Download or read book Shaping Fluid fluid Interfaces From Molecular Monolayers to Thin Liquid Films written by Emilie Marie Dressaire and published by . This book was released on 2009 with total page 504 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this thesis, we present studies on the regular structuring of fluid/fluid interfaces. In Chapter 1 through 3, we investigate the spreading of droplets and the impact of liquid jets on microtextured solid substrates. We show that the liquid films produced adopt the symmetry of the substrate topography, despite the different physical mechanisms involved in the film formation. When a droplet of partially wetting fluid spreads on a regular lattice of microposts, the shape of the resulting film depends on the dynamics of the spreading/imbibition, i.e. the geometrical features of the substrate and the contact angle of the fluid (Chapter 1). When a jet impacts a microtextured substrate, at high Reynolds number, the velocity field is no longer isotropic. The angular dependence results in the formation of polygonal hydraulic jumps (Chapter 2) and polygonal liquid sheet (Chapter 3). In Chapter 4 and 5, we study a highly stable dispersion of micron scale bubbles. We show that each bubble is coated with an insoluble layer of condensed surfactant molecules. Under compression, the shell initially buckles into nanometer scale hexagonal domains. The nanopatterned interface resists further shrinkage of the bubble and the gas dispersion is stable over a year. We rationalize the surface structure by considering the mechanical features and the chemical composition of the interface. Finally, in Chapter 6, we present an experimental study on the clogging of microchannels by colloidal suspensions and document the role of the interaction between particles and the flow properties.
Download or read book Particles at Fluid Interfaces and Membranes written by P. Kralchevsky and published by Elsevier. This book was released on 2001-01-22 with total page 669 pages. Available in PDF, EPUB and Kindle. Book excerpt: In the small world of micrometer to nanometer scale many natural and industrial processes include attachment of colloid particles (solid spheres, liquid droplets, gas bubbles or protein macromolecules) to fluid interfaces and their confinement in liquid films. This may lead to the appearance of lateral interactions between particles at interfaces, or between inclusions in phospholipid membranes, followed eventually by the formation of two-dimensional ordered arrays. The book is devoted to the description of such processes, their consecutive stages, and to the investigation of the underlying physico-chemical mechanisms. The first six chapters give a concise but informative introduction to the basic knowledge in surface and colloid science, which includes both traditional concepts and some recent results. Chapters 1 and 2 are devoted to the basic theory of capillarity, kinetics of surfactant adsorption, shapes of axisymmetric fluid interfaces, contact angles and line tension. Chapters 3 and 4 present a generalization of the theory of capillarity to the case, in which the variation of the interfacial (membrane) curvature contributes to the total energy of the system. The generalized Laplace equation is applied to determine the configurations of free and adherent biological cells. Chapters 5 and 6 are focused on the role of thin liquid films and hydrodynamic factors in the attachment of solid and fluid particles to an interface. Surface forces of various physical nature are presented and their relative importance is discussed. Hydrodynamic interactions of a colloidal particle with an interface (or another particle) are also considered.Chapters 7 to 10 are devoted to the theoretical foundation of various kinds of capillary forces. When two particles are attached to the same interface (membrane), capillary interactions, mediated by the interface or membrane, appear between them. Two major kinds of capillary interactions are described: (i) capillary immersion force related to the surface wettability (Chapter 7), (ii) capillary flotation force originating from interfacial deformations due to particle weight (Chapter 8). Special attention is paid to the theory of capillary immersion forces between particles entrapped in spherical liquid films (Chapter 9). A generalization of the theory of immersion forces allows one to describe membrane-mediated interactions between protein inclusions into a lipid bilayer (Chapter 10).Chapter 11 is devoted to the theory of the capillary bridges and the capillary-bridge forces, whose importance has been recognized in phenomena like consolidation of granules and soils, wetting of powders, capillary condensation, long-range hydrophobic attraction, etc. The nucleation of capillary bridges is also examined.Chapter 12 considers solid particles, which have an irregular wetting perimeter upon attachment to a fluid interface. The undulated contact line induces interfacial deformations, which engender a special lateral capillary force between the particles. The latter contributes to the dilatational and shear elastic moduli of particulate adsorption monolayers.Chapter 13 describes how lateral capillary forces, facilitated by convective flows and some specific and non-specific interactions, can lead to the aggregation and ordering of various particles at fluid interfaces or in thin liquid films. Recent results on fabricating two-dimensional (2D) arrays from micrometer and sub-micrometer latex particles, as well as 2D crystals from proteins and protein complexes, are reviewed. Chapter 14 presents applied aspects of the particle-surface interaction in antifoaming and defoaming. The mechanisms of antifoaming action involve as a necessary step the entering of an antifoam particle at the air-water interface. The considered mechanisms indicate the factors for control of foaminess.
