Download or read book Screening and Evaluating Environmentally Friendly Corrosion Inhibitors for Amine Based CO2 Absorption Process written by Sureshkumar Srinivasan and published by . This book was released on 2018 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: This chapter evaluated the performance of environmentally friendly organic corrosion inhibitors on carbon steel in the amine-based carbon dioxide (CO2) absorption process. The evaluation was experimentally conducted using electrochemical techniques in 5.0 kmol/m3 monoethanolamine (MEA) solutions in the absence and presence of process contaminants, namely formate and chloride, at 80°C and 0.55 mol/mol CO2 loading. The results show, in the absence of process contaminants, that 2-aminobenzene sulfonic acid, 3-aminobenzene sulfonic acid, 4-aminobenzene sulfonic acid, sulfapyridine, and sulfolane yielded 85-92% corrosion inhibition efficiencies, while sulfanilamide yielded the lowest efficiency of 20-42%. Sulfolane was the only tested inhibitor whose performance could be maintained in chloride- and formate-containing MEA solutions. On the contrary, the performance of 3-aminobenzene sulfonic acid and sulfapyridine was decreased by chloride. The performance of all the tested aminobenzene sulfonic acids was compromised by formate.
Download or read book Environmentally Friendly Corrosion Inhibitors for the Amine Based CO2 Absorption Process written by Sureshkumar Srinivasan and published by . This book was released on 2013 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Performance Evaluation of Condiments as Environmentally Friendly Corrosion Inhibitors for Amine Based Carbon Dioxide Absorption Process written by Sockalingam Sekkappan and published by . This book was released on 2018 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Corrosion of process equipment and piping in the amine-based carbon dioxide (CO2) absorption process causes considerable expenditures for maintenance and repair. The addition of effective corrosion inhibitors to the amine solutions is a common practice for corrosion mitigation. Despite their inhibition effectiveness, those corrosion inhibitors used in the amine-based CO2 absorption process are not environmentally friendly and require costly waste handling and disposal. To reduce such cost and prepare for more stringent environmental regulations for chemical uses and disposal, this work investigated the feasibility of using condiments as environmentally friendly corrosion inhibitors in the amine-based CO2 absorption process. In this study, five condiments including powders of garlic, mustard, horseradish, onion and turmeric were selected and evaluated for their corrosion inhibition performance on carbon steel (CS1018) in the environment of 5.0 kmol/m3 aqueous solutions of monoethanolamine (MEA) saturated with dissolved CO2. The evaluation was carried out in corrosion experiments that employed cyclic and poteniodynamic polarization and electrochemical impedance spectroscopy for corrosion measurement and analysis. Results show that the powders of garlic, mustard, horseradish, onion showed great promise for corrosion reduction in both MEA-CO2 and MEA-CO2-oxygen (O2) solutions. They performed well with inhibition efficiencies in the range of 80- 95% even at elevated temperatures and the presence of process contaminants (i.e., chloride and oxalate) which were found to slightly affect the inhibition performance. These four condiments were proved to be mixed-type (anodic and cathodic) corrosion inhibitors that protected the metal surface by undergoing endothermic physical and chemical adsorption with the Langmuir adsorption isotherm. Sulfur, nitrogen, phosphorus functional groups were the primary contributors to the inhibition effectiveness. Unlike these four condiments, the powder of turmeric was not promising as it yielded lower inhibition efficiency and induced pitting corrosion for most tested conditions.
Download or read book Corrosion Inhibitors Principles and Recent Applications written by Mahmood Aliofkhazraei and published by BoD – Books on Demand. This book was released on 2018-04-04 with total page 264 pages. Available in PDF, EPUB and Kindle. Book excerpt: To protect metals or alloys from corrosion, some methods can be used such as isolating the structure from the aggressive media or compensating the loss of electrons from the corroded structure. The use of corrosion inhibitors may include organic and inorganic compounds that adsorb on the metallic structure to isolate it from its surrounding media to decrease oxidation-reduction processes. This book collects new developments about corrosion inhibitors and their recent applications.
Download or read book Corrosion Inhibition Performance of Methionine for CO2 Absorption Plants written by Balaji Udayappan and published by . This book was released on 2021 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Inorganic corrosion inhibitors including heavy metals have been widely used in the carbon dioxide (CO2) absorption process for corrosion control. However, they are not environmentally friendly causing costly handling and disposal costs. This work therefore evaluated corrosion inhibition performance of an organic amino acid compound, namely Methionine (MTI) which is less toxic, more readily biodegradable, and has lower potential for bioaccumulation in aquatic organisms compared to common amine absorption solvents. The evaluation was experimentally implemented using electrochemical and weight loss methods. Carbon steel (CS1018) and 5.0 kmol/m3 Monoethanolamine (MEA) purged with 85% CO2 and 15% oxygen (O2) were used as tested material and absorption solution, respectively. The electrochemical results showed that at solution temperatures up to 80oC, MTI effectively reduced corrosion rates of CS1018 with maximum inhibition efficiencies of 83.56% ± 1.82% under a static condition (0 rpm) and 74.96% ± 0.95% under a dynamic condition (1500 rpm). Its inhibition performance was found to increase with inhibitor concentration and solution temperature but decrease with rotational speed. MTI acted as a mixed-type inhibitor and exhibited pitting tendency. The optimal MTI concentrations were 1500 ppm at 0 rpm and 2000 ppm at 1500 rpm. The post data analysis involving adsorption isotherm and activation thermodynamic properties revealed that MTI protected metal surface by undergoing spontaneous and endothermic physical adsorption. Its adsorption characteristic matched well with the Langmuir adsorption isotherm, thereby suggesting that MTI formed a protective monolayer on the metal surface. The results of quantum chemical analysis suggested MTI has higher affinity, polarizability, and electron donating ability than MEA. III The results of weight loss experiments carried out for up to 28 days showed that at 120oC, 5 bar and 1500 rpm, MTI was able to reduce corrosion rates of CS1018 to below 1 mmpy. The inhibition efficiencies were up to 78.7% for carbon steel specimens fully immersed in the MEA solutions, 53.5% for those partially immersed in the MEA solution and partially exposed to vapor, and 85.6% for those fully exposed to vapor. Pits were observed on carbon steel specimens fully immersed in both uninhibited and MTI inhibited solutions.
Download or read book Corrosion Evaluation for Absorption Based CO2 Capture Process Using Single and Blended Amines written by Prakashpathi Gunasekaran and published by . This book was released on 2013 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Corrosion Inhibition Performance of Copper Carbonate in CO2 Absorption Process Using Aqueous Solution of Monoethanolamine written by Immanuelraj Soosaiprakasam and published by . This book was released on 2007 with total page 292 pages. Available in PDF, EPUB and Kindle. Book excerpt: Corrosion is one of the most severe operational problems in CO2 absorption processes, which use aqueous solutions of alkanolamines, especially when carbon steel is used for plant construction. Corrosion inhibitors are widely applied used in this process to suppress severe corrosion to an acceptable level. However, currently available corrosion inhibitors are heavy metals, which are toxic to human health and the environment, making solvent handling and waste disposal more difficult and costly. This work evaluated a low-toxic corrosion inhibitor, copper carbonate (CuCO3), as a replacement for toxic corrosion inhibitors. An inhibition evaluation was performed on copper carbonate by examining its parametric effects on the corrosion rate and corrosion behavior of carbon steel.
Download or read book Corrosion Inhibition Performance of Sulfur and Nitrogen Based Environmentally Friendly Inhibitors for CO2 Absorption Plants written by Prathap Iyapazham Vaigunda Suba and published by . This book was released on 2020 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book A New Test Method for Evaluating Corrosion Inhibitors Used in CO2 Containing Wells and Pipelines written by Anthony Okay Machie and published by . This book was released on 1990 with total page 184 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Novel Corrosion Inhibitors for Protection from CO2 Corrosion written by Hany M. Abd El-Lateef and published by LAP Lambert Academic Publishing. This book was released on 2012 with total page 240 pages. Available in PDF, EPUB and Kindle. Book excerpt: Carbon dioxide (CO2) corrosion is of great concern in oil and gas production, transportation and processing. Despite the fact that steel has low resistance to CO2 environments, it is widely used in the petroleum industry mainly due to economical reasons. The use of corrosion inhibitors is very important in the protection of steels. Most of the inhibitors used in petroleum industry are organic compounds containing multiple bonds in their molecules that mainly contain nitrogen, sulphur, and/or oxygen atoms through which they get adsorbed on the metal surface. However, most of these substances are toxic and using them is harmful for both human health and environment. Therefore, in this work, we accomplished synthesis of new environment friendly effective corrosion inhibitors for oil and gas industry in the protection of equipment and pipelines transporting multiphase systems based on vegetable oils. Vegetable oils are of the greatest interest because of its technological properties, accessibility, and relatively low price. The performed research is indicating that the vegetable oil can be good raw material for preparation of "environmentally friendly" corrosion inhibitors.
