Download or read book Predicting Sooting Tendencies from Chemical Structure with Experimental and Theoretical Insight written by and published by . This book was released on 2019 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Particulate matter (PM) emissions from internal combustion engines negatively impact public health and global climate. These problems are exacerbated by newer gasoline direct injection engines, which are more fuel-efficient, but also produce more soot than traditional spark ignited engines. Reducing soot formation is therefore of paramount importance in the development of new fuels. A fuel's sooting tendency is a quantitative parameter that describes the sooting behavior of a pure compound or fuel mixture. The yield sooting index (YSI), developed by McEnally and Pfefferle, accurately measures sooting tendencies using small sample quantities. Using an experimental sooting tendency database, we have developed a predictive model for sooting behavior from a quantitative structure-activity relationship (QSAR). It was developed so that input molecules are first decomposed into individual carbon-type fragments for which the sooting tendency contribution can be assigned based on a Bayesian linear regression against the experimental database. The model's predictive accuracy is comparable to its training performance using leave-one-out cross-validation. We have used this model to provide quantitative insights into the effects of chemical structure on soot formation, but excitingly, we have also been able to readily identify the presence of more complicated kinetic sooting mechanisms for structures which are extreme outliers. Oxygenated aromatics can be produced readily from biomass as renewable sources and oxygenated aromatics with very similar structures tend to have a much lower sooting tendency, for example methoxybenzene (anisole, 107), 2-methylphenol (m-cresol, 103), 2-ethylphenol (120), 3-ethylphenol (138) and 1-phenylethanol (142). Thus, the presence of just one oxygen atom in an aromatic compound can drastically alter the reaction pathways leading to soot precursors. We have applied density functional theory (DFT) calculations and flow reactor experiments to examine how oxygenation alters reaction pathways in a combustion environment. This study has allowed us to gain understanding on how the location of an oxygenated functional group influences soot formation. Our work provides a blueprint for the design of oxygenated fuels from biomass, which minimize the production of soot in low oxygen environments.
Download or read book Social Science Research written by Anol Bhattacherjee and published by CreateSpace. This book was released on 2012-04-01 with total page 156 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is designed to introduce doctoral and graduate students to the process of conducting scientific research in the social sciences, business, education, public health, and related disciplines. It is a one-stop, comprehensive, and compact source for foundational concepts in behavioral research, and can serve as a stand-alone text or as a supplement to research readings in any doctoral seminar or research methods class. This book is currently used as a research text at universities on six continents and will shortly be available in nine different languages.
Download or read book The Yaws Handbook of Thermodynamic Properties for Hydrocarbons and Chemicals written by Marco Satyro and published by Gulf Professional Publishing. This book was released on 2018-02-01 with total page 1000 pages. Available in PDF, EPUB and Kindle. Book excerpt: Petroleum and chemical engineers are constantly looking for reliable data yet don’t have the time to search through multiple sources and articles to get the most accurate pieces of data. The Yaws Handbook of Thermodynamic Properties for Hydrocarbons and Chemicals, 2nd edition brings a one-stop database reference for engineers to quickly gain access on over 12,000 compounds, simple and complex fluids, and an extensive list of properties – all to validate and improve on their thermodynamic modeling. Enhanced with eight new chapters covering more equation of state parameters, Yaws’ product continues to remain a go-to source to crosscheck critical properties available on process simulators or PVT software and estimate these properties based on the group contribution methods described in the different chapters. The Yaws Handbook of Thermodynamic Properties for Hydrocarbons and Chemicals, 2nd edition stands as the trusted database to optimize petrochemical processes, equipment, and operations. Provides a reliable database reference for thermodynamic properties, even varied by temperature, as well as simple and complex fluids, mixtures, and property calculations Updated with eight additional new chapters covering a modern platform of practical applications in modelling both pure fluids and mixtures with cubic equations of state Delivers accurate and quick options and solutions to size or simulate petrochemical processes and develop better predictive models
Download or read book Bulletin of the Atomic Scientists written by and published by . This book was released on 1961-05 with total page 88 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Bulletin of the Atomic Scientists is the premier public resource on scientific and technological developments that impact global security. Founded by Manhattan Project Scientists, the Bulletin's iconic "Doomsday Clock" stimulates solutions for a safer world.
