Download or read book Rare Earth Doped Anatase TiO2 Nanoparticles written by Vesna Đorđević and published by . This book was released on 2017 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Titanium dioxide is a wide band-gap semiconductor of high chemical stability, nontoxicity and large refractive index. Because of the high photocatalytic activity, anatase is a preferred TiO2 form in many applications such as for air and water splitting and purification. Doping of TiO2 with various ions can increase the photocatalytic activity by enhancing light absorption in visible region and can alter structure, surface area and morphology. Also, by doping TiO2 with optically active ions, visible light via up- or downconversion luminescence can be produced. It is a challenge to optimize the synthesis procedure to incorporate rare earth RE3+ ions into the TiO2 structure due to large mismatch in ionic radii between the Ti4+ and RE3+ and because of the charge imbalance. Visible (VIS) and ultraviolet (UV) luminescence of several RE3+ ions can be obtained when incorporated into anatase TiO2, also affecting microstructural characteristics of TiO2. It is of great importance to summarize publications on rare earth-doped anatase TiO2 nanoparticles to find correct TiO2-RE combination to sensitize trivalent rare earths luminescence, as well as to predict or tune structural and morphological properties. A better understanding on these topics may progress the desired design of this kind of material towards specific applications.
Download or read book Titanium Dioxide written by Magdalena Janus and published by BoD – Books on Demand. This book was released on 2017-07-26 with total page 260 pages. Available in PDF, EPUB and Kindle. Book excerpt: Titanium dioxide is mainly used as a pigment and photocatalyst. It is possible to find it in food, cosmetics, building materials, electric devices, and others. This book contains chapters about characteristics of anatase and rutile crystallographic structure of titanium dioxide and the use of theoretical calculation for photoactivity determination.
Download or read book Investigation of Lanthanide doped Anatase TiO2 Core shell Nanoparticles for Photocatalysis and Gas Sensing written by Rezwanur Rahman and published by . This book was released on 2015 with total page 106 pages. Available in PDF, EPUB and Kindle. Book excerpt: Anatase TiO2 has been shown to be potential applications for photo-remediation of chemical waste as well as for photocatalytic splitting of water. The catalytic properties of TiO2 materials can be modified by doping with lanthanide (Ln) ions. In order to minimize the distortion and/or change of the structure of TiO2 nanoparticles, surface doping of anatase TiO2 nanoparticles (~ 14 nm) with several Ln ions (Nd3+, Gd3+, Eu3+, Yb3+ has been successfully made. X-ray diffraction (XRD) and Raman characterization shows that the anatase phase of treated nanoparticles is well preserved. Scanning electron microscopy (SEM) shows that the majority of the nanoparticles exhibit nanocrystalline shape and transmission electron microscopy (TEM) shows TiO2 core and Ln-TiO2 shell structure having a uniform phase consistent with the anatase atomic-scale structure. Energy Dispersive X-ray (EDX) spectroscopy confirms the presence of Ln ions within the Ln-TiO2 nanoparticles. Temperature dependent in situ optical measurements show an increase in photoluminescence (PL) in forming gas (5% H2 + 95% Ar) at 520 °C which is attributed to nanoparticle modification (i.e. core-shell structure) induced by doping and use of the hydrothermal treatment. The increase in the distinguishable features in the PL spectrum at low and high (near IR) wavelength regions are attributed to various contributions from oxygen-vacancies and trapped electrons, respectively. Furthermore, X-ray Photoelectron Spectroscopy (XPS) has been performed to observe the shift in the local chemical states due to Ln incorporation into the anatase TiO2 structure.
Download or read book Synthesis of Rare Earth Doped TiO2 Nanorods as Photocatalysts for Lignin Degradation written by and published by . This book was released on 2015 with total page 9 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this paper, a two-step process is developed to synthesize rare earth doped titania nanorods (RE-TiO2 NRs) as photocatalysts for efficient degradation of lignin under simulated sunlight irradiation. In this approach, protonated titanate nanotubes with layered structures were first prepared by a hydrothermal approach, and rare earth metal ions were subsequently bound to the negatively charged surface of the synthesized titanate via electrostatic incorporation. The as-synthesized RE-TiO2 NRs after calcination generally showed much higher photocatalytic efficiencies than those of undoped TiO2 NRs or the commercial P25 TiO2 photocatalyst. Using methyl orange (MO) as a probing molecule, we demonstrate that Eu-TiO2 NRs are among the best for degrading MO, with an observed rate constant of 4.2 × 10-3 s-1. The La3+, Sm3+, Eu3+ and Er3+ doped TiO2 NRs also showed higher photocatalytic efficiencies in degrading MO than the commercial P25 TiO2. Finally, we further demonstrate that lignin can be photodegraded effectively and rapidly at room temperature under simulated sunlight through two reaction routes, which could be important in controlling ways of lignin depolymerization or the formation of reaction products.
Download or read book TiO2 Nanoparticles written by Aiguo Wu and published by John Wiley & Sons. This book was released on 2020-06-02 with total page 252 pages. Available in PDF, EPUB and Kindle. Book excerpt: A unique book that summarizes the properties, toxicology, and biomedical applications of TiO2-based nanoparticles Nanotechnology is becoming increasingly important for products used in our daily lives. Nanometer-sized titanium dioxide (TiO2) are widely used in industry for different purposes, such as painting, sunscreen, printing, cosmetics, biomedicine, and so on. This book summarizes the advances of TiO2 based nanobiotechnology and nanomedicine, covering materials properties, toxicological research, and biomedical application, such as antibacter, biosensing, and cancer theranostics. It uniquely integrates the TiO2 applications from physical properties, toxicology to various biomedical applications, and includes black TiO2 based cancer theranostics. Beginning with a comprehensive introduction to the properties and applications of nanoparticles, TiO2 Nanoparticles: Applications in Nanobiotechnology, Theranostics and Nanomedicine offers chapters on: Toxicity of TiO2 Nanoparticles; Antibacterial Applications of TiO2 Nanoparticles; Surface Enhanced Raman Spectrum of TiO2 Nanoparticle for Biosensing (TiO2 Nanoparticle Served as SERS Sensing Substrate); TiO2 as Inorganic Photosensitizer for Photodynamic Therapy; Cancer Theranostics of Black TiO2 Nanoparticles; and Neurodegenerative Disease Diagnostics and Therapy of TiO2-Based Nanoparticles. This title: -Blends the physical properties, toxicology of TiO2 nanoparticles to the many biomedical applications -Includes black TiO2 based cancer theranostics in its coverage -Appeals to a broad audience of researchers in academia and industry working on nanomaterials-based biosensing, drug delivery, nanomedicine TiO2 Nanoparticles: Applications in Nanobiotechnology, Theranostics and Nanomedicine is an ideal book for medicinal chemists, analytical chemists, biochemists, materials scientists, toxicologists, and those in the pharmaceutical industry.
Download or read book Ceramic Science and Engineering written by Kamakhya Prakash Misra and published by Elsevier. This book was released on 2022-05-03 with total page 618 pages. Available in PDF, EPUB and Kindle. Book excerpt: Ceramic Science and Engineering: Basics to Recent Advancements covers the fundamentals, classification and applications surrounding ceramic engineering. In addition, the book contains an extensive review of the current published literature on established ceramic materials. Other sections present an extensive review of up-to-date research on new innovative ceramic materials and reviews recently published articles, case studies and the latest research outputs. The book will be an essential reference resource for materials scientists, physicists, chemists and engineers, postgraduate students, early career researchers, and industrial researchers working in R&D in the development of ceramic materials. Ceramic engineering deals with the science and technology of creating objects from inorganic and non-metallic materials. It combines the principles of chemistry, physics