Download or read book Process Design and Economics for Biochemical Conversion of Lignocellulosic Biomass to Ethanol written by and published by . This book was released on 2011 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Process Design and Economics for Biochemical Conversion of Lignocellulosic Biomass to Ethanol written by and published by . This book was released on 2011 with total page 136 pages. Available in PDF, EPUB and Kindle. Book excerpt: This report describes one potential biochemical ethanol conversion process, conceptually based upon core conversion and process integration research at NREL. The overarching process design converts corn stover to ethanol by dilute-acid pretreatment, enzymatic saccharification, and co-fermentation. Building on design reports published in 2002 and 1999, NREL, together with the subcontractor Harris Group Inc., performed a complete review of the process design and economic model for the biomass-to-ethanol process. This update reflects NREL's current vision of the biochemical ethanol process and includes the latest research in the conversion areas (pretreatment, conditioning, saccharification, and fermentation), optimizations in product recovery, and our latest understanding of the ethanol plant's back end (wastewater and utilities). The conceptual design presented here reports ethanol production economics as determined by 2012 conversion targets and "nth-plant" project costs and financing. For the biorefinery described here, processing 2,205 dry ton/day at 76% theoretical ethanol yield (79 gal/dry ton), the ethanol selling price is $2.15/gal in 2007 dollars.
Download or read book Process Design and Economics for the Conversion of Lignocellulosic Biomass to Hydrocarbon Fuels and Coproducts 2018 Biochemical Design Case Update Biochemical Deconstruction and Conversion of Biomass to Fuels and Products via Integrated Biorefinery Pathways written by and published by . This book was released on 2018 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Over the past decade, NREL conducted a campaign to quantify the economic implications associated with observed and future targeted performance for the biochemical conversion of corn stover to ethanol through techno-economic modeling. This report serves as an update to the biological sugar conversion approach, reflecting modifications to underlying conversion operational strategies, as well as refinements to the techno-economic model details. In addition, the report includes a more quantitative focus on envisioned processing requirements for achieving final fuel cost goals moving further into the future, via inclusion of value-added coproducts.
Download or read book Process Design and Economics for Conversion of Lignocellulosic Biomass to Ethanol written by and published by . This book was released on 2011 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Process Design and Economics for Conversion of Lignocellulosic Biomass to Ethanol written by and published by . This book was released on 2011 with total page 187 pages. Available in PDF, EPUB and Kindle. Book excerpt: This design report describes an up-to-date benchmark thermochemical conversion process that incorporates the latest research from NREL and other sources. Building on a design report published in 2007, NREL and its subcontractor Harris Group Inc. performed a complete review of the process design and economic model for a biomass-to-ethanol process via indirect gasification. The conceptual design presented herein considers the economics of ethanol production, assuming the achievement of internal research targets for 2012 and nth-plant costs and financing.
