Download or read book Solid stabilisation of Industrial Brines by Zeolite and Sodalite Formation written by and published by . This book was released on 2000 with total page 14 pages. Available in PDF, EPUB and Kindle. Book excerpt: The recovery of water from industrial effluents by reverse osmosis and other methods is important in arid countries such as South Africa. However, these processes generate brines that usually contain high concentrations of soluble ions (Na, K, Cl, SO4). The brines require either further treatment or must be stored in expensive lined dams to minimise their environmental impact. Once such treatment option for brines is their stabilisation within mineral phases that immobilise the soluble components.^L^LThe zeolite and sodalite groups of minerals show potential to stabilise these components. Both consist of an alumino-silicate framework structure. While zeolites have an open structure of cages and channels that can accommodate cations, the cage structure of sodalites is more compact and can contain both cations and anions.^L^LThe synthesis of zeolites under hydrothermal conditions from local fly ashes has been studied at various temperatures, reaction times and alkalinity. The solids formed have been characterised by X-ray diffraction When caustic soda was used for the alkaline activation of the fly ash, various zeolitic phases such as zeolite P, zeolite 4A, and analcime formed as major phases, depending on the reaction conditions. The possibility of using less expensive reagents than caustic soda, i.e. lime, was also investigated, but no zeolitic phases were formed in these instances. The availability of Ca, Al and Si caused the formation of insoluble calcium aluminium silicates and prevented zeolite formation.^L^LThe addition of solid NaCl to the zeolites and heating the mixture to 1000 degrees Celsius resulted in the formation of sodalite (Na4Al3Si3O12Cl). When zeolite samples were calcined with a brine that contained Na, K, So4 and Cl ions, the formation of nosean (Na8Al6Si6O24SO4), a member of the sodalite group of minerals, as the main mineral phase was observed. Leaching tests conducted on these solids indicated up to 99% immobilisation of Na, K and Cl, and up to 70% immobilisation of SO4. The reasons for the lower SO4 immobilisation may lie in the difference in size between Cl and SO4 and should be further investigated.^L^LThe results of this study indicate that sodalites are a suitable reservoir mineral to immobilise the soluble ions Na, K, Cl and, to certain degree, also SO4, that are present in the brine. The potential industrial applications of this work are also discussed briefly.
Download or read book Synthesis of Zeolites from Coal Fly Ash written by Guido Gerard Hollman and published by . This book was released on 1999 with total page 154 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book South African Journal of Science written by and published by . This book was released on 1999 with total page 696 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Zeolite Synthesis written by Mario L. Occelli and published by . This book was released on 1989 with total page 672 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume is a complete progress report on the various aspects of zeolite synthesis on a molecular level. It provides many examples that illustrate how zeolites can be crystallized and what the important parameters are that control crystallization. Forty-two chapters cover such topics as: crystallization techniques; gel chemistry; crystal size and morphology; the role of organic compounds; and novel synthesis procedures. It offers a complete review of zeolite synthesis as well as the latest finding in this important field. Contains benchmark contributions from many notable pioneers in the field, including R.M. Barrer, H. Robson, and Robert Milton.
Download or read book Natural Zeolites written by G. Gottardi and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 419 pages. Available in PDF, EPUB and Kindle. Book excerpt: Zeolites form a family of minerals which have been known since the 18th century, but they remained a curiosity for scientists and collectors until 60 years ago, when their unique physicochemical properties attracted the attention of many researchers. In the past 30 years there has been an ex traordinary development in zeolite science; six International Conferences on Zeolites have been held every 3 years since 1967, and a large number of interesting contributions have been published in their proceedings. Many books, written either by individual authors or by several authors under a leading editor, have been published on these interesting silicate phases, but none has been devoted specifically to natural zeolites, even though this theme may be of interest not only to earth scientists, but also to chemists, as the in formation obtained from natural samples completes and in tegrates the characterization of many zeolites. We are trying to fill this gap on the basis of 20 years of research on natural zeolites, which we performed at the University of Modena together with many friends and colleagues. If it is in general difficult to write a scientific book with out upsetting somebody, this is particularly true for a book on natural crystals, because mineralogy is an interdisciplin ary science which covers some fields of physics, chemistry, it is almost impossible to meet every petrology, geology, and requirement.
Download or read book Fly Ash Zeolites written by Bhagwanjee Jha and published by Springer. This book was released on 2016-05-27 with total page 233 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents a thorough review of the state-of-knowledge and recent innovations in the synthesis of pure and improved grades of fly ash zeolites (FAZ). Addressing improvements to conventional methods, it also showcases a novel technique for the synthesis of high cation exchangers from fly ash and detailed characterization techniques for the products obtained. In addition, it examines in detail various areas of specific applications of fly ash zeolites. Over the years, several methods such as hydrothermal, fusion prior to hydrothermal, microwave assisted hydrothermal and molten salt techniques for producing FAZ have been developed. However, one-step and two-step reactions between the fly ash and alkali usually generate alkaline wastes that may cause environmental contamination. In addition, the separation of FAZ from the partially activated fly ash (the impurities) remains a major concern for researchers and industrialists alike. /divIn view of these challenges, this book presents a novel technique for three-step activation (TSA), which focuses on recycling the fly ash-NaOH-water reaction by-products until zeolitic residue is formed. The FAZ (the final residue after third step reactions) synthesized in this manner exhibits exceptionally high cation exchange capacity, specific surface area and pore area. This book offers a comprehensive compendium of reading material on fly ash and its recycled product, the zeolites. Students at both undergraduate and graduate levels, researchers, and practicing engineers will all find this book to be a valuable guide in their respective fields.
Download or read book Zeolites and Metal organic Frameworks written by Vincent Blay and published by . This book was released on 2018 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book examines Zeolites and Metal-Organic Frameworks. It explains the different synthetic routes available to prepare these materials, and examines how they are used by science and industry.
Download or read book Natural Microporous Materials in Environmental Technology written by P. Misaelides and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 506 pages. Available in PDF, EPUB and Kindle. Book excerpt: Proceedings of the NATO Advanced Research Workshop on the Application of Natural Microporous Materials for Environmental Technology, Smolenice Castle, Slovakia, 26-30 October 1998
Download or read book Handbook of Zeolite Science and Technology written by Scott M. Auerbach and published by CRC Press. This book was released on 2003-07-31 with total page 1202 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Handbook of Zeolite Science and Technology offers effective analyses ofsalient cases selected expressly for their relevance to current and prospective research. Presenting the principal theoretical and experimental underpinnings of zeolites, this international effort is at once complete and forward-looking, combining fundamental
Download or read book Minerals as Advanced Materials II written by S V Krivovichev and published by Springer Science & Business Media. This book was released on 2011-12-01 with total page 424 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is a collection of papers that are devoted to various aspects of interactions between mineralogy and material sciences. It will include reviews, perspective papers and original research papers on mineral nanostructures, biomineralization, micro- and nanoporous mineral phases as functional materials, physical and optical properties of minerals, etc. Many important materials that dominate modern technological development were known to mineralogists for hundreds of years, though their properties were not fully recognized. Mineralogy, on the other hand, needs new impacts for the further development in the line of modern scientific achievements such as bio- and nanotechnologies as well as by the understanding of a deep role that information plays in the formation of natural structures and definition of natural processes. It is the idea of this series of books to provide an arena for interdisciplinary discussion on minerals as advanced materials.
Download or read book Industrial Minerals and Their Uses written by Peter A. Ciullo and published by William Andrew. This book was released on 1996-12-31 with total page 625 pages. Available in PDF, EPUB and Kindle. Book excerpt: This multi-authored handbook is a unique cross-industry resource for formulators and compounders, and an invaluable reference for the producers of formulated commodities and industrial minerals. Monographs on each of the common functional industrial mineralsùasbestos, barite, calcium carbonate, diatomite, feldspar, gypsum, hormite, kaolin, mica, nepheline syenite, perlite, pyrophyllite, silica, smectite, talc, vermiculite, wollastonite, and zeoliteùinclude an overview of natural and commercial varieties, market size, and application areas. These are supported by descriptions of mineral structures and the wedding of minerals and chemicals through mineral surface modification. This orientation to the minerals and their uses forms the foundation for chapters where they are presented in the context of the overall technology of various consuming industries. Each of these industry-specific presentations covers both the chemical and mineral raw materials used by the formulator, how these are combined, and relevant test methods. These chapters serve a dual purpose. Each clarifies for technologists the function and value of the mineral constituents of their products. Equally important, they provide a primer on the technology of industries other than their own, so that raw material, formulation, processing and testing considerations can be compared and contrasted.The book concludes with a formulary demonstrating how specific mineral and chemical ingredients are actually compounded in major application areas, and technical data on scores of commercial mineral products.
