Download or read book Rheology Modifiers Applied to Kaolin Bentonite Slurries for SRNL WTP Pulse Jets Tank Pilot Work in Support of RPP at Hanford written by and published by . This book was released on 2005 with total page 5 pages. Available in PDF, EPUB and Kindle. Book excerpt: Savannah River National Laboratory (SRNL) was tasked to find and characterize the impact of rheological modifiers to a clay (Kaolin-Bentonite) slurry having 23.1 total wt percent solids, 1.165 g/ml, and Bingham Plastic yield stress of 13 Pa and plastic viscosity of 24 mPa-sec. The primary objective was to find rheological modifiers when blended with this clay slurry that would provide a vane yield stress of 300 Pa when the slurry was undisturbed for 24 hours. A secondary objective was to find a modifier that after shearing would produce a Bingham Plastic yield stress of 30 Pa and plastic viscosity of 30 mPa-sec. Two parallel paths were chosen with one examining a variety of organic/inorganic modifiers and another using just the inorganic modifier Laponite (R). The addition of organic modifiers hydroxyethylcellulose, hydroxypropylmethylcellulose, and hydroxypropylcellulose at a target 0.50 wt percent dramatically increased the vane yield stress over the range 311 - 724 Pa, and also increased the Bingham plastic yield stress and plastic viscosities over the range 33-112 Pa and 27-166 mPa-sec, respectively. The organic modifiers also showed elastic behavior, yielding a very unpredictable up flow curve. The 0.50 wt percent addition of inorganic modifiers magnesium aluminum silicate and hydrate magnesium aluminum silicate only increased the vane yield stress to 36-46 Pa and had little impact on the Bingham Plastic parameters. A range of an inorganic (2-4 wt percent magnesium aluminum silicate) and combination of a range of an inorganic (2-3 wt percent magnesium aluminum silicate) and organic (0.03-0.05 wt percent sodium carboxymethylcellulose) modifiers were then tested. These results showed that the target vane yield stress could be obtained but the Bingham Plastic yield stress and plastic viscosity were 3 times too high. Reducing the organic modifier weight percent by a few hundredths, the Bingham Plastic yield stress could be obtained, but then the vane yield stress would be too low. The addition of Laponite (R) (synthetic lithium aluminum silicate) increased the vane yield stress of the clay slurry to values as high as 1500 Pa. However, the flow curve behavior for the laponite samples was not predictable and the secondary objective was dropped based on customer needs and time constraints. Ultimately a 3-wt percent addition of Laponite (R) was chosen to produce a 600 Pa vane yield stress mixture.
Download or read book Kaolin Rheology Modifier Study for SRNL WTP Pulse Jets Tank Pilot Work in Support of RPP at Hanford written by Russ Eibling and published by . This book was released on 2005 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Demonstration of Mixing and Transferring Settling Cohesive Slurry Simulants in the AY 102 Tank written by and published by . This book was released on 2012 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: In support of Hanford's feed delivery of high level waste (HLW) to the Waste Treatment and Immobilization Plant (WTP), pilot-scale testing and demonstrations with simulants containing cohesive particles were performed as a joint collaboration between Savannah River National Laboratory (SRNL) and the Pacific Northwest National Laboratory (PNNL) staff. The objective of the demonstrations was to determine the impact that cohesive particle interactions in the simulants, and the resulting non-Newtonian rheology, have on tank mixing and batch transfer of large and dense seed particles. The work addressed the impacts cohesive simulants have on mixing and batch transfer performance in a pilot-scale system. Kaolin slurries with a range of wt% concentrations to vary the Bingham yield stress were used in all the non-Newtonian simulants. To study the effects of just increasing the liquid viscosity (no yield stress) on mixing and batch transfers, a glycerol/water mixture was used. Stainless steel 100 micron particles were used as seed particles due to their density and their contrasting color to the kaolin and glycerol. In support of Hanford's waste certification and delivery of tank waste to the Waste Treatment and Immobilization Plant (WTP), Savannah River National Laboratory (SRNL) was tasked by Washington River Protection Solutions (WRPS) to evaluate the effectiveness of mixing and transferring tank waste in a Double Shell Tank (DST) to the WTP Receipt Tank. The work addresses the impacts cohesive simulants have on mixing and batch transfer performance. This work is follow-on to the previous tasks 'Demonstration of Mixer Jet Pump Rotational Sensitivity on Mixing and Transfers of the AY-102 Tank' and 'Demonstration of Simulated Waste Transfers from Tank AY-102 to the Hanford Waste Treatment Facility'. The cohesive simulants were investigated and selected jointly by SRNL and PNNL and a white paper was written on this evaluation. The testing and demonstrations of cohesive simulants was a joint effort performed as collaboration between SRNL and PNNL staff. The objective of the demonstrations was to determine the impact that cohesive particle interactions in the simulants have on tank mixing using the 1/22nd scale mixing system and batch transfer of seed particles. Seed particles are particles of contracting color added to mixing tank for visual inspection and an indicator of how well the contents of the tank are mixing. Also the seed particles serve as a measuring stick for how well the contents of the tank are transferred from the mixing tank during batch transfers. This testing is intended to provide supporting evidence to the assumption that Hanford Small Scale Mixing Demonstration (SSMD) testing in water is conservative.
Download or read book Mudflow Rheology and Dynamics written by Philippe Coussot and published by Routledge. This book was released on 2017-11-01 with total page 217 pages. Available in PDF, EPUB and Kindle. Book excerpt: Presenting current knowledge in the field of mudflows, this book includes both rheological mudflow aspects, and information on mudflow characteristics in open channels. It includes sections on: · physical properties of suspensions · shear rheometry with suspensions · rheology of clay-water mixtures · rheology of mud suspensions · gradually and rapidly varied free surface flows Part of the IAHR Monograph Series, this informative book also includes fundamental equations for viscoplastic flows and provides the reader with helpful introductions to all the aspects it covers.
Download or read book Handbook of Clay Science written by and published by Newnes. This book was released on 2013-07-23 with total page 1748 pages. Available in PDF, EPUB and Kindle. Book excerpt: The first edition of the Handbook of Clay Science published in 2006 assembled the scattered literature on the varied and diverse aspects that make up the discipline of clay science. The topics covered range from the fundamental structures (including textures) and properties of clays and clay minerals, through their environmental, health and industrial applications, to their analysis and characterization by modern instrumental techniques. Also included are the clay-microbe interaction, layered double hydroxides, zeolites, cement hydrates, and genesis of clay minerals as well as the history and teaching of clay science. The 2e adds new information from the intervening 6 years and adds some important subjects to make this the most comprehensive and wide-ranging coverage of clay science in one source in the English language. - Provides up-to-date, comprehensive information in a single source - Covers applications of clays, as well as the instrumental analytical techniques - Provides a truly multidisciplinary approach to clay science
Download or read book Surfactants in Upstream E P written by Theis Solling and published by Springer Nature. This book was released on 2021-06-19 with total page 458 pages. Available in PDF, EPUB and Kindle. Book excerpt: This edited book explores the use of surfactants in upstream exploration and production (E&P). It provides a molecular, mechanistic and application-based approach to the topic, utilising contributions from the leading researchers in the field of organic surfactant chemistry and surfactant chemistry for upstream E&P. The book covers a wide range of problems in enhanced oil recovery and surfactant chemistry which have a large importance in drilling, fracking, hydrate inhibition and conformance. It begins by discussing the fundamentals of surfactants and their synthesis. It then moves on to present their applicability to a variety of situations such as gas injections, shale swelling inhibition, and acid stimulation. This book presents research in an evolving field, making it interesting to academics, postgraduate students, and experts within the field of oil and gas.
Download or read book The Structure and Rheology of Complex Fluids written by Ronald G. Larson and published by OUP USA. This book was released on 1999-01-28 with total page 688 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Structure and Rheology of Complex Fluids describes the microstructures of polymeric, colloidal, amphiphilic, and liquid crystalline liquids, and the relationship between microstructure and mechanical and flow properties. It provides illustrations, practical examples, and worked problems. This book can serve as both a textbook for a graduate course and a research monograph.
Download or read book Microstructure of Fine Grained Sediments written by Richard Harold Bennett and published by Springer Science & Business Media. This book was released on 1991 with total page 614 pages. Available in PDF, EPUB and Kindle. Book excerpt: Knowledge of basic clay microstructure is fundamental to an understanding of the physical, chemical, and mechanical properties of fine-grained sediments and rocks. This compilation of fifty-nine peer-reviewed papers examines clay microstructure in detail with comprehensive sections focusing on microstructure signatures, environmental processes, modeling, measurement techniques, and future research recommendations. Many of these topics are discussed in light of geological and engineering applications, such as hazardous waste disposal, construction techniques, and drilling programs. The field of clay microstructure is developing rapidly. The concepts, observations, and principles presented in this book will help stimulate new thought and be a "spring board" for exciting new research.
Download or read book Developments in Palygorskite Sepiolite Research written by and published by Elsevier. This book was released on 2011-07-20 with total page 529 pages. Available in PDF, EPUB and Kindle. Book excerpt: The aim of this comprehenvise book is to present the most important results achieved in the research of the clay minerals palygorskite and sepiolite. Palygorskite and sepiolite have found to be useful in a huge variety of industrial and medical applications. As a result, research on these clays has been intensified during the last two decades, and important advances in their characterization have been made. The book contains contributions from distinguished scientists in the field. - Comprehensive treatment of palygorskite and sepiolite - Cutting-edge developments in industrial minerals and applications - Written by distinguished scientists in the field
