Download or read book Progress in Organosilicon Chemistry written by Bogdan Marciniec and published by Taylor & Francis. This book was released on 1995 with total page 620 pages. Available in PDF, EPUB and Kindle. Book excerpt: Progress in Organosilicon Chemistry comprises more than thirty papers presented by many of the world's most eminent organosilicon specialists at the Tenth International Symposium on Organosilicon Chemistry held in Poznan, Poland in August 1993. The conference marked the fiftieth anniversary of the discovery and exploration of "direct synthesis." As much attention today is directed beyond silicon polymers, chemists have become involved with the use of elementary silicon and its applications, including ultrapure silicon in transistors and computers, silicon precursors of polymers, and other silicon-based materials as well as fine chemicals. This book provides an overview of organosilicon chemistry, including organic and inorganic chemistry of silicon, silicon polymers and oligomers; theoretical and structural chemistry of silicon; silicon-based materials and their applications; silicon in organic synthesis; mechanistic organosilicon chemistry; and bio- and environmental organosilicon chemistry. This diverse range of topics makes the book a valuable reference for chemists working in both applied and theoretical chemistry.
Download or read book Coordination Chemistry of Silicon written by Prof. Dr. Shigeyoshi Inoue and published by MDPI. This book was released on 2019-03-04 with total page 228 pages. Available in PDF, EPUB and Kindle. Book excerpt: The chemistry of silicon has always been a field of major concern due to its proximity to carbon on the periodic table. From the molecular chemist’s viewpoint, one of the most interesting differences between carbon and silicon is their divergent coordination behavior. In fact, silicon is prone to form hyper-coordinate organosilicon complexes, and, as conveyed by reports in the literature, highly sophisticated ligand systems are required to furnish low-coordinate organosilicon complexes. Tremendous progress in experimental, as well as computational, techniques has granted synthetic access to a broad range of coordination numbers for silicon, and the scientific endeavor, which was ongoing for decades, was rewarded with landmark discoveries in the field of organosilicon chemistry. Molecular congeners of silicon(0), as well as silicon oxides, were unveiled, and the prominent group 14 metalloid proved its applicability in homogenous catalysis as a supportive ligand or even as a center of catalytic activity. This book focuses on the most recent advances in the coordination chemistry of silicon with transition metals as well as main group elements, including the stabilization of low-valent silicon species through the coordination of electron donor ligands. Therefore, this book is associated with the development of novel synthetic methodologies, structural elucidations, bonding analysis, and also possible applications in catalysis or chemical transformations using related organosilicon compounds.
Download or read book Organosilicon Compounds written by Vladimir Ya Lee and published by Academic Press. This book was released on 2017-08-22 with total page 758 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organosilicon Compounds: Theory and Experiment (Synthesis), volume 1, comprises two parts. The first part, Theory, covers state-of-the-art computational treatments of unusual nonstandard organosilicon compounds that classical bonding theory fails to describe adequately. The second part, Experiment (Synthesis), describes recent synthetic advances in the preparation of a variety of organosilicon compounds with different coordination numbers of the central silicon: from tetracoordinate to low-coordinate to hypercoordinate derivatives. Organosilicon Compounds: From Theory to Synthesis to Applications provides a comprehensive overview of this important area of organic and organometallic chemistry, dealing with compounds containing carbon–silicon bonds. This field, which includes compounds that are widely encountered in commercial products such as in the fabrication of sealants, adhesives, and coatings, has seen many milestone discoveries reported during the last two decades. Beginning with the theoretical aspects of organosilicon compounds' structure and bonding, the book then explores their synthetic aspects, including main group element organosilicon compounds, transition metal complexes, silicon cages and clusters, low-coordinate organosilicon derivatives (cations, radicals, anions, multiple bonds to silicon, silaaromatics), and more. Next, readers will find valuable sections that explore physical and chemical properties of organosilicon compounds by means of X-ray crystallography, 29Si NMR spectroscopy, photoelectron spectroscopy, and other methods. Finally, the work delves into applications for industrial uses and in many related fields, such as polymers, material science, nanotechnology, bioorganics, and medicinal silicon chemistry. - Features valuable contributions from prominent experts that cover both fundamental (theoretical, synthetic, physico-chemical) and applied (material science, applications) aspects of modern organosilicon chemistry - Covers important breakthroughs in the field, along with the historically significant achievements of the past - Includes applied information for a wide range of specialists, from junior and senior researchers (from both academia and industry) - Ideal reference for those working in organometallic, organosilicon, main group element, transition metal, and industrial silicon chemistry, as well as those from interdisciplinary fields, such as polymer, material science, and nanotechnology
