Download or read book Preparation of Silica Aerogels with Improved Mechanical Properties and Extremely Low Thermal Conductivities Through Modified Sol gel Process written by Yanjia Zuo and published by . This book was released on 2010 with total page 96 pages. Available in PDF, EPUB and Kindle. Book excerpt: Reported silica aerogels have a thermal conductivity as low as 15 mW/mK. The fragility of silica aerogels, however, makes them impractical for structural applications. The purpose of the study is to improve the ductility of aerogels while retain the low thermal conductivity of silica aerogels. We have established a new synthesis route, a 3-step sol-gel processing method. The method provides better control of the formation of aerogel structures. The produced silica aerogels show much improved ductility compared to conventional methods in literatures. Furthermore, the synthesized silica aerogels have thermal conductivities as low as about 9 mW/mK, which is the lowest in all reported solids. The ultra low thermal conductivity can be explained with nano-scale structures for the silica aerogels, which have been characterized using advanced techniques including BET and SEM. We have further investigated and demonstrated the ability of enhancing mechanical properties of silica aerogels through structure modification using the proposed 3-step sol-gel processing method. The molecular-level synergism between silica particles/clusters and the doped functional materials inverts the relative host-guest roles in the produced aerogel composite, leading to new stronger and more robust low-density materials.

Download or read book Aerogels Handbook written by Michel Andre Aegerter and published by Springer Science & Business Media. This book was released on 2011-06-10 with total page 929 pages. Available in PDF, EPUB and Kindle. Book excerpt: Aerogels are the lightest solids known. Up to 1000 times lighter than glass and with a density as low as only four times that of air, they show very high thermal, electrical and acoustic insulation values and hold many entries in Guinness World Records. Originally based on silica, R&D efforts have extended this class of materials to non-silicate inorganic oxides, natural and synthetic organic polymers, carbon, metal and ceramic materials, etc. Composite systems involving polymer-crosslinked aerogels and interpenetrating hybrid networks have been developed and exhibit remarkable mechanical strength and flexibility. Even more exotic aerogels based on clays, chalcogenides, phosphides, quantum dots, and biopolymers such as chitosan are opening new applications for the construction, transportation, energy, defense and healthcare industries. Applications in electronics, chemistry, mechanics, engineering, energy production and storage, sensors, medicine, nanotechnology, military and aerospace, oil and gas recovery, thermal insulation and household uses are being developed with an estimated annual market growth rate of around 70% until 2015. The Aerogels Handbook summarizes state-of-the-art developments and processing of inorganic, organic, and composite aerogels, including the most important methods of synthesis, characterization as well as their typical applications and their possible market impact. Readers will find an exhaustive overview of all aerogel materials known today, their fabrication, upscaling aspects, physical and chemical properties, and most recent advances towards applications and commercial products, some of which are commercially available today. Key Features: •Edited and written by recognized worldwide leaders in the field •Appeals to a broad audience of materials scientists, chemists, and engineers in academic research and industrial R&D •Covers inorganic, organic, and composite aerogels •Describes military, aerospace, building industry, household, environmental, energy, and biomedical applications among others

Download or read book Advances in Aerogel Composites for Environmental Remediation written by Aftab Aslam Parwaz Khan and published by Elsevier. This book was released on 2021-05-29 with total page 398 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advances in Aerogel Composites for Environmental Remediation presents both contextual information aboutaerogels and details about their application in environmental remediation. A wide variety of aerogels are discussed, rangingfrom common to advanced and from natural to synthetic. By exploring ongoing research and developments in the environmentalremediation technologies using aerogel and its composites, this book addresses common day-to-day environmental problemsand presents solutions to the use of aerogel materials. The chapters discuss fabrication of various aerogel composites, alongwith their design and applications toward different environmental remediation technologies. Additionally, the properties andadvantages of aerogels are compared and contrasted to those of traditional materials. Given the consistent increase in environmental pollution, there is an urgent need to explore new materials for advances in remediationtechnology. Advances in Aerogel Composites for Environmental Remediation brings researchers and practitionersin the fields of environmental remediation, environmental science, and engineering to the forefront of remediation technologieswith a thorough breakdown of the benefits of and techniques relevant to aerogel composites. Covers basic properties, unique properties, and fabrication techniques of aerogels, from basic silica aerogels topresent-day conventional aerogels Discusses most of the major environmental remediation techniques and the advantages of using aerogels for theseremediation techniques in comparison to using traditional methods Presents future prospects for utilizing aerogels in modern day-to-day life and in the fabrication of tangible new products

Download or read book Adsorption Surface Area and Porosity written by Sidney John Gregg and published by . This book was released on 1991 with total page 328 pages. Available in PDF, EPUB and Kindle. Book excerpt: The principal aim of the second edition of this book remains the same as that of the first edition: to give a critical exposition of the use of the adsorption methods for the assessment of the surface and pore size distribution of finely divided and porous solids.