Download or read book Biochemical Conversion of Lignocellulosic Biomass to Ethanol written by Deepak Kumar and published by . This book was released on 2014 with total page 207 pages. Available in PDF, EPUB and Kindle. Book excerpt: Ethanol production from lignocellulosic feedstock has been under intense scrutiny as a transportation fuel due to its potential to address concerns of increasing energy consumption, limited fossil energy resources, climate changes due to greenhouse gas emissions from fossil fuels, and especially use of non-food biomaterials, which address the biggest limitation of first generation bioethanol. Despite these advantages, the lignocellulosic ethanol production on commercial scale is still on verge because of high processing costs of ethanol production. In the biochemical conversion process, biomass is converted to ethanol by sequential steps of pretreatment (to reduce the recalcitrance of biomass), hydrolysis (conversion of sugar polymers to monomers) and fermentation (sugars to ethanol). Every year, about a million ton of grass straw is available as agricultural residue in Pacific Northwest. There were no previous comprehensive studies to evaluate the technical feasibility, economic viability and environmental sustainability of the bioethanol produced using grass straw in Willamette valley. The focus of this dissertation was to investigate the potential of cellulosic ethanol production from grass straw, assess the techno-economic viability and environmental impacts of the bioethanol production and development of a stochastic molecular model for modeling cellulose hydrolysis. This dissertation was divided into four studies focused on individual aspects of the overall objective. The first study evaluated the ethanol production potential from straws produced from three major grass seed varieties (perennial ryegrass (Lolium perenne L.), tall fescue (Festuca arundinacea Schreb) and bentgrass (Agrostis sp.)) in Pacific Northwest. Feedstocks were pretreated using three chemical pretreatments (dilute acid, dilute alkali, and hot water) and subsequently hydrolyzed enzymatically to investigate the effect of pretreatment and estimate the potential ethanol yields. Carbohydrate content in biomass varied from 40.6 to 52.9%, with tall fescue having the maximum cellulose content of 32.4%. All pretreatment were effective in increasing the hydrolysis yields, and theoretical maximum ethanol yields were in the range of 276 to 360 L per ton of biomass. The second study performed the comprehensive techno-economic analysis of ethanol production from tall fescue using dilute acid, dilute alkali, hot water, and steam explosion pretreatment technologies. Detailed process models incorporating all unit operations in lignocellulosic ethanol plant with 250,000 metric ton biomass/ year processing capacity were developed in SuperPro Designer. The ethanol production cost were estimated from $0.81 to $0.88/ L of ethanol, and were found highly sensitive to biomass price, enzyme cost, and pentose sugar fermentation efficiency. Energy from lignin residue burning was found sufficient to meet the steam requirement in the production process. Third study performed the life cycle assessment for bioethanol production from grass straw considering various pretreatment technology options. The study revealed that ethanol production from grass straw provide environmental benefits compared to use of gasoline, with 57.43-112.67% reduction in fossil energy use to produce 10,000 MJ of fuel. The GHG emissions during life cycle of ethanol production were estimated in the range of -131 to -555.4 kg CO2 eq. per 10,000 MJ of fuel. It was observed that assumptions and allocation procedure used during the analysis had a significant effect on the LCA results. During the techno-economic assessment of bioethanol process, it was found that cost of cellulose enzymes was significant fraction of the total ethanol production cost. A comprehensive enzymatic hydrolysis model can play critical role in optimizing the enzyme composition and dosage, improving understanding of the process mechanism and reducing the cost of enzymes, a major bottleneck in the ethanol production process. A novel approach of stochastic molecular modeling, in which each hydrolysis event is translated into a discrete event, was used to develop a mechanistic model for cellulose hydrolysis in the fourth study. Cellulose structure was modeled as a group of microfibrils consisting of elementary fibrils bundles, where each elementary fibril was represented as a three dimensional matrix of glucose molecules. Major structural properties: crystallinity, degree of polymerization, surface accessibility, and enzyme characteristics: mode of action, binding and surface blockage, inhibition, along with the dynamic morphological changes in structure of cellulose were incorporated in the model. Hydrolysis of cellulose was simulated based on Monte Carlo simulation technique. Hydrolysis results predicted by model simulations had shown a good fit with the experimental data from hydrolysis of pure cellulose using purified enzymes for various hydrolysis conditions. The model was effective in capturing the dynamic behavior of cellulose hydrolysis during action of individual as well as multiple cellulases. Model was able to simulate and validate all the important expected experimental observations: effect of structural properties, enzyme inhibition and enzyme loadings on the hydrolysis and degree of synergism on different substrates. The work from this dissertation proved the significance of choosing technology options, drew a comparison among different pretreatment technologies, identified the critical processes and inputs that have significant effect on the ethanol production cost, net energy, and GHG emissions. Results from the last study confirmed the validity of using the stochastic molecular modeling approach to quantitatively and qualitatively describe the cellulose hydrolysis, which has wide potential application in bioethanol production research to reduce the enzyme cost.
