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Book Preparation of Uranium Pentafluoride

Download or read book Preparation of Uranium Pentafluoride written by Homer F. Priest and published by . This book was released on 1946 with total page 8 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Development of the Excer Process III

Download or read book Development of the Excer Process III written by W. J. Neill and published by . This book was released on 1958 with total page 20 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Process and Preparation Facility for Uranium Tetrafluoride

Download or read book Process and Preparation Facility for Uranium Tetrafluoride written by and published by . This book was released on 1989 with total page 16 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Fluid Bed Conversion of Uranium Tetrafluoride to Uranium Hexafluoride

Download or read book Fluid Bed Conversion of Uranium Tetrafluoride to Uranium Hexafluoride written by G. J. Vogel and published by . This book was released on 1959 with total page 32 pages. Available in PDF, EPUB and Kindle. Book excerpt: Experiments conducted in a 2 1/2-inch diameter reactor have demonstrated that the continuous fluorination of uranium tetrafluoride to hexafluoride with elemental fluorine in a fluidized bed is possible. Practicable fluorine efficiencies and conversion rates were attained with good temperature control in experiments with refined uranium tetrafluoride. Runs made with crude uranium tetrafluoride, derived from the reduction and hydro-fluorination of ore concentrates produced by the acid-leach process, indicated that these also can be processed at satisfactory rates and efficiencies. Uranium tetrafluoride derived from carbonate-leached ore concentrate gave a lower production rate and was more difficult to process because of sintering tendencies.

Book Precipitation of Uranium Ammonium Fluoride from UNH Solutions as an Intermediate in the Preparation of Uranium Tetrafluoride

Download or read book Precipitation of Uranium Ammonium Fluoride from UNH Solutions as an Intermediate in the Preparation of Uranium Tetrafluoride written by W. B. Tolley and published by . This book was released on 1955 with total page 12 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book The Preparation of Uranium Hexafluoride

Download or read book The Preparation of Uranium Hexafluoride written by Francis A. Regan and published by . This book was released on 1941 with total page 50 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Uranium Production Technology

Download or read book Uranium Production Technology written by Charles D. Harrington and published by . This book was released on 1959 with total page 600 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Dry Process Fluorination of Uranium Dioxide Using Ammonium Bifluoride

Download or read book Dry Process Fluorination of Uranium Dioxide Using Ammonium Bifluoride written by Charles Burnett Yeamans and published by . This book was released on 2003 with total page 86 pages. Available in PDF, EPUB and Kindle. Book excerpt: An experimental study was conducted to determine the practicality of various unit operations for fluorination of uranium dioxide. The objective was to prepare ammonium uranium fluoride double salts from uranium dioxide and ammonium bifluoride, then decompose these salts to uranium tetrafluoride through heating to temperatures near 425 °C in either a fluidized bed or a stirred bed. Fluorination in the stirred bed was attempted without pretreatment of the reagents. For the fluidized bed experiments, reagents were ball-milled prior to being heated in the bed. Experiments were conducted in either argon or 4% hydrogen in argon. The ball mill appeared to be an effective technique for fluorinating uranium dioxide with ammonium bifluoride. Samples changed color from brown to bright green, and no oxides could be detected in the x-ray diffraction pattern of the product. It was found that stainless steel is a suitable material of construction for reaction vessels, whereas mild steel parts corroded quickly. Only a small degree of fluidization provided adequate mixing in fluidized beds, but a paddle mixing the stirred beds left an unmixed region around the bed perimeter. Results from the stirred beds showed the initial fluorination reaction completed only when the reagents were heated to 110 °C for at least three hours under argon. Decomposition took place under argon with a temperature ramp up to 425 °C. The product UF4 contained less than 1% oxide as an impurity, and the decomposition appeared to be complete. Fluidized beds were run with both argon and 4% hydrogen in argon as carrier gases. Experiments with 4% hydrogen in argon produced uranium tetrafluoride, with ammonium uranium pentafluoride and uranium dioxide as impurties. Experiments in argon produced uranium tetrafluoride, with uranyl difluoride, ammonium diuranyl pentafluoride and triuranium octoxide as impurities. Minimum temperatures and times needed to decompose the double salt in the fluidized beds were 200 minutes at 115 °C, a 500-minute ramp to 425 °C, and 200 minutes at 425 °C. The intermediate double salt produced at 110 °C appeared to be triammonium uranium septafluoride.

Book Preparation of Uranium Hexafluoride

Download or read book Preparation of Uranium Hexafluoride written by and published by . This book was released on with total page 20 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Chemistry of Uranium

Download or read book Chemistry of Uranium written by Joseph Jacob Katz and published by . This book was released on 1958 with total page 448 pages. Available in PDF, EPUB and Kindle. Book excerpt: