Zeolitic Materials contains all the recipes from the first edition plus 24 new recipes. Five new introductory articles have been included plus those from the first edition, some of which have been substantially revised. The XRD patterns have been recorded using different instrument settings from those in the first edition and are intended to conform to typical X-ray diffraction practice. In most cases, only the XRD pattern for the productas synthesised is printed here. The exceptions are those phases which show marked changes in the XRD pattern upon calcination.
Download or read book Metal Oxide Nanoparticles in Organic Solvents written by Markus Niederberger and published by Springer Science & Business Media. This book was released on 2009-09-17 with total page 223 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal Oxide Nanoparticles in Organic Solvents discusses recent advances in the chemistry involved for the controlled synthesis and assembly of metal oxide nanoparticles, the characterizations required by such nanoobjects, and their size and shape depending properties. In the last few years, a valuable alternative to the well-known aqueous sol-gel processes was developed in the form of nonaqueous solution routes. Metal Oxide Nanoparticles in Organic Solvents reviews and compares surfactant- and solvent-controlled routes, as well as providing an overview of techniques for the characterization of metal oxide nanoparticles, crystallization pathways, the physical properties of metal oxide nanoparticles, their applications in diverse fields of technology, and their assembly into larger nano- and mesostructures. Researchers and postgraduates in the fields of nanomaterials and sol-gel chemistry will appreciate this book’s informative approach to chemical formation mechanisms in relation to metal oxides.
Download or read book Perovskite Materials written by Likun Pan and published by BoD – Books on Demand. This book was released on 2016-02-03 with total page 652 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book summarizes the current state of the know-how in the field of perovskite materials: synthesis, characterization, properties, and applications. Most chapters include a review on the actual knowledge and cutting-edge research results. Thus, this book is an essential source of reference for scientists with research fields in energy, physics, chemistry and materials. It is also a suitable reading material for graduate students.
