Download or read book Removal of Technetium Carbon Tetrachloride and Metals from DOE Properties written by and published by . This book was released on 2000 with total page 5 pages. Available in PDF, EPUB and Kindle. Book excerpt: The objective of this research is to prepare, characterize, and evaluate new materials for the removal of technetium (Tc) compounds, halogenated organics, and other troublesome metals from DOE waste streams and contaminated areas. This work follows the discovery that a nanoscale form of zero-valent iron, dispersed on high surface area supports, reduces metal ions (Cr, Hg, Pb, Cd) and Re (as a surrogate for Tc) to insoluble forms faster and with higher efficiency than does unsupported iron. Liquid-liquid extraction methods are also being developed for quantitative removal of Cs from tetraphenylborate salt mixtures, which are generated in waste processing at Savannah River, and conversion to vitrifiable inorganic Cs salts.
Download or read book Removal of Technetium Carbon Tetrachloride and Metals from DOE Properties 1998 Annual Progress Report written by and published by . This book was released on 1998 with total page 4 pages. Available in PDF, EPUB and Kindle. Book excerpt: The objective of the project is to develop and characterize supported reducing agents, and solid waste forms derived from them, which will be effective in the removal of transition metal ions, chlorinated organic molecules, and technetium from aqueous mixed wastes. This work follows the discovery that a nanoscale form of zero-valent iron, dispersed on high surface area supports, reduces metal ions (chromium, mercury, and lead) and rhenium (as a surrogate for technetium) to insoluble forms much faster than does unsupported iron. The scientific goals of the project are to better understand the mechanism of the reduction process, to develop supports that are compatible with a variety of mixed waste compositions, and to develop surface modifiers for the supported iron aggregates that will optimize their selectivity for the contaminants of interest. The support composition is of particular interest in the case of technetium (Tc) separation and stabilization in the Hanford tank wastes. While it is expected that pertechnetate will be reduced insoluble TcO2, the support material must be compatible with the vitrification process used in the final waste disposition. The surface modifications are also a focal point for Hanford applications because of the complex and variable makeup of the tank wastes. This report summarizes progress in the first 8 months of a 3-year collaborative project involving Penn State and Pacific Northwest National Laboratory (PNNL).
Download or read book Removal of Technetium Carbon Tetrachloride and Metals from DOE Properties Final Report written by and published by . This book was released on 2000 with total page 5 pages. Available in PDF, EPUB and Kindle. Book excerpt: This research is a three year project involving close collaboration between chemists at Pennsylvania State University and materials scientists at Pacific Northwest National Laboratory (PNNL). The goal of the project is the development and characterization of supported reducing agents, and solid waste forms derived from them, which will be effective in remediation of aqueous wastes. The work follows the recent discovery that zero-valent metals, such as iron, are effective decontaminants for waste streams containing chlorinated hydrocarbons. Preliminary data, obtained at Penn State and elsewhere, have shown that the same strategy will be effective in reducing soluble compounds containing toxic metals (technetium, lead, mercury, and chromium) to insoluble forms. The Penn State group has prepared a new class of powerful reducing agents, called Ferragels, which consist of finely divided zero-valent metals on high surface area supports. Because the rate of the surface oxidation-reduction reaction depends on available surface area, Ferragels are more effective in every case tested to date than unsupported metals. The project will further develop and investigate the application of these composite materials to problems relevant to the DOE-EM mission, namely the detoxification of waste streams containing technetium, carbon tetrachloride, and toxic metal ions. The Penn State group will work closely with the PNNL group to prepare materials that are compatible with the highly corrosive liquid fraction of Hanford site tank waste, to conduct tests with waste simulants containing technetium, and to formulate and characterize vitrified waste forms derived from these materials.
Download or read book The Office of Environmental Management Technical Reports written by and published by . This book was released on 1997 with total page 972 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Process for Removing Technetium from Iron and Other Metals written by and published by . This book was released on 1997 with total page 16 pages. Available in PDF, EPUB and Kindle. Book excerpt: Technetium is a radioactive product of the nuclear fission process. During reprocessing of spent or partially spent fuel from nuclear reactors, the technetium can be released and contaminate other, otherwise good, metals. A specific example is equipment in gaseous diffusion uranium enrichment cascades which have been used to process fuel which was returned from reactors, so-called reactor returns. These returns contained volatile technetium compounds which contaminated the metals in the equipment. Present regulations require that technetium be removed before the metal can be re-used at non-radioactive sites. Removing the technetium from contaminated metals has two desirable results. First, the large amount of nonradioactive metal produced by the process herein described can be recycled at a much lower cost than virgin metal can be produced. Second, large amounts of radioactively contaminated metal can be reduced to relatively small amounts of radioactive slag and large amounts of essentially uncontaminated metal. A new and improved process for removing technetium from iron and other metals is described in which between 1/10 atom % and 5 atom % of manganese is added to the contaminated metal in order to replace the technetium.
Download or read book Energy Research Abstracts written by and published by . This book was released on 1994-02 with total page 484 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Assessment and Management of Environmental Risks written by Igor Linkov and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 451 pages. Available in PDF, EPUB and Kindle. Book excerpt: Managing environmental contamination requires decision makers to weigh eXlstmg risks against the potential effects of implementing environmental policies - considering both the benefits and disruptions that may result from different actions. The NATO Advanced Research Workshop in Lisbon was an important step in the development and application of cost efficient methods of risk assessment especiaIly within the constraints of a budget. The goal of the workshop was to evaluate the potential for risk assessment to serve as a unified and unifying technique in addressing a wide range of environmental problems. Papers presented in this book discuss issues ranging from specific and local studies (specific site, ecosystem, pollutant) to global decision and management frameworks (watersheds, regions, integration of multiple poIlutants and stressors); they develop a range of approaches starting from specific methods to widely applied public policies (Figure 1). The papers show that the use of risk assessment can provide the scientific basis for environmentaIly sound and cost-efficient policies, strategies, and solutions to our environmental chaIlenges. The organization of the Proceedings reflects sessions and discussions during the workshop. The papers in the introductory Chapter summarize the positions of Drs. Glenn Suter (EPA) and Jim Wilson (Resources for the Future) regarding whether the use of often-expensive risk assessments in developing countries can be justified, given evolving regulatory institutions and limited resources.
Download or read book Radiopharmaceutical Chemistry written by Jason S. Lewis and published by Springer. This book was released on 2019-04-02 with total page 648 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is a comprehensive guide to radiopharmaceutical chemistry. The stunning clinical successes of nuclear imaging and targeted radiotherapy have resulted in rapid growth in the field of radiopharmaceutical chemistry, an essential component of nuclear medicine and radiology. However, at this point, interest in the field outpaces the academic and educational infrastructure needed to train radiopharmaceutical chemists. For example, the vast majority of texts that address radiopharmaceutical chemistry do so only peripherally, focusing instead on nuclear chemistry (i.e. nuclear reactions in reactors), heavy element radiochemistry (i.e. the decomposition of radioactive waste), or solely on the clinical applications of radiopharmaceuticals (e.g. the use of PET tracers in oncology). This text fills that gap by focusing on the chemistry of radiopharmaceuticals, with key coverage of how that knowledge translates to the development of diagnostic and therapeutic radiopharmaceuticals for the clinic. The text is divided into three overarching sections: First Principles, Radiochemistry, and Special Topics. The first is a general overview covering fundamental and broad issues like “The Production of Radionuclides” and “Basics of Radiochemistry”. The second section is the main focus of the book. In this section, each chapter’s author will delve much deeper into the subject matter, covering both well established and state-of-the-art techniques in radiopharmaceutical chemistry. This section will be divided according to radionuclide and will include chapters on radiolabeling methods using all of the common nuclides employed in radiopharmaceuticals, including four chapters on the ubiquitously used fluorine-18 and a “Best of the Rest” chapter to cover emerging radionuclides. Finally, the third section of the book is dedicated to special topics with important information for radiochemists, including “Bioconjugation Methods,” “Click Chemistry in Radiochemistry”, and “Radiochemical Instrumentation.” This is an ideal educational guide for nuclear medicine physicians, radiologists, and radiopharmaceutical chemists, as well as residents and trainees in all of these areas.
Download or read book Hanford Remedial Action Comprehensive Land use Plan Hanford Site in the Pasco Basin of the Columbia Plateau written by and published by . This book was released on 1999 with total page 170 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book The Office of Environmental Management Technical Reports written by and published by . This book was released on 1997 with total page 968 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Research Needs for High Level Waste Stored in Tanks and Bins at U S Department of Energy Sites written by National Research Council and published by National Academies Press. This book was released on 2001-10-05 with total page 146 pages. Available in PDF, EPUB and Kindle. Book excerpt: The United States Department of Energy (DOE) has approximately 400 million liters (100 million gallons) of liquid high-level waste (HLW) stored in underground tanks and approximately 4,000 cubic meters of solid HLW stored in bins. The current DOE estimate of the cost of converting these liquid and solid wastes into stable forms for shipment to a geological repository exceeds $50 billion to be spent over several decades (DOE, 2000). The Committee on Long-Term Research Needs for Radioactive High-Level Waste at Department of Energy Sites was appointed by the National Research Council (NRC) to advise the Environmental Management Science Program (EMSP) on a long-term research agenda addressing the above problems related to HLW stored in tanks and bins at DOE sites.
Download or read book Nuclear Wastes written by National Research Council and published by National Academies Press. This book was released on 1996-02-23 with total page 590 pages. Available in PDF, EPUB and Kindle. Book excerpt: Disposal of radioactive waste from nuclear weapons production and power generation has caused public outcry and political consternation. Nuclear Wastes presents a critical review of some waste management and disposal alternatives to the current national policy of direct disposal of light water reactor spent fuel. The book offers clearcut conclusions for what the nation should do today and what solutions should be explored for tomorrow. The committee examines the currently used "once-through" fuel cycle versus different alternatives of separations and transmutation technology systems, by which hazardous radionuclides are converted to nuclides that are either stable or radioactive with short half-lives. The volume provides detailed findings and conclusions about the status and feasibility of plutonium extraction and more advanced separations technologies, as well as three principal transmutation concepts for commercial reactor spent fuel. The book discusses nuclear proliferation; the U.S. nuclear regulatory structure; issues of health, safety and transportation; the proposed sale of electrical energy as a means of paying for the transmutation system; and other key issues.
Download or read book Introduction to X Ray Powder Diffractometry written by Ron Jenkins and published by Wiley-Interscience. This book was released on 1996-07-12 with total page 440 pages. Available in PDF, EPUB and Kindle. Book excerpt: Introduction to X-ray Powder Diffractometry fully updates the achievements in the field over the past fifteen years and provides a much-needed explanation of the state-of-the-art techniques involved in characterizing materials. It covers the latest instruments and methods, with an emphasis on the fundamentals of the diffractometer, its components, alignment, calibration, and automation. While the material is presented in an orderly progression, beginning with basic concepts and moving on to more complex material, each chapter stands on its own and can be studied independently or used as a professional reference. More than 230 illustrations and tables demonstrate techniques and clarify complex material.
Download or read book Scientific and Technical Aerospace Reports written by and published by . This book was released on 1984 with total page 1278 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Improving the Scientific Basis for Managing DOE s Excess Nuclear Materials and Spent Nuclear Fuel written by National Research Council and published by National Academies Press. This book was released on 2003-06-09 with total page 124 pages. Available in PDF, EPUB and Kindle. Book excerpt: The production of nuclear materials for the national defense was an intense, nationwide effort that began with the Manhattan Project and continued throughout the Cold War. Now many of these product materials, by-products, and precursors, such as irradiated nuclear fuels and targets, have been declared as excess by the Department of Energy (DOE). Most of this excess inventory has been, or will be, turned over to DOE's Office of Environmental Management (EM), which is responsible for cleaning up the former production sites. Recognizing the scientific and technical challenges facing EM, Congress in 1995 established the EM Science Program (EMSP) to develop and fund directed, long-term research that could substantially enhance the knowledge base available for new cleanup technologies and decision making. The EMSP has previously asked the National Academies' National Research Council for advice for developing research agendas in subsurface contamination, facility deactivation and decommissioning, high-level waste, and mixed and transuranic waste. For this study the committee was tasked to provide recommendations for a research agenda to improve the scientific basis for DOE's management of its high-cost, high-volume, or high-risk excess nuclear materials and spent nuclear fuels. To address its task, the committee focused its attention on DOE's excess plutonium-239, spent nuclear fuels, cesium-137 and strontium-90 capsules, depleted uranium, and higher actinide isotopes.
Download or read book Research Development written by and published by . This book was released on 1998-09 with total page 584 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Metals Abstracts written by and published by . This book was released on 1991 with total page 948 pages. Available in PDF, EPUB and Kindle. Book excerpt:
