Download or read book Reactions of Coordinated Ligands and Homogeneous Catalysis written by Daryl Hadley Bush and published by . This book was released on 1988 with total page 255 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Reactions of Coordinated Ligands written by P.S. Braterman and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 419 pages. Available in PDF, EPUB and Kindle. Book excerpt: This, the second and final volume of Reactions of Coordinated Ligands, describes the chemistry of ligands bound through non-carbon atoms, and of coordinated carbon dioxide. As before, emphasis is on the underlying mechanisms, which provide a unity of understanding for superficially disparate processes. The wide range of topics covered illustrates well both the versatility and the usefulness of coordination chemistry in the controlled activation of ligands. Looking to the future, carbon dioxide is the feedstock of last resort. The homogeneous reduction of dinitrogen to ammonia now seems unlikely to replace the Haber process, but solution reactions also lead to more complex, varied, and valuable products. Nitrogen monoxide, a "non innocent" ligand, impinges as pollutant and reagent. Its rich chemistry stems from its linked roles as three-electron donor, and as extremely powerful -acceptor. In the hydrolysis and condensation of complexed amides, esters etc. , metals act both as templates and as tunable and poly functional Lewis acids. Here the control of hydrophobic and steric interactions begins to model the subtle mechanisms of biological specificity. Finally, phosphorus and sulfur are imporant both as ligand atoms in themselves, and as anchors for other functionalities. I would like to thank all those who have been involved in the writing and production of this work, and also my colleagues old and new, at Glasgow and the University of North Texas, for their support. Paul S. Braterman v CONTENTS 1. Reactions of Coordinated Carbon Dioxide 1 J. D. Miller 1.

Download or read book Reactions of Coordinated Ligands and Homogeneous Catalysis written by Daryle H. Busch and published by . This book was released on 1963 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Reactions of Coordinated Ligands written by P.S. Braterman and published by Springer. This book was released on 2011-11-10 with total page 1064 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is aimed at graduate students and research workers in aU branches of ohemistry, who wish to gain insight into what continues'to be one of the fastest growing areas of the subject. Aonding to a metal center may stabilize a ligand towards some reagents, activate it towards others, or modify its chemical behavior in more subtle ways. AU these effects have their uses, and aU invite understanding in terms of mechanism. Thus mechanistic insight is linked to control of reaction pathways. The detailed working out of this relationship provides the central theme of the book. The effect of the metal may be electronic or steric, and may involve the energy or the entropy of activation. It may depend on changes induced in the initial state of the ligand, or on those that only arise further along the reaction pathway. It may involve one coordination site or several, and the effects may be more, or less, specific to the metal involved and more, or less, amenable to control through the other Jigands. These remarks apply equaUy strongly to the carbon-bound ligands which occupy the major part of this work, and to those attached by other atoms. Thus the reactions discussed here are relevant in such diverse areas as bulk homogeneous catalysis, stereoselective stoichiometric synthesis, and bioinorganic chemistry.

Download or read book Reactions of coordinated ligands and homogeneous catalysis written by and published by . This book was released on 1963 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Reactions of Coordinated Ligands and Homogeneous Catalysis written by American Chemical Society. Division of Inorganic Chemistry and published by . This book was released on 1963 with total page 268 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Reactions of Coordinated Ligands and Homogeneous Catalysis written by Daryl H. Busch and published by . This book was released on 1963 with total page 255 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Reactions of coordinated ligands and homogeneous catalysis a symposium sponsored by the Division of Inorganic Chemistry at the 141st meeting of the American Chemical Society Wash D C March 22 24 1962 D H Busch symposium chairman written by Daryl Hadley Busch and published by . This book was released on with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Reactions of Coordinated Ligands and Homogeneous Catalysis written by American Chemical Society. Division of Inorganic Chemistry and published by . This book was released on 1963 with total page 255 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book REACTIONS OF COORDINATED LIGANDS AND HOMOGENEOUS CATALYSIS SYMPOSIUM OF THE DIVISION OF INORGANIC CHEMISTRY AT THE 141ST MEETING ACS written by and published by . This book was released on with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Reactions of Co ordinated Ligands and Homogeneous Catalysis written by and published by . This book was released on 1963 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Reactions of Coordinated Ligands and Homogeneous Catalysis written by American Chemical Society. Division of Inorganic Chemistry and published by . This book was released on 1963 with total page 255 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Reactions of Coordinated Ligands and Homogeneous Catalysis written by Symposium Reactions of Coordinated Ligands of Homogeneous Catalysis. 1962, Washington, DC. and published by . This book was released on 1963 with total page 255 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Reactions of Coordinated Ligands and Homogeneous Catalysis written by American Chemical Society. Division of Inorganic Chemistry and published by . This book was released on 1963 with total page 255 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Reactions of Coordinated Ligands and Homogeneous Catalysis written by American Chemical Society. Division of Inorganic Chemistry and published by . This book was released on 1963 with total page 262 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Handbook of Coordination Catalysis in Organic Chemistry written by Penny A Chaloner and published by Butterworth-Heinemann. This book was released on 2013-10-22 with total page 1009 pages. Available in PDF, EPUB and Kindle. Book excerpt: Handbook of Coordination Catalysis in Organic Chemistry presents the increasing importance of homogeneous catalysis by metal complexes. This book highlights special selectivities that can be obtained using coordination complexes as catalysts, including a discussion of homogeneous catalysts and closely related polymer supported complexes. Other topics include hydrogenation and related reactions, reactions of carbon monoxide, and additions to carbon-carbon multiple bonds. The isomerization reactions, reactions of the carbonyl group, formation of carbon-carbon bonds, and alkene metathesis are also deliberated. This publication is intended for organic chemists, but is also useful to specialists and researchers interested in the coordination catalysis in organic chemistry.

Download or read book Homogeneous Catalysis with Metal Phosphine Complexes written by Louis M. Pignolet and published by Springer Science & Business Media. This book was released on 2013-11-21 with total page 494 pages. Available in PDF, EPUB and Kindle. Book excerpt: The field of transition metal catalysis has experienced incredible growth during the past decade. The reasons for this are obvious when one considers the world's energy problems and the need for new and less energy demanding syntheses of important chemicals. Heterogeneous catalysis has played a major industrial role; however, such reactions are generally not selective and are exceedingly difficult to study. Homogeneous catalysis suffers from on-site engineering difficulties; however, such reactions usually provide the desired selectivity. For example, Monsanto's synthesis of optically-active amino acids employs a chiral homogeneous rhodium diphosphine catalyst. Industrial uses of homogeneous catalyst systems are increasing. It is not by accident that many homogeneous catalysts contain tertiary phosphine ligands. These ligands possess the correct steric and electronic properties that are necessary for catalytic reactivity and selectivity. This point will be emphasized throughout the book. Thus the stage is set for a comprehensive be treatment of the many ways in which phosphine catalyst systems can designed, synthesized, and studied.