Download or read book Translucent Silica Aerogel written by Cinzia Buratti and published by . This book was released on 2019 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Silica translucent aerogels are unique materials able to improve the thermal insulation performance of buildings without compromising daylight transmission. The aim of the book is to give a general overview on state of the art research on translucent aerogels and their applications in buildings and to provide a data set about thermal and physical properties, useful in buildings' energy performance simulation and design.Silica aerogels are nanostructured solid materials made of approximately 96% air and 4% silica. They show a thermal conductivity in the 0.012-0.020 W/mK range and excellent optical properties, especially visible transmission. They come in granular and monolithic form. Granular aerogels are relatively easy to produce and less expensive than monolithic panes, but show worse optical and thermal performance. Monolithic aerogels enable vision through the material, but their fabrication process is not developed at an industrial scale.The book collects the contributions of experts in the field of translucent aerogels from all over the world. The contents of the eight chapters are detailed as follows:Chapter 1 is the contribution from Union College, Schenectady (USA). The chapter reviews the chemical approaches to silica wet gels preparation, the drying methods used to yield monoliths, and the challenges and limitations associated with its production.Chapter 2 is a contribution from EMPA, Dübendorf (Switzerland). It is a review of current state of the art research on silica aerogel granulate production, including raw materials selection, hydrophobization strategies, and drying methodologies. Chapter 3 is a contribution from Takenaka Corporation, Tokyo (Japan). The main techniques for the optical properties evaluation are described and data are provided. An original application of translucent aerogels in buildings and future research topics are also proposed.Chapter 4 is a contribution from Recep Tayyip Erdogan University, Rize and Ataturk University, Erzurum (Turkey). A review of the thermal properties of aerogels is provided, highlighting their better performance when compared to conventional and superinsulation materials.Chapter 5 is a contribution from the University of Perugia, Perugia (Italy). The acoustic properties of both granular and monolithic systems are investigated. For example, the influence of granule size and layer thickness that is deepened for granular aerogels is discussed, while for the monolithic form, the little data that is currently available is reported on. Chapter 6 is a contribution from the University of Tuscia, Viterbo (Italy) and Buro Happold Ltd, London (UK). It is focused on Life Cycle Assessment of silica aerogel, showing the research challenges in understanding its environmental impact, lower than the one of conventional thermal insulating glazing systems.Chapter 7 is a contribution from the University of Lyon and INSA-Lyon, Lyon (France). An overview of measurement methods and modeling tools available in literature is provided and a summary of the main mechanical properties of both monolithic and granular aerogels is reported on.Chapter 8 is a contribution from the Norwegian University of Science and Technology, Trondheim and SINTEF, Trondheim (Norway). Authors present their experimental investigations on various aerogel systems in different building envelopes (new aerogel glass material, aerogel-incorporated concrete, and so forth).

Download or read book Silica Aerogel Composites written by Mahesh Sachithanadam and published by Springer. This book was released on 2016-01-13 with total page 149 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book explores the improvement in thermal insulation properties of protein-based silica aerogel composites fabricated by a novel, inexpensive and feasible method. The resulting material exhibits polymeric foam behavior including high compressibility, super-hydrophobic qualities and excellent strain recovery in addition to low thermal conductivity. The fabrication methodologies are explained in great detail and represented in flowcharts for easy reference and understanding. This monograph gives readers a new perspective on composite fabrication using methods other than the traditional ones and explores the endless ways of altering the composition to modify the properties of the silica aerogel composites. Applications for this novel composite are diverse and range from those in the pharmaceutical and aerospace industries to the oil and gas industries.