Download or read book Thinning Films and Tribological Interfaces written by D. Dowson and published by Elsevier. This book was released on 2000-09-01 with total page 857 pages. Available in PDF, EPUB and Kindle. Book excerpt: This collection of fully peer-reviewed papers were presented at the 26th Leeds-Lyon Tribology Symposium which was held in Leeds, UK, 14-17 September, 1999. The Leeds-Lyon Symposia on Tribology were launched in 1974, and the large number of references to original work published in the Proceedings over many years confirms the quality of the published papers. It also indicates that the volumes have served their purpose and become a recognised feature of the tribological literature. This year's title is 'Thinning Films and Tribological Interfaces', and the papers cover practical applications of tribological solutions in a wide range of situations. The evolution of a full peer review process has been evident for a number of years. An important feature of the Leeds-Lyon Symposia is the presentation of current research findings. This remains an essential feature of the meetings, but for the 26th Symposium authors were invited to submit their papers for review a few weeks in advance of the Symposium. This provided an opportunity to discuss recommendations for modifications with the authors.
Download or read book Shape of Fluid Drops at Fluid liquid Interfaces and Permeability of Soap Films to Gases written by Henricus Mattheus Princen and published by . This book was released on 1965 with total page 114 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Fluid Interfaces written by Eduardo Guzmán and published by MDPI. This book was released on 2021-03-02 with total page 232 pages. Available in PDF, EPUB and Kindle. Book excerpt: Fluid interfaces are promising candidates for confining different types of materials, e.g., polymers, surfactants, colloids, and even small molecules, to be used in designing new functional materials with reduced dimensionality. The development of such materials requires a deepening of the physicochemical bases underlying the formation of layers at fluid interfaces as well as on the characterization of their structures and properties. This is of particular importance because the constraints associated with the assembly of materials at the interface lead to the emergence of equilibrium and features of dynamics in the interfacial systems, which are far removed from those conventionally found in traditional materials. This Special Issue is devoted to studies on the fundamental and applied aspects of fluid interfaces, and attempts to provide a comprehensive perspective on the current status of the research field.
Download or read book Interfacial Fluid Mechanics written by Vladimir S. Ajaev and published by Springer Science & Business Media. This book was released on 2012-02-07 with total page 219 pages. Available in PDF, EPUB and Kindle. Book excerpt: Interfacial Fluid Mechanics: A Mathematical Modeling Approach provides an introduction to mathematical models of viscous flow used in rapidly developing fields of microfluidics and microscale heat transfer. The basic physical effects are first introduced in the context of simple configurations and their relative importance in typical microscale applications is discussed. Then, several configurations of importance to microfluidics, most notably thin films/droplets on substrates and confined bubbles, are discussed in detail. Topics from current research on electrokinetic phenomena, liquid flow near structured solid surfaces,evaporation/condensation, and surfactant phenomena are discussed in the later chapters.
Download or read book Molecules in Interaction with Surfaces and Interfaces written by Reinhold Haberlandt and published by Springer Science & Business Media. This book was released on 2004-03-15 with total page 546 pages. Available in PDF, EPUB and Kindle. Book excerpt: The study of the interaction of molecules with surfaces and interfaces is of great importance for the understanding of adsorption and catalysis on solid surfaces, the complex properties of molecules on fluid interfaces and the relationship between structure and functionality in macromolecular biological systens. It is the aim of this volume to present and analyse in a comprehensive and accesible way the methodical achievements and the recent proress in this field. The broadness of both scope and selection of the topics should help in particular non-expert readers to become familiar with this exciting field of research.
Download or read book Fundamentals of Surface Thermodynamics written by Ronaldo Gonçalves dos Santos and published by Springer Nature. This book was released on with total page 185 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Summaries of Projects Completed written by National Science Foundation (U.S.) and published by . This book was released on with total page 488 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Interfacial Catalysis written by Alexander G. Volkov and published by CRC Press. This book was released on 2002-12-12 with total page 690 pages. Available in PDF, EPUB and Kindle. Book excerpt: A comprehensive volume on interfacial catalysis, this book includes contributions from an international group of specialists in chemistry, environmental science, informatics, physiology, nuclear energy, and physics. The editor has organized the material into the main topics of fundamental characteristics, phase transfer catalysis, reversed micelles, biological aspects, and interfacial photocatalysis. Individual topics include self-organized microheterogeneous structures, nanochemistry, interfacial catalysis in metal complexation, the role of water molecules in ion transfer at the oil/water interface, and ultrathin films in enhanced oil recovery.
Download or read book Encyclopedia of Surface and Colloid Science written by Arthur T. Hubbard and published by CRC Press. This book was released on 2002-07-18 with total page 1580 pages. Available in PDF, EPUB and Kindle. Book excerpt: This comprehensive reference collects fundamental theories and recent research from a wide range of fields including biology, biochemistry, physics, applied mathematics, and computer, materials, surface, and colloid science-providing key references, tools, and analytical techniques for practical applications in industrial, agricultural, and forensic processes, as well as in the production of natural and synthetic compounds such as foods, minerals, paints, proteins, pharmaceuticals, polymers, and soaps.
