Download or read book Separation Of Uranium And Plutonium Isotopes For Measurement By Multi Collector Inductively Coupled Plasma Mass Spectroscopy written by and published by . This book was released on 2009 with total page 16 pages. Available in PDF, EPUB and Kindle. Book excerpt: Uranium (U) and plutonium (Pu) isotopes in coral soils, contaminated by nuclear weapons testing in the northern Marshall Islands, were isolated by ion-exchange chromatography and analyzed by mass spectrometry. The soil samples were spiked with 233U and 242Pu tracers, dissolved in minerals acids, and U and Pu isotopes isolated and purified on commercially available ion-exchange columns. The ion-exchange technique employed a TEVA{reg_sign} column coupled to a UTEVA{reg_sign} column. U and Pu isotope fractions were then further isolated using separate elution schemes, and the purified fractions containing U and Pu isotopes analyzed sequentially using multi-collector inductively coupled plasma mass spectrometer (MCICP-MS). High precision measurements of 234U/235U, 238U/235U, 236U/235U, and 24°Pu/239Pu in soil samples were attained using the described methodology and instrumentation, and provide a basis for conducting more detailed assessments of the behavior and transfer of uranium and plutonium in the environment.
Download or read book Handbook of Radioactivity Analysis written by Michael F. L'Annunziata and published by Academic Press. This book was released on 2012-08-16 with total page 1420 pages. Available in PDF, EPUB and Kindle. Book excerpt: Authoritative reference providing the principles, practical techniques, and procedures for the accurate measurement of radioactivity.
Download or read book Analysis of Environmental Radionuclides written by Pavel P. Povinec and published by Elsevier. This book was released on 2011-07-28 with total page 539 pages. Available in PDF, EPUB and Kindle. Book excerpt: The purpose of this book is to present a state of art summary of current knowledge of methods of assessment of radionuclides in the terrestrial and marine environments. It cover the traditional methods of radioactivity measurements such as radiometrics techniques, but also recent developments in the mass spectrometry sector. The book starts with a short preface introducing the subject of the book, summarising content and philosophy of the book, as well as the most important historical achievements. The scientific topics are introduced by description of sampling methods, optimisation of sampling sites and sampling frequency. The recent developments in radiochemical separation methods using chromatography resins for the treatment of actinides, transuranics and other groups of radioelements are also described. No other book is available covering all aspects of environmental radioactivity measurements, although remarkable progress has been made in detection techniques over the last ten years. At present the new methods enable to carry out investigations which were not possible before, either because of lack of sensitivity or because of the fact that they required too large samples.
Download or read book RAPID DETERMINATION OF 237 NP AND PU ISOTOPES IN WATER BY INDUCTIVELY COUPLED PLASMA MASS SPECTROMETRY AND ALPHA SPECTROMETRY written by and published by . This book was released on 2010 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: A new method that allows rapid preconcentration and separation of plutonium and neptunium in water samples was developed for the measurement of 237Np and Pu isotopes by inductively-coupled plasma mass spectrometry (ICP-MS) and alpha spectrometry; a hybrid approach. 238U can interfere with 239Pu measurement by ICP-MS as 238UH mass overlap and 237Np via peak tailing. The method provide enhanced removal of uranium by separating Pu and Np initially on TEVA Resin, then moving Pu to DGA resin for additional removal of uranium. The decontamination factor for uranium from Pu is almost 100,000 and the decontamination factor for U from Np is greater than 10,000. This method uses stacked extraction chromatography cartridges and vacuum box technology to facilitate rapid separations. Preconcentration is performed using a streamlined calcium phosphate precipitation method. Purified solutions are split between ICP-MS and alpha spectrometry so that long and short-lived Pu isotopes can be measured successfully. The method allows for simultaneous extraction of 20 samples (including QC samples) in 4 to 6 hours, and can also be used for emergency response. 239Pu, 242Pu and 237Np were measured by ICP-MS, while 236Pu, 238Pu, and 239Pu were measured by alpha spectrometry.