Download or read book Sol Gel Science written by C. Jeffrey Brinker and published by Academic Press. This book was released on 2013-10-22 with total page 925 pages. Available in PDF, EPUB and Kindle. Book excerpt: Sol-Gel Science: The Physics and Chemistry of Sol-Gel Processing presents the physical and chemical principles of the sol-gel process. The book emphasizes the science behind sol-gel processing with a chapter devoted to applications. The first chapter introduces basic terminology, provides a brief historical sketch, and identifies some excellent texts for background reading. Chapters 2 and 3 discuss the mechanisms of hydrolysis and condensation for nonsilicate and silicate systems. Chapter 4 deals with stabilization and gelation of sols. Chapter 5 reviews theories of gelation and examines the predicted and observed changes in the properties of a sol in the vicinity of the gel point. Chapter 6 describes the changes in structure and properties that occur during aging of a gel in its pore liquor (or some other liquid). The discussion of drying is divided into two parts, with the theory concentrated in Chapter 7 and the phenomenology in Chapter 8. The structure of dried gels is explored in Chapter 9. Chapter 10 shows the possibility of using the gel as a substrate for chemical reactions or of modifying the bulk composition of the resulting ceramic by performing a surface reaction (such as nitridation) on the gel. Chapter 11 reviews the theory and practice of sintering, describing the mechanisms that govern densification of amorphous and crystalline materials, and showing the advantages of avoiding crystallization before sintering is complete. The properties of gel-derived and conventional ceramics are discussed in Chapter 12. The preparation of films is such an important aspect of sol-gel technology that the fundamentals of film formation are treated at length in Chapter 13. Films and other applications are briefly reviewed in Chapter 14. Materials scientists and researchers in the field of sol-gel processing will find the book invaluable.

Download or read book Aerogels I written by Inamuddin and published by Materials Research Forum LLC. This book was released on 2020-11-15 with total page 282 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book focuses on aerogels and their applications in such areas as energy storage, thermal storage, catalysis, water splitting and environmental remediation. The materials covered include nanocellulose-, porous-, silica-, hybrid silica-, carbon-, graphene- and magnetic aerogels. Ways of modulating the pore structure of aerogels are presented, as well as surface modifications and the application of coatings. Future perspectives focus on functional foods, thickeners, stabilizers, and scaffolding in tissue repair. Keywords: Aerogels, Nanocellulose Aerogels, Non-Silicate Aerogels, Organic Aerogels, Composite Hybrid Aerogels, Carbon-based and Graphene-based Aerogels, Biogels, Hybrid Silica-based Aerogels, Energy Storage, Thermal Storage, Catalysis, Water Splitting, Environmental Remediation, Absorbents, Gas Filters, Packaging Materials, Electrical Devices, Thermal Insulations, Fire Retardants, Pharmaceutical and Biomedical Applications, Functional Foods, Thickeners, Stabilizers, Scaffolding in Tissue Repair.

Download or read book The Sol Gel Handbook written by David Levy and published by John Wiley & Sons. This book was released on 2015-08-28 with total page 1616 pages. Available in PDF, EPUB and Kindle. Book excerpt: This comprehensive three-volume handbook brings together a review of the current state together with the latest developments in sol-gel technology to put forward new ideas. The first volume, dedicated to synthesis and shaping, gives an in-depth overview of the wet-chemical processes that constitute the core of the sol-gel method and presents the various pathways for the successful synthesis of inorganic and hybrid organic-inorganic materials, bio- and bio-inspired materials, powders, particles and fibers as well as sol-gel derived thin films, coatings and surfaces. The second volume deals with the mechanical, optical, electrical and magnetic properties of sol-gel derived materials and the methods for their characterization such as diffraction methods and nuclear magnetic resonance, infrared and Raman spectroscopies. The third volume concentrates on the various applications in the fields of membrane science, catalysis, energy research, biomaterials science, biomedicine, photonics and electronics.

Download or read book The Sol Gel Handbook 3 Volume Set written by David Levy and published by John Wiley & Sons. This book was released on 2015-11-02 with total page 1604 pages. Available in PDF, EPUB and Kindle. Book excerpt: This comprehensive three-volume handbook brings together a review of the current state together with the latest developments in sol-gel technology to put forward new ideas. The first volume, dedicated to synthesis and shaping, gives an in-depth overview of the wet-chemical processes that constitute the core of the sol-gel method and presents the various pathways for the successful synthesis of inorganic and hybrid organic-inorganic materials, bio- and bio-inspired materials, powders, particles and fibers as well as sol-gel derived thin films, coatings and surfaces. The second volume deals with the mechanical, optical, electrical and magnetic properties of sol-gel derived materials and the methods for their characterization such as diffraction methods and nuclear magnetic resonance, infrared and Raman spectroscopies. The third volume concentrates on the various applications in the fields of membrane science, catalysis, energy research, biomaterials science, biomedicine, photonics and electronics.