Download or read book Advances in Organometallic Chemistry written by and published by Elsevier. This book was released on 2004-02-10 with total page 471 pages. Available in PDF, EPUB and Kindle. Book excerpt: Almost all branches of chemistry and material science now interface with organometallic chemistry - the study of compounds containing carbon-metal bonds. The widely acclaimed serial Advances in Organometallic Chemistry contains authoritative reviews that address all aspects of organometallic chemistry, a field which has expanded enormously since the publication of Volume 1 in 1964. - Provides an authoritative, definitive review addressing all aspects of organometallic chemistry - Useful to all researchers within this active field and is a must for every modern library of chemistry - High quality research book within this rapidly developing field
Download or read book Efficient Methods for Preparing Silicon Compounds written by Herbert W Roesky and published by Academic Press. This book was released on 2016-05-12 with total page 540 pages. Available in PDF, EPUB and Kindle. Book excerpt: Efficient Methods for Preparing Silicon Compounds is a unique and valuable handbook for chemists and students involved in advanced studies of preparative chemistry in academia and industry. Organized by the various coordination numbers (from two to six) of the central silicon atom of the reported compounds, this book provides researchers with a handy and immediate reference for any compound or properties needed in the area. Edited by a renowned expert in the field, each chapter explores a different type of compound, thoroughly illustrated with useful schemes and supplemented by additional references. Knowledgeable contributors report on a broad range of compounds on which they have published and which are already used on a broad scale or have the potential to be used in the very near future to develop a new field of research or application in silicon chemistry. - Includes contributions and edits from leading experts in the field - Includes detailed chemical schemes and useful references for each preparative method - Organized by the coordination numbers of the central silicon atom for each compound for easy navigation - Serves as a go-to primer for researchers in novel compositions of silicon matter
Download or read book Silicon and Silicones written by Eugene G. Rochow and published by Springer. This book was released on 1987-05-27 with total page 180 pages. Available in PDF, EPUB and Kindle. Book excerpt: An Overview for the General Reader The fact that silicone rubber boots made those footprints on the moon, and that other silicone polymers made possible the construc tion and functioning of space suits and space vehicles, has led to the general belief that silicones are very modem materials conjured up to meet the needs of space travel. Actually, though, silicone chemis try has deep roots in human history, dating from the dawn of the race and extending through all of geology, mineralogy, and the ancient ceramic arts. This little book seeks to put the development of silicone materials in perspective as part of the fascinating involvement of the element silicon in our daily lives, from the stuff the earth and the moon are made of to the modem use of ultra pure silicon in transistors and computers, and the use of ordi nary elementary silicon to make silicone rubber, silicone oil, sili cone resins, and silicon or silicone-containing polishes, drugs, and fragrances. Of course these are not our only connections with silicon. The natural compounds of silicon and oxygen (the silicates) are the starting materials for making bricks, tile, cement, glass, and a host of modem ceramic products. The widespread usefulness of silicon and its compounds comes about for two reasons: first, there is so much of it, and second, it is so versatile.
Download or read book Organosilicon Chemistry III written by Norbert Auner and published by John Wiley & Sons. This book was released on 2008-08-29 with total page 742 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organosilicon Chemistry at its best ...((kursiv)) Like its two hugely successful predecessors, the third volume again presents the latest developments in a rapidly developing field of industsrial and academic research. The contributions from approx. 80 internationally renowned experts and researchers in this fascinating part of the rapidly growing field of main group chemistry describe current trends in organosilicon chemistry and provide summaries of the latest (1997!) knowledge in this area. To facilitate access to the ongoing research this volume is split into two parts, each with a comprehensive introduction: Part 1: Fascinating Organosilicon Compounds Part 2: Silicon Based Materials
Download or read book Organosilicon Chemistry written by Tamejiro Hiyama and published by John Wiley & Sons. This book was released on 2020-02-18 with total page 566 pages. Available in PDF, EPUB and Kindle. Book excerpt: Provides a unique summary of important catalytic reactions in the presence of silicon A must-have for all synthetic chemists, this book summarizes all of the important developments in the application of organosilicon compounds in organic synthesis and catalysis. Edited by two world leaders in the field, it describes different approaches and covers a broad range of reactions, e.g. catalytic generation of silicon nucleophiles, Si-H Bond activation, C-H bond silylation, silicon-based cross-coupling reactions, and hydrosilylation in the presence of earth-abundant metals. In addition to the topics covered above, Organosilicon Chemistry: Novel Approaches and Reactions features chapters that look at Lewis base activation of silicon Lewis acids, silylenes as ligands in catalysis, and chiral silicon molecules. -The first book about this topic in decades, covering a broad range of reactions -Covers new approaches and novel catalyst systems that have been developed in recent years -Written by well-known, international experts in the areas of organometallic silicon chemistry and organosilicon cross-coupling reactions Organosilicon Chemistry: Novel Approaches and Reactions is an indispensable source of information for synthetic chemists in academia and industry, working in the field of organic synthesis, catalysis, and main-group chemistry.
Download or read book Organosilicon Compounds Two volume set written by Vladimir Ya Lee and published by Academic Press. This book was released on 2017-10-01 with total page 1436 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organosilicon Compounds provides readers with the state-of-the-art status of organosilicon chemistry, including its theoretical, synthetic, physico-chemical and applied aspects. By including high quality content in a key strategic signing area, this work is a strong addition to chemistry offerings in organic, main group and organometallic research. Organosilicon chemistry deals with compounds containing carbon–silicon bonds, an essential part of organic and organometallic chemistry. This book presents the many milestone in the field that have been discovered during the last few years, also detailing its usage in commercial products, such as sealants, adhesives and coatings. - Features valuable contributions from prominent experts who cover both fundamental (theoretical, synthetic, physico-chemical) and applied (material science, applications) aspects - Covers important breakthroughs in the field, along with historically significant achievements - Includes applied information for a wide range of specialists, from junior and senior researchers (from both academia and industry) working in organometallic, organosilicon, main group element, transition metal, industrial silicon chemistry, and more
Download or read book Hydrosilylation written by Bogdan Marciniec and published by Springer Science & Business Media. This book was released on 2008-11-09 with total page 424 pages. Available in PDF, EPUB and Kindle. Book excerpt: For fifty years, Hydrosilylation has been one of the most fundamental and elegant methods for the laboratory and industrial synthesis of organosilicon and silicon related compounds. Despite the intensive research and continued interest generated by organosilicon compounds, no comprehensive book incorporating its various aspects has been published this century. The aim of this book is to comprehensively review the advances of hydrosilylation processes since 1990. The survey of the literature published over the last two decades enables the authors to discuss the most recent aspects of hydrosilylation advances (catalytic and synthetic) and to elucidate the reaction mechanism for the given catalyst used and the reaction utilization. New catalytic pathways under optimum conditions necessary for efficient synthesis of organosilicon compounds are presented. This monograph shows the extensive development in the application of hydrosilylation in organic and asymmetric syntheses and in polymer and material science.
Download or read book Advances in Organometallic Chemistry written by Anthony F. Hill and published by Academic Press. This book was released on 2013-09-11 with total page 484 pages. Available in PDF, EPUB and Kindle. Book excerpt: Almost all branches of chemistry and material science now interface with organometallic chemistry--the study of compounds containing carbon-metal bonds. This widely acclaimed serial contains authoritative reviews that address all aspects of organometallic chemistry, a field that has expanded enormously since the publication of Volume 1 in 1964. - Informs and updates on all the latest developments in the field - Contributions from leading authorities and industry experts
Download or read book Membrane Materials for Gas and Separation written by Yuri Yampolskii and published by John Wiley & Sons. This book was released on 2017-01-10 with total page 440 pages. Available in PDF, EPUB and Kindle. Book excerpt: Si containing polymers have been instrumental in the development of membrane gas separation practices since the early 1970s. Their function is to provide a selective barrier for different molecular species, where selection takes place either on the basis of size or on the basis of physical interactions or both. Combines membrane science, organosilicon chemistry, polymer science, materials science, and physical chemistry Only book to consider polymerization chemistry and synthesis of Si-containing polymers (both glassy and rubbery), and their role as membrane materials Membrane operations present environmental benefits such as reduced waste, and recovered/recycled valuable raw materials that are currently lost to fuel or to flares
Download or read book Gas Phase Reactions in Organic Synthesis written by Yannick Vallee and published by CRC Press. This book was released on 1998-01-29 with total page 322 pages. Available in PDF, EPUB and Kindle. Book excerpt: Flash Vacuum Thermolysis (FVT) techniques have become well-established methods and occupy an increasingly important place in synthesis. Gas Phase Reactions in Organic Synthesis is a complete review of the applications of flash vacuum thermolysis in organic chemistry; it features new developments in FVT, flow thermolysis and vacuum gas-solid reactions which have appeared in scientific literature since 1980.
Download or read book Nuclear Magnetic Resonance written by G A Webb and published by Royal Society of Chemistry. This book was released on 2007-10-31 with total page 568 pages. Available in PDF, EPUB and Kindle. Book excerpt: As a spectroscopic method, Nuclear Magnetic Resonance (NMR) has seen spectacular growth over the past two decades, both as a technique and in its applications. Today the applications of NMR span a wide range of scientific disciplines, from physics to biology to medicine. Each volume of Nuclear Magnetic Resonance comprises a combination of annual and biennial reports which together provide comprehensive of the literature on this topic. This Specialist Periodical Report reflects the growing volume of published work involving NMR techniques and applications, in particular NMR of natural macromolecules which is covered in two reports: "NMR of Proteins and Acids" and "NMR of Carbohydrates, Lipids and Membranes". For those wanting to become rapidly acquainted with specific areas of NMR, this title provides unrivalled scope of coverage. Seasoned practitioners of NMR will find this an in valuable source of current methods and applications. Specialist Periodical Reports provide systematic and detailed review coverage in major areas of chemical research. Compiled by teams of leading authorities in the relevant subject areas, the series creates a unique service for the active research chemist, with regular, in-depth accounts of progress in particular fields of chemistry. Subject coverage within different volumes of a given title is similar and publication is on an annual or biennial basis.
Download or read book The Chemistry of Organic Silicon Compounds Volume 2 Parts 1 2 and 3 3 Part Set written by Zvi Rappoport and published by John Wiley & Sons. This book was released on 1998-09-16 with total page 968 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organosilicon compounds are key organometallic compounds (R-Si)which have many uses in materials science and in metallurgy. Theirapplications include the synthesis of sugars and in the synthesisof organic compounds for the pharmaceutical industry. This volumewill contain both updated chapters on key topics included in theoriginal volumes as well as a number of new chapters reflecting therapid developments made in silicon chemistry and its applicationsto organometallic chemistry, materials science, and semiconductors,over the last five years. As for the majority of volumes in thisseries, chapters will be prepared by leading scientists in thefield. This volume is now available in electronic format from BooksOnline.
Download or read book Inorganic Reactions and Methods The Formation of Bonds to Transition and Inner Transition Metals written by A. P. Hagen and published by John Wiley & Sons. This book was released on 2009-09-17 with total page 727 pages. Available in PDF, EPUB and Kindle. Book excerpt: Boasting numerous industrial applications, inorganic chemistry forms the basis for research into new materials and bioinorganic compounds such as calcium that act as biological catalysts. Now complete, this highly acclaimed series presents current knowledge in all areas of inorganic chemistry, including chemistry of the elements; organometallic, polymeric and solid-state materials; and compounds relevant to bioinorganic chemistry.
Download or read book Organosilicon Chemistry written by Sam Stuart and published by Elsevier. This book was released on 2013-09-11 with total page 350 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organosilicon Chemistry provides information pertinent to the fundamental aspects and application of organosilicon chemistry. This book discusses the exact manner and extent of d-orbital involvement in organosilicon compounds in ground, electronic, and transition excited states. Organized into two parts encompassing 21 chapters, this book begins with an overview of preparing stable organosiliconium ions. This text then discusses the use of fused salts as reaction media in the preparative chemistry. Other chapters consider a detailed investigation on the molecular association and volatility of alkoxides of group (IV) elements. This book discusses as well the reaction between dimethyldichlorosilane and ethylene glycon, which has been shown to produce a dimeric ten-membered ring compound. The final chapter deals with the results of the investigations concerning the properties of the contact mass and of the non-volatile silicon-free products, which are produced in the direct synthesis of phenylhalogenosilanes. This book is a valuable resource for chemists and research workers.