Download or read book The New Nuclear Forensics written by Vitaly Fedchenko and published by Oxford University Press. This book was released on 2015 with total page 310 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nuclear material changes its form and properties as it moves through the nuclear fuel cycle, from one facility to another. Each step of the fuel cycle or each use of the material will inevitably leave its mark. The science of determining the history of a sample of nuclear material through the study of these characteristics is known as nuclear forensics. While nuclear forensic analysis has normally been associated with investigations and prosecutions in the contextof trafficking of nuclear materials or nuclear terrorism, it had wider applications in in national security contexts, such as nuclear non-proliferation, disarmament, and arms control. The New Nuclear Forensics is the first book to give a definitive guide to this broader definition of nuclear forensic analysis. This book describes the various methods used in nuclear forensics, giving first a broad introduction to the process followed by details of relevant measurement techniques and procedures. In each case, the advantages and limitations are outlined. To put these methods in context, the book also recounts the history of the discipline anddescribes the diverse contemporary applications of nuclear forensics.
Download or read book Isolation and Puification of Uranium Isotopes for Measurement by Mass Spectrometry 233 234 235 236 238U and Alpha Spectrometry 232U written by and published by . This book was released on 2006 with total page 18 pages. Available in PDF, EPUB and Kindle. Book excerpt: This report describes a standardized methodology used by researchers from the Center for Accelerator Mass Spectrometry (CAMS) (Energy and Environment Directorate) and the Environmental Radiochemistry Group (Chemistry and Materials Science Directorate) at the Lawrence Livermore National Laboratory (LLNL) for the full isotopic analysis of uranium from solution. The methodology has largely been developed for use in characterizing the uranium composition of selected nuclear materials but may also be applicable to environmental studies and assessments of public, military or occupational exposures to uranium using in-vitro bioassay monitoring techniques. Uranium isotope concentrations and isotopic ratios are measured using a combination of Multi Collector Inductively Coupled Plasma Mass Spectrometry (MC ICP-MS), Accelerator Mass Spectrometry (AMS) and Alpha Spectrometry.
Download or read book Radiochemistry and Nuclear Chemistry Volume II written by Sandor Nagy and published by EOLSS Publications. This book was released on 2009-08-24 with total page 472 pages. Available in PDF, EPUB and Kindle. Book excerpt: Radiochemistry and Nuclear Chemistry theme is a component of Encyclopedia of Chemical Sciences, Engineering and Technology Resources in the global Encyclopedia of Life Support Systems (EOLSS), which is an integrated compendium of twenty one Encyclopedias. The content of the Theme on Radiochemistry and Nuclear Chemistry provides the essential aspects and a myriad of issues of great relevance to our world such as: Isotope Effects, Isotope Separation and Isotope Fractionation; Radiometric Dating and Tracing; Radiochemical Techniques; Radionuclides in Chemical Research; Nuclear Methods in Material Research; Radiation Chemistry; Radiation Biology and Radiation Protection; Radiochemistry and Radiopharmaceutical Chemistry for Medicine; Chemistry of the Actinide Elements; Production And Chemistry Of Transactinide Elements; Nuclear Waste Management and the Nuclear Fuel Cycle; High-intensity Lasers in Nuclear Science; Nuclear Forensics; Nuclear Processes in Nature; Subatomic Particles, Nuclear Structure and Stability. These two volumes are aimed at the following five major target audiences: University and College students Educators, Professional practitioners, Research personnel and Policy analysts, managers, and decision makers and NGOs.