Download or read book SILICA AEROGEL POLYMER NANOCOMPOSITES AND NEW NANOPARTICLE SYNTHESES written by and published by . This book was released on 2009 with total page 652 pages. Available in PDF, EPUB and Kindle. Book excerpt: Aerogels are extremely high surface area, low density materials with applications including thermal and acoustic insulators, radiation detectors and cometary dust particle traps. However, their low density and aggregate structure makes them extremely fragile and practically impossible to machine or handle without breaking. This has led to the development of aerogel composites with enhanced mechanical properties through the addition of polymers or surface modifiers. To date, attempts to strengthen aerogels have come with significant increases in density and processing time. Here I will describe our search for a solution to these problems with our invention using methyl cyanoacrylate chemical vapor deposition (CVD) to strengthen silica, aminated silica and bridged polysilsesquioxane aerogels. This approach led to a strength improvement of the composites within hours and the strongest composite prepared had a 100x strength improvement over the precursor aerogel. We also developed the first approach to control the molecular weight of the polymers that reinforce silica aerogels using surface-initiated atom transfer radical polymerization (SI-ATRP). Although PMMA reinforcement of silica aerogels improved the mechanical properties, further strength improvements were achieved by cross-linking the grafted PMMA. Additionally, we developed the first silica aerogels reinforced with polyaniline nanofibers that were strong and electrically conductive. Reinforcing silica aerogels with polyaniline allowed them to be used as a sensor for the detection of protonating and deprotonating gaseous species. Finally we developed a new approach for the synthesis of silica and bridged polysilsesquioxane spheres using a surfactant free synthesis. This approach allowed for the first in-situ incorporation of base sensitive functionalities during the sol-gel polymerization.

Download or read book Introduction to Sol Gel Processing written by Alain C. Pierre and published by Springer Nature. This book was released on 2020-03-10 with total page 716 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents a broad, general introduction to the processing of Sol-Gel technologies. This updated volume serves as a general handbook for researchers and students entering the field. This new edition provides updates in fields that have undergone rapid developments, such as Ceramics, Catalysis, Chromatropgraphy, biomaterials, glass science, and optics. It provides a simple, compact resource that can also be used in graduate-level materials science courses.

Download or read book Springer Handbook of Aerogels written by Michel A. Aegerter and published by Springer Nature. This book was released on 2023-10-01 with total page 1778 pages. Available in PDF, EPUB and Kindle. Book excerpt: This indispensable handbook provides comprehensive coverage of the current state-of-the-art in inorganic, organic, and composite aerogels – from synthesis and characterization to cutting-edge applications and their potential market impact. Built upon Springer’s successful Aerogels Handbook published in 2011, this handbook features extensive revisions and timely updates, reflecting the changes in this fast-growing field. Aerogels are the lightest solids known to man. Up to 1000 times lighter than glass and with a density only four times that of air, they possess extraordinarily high thermal, electrical, and acoustic insulation properties, and boast numerous entries in Guinness World Records. Originally based on silica, R&D efforts have extended this class of materials to incorporate non-silicate inorganic oxides, natural and synthetic organic polymers, carbon, metal, and ceramic materials. Composite systems involving polymer-crosslinked aerogels and interpenetrating hybrid networks have been developed and exhibit remarkable mechanical strength and flexibility. Even more exotic aerogels based on clays, chalcogenides, phosphides, quantum dots, and biopolymers such as chitosan are opening new applications for the construction, transportation, energy, defense and healthcare industries. Applications in electronics, chemistry, mechanics, engineering, energy production and storage, sensors, medicine, nanotechnology, military and aerospace, oil and gas recovery, thermal insulation, and household uses are being developed. Readers of this fully updated and expanded edition will find an exhaustive source for all aerogel materials known today, their fabrication, upscaling aspects, physical and chemical properties, and the most recent advances towards applications and commercial use. This key reference is essential reading for a combined audience of graduate students, academic researchers, and industry professionals.