and engineering. Fiber-optic devices, microprocessors and solar panels are just a few examples of ceramic engineering being applied in everyday life. Advanced ceramics such as alumina, aluminum nitride, zirconia, ZnO, silicon carbide, silicon nitride and titania-based materials, each of which have their own specific characteristics and offer an economic and high-performance alternative to more conventional materials such as glass, metals and plastics are also discussed. - Covers environmental barrier ceramic coatings, advanced ceramic conductive fuel cells, processing and machining technology in ceramic and composite materials, photoluminescent ceramic materials, perovskite ceramics and bioinspired ceramic materials - Reviews both conventional, established ceramics and new, innovative advanced ceramics - Contains an extensive review of the current published literature on established ceramic materials
Download or read book Powder Surface Area and Porosity written by S. Lowell and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 244 pages. Available in PDF, EPUB and Kindle. Book excerpt: The rapid growth of interest in powders and their surface properties in many diverse industries prompted the writing of this book for those who have the need to make meaningful measurements without the benefit of years of experience. It is intended as an introduction to some of the elementary theory and experimental methods used to study the surface area, porosity and density of powders. It may be found useful by those with little or no training in solid surfaces who have the need to quickly learn the rudiments of surface area, density and pore-size measurements. Syosset, New York S. Lowell May, 1983 J. E. Shields Xl List of symbols Use of symbols for purposes other than those indicated in the following list are so defined in the text. Some symbols not shown in this list are defined in the text. d adsorbate cross-sectional area A area; condensation coefficient; collision frequency C BET constant c concentration D diameter; coefficient of thermal diffusion E adsorption potential f permeability aspect factor F flow rate; force; feed rate 9 gravitational constant G Gibbs free energy GS free surface energy h heat of immersion per unit area; height H enthalpy Hi heat of immersion Hsv heat of adsorption BET intercept; filament current k thermal conductivity; specific reaction rate K Harkins-Jura constant I length L heat of liquefaction M mass M molecular weight n number of moles N number of molecules; number of particles N Avagadro's number .
Download or read book TiO2 Nanoparticles written by Aiguo Wu and published by John Wiley & Sons. This book was released on 2020-02-12 with total page 311 pages. Available in PDF, EPUB and Kindle. Book excerpt: A unique book that summarizes the properties, toxicology, and biomedical applications of TiO2-based nanoparticles Nanotechnology is becoming increasingly important for products used in our daily lives. Nanometer-sized titanium dioxide (TiO2) are widely used in industry for different purposes, such as painting, sunscreen, printing, cosmetics, biomedicine, and so on. This book summarizes the advances of TiO2 based nanobiotechnology and nanomedicine, covering materials properties, toxicological research, and biomedical application, such as antibacter, biosensing, and cancer theranostics. It uniquely integrates the TiO2 applications from physical properties, toxicology to various biomedical applications, and includes black TiO2 based cancer theranostics. Beginning with a comprehensive introduction to the properties and applications of nanoparticles, TiO2 Nanoparticles: Applications in Nanobiotechnology, Theranostics and Nanomedicine offers chapters on: Toxicity of TiO2 Nanoparticles; Antibacterial Applications of TiO2 Nanoparticles; Surface Enhanced Raman Spectrum of TiO2 Nanoparticle for Biosensing (TiO2 Nanoparticle Served as SERS Sensing Substrate); TiO2 as Inorganic Photosensitizer for Photodynamic Therapy; Cancer Theranostics of Black TiO2 Nanoparticles; and Neurodegenerative Disease Diagnostics and Therapy of TiO2-Based Nanoparticles. This title: Blends the physical properties, toxicology of TiO2 nanoparticles to the many biomedical applications Includes black TiO2 based cancer theranostics in its coverage Appeals to a broad audience of researchers in academia and industry working on nanomaterials-based biosensing, drug delivery, nanomedicine TiO2 Nanoparticles: Applications in Nanobiotechnology, Theranostics and Nanomedicine is an ideal book for medicinal chemists, analytical chemists, biochemists, materials scientists, toxicologists, and those in the pharmaceutical industry.