Download or read book Process Design and Economics for Conversion of Lignocellulosic Biomass to Ethanol written by National Renewable Energy Laboratory (Nr and published by Scholar's Choice. This book was released on 2015-02-15 with total page 190 pages. Available in PDF, EPUB and Kindle. Book excerpt: This work has been selected by scholars as being culturally important, and is part of the knowledge base of civilization as we know it. This work was reproduced from the original artifact, and remains as true to the original work as possible. Therefore, you will see the original copyright references, library stamps (as most of these works have been housed in our most important libraries around the world), and other notations in the work. This work is in the public domain in the United States of America, and possibly other nations. Within the United States, you may freely copy and distribute this work, as no entity (individual or corporate) has a copyright on the body of the work.As a reproduction of a historical artifact, this work may contain missing or blurred pages, poor pictures, errant marks, etc. Scholars believe, and we concur, that this work is important enough to be preserved, reproduced, and made generally available to the public. We appreciate your support of the preservation process, and thank you for being an important part of keeping this knowledge alive and relevant.
Download or read book Lignocellulose Conversion written by Vincenza Faraco and published by Springer Science & Business Media. This book was released on 2013-06-12 with total page 207 pages. Available in PDF, EPUB and Kindle. Book excerpt: Bioethanol has been recognized as a potential alternative to petroleum-derived transportation fuels. Even if cellulosic biomass is less expensive than corn and sugarcane, the higher costs for its conversion make the near-term price of cellulosic ethanol higher than that of corn ethanol and even more than that of sugarcane ethanol. Conventional process for bioethanol production from lignocellulose includes a chemical/physical pre-treatment of lignocellulose for lignin removal, mostly based on auto hydrolysis and acid hydrolysis, followed by saccharification of the free accessible cellulose portions of the biomass. The highest yields of fermentable sugars from cellulose portion are achieved by means of enzymatic hydrolysis, currently carried out using a mix of cellulases from the fungus Trichoderma reesei. Reduction of (hemi)cellulases production costs is strongly required to increase competitiveness of second generation bioethanol production. The final step is the fermentation of sugars obtained from saccharification, typically performed by the yeast Saccharomyces cerevisiae. The current process is optimized for 6-carbon sugars fermentation, since most of yeasts cannot ferment 5-carbon sugars. Thus, research is aimed at exploring new engineered yeasts abilities to co-ferment 5- and 6-carbon sugars. Among the main routes to advance cellulosic ethanol, consolidate bio-processing, namely direct conversion of biomass into ethanol by a genetically modified microbes, holds tremendous potential to reduce ethanol production costs. Finally, the use of all the components of lignocellulose to produce a large spectra of biobased products is another challenge for further improving competitiveness of second generation bioethanol production, developing a biorefinery.
Download or read book Lignocellulosic Biomass to Ethanol Process Design and Economics Utilizing Co Current Dilute Acid Prehydrolysis and Enzymatic Hydrolysis for Corn Stover Scholar s Choice Edition written by National Renewable Energy Laboratory (Nr and published by Scholar's Choice. This book was released on 2015-02-15 with total page 158 pages. Available in PDF, EPUB and Kindle. Book excerpt: This work has been selected by scholars as being culturally important, and is part of the knowledge base of civilization as we know it. This work was reproduced from the original artifact, and remains as true to the original work as possible. Therefore, you will see the original copyright references, library stamps (as most of these works have been housed in our most important libraries around the world), and other notations in the work. This work is in the public domain in the United States of America, and possibly other nations. Within the United States, you may freely copy and distribute this work, as no entity (individual or corporate) has a copyright on the body of the work.As a reproduction of a historical artifact, this work may contain missing or blurred pages, poor pictures, errant marks, etc. Scholars believe, and we concur, that this work is important enough to be preserved, reproduced, and made generally available to the public. We appreciate your support of the preservation process, and thank you for being an important part of keeping this knowledge alive and relevant.
Download or read book Cellulosic Ethanol from Corn Stover Cost Analysis Ethanol E11A written by Intratec and published by Intratec Solutions. This book was released on 2016-05-01 with total page 52 pages. Available in PDF, EPUB and Kindle. Book excerpt: This report presents a cost analysis of second generation Ethanol production from corn stover via a biochemical conversion process. The process examined is similar to the process reported by the National Renewable Energy Laboratory (NREL). This process involves the following steps in the production of hydrous Ethanol: corn stover pretreatment with dilute acid and ammonia conditioning; enzymatic hydrolysis; and fermentation. Electricity is also generated as by-product. This report examines one-time costs associated with the construction of a United States-based plant and the continuing costs associated with the daily operation of such a plant. More specifically, it discusses: * Capital Investment, broken down by: - Total fixed capital required, divided in production unit (ISBL); infrastructure (OSBL) and contingency - Alternative perspective on the total fixed capital, divided in direct costs, indirect costs and contingency - Working capital and costs incurred during industrial plant commissioning and start-up * Production cost, broken down by: - Manufacturing variable costs (raw materials, utilities) - Manufacturing fixed costs (maintenance costs, operating charges, plant overhead, local taxes and insurance) - Depreciation and corporate overhead costs * Raw materials consumption, products generation and labor requirements * Process block flow diagram and description of industrial site installations (production unit and infrastructure) This report was developed based essentially on the following reference(s): Humbird, D., et al., "Process Design and Economics for Biochemical Conversion of Lignocellulosic Biomass to Ethanol, " Report NREL/TP-5100-47764, National Renewable Energy Laboratory (NREL), 2011 Keywords: Ethyl Alcohol, Bioethanol, Lignocellulosic Biomass, 2nd Generation, Cellulosic Sugar, Hemicelluloses, Cellulose
Download or read book Lignocellulosic Biomass to Ethanol Process Design and Economics Utilizing Co current Dilute Acid Prehydrolysis and Enzymatic Hydrolysis for Corn Stover written by and published by . This book was released on 2002 with total page 154 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Lignocellulosic Biomass to Ethanol Process Design and Economics Utilizing Co current Dilute Acid Prehydrolysis and Enzymatic Hydrolysis Current and Future Scenarios written by and published by . This book was released on 1999 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: The National Renewable Energy Laboratory (NREL) has undertaken a complete review and update of the process design and economic model for the biomass-to-ethanol enzymatic based process. The process design includes the core technologies being researched by the U.S. Department of Energy (DOE): prehydrolysis, simultaneous saccharification and co-fermentation, and cellulase enzyme production. Inaddition, all ancillary areas--feed handling, product recovery and purification, wastewater treatment lignin burner and boiler-turbogenerator, and utilities--are included. NREL engaged Delta-T Corporation to assist in the process design evaluation, equipment costing and overal plant integration. The process design and costing for the lignin burner and boiler turbogenerator has been reviewed byReaction Engineering, Inc. and the wastewater treatment by Merrick & Company. An overview of both reviews is included here. The purpose of this update was to ensure that the process design and equipment costs were reasonable and consistent with good engineering practice for plants of this type using available technical data. This work has resulted in an economic model that can be used to predictthe cost of producing ethanol from cellulosic biomass using this technology if a plant were to be built in the next few years. The model was also extended using technology improvements that are expected to be developed based on the current DOE research plan. Future process designs and cost estimates are given for the year 2005, 2010, 2015.