Download or read book The Role of Halogens in Terrestrial and Extraterrestrial Geochemical Processes written by Daniel E. Harlov and published by Springer. This book was released on 2018-01-30 with total page 1029 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book summarizes the knowledge and experiences concerning the role of halogens during various geochemical processes, such as diagenesis, ore-formation, magma evolution, metasomatism, mineralization, and metamorphism in the crust and mantle of the Earth. It comprises the role of halogens in other terrestrial worlds like volatile-rich asteroids, Mars, and the ice moons of Jupiter and Saturn. Review chapters outline and expand upon the basis of our current understanding regarding how halogens contribute to the geochemical/geophysical evolution and stability of terrestrial worlds overall.
Download or read book Inorganic Membranes Synthesis Characterization and Applications written by Reyes Mallada and published by Elsevier. This book was released on 2008-05-01 with total page 477 pages. Available in PDF, EPUB and Kindle. Book excerpt: Approx.480 pagesApprox.480 pages
Download or read book Applied Mineralogy in the Mining Industry written by W. Petruk and published by Elsevier. This book was released on 2000-11-29 with total page 287 pages. Available in PDF, EPUB and Kindle. Book excerpt: Techniques of performing applied mineralogy investigations, and applications and capabilities of recently developed instruments for measuring mineral properties are explored in this book intended for practicing applied mineralogists, students in mineralogy and metallurgy, and mineral processing engineers. The benefits of applied mineralogy are presented by using in-depth applied mineralogy studies on base metal ores, gold ores, porphyry copper ores, iron ores and industrial minerals as examples. The chapter on base metal ores includes a discussion on the effects of liberation, particle sizes and surfaces coatings of Pb, Cu, Fe, Ca and So4- on the recoveries of sphalerite, galena and chalcopyrite. The chapter on gold discusses various methods of determining the quantities of gold in different minerals, including 'invisible' gold in pyrite and arsenopyrite, so that a balance of the distribution of gold among the minerals can be calculated. This book also discusses the roles of pyrite, oxygen, moisture and bacterial (thiobacillus ferrooxidans) on reactions that produce acidic drainage from tailings piles, and summarizes currently used and proposed methods of remediation of acidic drainage.
Download or read book Green Chemical Engineering written by S. Suresh and published by CRC Press. This book was released on 2014-12-18 with total page 544 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book explores a balance between energy and material, applied to chemical reactors with catalysis, to achieve a given purpose. It includes the fundamentals of chemical reaction engineering and explains reactor design fundamentals. The book spans the full range-from the fundamentals of kinetics and heterogeneous catalysis via modern experimental and theoretical results of model studies-to their equivalent large-scale industrial production processes. It also includes significant developments, with recent research case studies and literature.
Download or read book Active Protective Coatings written by Anthony E. Hughes and published by Springer. This book was released on 2016-03-01 with total page 429 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book covers a broad range of materials science that has been brought to bear on providing solutions to the challenges of developing self-healing and protective coatings for a range of metals. The book has a strong emphasis on characterisation techniques, particularly new techniques that are beginning to be used in the coatings area. It features many contributions written by experts from various industrial sectors which examine the needs of the sectors and the state of the art. The development of self-healing and protective coatings has been an expanding field in recent years and applies a lot of new knowledge gained from other fields as well as other areas of materials science to the development of coatings. It has borrowed from fields such as the food and pharmaceutical industries who have used, polymer techniques, sol-gel science and colloidosome technology for a range encapsulation techniques. It has also borrowed from fields like hydrogen storage such as from the development of hierarchical and other materials based on organic templating as “nanocontainers” for the delivery of inhibitors. In materials science, recent developments in high throughput and other characterisation techniques, such as those available from synchrotrons, are being increasing used for novel characterisation – one only needs to look at the application of these techniques in self healing polymers to gauge wealth of new information that has been gained from these techniques. This work is largely driven by the need to replace environmental pollutants and hazardous chemicals that represent risk to humans such as chromate inhibitors which are still used in some applications.
Download or read book Characterization of Minerals Metals and Materials 2020 written by Jian Li and published by Springer Nature. This book was released on 2020-01-23 with total page 723 pages. Available in PDF, EPUB and Kindle. Book excerpt: This collection gives broad and up-to-date results in the research and development of materials characterization and processing. Topics covered include advanced characterization methods, minerals, mechanical properties, coatings, polymers and composites, corrosion, welding, magnetic materials, and electronic materials. The book explores scientific processes to characterize materials using modern technologies, and focuses on the interrelationships and interdependence among processing, structure, properties, and performance of materials.