Download or read book Synthesis of TiO 1tn2 Based Nanoparticles for Photocatalytic Applications written by Kranthi Kumar Akurati and published by Cuvillier Verlag. This book was released on 2008 with total page 195 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Emerging Trends in TiO2 Photocatalysis and Applications written by Trong-On Do and published by MDPI. This book was released on 2020-12-28 with total page 596 pages. Available in PDF, EPUB and Kindle. Book excerpt: The semiconductor titanium dioxide (TiO2) has been evolved as a prototypical material to understand the photocatalytic process, and has been demonstrated for various photocatalytic applications such as pollutants degradation, water splitting, heavy metal reduction, CO2 conversion, N2 fixation, bacterial disinfection, etc. Rigorous photocatalytic studies on TiO2 have paved the way to understanding the various chemical processes involved and the physical parameters (optical and electrical) required to design and construct diverse photocatalytic systems. Accordingly, it has been realized that an effective photocatalyst should have ideal band edge potential, narrow band gap energy, reduced charge recombination, enhanced charge separation, improved interfacial charge transfer, surface-rich catalytic sites, etc. As a result, many strategies have been developed to design a variety of photocatalytic systems, which include doping, composite formation, sensitization, co-catalyst loading, etc. Towards highlighting the above-mentioned diversities in TiO2 photocatalysis, there have been many interesting original research works on TiO2, involving material designs for various photocatalytic applications published in this Special Issue. In addition, some excellent review papers have also been published in this Special Issue, focusing on the various TiO2-based photocatalytic systems and their mechanisms and applications.
Download or read book Rare Earth Metals Advances in Research and Application 2011 Edition written by and published by ScholarlyEditions. This book was released on 2012-01-09 with total page 158 pages. Available in PDF, EPUB and Kindle. Book excerpt: Rare Earth Metals: Advances in Research and Application: 2011 Edition is a ScholarlyEditions™ eBook that delivers timely, authoritative, and comprehensive information about Rare Earth Metals. The editors have built Rare Earth Metals: Advances in Research and Application: 2011 Edition on the vast information databases of ScholarlyNews.™ You can expect the information about Rare Earth Metals in this eBook to be deeper than what you can access anywhere else, as well as consistently reliable, authoritative, informed, and relevant. The content of Rare Earth Metals: Advances in Research and Application: 2011 Edition has been produced by the world’s leading scientists, engineers, analysts, research institutions, and companies. All of the content is from peer-reviewed sources, and all of it is written, assembled, and edited by the editors at ScholarlyEditions™ and available exclusively from us. You now have a source you can cite with authority, confidence, and credibility. More information is available at http://www.ScholarlyEditions.com/.
Download or read book Semiconductor Photocatalysis written by Wenbin Cao and published by BoD – Books on Demand. This book was released on 2016-08-24 with total page 678 pages. Available in PDF, EPUB and Kindle. Book excerpt: Photocatalysis is a hot topic because it is an environmentally friendly approach toward the conversion of light energy into chemical energy at mild reaction environments. Also, it is well applied in several major areas such as water splitting, bacterial inactivation, and pollutants elimination, which is a possible solution to energy shortage and environmental issues. The fundamental knowledge and the frontier research progress in typical photocatalytic materials, such as TiO2-based and non-TiO2-based photocatalysts, are included in this book. Methods to improve the photocatalytic efficiency and to provide a hint for the rational design of the new photocatalysts are covered.
Download or read book Rare Earth Activated Phosphors written by Vikas Dubey and published by Elsevier. This book was released on 2022-06-29 with total page 410 pages. Available in PDF, EPUB and Kindle. Book excerpt: Rare-Earth-Activated Phosphors: Chemistry and Applications outlines important fundamentals and properties and explores successful application that address key problems across the sciences. Sections introduce phosphors and luminescence, explore their properties, characteristics, synthesis and degradation and highlight key applications across telecommunications, lighting, electroluminescent devices, (bio-)analytical sensors, bio-imaging set-ups, drug delivery and sustainable energy devices. Drawing on the knowledge of an expert team of contributors, the book provides useful insight into successfully harnessing the properties of rare earth activated phosphors for a range of important applications.Rare-earth nano-phosphors offer an interesting array of characteristics, including sharp emission bands, exceptional optical damage thresholds, low toxicity, high selectivity and stability, and long luminescence lifetimes. Understanding these properties can help researchers effectively manipulate them for a range of important applications. - Provides a good introduction to the useful properties and characteristics of rare earth activated phosphors - Analyzes the use of rare earth activated phosphors for a broad variety of important applications, bridging the gap between theory and application - Encourages further discourse and development for improving the energy-efficiency of devices based on rare earth activated phosphors
Download or read book Photocatalysts written by Sher Bahadar Khan and published by BoD – Books on Demand. This book was released on 2019-03-06 with total page 158 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book enlightens the type, chemical structure, and application of photo-catalysts. It covers the recent developments in photo-catalysts and their applications, particularly in photo-catalytic degradation of different organic pollutants, hydrogen production, etc. It provides a concise but complete coverage and overview of photocatalysts and their recent advances for a broad audience: beginners, graduate students, and specialists in both academic and industrial sectors.