Download or read book DETERMINATION OF 237NP AND PU ISOTOPES IN LARGE SOIL SAMPLES BY INDUCTIVELY COUPLED PLASMA MASS SPECTROMETRY written by and published by . This book was released on 2010 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: A new method for the determination of 237Np and Pu isotopes in large soil samples has been developed that provides enhanced uranium removal to facilitate assay by inductively coupled plasma mass spectrometry (ICP-MS). This method allows rapid preconcentration and separation of plutonium and neptunium in large soil samples for the measurement of 237Np and Pu isotopes by ICP-MS. 238U can interfere with 239Pu measurement by ICP-MS as 238UH mass overlap and 237Np via 238U peak tailing. The method provides enhanced removal of uranium by separating Pu and Np initially on TEVA Resin, then transferring Pu to DGA resin for additional purification. The decontamination factor for removal of uranium from plutonium for this method is greater than 1 x 106. Alpha spectrometry can also be applied so that the shorter-lived 238Pu isotope can be measured successfully. 239Pu, 242Pu and 237Np were measured by ICP-MS, while 236Pu and 238Pu were measured by alpha spectrometry.
Download or read book Handbook of Nuclear Chemistry written by Attila Vértes and published by Springer Science & Business Media. This book was released on 2010-12-10 with total page 3693 pages. Available in PDF, EPUB and Kindle. Book excerpt: This revised and extended 6 volume handbook set is the most comprehensive and voluminous reference work of its kind in the field of nuclear chemistry. The Handbook set covers all of the chemical aspects of nuclear science starting from the physical basics and including such diverse areas as the chemistry of transactinides and exotic atoms as well as radioactive waste management and radiopharmaceutical chemistry relevant to nuclear medicine. The nuclear methods of the investigation of chemical structure also receive ample space and attention. The international team of authors consists of scores of world-renowned experts - nuclear chemists, radiopharmaceutical chemists and physicists - from Europe, USA, and Asia. The Handbook set is an invaluable reference for nuclear scientists, biologists, chemists, physicists, physicians practicing nuclear medicine, graduate students and teachers - virtually all who are involved in the chemical and radiopharmaceutical aspects of nuclear science. The Handbook set also provides further reading via the rich selection of references.
Download or read book Encyclopedia of Spectroscopy and Spectrometry written by and published by Academic Press. This book was released on 2016-09-22 with total page 3716 pages. Available in PDF, EPUB and Kindle. Book excerpt: This third edition of the Encyclopedia of Spectroscopy and Spectrometry, Three Volume Set provides authoritative and comprehensive coverage of all aspects of spectroscopy and closely related subjects that use the same fundamental principles, including mass spectrometry, imaging techniques and applications. It includes the history, theoretical background, details of instrumentation and technology, and current applications of the key areas of spectroscopy. The new edition will include over 80 new articles across the field. These will complement those from the previous edition, which have been brought up-to-date to reflect the latest trends in the field. Coverage in the third edition includes: Atomic spectroscopy Electronic spectroscopy Fundamentals in spectroscopy High-Energy spectroscopy Magnetic resonance Mass spectrometry Spatially-resolved spectroscopic analysis Vibrational, rotational and Raman spectroscopies The new edition is aimed at professional scientists seeking to familiarize themselves with particular topics quickly and easily. This major reference work continues to be clear and accessible and focus on the fundamental principles, techniques and applications of spectroscopy and spectrometry. Incorporates more than 150 color figures, 5,000 references, and 300 articles for a thorough examination of the field Highlights new research and promotes innovation in applied areas ranging from food science and forensics to biomedicine and health Presents a one-stop resource for quick access to answers and an in-depth examination of topics in the spectroscopy and spectrometry arenas
Download or read book Precise Isotope Ratio Measurements for Uranium Thorium and Plutonium by Quadrupole based Inductively Coupled Plasma Mass Spectrometry written by J. S. Becker and published by . This book was released on 1999 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Verifying Treaty Compliance written by Rudolf Avenhaus and published by Springer Science & Business Media. This book was released on 2007-04-21 with total page 618 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents an interdisciplinary collection of expert analyses and views of existing verification systems. It provides guidelines and advice for the improvement of those systems as well as for new challenges in the field.