Download or read book Corrosion in CO2 Absorption Process Using Aqueous Monoethanolamine piperazine Solution written by Manjula Nainar and published by . This book was released on 2007 with total page 312 pages. Available in PDF, EPUB and Kindle. Book excerpt: This work explores the promise of aqueous solutions of blended monoethanolamine (MEA) and piperazine (PZ) as a cost-effective solvent for carbon dioxide (CO2) capture from industrial flue gas streams with respect to addressing corrosion, which is regarded as one of the most severe operational problems in typical CO2 capture plants. Two types of corrosion experiments were carried out in bench-scale setups, electrochemical tests for short-term exposure and weight loss tests for long-term exposure. The results show that the blended MEA/PZ solutions are more corrosive than the MEA solutions. The corrosion rate of carbon steel increases with concentration of PZ, total amine concentration, CO2 loading of solution, solution temperature, the presence of heat stable salts, and the presence of the proprietary oxidative degradation inhibitor (Inhibitor A provided by the University of Texas at Austin). Among the tested heat-stable salts, formate is the most corrosive salt, followed by acetate, oxalate, and thiosulfate in the absence of oxygen (O2), while acetate is the most corrosive salt followed by formate, oxalate, and thiosulfate in the presence of O2. Based on the level of corrosion rate found in the MEA/PZ system, corrosion control is required during plant operation to suppress the corrosion rate of carbon steel to below an acceptable level. Sodium metavanadate (NaVO3) and copper carbonate (CuCO3) were proven to be effective corrosion inhibitors with inhibition performance of up to 94-98%. Dissolved O2 is required in the solution to maintain active Cu2 or V5+, which, thus, prevents the metallic copper (Cu) from plating out or the formation of other oxidative states of vanadate. The performance of these two inhibitors can be deteriorated by the presence of heat-stable salts in the solutions.
Download or read book The Cost of Corrosion in China written by Baorong Hou and published by Springer Nature. This book was released on 2019-09-26 with total page 953 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book comprehensively covers corrosion and corrosion protection in China in the areas including infrastructure, transportation, energy, water environment, as well as manufacturing and public utilities. Furthermore, it presents a major consulting project of Chinese Academy of Engineering, which was the largest corrosion investigation project in Chinese history, including the corresponding methods, processes and corrosion protection strategies, and provides valuable information for numerous industries. Sharing essential insights into corrosion prediction and decision-making, this book will help to decrease costs and extend the service life of equipment and facilities; accordingly, it will benefit scientists and engineers working on corrosion research and protection, as well as economists and government employees.
Download or read book Performance Studies of Novel Amine Blends in a Catalyst Aided CO2 Capture Process written by Foster Amoateng Appiah and published by . This book was released on 2021 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: This study focused on utilizing the combined effect between solvent development and the application of solid catalysis to enhance the reactive absorption-based CO2 capture process. First, the CO2 removal performance of three formulated amine bi-blends were evaluated using a semi-batch screening setup. The performance of each blend in terms of specific parameters such as linear absorption and desorption rates, CO2 equilibrium loading, cyclic capacity and solvent regeneration heat duty were compared with the activity of the standard 4M BEA/AMP blend. The bi-blends developed included 2M HMDA/PEI (1.85M: 0.15M), 2M AMP/PEI (1.7M: 0.3M) and 4M DMAE/AMP (2M: 2M). The screening results showed that by reason of higher reactivity resulting from increased number of amino groups in HMDA and PEI, better absorption performance was observed for 2M HMDA/PEI and 2M AMP/PEI bi-blends. However, from the absorption parameter and desorption parameter criterion, 4M DMAE/AMP was found to be the optimum bi-blend amongst the three blends. In addition, the effects of solid alkaline and acid catalysts on the CO2 absorption and desorption performance of the selected optimum blend were studied. Also, the different characteristics of the catalysts were investigated and related to the corresponding enhancement activity to identify and establish the activity-characteristics relationship. Employing the acid proprietary desorber catalyst (AD-1) increased the linear desorption rate and cyclic capacity of 4M DMAE/AMP by 21% and 8.1% respectively and reduced the solvent regeneration energy requirement by 17.3%. Between the absorber catalysts, an increase of 33.3% and 29% in absorption rates were measured for ACS and AB-1 respectively. Comparing the activity of ACS to AB-1, it was observed that the activity of catalyst depends on both the chemical properties (strength and number of basic sites) and physical properties (surface area and pore volume). Furthermore, a full cycle operation in a bench-scale CO2 capture unit was carried out to validate the performance of 4M DMAE/AMP and 2M HMDA/PEI bi-blends. The performance was evaluated as a function of time-on-stream. From the cyclic runs, higher CO2 absorption and desorption performance parameters were recorded for 4M DMAE/AMP relative to the 2M HMDA/PEI blend. The time-on-stream analysis revealed a general reduction in capture performance and an increase in heat duty for both bi-blends.