Download or read book Photocatalytic Functional Materials for Environmental Remediation written by Alagarsamy Pandikumar and published by John Wiley & Sons. This book was released on 2019-06-10 with total page 397 pages. Available in PDF, EPUB and Kindle. Book excerpt: A comprehensive volume on photocatalytic functional materials for environmental remediation As the need for removing large amounts of pollution and contamination in air, soil, and water grows, emerging technologies in the field of environmental remediation are of increasing importance. The use of photocatalysis—a green technology with enormous potential to resolve the issues related to environmental pollution—breaks down toxic organic compounds to mineralized products such as carbon dioxide and water. Due to their high performance, ease of fabrication, long-term stability, and low manufacturing costs, photofunctional materials constructed from nanocomposite materials hold great potential for environmental remediation. Photocatalytic Functional Materials for Environmental Remediation examines the development of high performance photofunctional materials for the treatment of environmental pollutants. This timely volume assembles and reviews a broad range of ideas from leading experts in fields of chemistry, physics, nanotechnology, materials science, and engineering. Precise, up-to-date chapters cover both the fundamentals and applications of photocatalytic functional materials. Semiconductor-metal nanocomposites, layered double hydroxides, metal-organic frameworks, polymer nanocomposites, and other photofunctional materials are examined in applications such as carbon dioxide reduction and organic pollutant degradation. Providing interdisciplinary focus to green technology materials for the treatment of environmental pollutants, this important work: Provides comprehensive coverage of various photocatalytic materials for environmental remediation useful for researchers and developers Encompasses both fundamental concepts and applied technology in the field Focuses on novel design and application of photocatalytic materials used for the removal of environmental contaminates and pollution Offers in-depth examination of highly topical green-technology solutions Presents an interdisciplinary approach to environmental remediation Photocatalytic Functional Materials for Environmental Remediation is a vital resource for researchers, engineers, and graduate students in the multi-disciplinary areas of chemistry, physics, nanotechnology, environmental science, materials science, and engineering related to photocatalytic environmental remediation.
Download or read book Photocatalytic Nanomaterials for Environmental Applications written by Rajesh J. Tayade and published by Materials Research Forum LLC. This book was released on 2018-02-25 with total page 486 pages. Available in PDF, EPUB and Kindle. Book excerpt: Photocatalytic nanomaterials have a great potential in such applications as reduction of carbon dioxide and degradation of various pollutants. They are equally important in the production and storage of energy, e.g. in the conversion of solar energy to electricity, and the production of hydrogen in photoelectrochemical cells. Research on synthesis, characterization and specific applications is reported for titanium oxide and a number of other promising catalysts, such as silver phosphate, cerium oxide, zinc oxide and zinc sulfide.
Download or read book Nanoscale Materials in Water Purification written by Sabu Thomas and published by Elsevier. This book was released on 2018-11-14 with total page 892 pages. Available in PDF, EPUB and Kindle. Book excerpt: Novel nanoscale materials are now an essential part of meeting the current and future needs for clean water, and are at the heart of the development of novel technologies to desalinate water. The unique properties of nanomaterials and their convergence with current treatment technologies present great opportunities to revolutionize water and wastewater treatment. Nanoscale Materials for Water Purification brings together sustainable solutions using novel nanomaterials to alleviate the physical effects of water scarcity. This book covers a wide range of nanomaterials, including noble metal nanoparticles, magnetic nanoparticles, dendrimers, bioactive nanoparticles, polysaccharidebased nanoparticles, nanocatalysts, and redox nanoparticles for water purification. Significant properties and characterization methods of nanomaterials such as surface morphology, mechanical properties, and adsorption capacities are also investigated - Explains how the unique properties of a range of nanomaterials makes them important water purification agents - Shows how the use of nanotechnology can help create cheaper, more reliable, less energy-intensive, more environmentally friendly water purification techniques - Includes case studies to show how nanotechnology has successfully been integrated into water purification system design