Download or read book Aerogels for Energy Saving and Storage written by Meldin Mathew and published by John Wiley & Sons. This book was released on 2024-07-02 with total page 548 pages. Available in PDF, EPUB and Kindle. Book excerpt: Explore the energy storage applications of a wide variety of aerogels made from different materials In Aerogels for Energy Saving and Storage, an expert team of researchers delivers a one-stop resource covering the state-of-the-art in aerogels for energy applications. The book covers their morphology, properties, and processability and serves as a valuable resource for researchers and professionals working in materials science and environmentally friendly energy and power technology. The authors offer a comprehensive review of highly efficient energy applications of aerogels that bridges the gap between engineering, science, and chemistry and advances the field of materials development. They provide a Life Cycle Assessment of aerogels in energy systems, as well as discussions of their impact on the environment. Aerogel synthesis, characterization, fabrication, morphology, properties, energy-related applications, and simulations are all explored, and likely future research directions are provided. Readers will also find: A thorough introduction to aerogels in energy, including state-of-the-art advancements and challenges newly encountered Comprehensive explorations of chitin-based and cellulose-derived aerogels, as well as lignin-, clay-, and carbon nanotube-based aerogels Practical discussions of organic, natural, and inorganic aerogels, with further analyses of the lifecycle of aerogels In-depth examinations of the theory, modeling, and simulation of aerogels Perfect for chemical and environmental engineers, Aerogels for Energy Saving and Storage will also earn a place in the libraries of chemistry and materials science researchers in academia and industry.

Download or read book Food Packaging and Preservation written by Alexandru Mihai Grumezescu and published by Academic Press. This book was released on 2017-10-20 with total page 590 pages. Available in PDF, EPUB and Kindle. Book excerpt: Food Packaging and Preservation, Volume 9 in the Handbook of Food Bioengineering series, explores recent approaches to preserving and prolonging safe use of food products while also maintaining the properties of fresh foods. This volume contains valuable information and novel ideas regarding recently investigated packaging techniques and their implications on food bioengineering. In addition, classical and modern packaging materials and the impact of materials science on the development of smart packaging approaches are discussed. This book is a one-stop-shop for anyone in the food industry seeking to understand how bioengineering can foster research and innovation. Presents cutting technologies and approaches utilized in current and future food preservation for both food and beverages Offers research methods for the creation of novel preservatives and packaging materials to improve the quality and lifespan of preserved foods Features techniques to ensure the safe use of foods for longer periods of time Provides solutions of antimicrobial films and coatings for food packaging applications to enhance food safety and quality

Download or read book Sol Gel Derived Silicon Containing Hybrids written by Maria Zielecka and published by . This book was released on 2017 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Silicone-containing hybrid systems including functionalized and modified silica nanospheres as well as silica aerogels were synthesized using sol-gel process. The most important advantage of the developed silicon-containing hybrids lies in their high application potential, e.g. for the production of façade paints, polymer nanocomposites, highly efficient insulating materials and other high-tech products for construction industry. The possibility of precise steering of sol-gel process and synergism of very rich silicon compound chemistry allows to obtain materials with strategically designed architecture. Original methods of manufacturing following silicon-containing hybrids such as functionalized and non-functionalized silica nanospheres, silica nanospheres containing immobilized silver and/or copper nanoparticles and silica aerogels were developed. Homogeneous structural properties of synthesized materials were achieved due to carefully selected parameters of sol-gel process. The technology offers a possibility to control the grain size and uniformity of nanospheres by process parameters. The smallest nanosphere size is 10 nm and the largest 600 nm. The properties of aerogels obtained according to the original technology developed in the Industrial Chemistry Research Institute (ICRI) are extremely good and repetitive particularly taking into account their thermal conductivity. The main advantages of the developed aerogels are very good mechanical properties, very low dust formation and significantly decreased costs when compared to traditional silica aerogels.

Download or read book Recent Applications in Sol Gel Synthesis written by Usha Chandra and published by BoD – Books on Demand. This book was released on 2017-07-05 with total page 312 pages. Available in PDF, EPUB and Kindle. Book excerpt: Versatility, extended compositional ranges, better homogeneity, lesser energy consumption, and requirement of nonexpensive equipments have boosted the use of sol-gel process on top of the popularity in the synthesis of nanosystems. The sol-gel technique has not only revolutionized oxide ceramics industry and/or material science but has also extended widely into multidimensional applications. The book Recent Applications in Sol-Gel Synthesis comprises 14 chapters that deal mainly with the application-oriented aspects of the technique. Sol-gel prepared metal oxide (MO) nanostructures like nanospheres, nanorods, nanoflakes, nanotubes, and nanoribbons have been employed in biomedical applications involving drug deliveries, mimicking of natural bone, and antimicrobial activities. The possibility of controlling grain size in aerogel and preparation of ultrahigh-temperature ceramic (UHTC)-based materials, fluorescent glasses, ultraviolet photosensors, and photocatalysts have been discussed in detail by the experts in the field. The usefulness of sol-gel materials as active GRIN, as textile finisher, and as leather modifier with water-repellent and oil-resistive properties would be an incentive for researchers keen to pursue the field.