Download or read book Environmentally Friendly Corrosion Inhibitors written by Rafael Martinez Palou and published by . This book was released on 2014 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Environmentally Friendly Corrosion Inhibitors.
Download or read book Energy Efficient Solvents for CO2 Capture by Gas Liquid Absorption written by Wojciech M. Budzianowski and published by Springer. This book was released on 2016-12-01 with total page 282 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book reviews and characterises promising single-compound solvents, solvent blends and advanced solvent systems suitable for CO2 capture applications using gas-liquid absorption. Focusing on energy efficient solvents with minimal adverse environmental impact, the contributions included analyse the major technological advantages, as well as research and development challenges of promising solvents and solvent systems in various sustainable CO2 capture applications. It provides a valuable source of information for undergraduate and postgraduate students, as well as for chemical engineers and energy specialists.
Download or read book Corrosion Inhibitors in the Oil and Gas Industry written by Viswanathan S. Saji and published by John Wiley & Sons. This book was released on 2020-06-02 with total page 458 pages. Available in PDF, EPUB and Kindle. Book excerpt: Provides comprehensive coverage of corrosion inhibitors in the oil and gas industries Considering the high importance of corrosion inhibitor development for the oil and gas sectors, this book provides a thorough overview of the most recent advancements in this field. It systematically addresses corrosion inhibitors for various applications in the oil and gas value chain, as well as the fundamentals of corrosion inhibition and interference of inhibitors with co-additives. Corrosion Inhibitors in the Oil and Gas Industries is presented in three parts. The first part on Fundamentals and Approaches focuses on principles and processes in the oil and gas industry, the types of corrosion encountered and their control methods, environmental factors affecting inhibition, material selection strategies, and economic aspects of corrosion. The second part on Choice of Inhibitors examines corrosion inhibitors for acidizing processes, inhibitors for sweet and sour corrosion, inhibitors in refinery operations, high-temperature corrosion inhibitors, inhibitors for challenging corrosive environments, inhibitors for microbiologically influenced corrosion, polymeric inhibitors, vapor phase inhibitors, and smart controlled release inhibitor systems. The last part on Interaction with Co-additives looks at industrial co-additives and their interference with corrosion inhibitors such as antiscalants, hydrate inhibitors, and sulfide scavengers. -Presents a well-structured and systematic overview of the fundamentals and factors affecting corrosion -Acts as a handy reference tool for scientists and engineers working with corrosion inhibitors for the oil and gas industries -Collectively presents all the information available on the development and application of corrosion inhibitors for the oil and gas industries -Offers a unique and specific focus on the oil and gas industries Corrosion Inhibitors in the Oil and Gas Industries is an excellent resource for scientists in industry as well as in academia working in the field of corrosion protection for the oil and gas sectors, and will appeal to materials scientists, electrochemists, chemists, and chemical engineers.
Download or read book Green Corrosion Inhibitors written by V. S. Sastri and published by John Wiley & Sons. This book was released on 2012-02-14 with total page 267 pages. Available in PDF, EPUB and Kindle. Book excerpt: A book to cover developments in corrosion inhibitors is long overdue. This has been addressed by Dr Sastri in a book which presents fundamental aspects of corrosion inhibition, historical developments and the industrial applications of inhibitors. The book deals with the electrochemical principles and chemical aspects of corrosion inhibition, such as stability of metal complexes, the Hammett equation, hard and soft acid and base principle, quantum chemical aspects and Hansch' s model and also with the various surface analysis techniques, e.g. XPS, Auger, SIMS and Raman spectroscopy, that are used in industry for corrosion inhibition. The applications of corrosion inhibition are wide ranging. Examples given in this book include: oil and gas wells, petrochemical plants, steel reinforced cement, water cooling systems, and many more. The final chapters discuss economic and environmental considerations which are now of prime importance. The book is written for researchers in academia and industry, practicing corrosion engineers and students of materials science, engineering and applied chemistry.