Download or read book ATSDR written by United States. Congress. House. Committee on Science and Technology (2007). Subcommittee on Investigations and Oversight and published by . This book was released on 2009 with total page 372 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Inorganic Mass Spectrometry written by Sabine Becker and published by John Wiley & Sons. This book was released on 2008-02-28 with total page 514 pages. Available in PDF, EPUB and Kindle. Book excerpt: Providing an exhaustive review of this topic, Inorganic Mass Spectrometry: Principles and Applications provides details on all aspects of inorganic mass spectrometry, from a historical overview of the topic to the principles and functions of mass separation and ion detection systems. Offering a comprehensive treatment of inorganic mass spectrometry, topics covered include: Recent developments in instrumentation Developing analytical techniques for measurements of trace and ultratrace impurities in different materials This broad textbook in inorganic mass spectrometry, presents the most important mass spectrometric techniques used in all fields of analytical chemistry. By covering recent developments and advances in all fields of inorganic mass spectrometry, this text provides researchers and students with information to answer any questions on this topic as well as providing the basic fundamentals for understanding this potentially complex, but increasingly relevant subject.
Download or read book Determination of Total and Isotopic Uranium by Inductively Coupled Plasma mass Spectrometry at the Fernald Environmental Management Project written by and published by . This book was released on 1995 with total page 13 pages. Available in PDF, EPUB and Kindle. Book excerpt: At the Fernald Environmental Management Project (FEMP) in southwestern Ohio, ICP-mass spectrometry (ICP-MS), with sample introduction by peristaltic pumping, is used to determine total and isotopic uranium (U-234, U-235, U-236 and U-238) in soil samples. These analyses are conducted in support of the environmental cleanup of the FEMP site. Various aspects of the sample preparation and instrumental analysis will be discussed. Initial sample preparation consists of oven drying to determine moisture content, and grinding and rolling to homogenize the sample. This is followed by a nitric/hydrofluoric acid digestion to bring the uranium in the sample into solution. Bismuth is added to the sample prior to digestion to monitor for losses. The total uranium (U-238) content of this solution and the U235/U238 ratio are measured on the first pass through the ICP-MS. To determine the concentration of the less abundant U234 and U236 isotopes, the digestate is further concentrated by using Eichrom TRU-Spec extraction columns before the second pass through the ICP-MS. Quality controls for both the sample preparation and instrumental protocols will also be discussed. Finally, an explanation of the calculations used to report the data in either weight percent or activity units will be given.
Download or read book Annual Book of ASTM Standards written by ASTM International and published by . This book was released on 2003 with total page 1196 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Fukushima Accident written by Pavel P. Povinec and published by Newnes. This book was released on 2013-07-09 with total page 397 pages. Available in PDF, EPUB and Kindle. Book excerpt: Fukushima Accident presents up-to-date information on radioactivity released to the atmosphere and the ocean after the accident on the Fukushima Dai-ichi nuclear power plant, on the distribution of radionuclides in the world atmosphere and oceans, and their impact on the total environment (man, fauna, and flora). The book will evaluate and discuss the post-Fukushima situation, emphasizing radionuclide impacts on the terrestrial and marine environments, and compare it with the pre-Fukushima sources of radionuclides in the environment. The authors' results, as well as knowledge gathered from the literature, will provide up-to-date information on the present status of the topics. Fukushima Accident is based on the environmental and nuclear research; however, the presentation will be suitable for university-level readers. - 2013 PROSE Award winner in Environmental Science from the Association of American Publishers - Covers atmospheric and marine radioactivity, providing information on the global atmospheric dispersion of radionuclides in the atmosphere and world oceans - Examines radiation doses to the public and biota to understand the health risks to the public and ecosystems - Provides information on monitoring radionuclides in the environment – information on sources of radionuclides, their temporal and spatial variations, and radionuclide levels - Covers transport of radionuclides from different sources (e.g. nuclear power plants) as well as atmospheric simulations and modeling approaches