Download or read book Lignocellulosic Biomass to Ethanol Process Design and Economics Utilizing Co Current Dilute Acid Prehydrolysis and Enzymatic Hydrolysis Current and Futuristic Scenarios written by and published by . This book was released on 1999 with total page 5 pages. Available in PDF, EPUB and Kindle. Book excerpt: The National Renewable Energy Laboratory (NREL) has undertaken a complete review and update of the process design and economic model for the biomass-to-ethanol enzymatic based process. The process design includes the core technologies being researched by the U.S. Department of Energy (DOE): prehydrolysis, simultaneous saccharification and co-fermentation, and cellulase enzyme production. In addition, all ancillary areas--feed handling, product recovery and purification, wastewater treatment lignin burner and boiler--turbogenerator, and utilities--are included. NREL engaged Delta-T Corporation to assist in the process design evaluation, equipment costing, and overall plant integration. The process design and costing for the lignin burner and boiler turbogenerator has been reviewed by Reaction Engineering Inc. and the wastewater treatment by Merrick and Company. An overview of both reviews is included here. The purpose of this update was to ensure that the process design and equipment costs were reasonable and consistent with good engineering practice for plants of this type using available technical data. This work has resulted in an economic model that can be used to predict the cost of producing ethanol from cellulosic biomass using this technology if a plant were to be built in the next few years. The model was also extended using technology improvements that are expected to be developed based on the current DOE research plan. Future process designs and cost estimates are given for the years 2005, 2010, and 2015.
Download or read book Bioalcohol Production written by K. Waldron and published by CRC Press. This book was released on 2010-07-07 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Bioethanol is one of the main biofuels capable of substituting petroleum usage in vehicles, and has had one of the largest impacts to date. The first generation of bioethanol production has had a worldwide impact, though it is restricted by energy intensive grain-to-bioethanol production technology, and land usage pressures (food vs. fuel). The development of second generation production technology, producing a wider range of bioalcohols from lignocellulosic biomass, removes many of the obstacles and expenses that first generation production faces. This book provides a comprehensive and timely reference on the biochemical conversion of lignocellulosic biomass for the production of fuel alcohols, expertly reviewing the development of the entire second-generation bioalcohol production chain. The book covers the process engineering, technology, modeling, and integration of the entire production chain, from feedstock pretreatment on to hydrolysis, to fermentation, and on to purification. The book primarily covers the production of bioethanol, but extends into coverage of the production of longer-chain bioalcohols that will be elemental to future biofuel utilization.
Download or read book Proceedings of the 8th International Conference on Foundations of Computer Aided Process Design written by and published by Elsevier. This book was released on 2014-07-14 with total page 835 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume collects together the presentations at the Eighth International Conference on Foundations of Computer-Aided Process Design, FOCAPD-2014, an event that brings together researchers, educators, and practitioners to identify new challenges and opportunities for process and product design. The chemical industry is currently entering a new phase of rapid evolution. The availability of low-cost feedstocks from natural gas is causing renewed investment in basic chemicals in the OECD, while societal pressures for sustainability and energy security continue to be key drivers in technology development and product selection. This dynamic environment creates opportunities to launch new products and processes and to demonstrate new methodologies for innovation, synthesis and design. FOCAPD-2014 fosters constructive interaction among thought leaders from academia, industry, and government and provides a showcase for the latest research in product and process design. - Focuses exclusively on the fundamentals and applications of computer-aided design for the process industries. - Provides a fully archival and indexed record of the FOCAPD14 conference - Aligns the FOCAPD series with the ESCAPE and PSE series
Download or read book Process Design and Economics for the Conversion of Lignocellulosic Biomass to Hydrocarbons written by Ryan Davis and published by . This book was released on 2013 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Process Design and Economics for the Conversion of Lignocellulosic Biomass to Hydrocarbons Dilute Acid and Enzymatic Deconstruction of Biomass to Sugars and Catalytic Conversion of Sugars to Hydrocarbons written by and published by . This book was released on 2015 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: This report describes one potential conversion process to hydrocarbon products by way of catalytic conversion of lignocellulosic-derived hydrolysate. This model leverages expertise established over time in biomass deconstruction and process integration research at NREL, while adding in new technology areas for sugar purification and catalysis. The overarching process design converts biomass to diesel- and naphtha-range fuels using dilute-acid pretreatment, enzymatic saccharification, purifications, and catalytic conversion focused on deoxygenating and oligomerizing biomass hydrolysates.