Download or read book Molecular Assembly of Biomimetic Systems written by Junbai Li and published by John Wiley & Sons. This book was released on 2010-12-23 with total page 288 pages. Available in PDF, EPUB and Kindle. Book excerpt: This handy reference details state-of-the-art preparation of molecular assemblies of biotechnologically relevant biomimetic systems (artificial proteins, peptides, molecular motors, photosensitive systems) with an emphasis on biomimetic membranes, capsules, and interfaces. Medical applications such as drug release, gene therapy, and tissue engineering as well as biosensing, biocatalysis, and energy storage are highlighted.
Download or read book Eli Ruckenstein written by D. Dadyburjor and published by Taylor & Francis. This book was released on 1987 with total page 320 pages. Available in PDF, EPUB and Kindle. Book excerpt: First published in 1987. Routledge is an imprint of Taylor & Francis, an informa company.
Download or read book Particles at Fluid Interfaces and Membranes written by P. Kralchevsky and published by . This book was released on 2001-01-22 with total page 680 pages. Available in PDF, EPUB and Kindle. Book excerpt: Planar fluid interfaces -- Interfaces of moderate curvature : theory of capillarity -- Surface bending moment and curvature elastic moduli -- General curved interfaces and biomembranes -- Liquid films and interactions between particle and surface -- Particles at interfaces : deformations and hydrodynamic interactions -- Lateral capillary forces between partially immersed bodies -- Lateral capillary forces between floating particles -- Capillary forces between particles bound to a spherical interface -- Mechanics of lipid membranes and interaction between inclusions -- Capillary bridges and capillary-bridge forces -- Capillary forces between particles of irregular contact line -- Two-dimensional crystallization of particulates and proteins -- Effect of oil drops and particulates on the stability of foams.
Download or read book Surfactants written by Bob Aveyard and published by Oxford University Press. This book was released on 2019-10-09 with total page 400 pages. Available in PDF, EPUB and Kindle. Book excerpt: Surfactants... today you have probably eaten some, or rubbed others on your body. Plants, animals (including you) and microorganisms make them, and many everyday products (e.g. detergents, cosmetics, foodstuffs) contain them. Surfactant molecules have one part which is soluble in water and another which is not. This gives surfactant molecules two valuable properties: 1) they adsorb at surfaces (e.g. of an oil droplet in water), and 2) they stick together (aggregate) in water. The aggregates (micelles) are able to dissolve materials not soluble in water alone, and adsorbed surfactant layers, at the surfaces of particles or (say) oil droplets in water, stop the particles or drops sticking together. This is why stable emulsions such as milk do not separate into layers. This book treats the basic physical chemistry and physics underlying the behaviour of surfactant systems. In this book, you will first learn about some background material including hydrophobic hydration, interfacial tension and capillarity (Section I). Discussion of surfactant adsorption at liquid/fluid and solid/liquid interfaces is given in Section II, and includes thermodynamics of adsorption, dynamic and rheological aspects of liquid interfaces and the direct characterisation of surfactant monolayers. In Section III, a description is given of surfactant aggregation to give micelles, lyotropic liquid crystals, microemulsions and Winsor systems. There follows a discussion of surface forces and the way they confer stability on lyophobic colloids and thin liquid films (Section IV). Various dispersions stabilised by adsorbed surfactant or polymer (including solid in liquid dispersions, emulsions and foams) are considered in Section V. The wetting of solids and liquids is explored in Section VI. Like surfactants, small solid particles can adsorb at liquid/fluid interfaces, form monolayers and stabilise emulsions and foams. Such behaviour is covered in Section VII. It is assumed the reader has a knowledge of undergraduate physical chemistry, particularly chemical thermodynamics, and of simple physics. Mathematics (elementary algebra and calculus) is kept at a level consistent with the straightforward derivation of many of the equations presented.
Download or read book Colloid and Interface Science written by Pallab Ghosh and published by PHI Learning Pvt. Ltd.. This book was released on 2009 with total page 519 pages. Available in PDF, EPUB and Kindle. Book excerpt: Provides a thorough understanding of the fundamental concepts and applications of colloid and interface science. It deals with the colloid chemistry and interfacial phenomena at both fluid-fluid and solid-fluid interfaces. The emerging areas of colloid and interface science such as nanomaterials and nanotechnology are also discussed.
Download or read book Handbook of Nanophysics written by Klaus D. Sattler and published by CRC Press. This book was released on 2010-09-17 with total page 816 pages. Available in PDF, EPUB and Kindle. Book excerpt: Covering the key theories, tools, and techniques of this dynamic field, Handbook of Nanophysics: Principles and Methods elucidates the general theoretical principles and measurements of nanoscale systems. Each peer-reviewed chapter contains a broad-based introduction and enhances understanding of the state-of-the-art scientific content through fund