Download or read book Applied Mechanics Reviews written by and published by . This book was released on 1975 with total page 1000 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book International Aerospace Abstracts written by and published by . This book was released on 1996 with total page 1012 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Modeling of Molecular Properties written by Peter Comba and published by Wiley-VCH. This book was released on 2011-10-17 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Molecular modeling encompasses applied theoretical approaches and computational techniques to model structures and properties of molecular compounds and materials in order to predict and / or interpret their properties. The modeling covered in this book ranges from methods for small chemical to large biological molecules and materials. With its comprehensive coverage of important research fields in molecular and materials science, this is a must-have for all organic, inorganic and biochemists as well as materials scientists interested in applied theoretical and computational chemistry. The 28 chapters, written by an international group of experienced theoretically oriented chemists, are grouped into four parts: Theory and Concepts; Applications in Homogeneous Catalysis; Applications in Pharmaceutical and Biological Chemistry; and Applications in Main Group, Organic and Organometallic Chemistry. The various chapters include concept papers, tutorials, and research reports.
Download or read book Soot Formation in Combustion written by Henning Bockhorn and published by Springer Science & Business Media. This book was released on 2013-03-08 with total page 595 pages. Available in PDF, EPUB and Kindle. Book excerpt: Soot Formation in Combustion represents an up-to-date overview. The contributions trace back to the 1991 Heidelberg symposium entitled "Mechanism and Models of Soot Formation" and have all been reedited by Prof. Bockhorn in close contact with the original authors. The book gives an easy introduction to the field for newcomers, and provides detailed treatments for the specialists. The following list of contents illustrates the topics under review:
Download or read book Fuel Effects on Operability of Aircraft Gas Turbine Combustors written by Meredith Colket and published by . This book was released on 2021 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: In summarizing the results obtained in the first five years of the National Jet Fuel Combustion Program (NJFCP), this book demonstrates that there is still much to be learned about the combustion of alternative jet fuels.
Download or read book Global Trends 2040 written by National Intelligence Council and published by Cosimo Reports. This book was released on 2021-03 with total page 158 pages. Available in PDF, EPUB and Kindle. Book excerpt: "The ongoing COVID-19 pandemic marks the most significant, singular global disruption since World War II, with health, economic, political, and security implications that will ripple for years to come." -Global Trends 2040 (2021) Global Trends 2040-A More Contested World (2021), released by the US National Intelligence Council, is the latest report in its series of reports starting in 1997 about megatrends and the world's future. This report, strongly influenced by the COVID-19 pandemic, paints a bleak picture of the future and describes a contested, fragmented and turbulent world. It specifically discusses the four main trends that will shape tomorrow's world: - Demographics-by 2040, 1.4 billion people will be added mostly in Africa and South Asia. - Economics-increased government debt and concentrated economic power will escalate problems for the poor and middleclass. - Climate-a hotter world will increase water, food, and health insecurity. - Technology-the emergence of new technologies could both solve and cause problems for human life. Students of trends, policymakers, entrepreneurs, academics, journalists and anyone eager for a glimpse into the next decades, will find this report, with colored graphs, essential reading.
Download or read book Surfing Uncertainty written by Andy Clark and published by Oxford University Press, USA. This book was released on 2016 with total page 425 pages. Available in PDF, EPUB and Kindle. Book excerpt: This title brings together work on embodiment, action, and the predictive mind. At the core is the vision of human minds as prediction machines - devices that constantly try to stay one step ahead of the breaking waves of sensory stimulation, by actively predicting the incoming flow. In every situation we encounter, that complex prediction machinery is already buzzing, proactively trying to anticipate the sensory barrage. The book shows in detail how this strange but potent strategy of self-anticipation ushers perception, understanding, and imagination simultaneously onto the cognitive stage.
Download or read book Sixth International Microgravity Combustion Workshop written by and published by . This book was released on 2001 with total page 490 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Experimental and Quasi Experimental Designs for Research written by Donald T. Campbell and published by Ravenio Books. This book was released on 2015-09-03 with total page 172 pages. Available in PDF, EPUB and Kindle. Book excerpt: We shall examine the validity of 16 experimental designs against 12 common threats to valid inference. By experiment we refer to that portion of research in which variables are manipulated and their effects upon other variables observed. It is well to distinguish the particular role of this chapter. It is not a chapter on experimental design in the Fisher (1925, 1935) tradition, in which an experimenter having complete mastery can schedule treatments and measurements for optimal statistical efficiency, with complexity of design emerging only from that goal of efficiency. Insofar as the designs discussed in the present chapter become complex, it is because of the intransigency of the environment: because, that is, of the experimenter’s lack of complete control.
Download or read book Democracy and Education written by John Dewey and published by Createspace Independent Publishing Platform. This book was released on 1916 with total page 456 pages. Available in PDF, EPUB and Kindle. Book excerpt: . Renewal of Life by Transmission. The most notable distinction between living and inanimate things is that the former maintain themselves by renewal. A stone when struck resists. If its resistance is greater than the force of the blow struck, it remains outwardly unchanged. Otherwise, it is shattered into smaller bits. Never does the stone attempt to react in such a way that it may maintain itself against the blow, much less so as to render the blow a contributing factor to its own continued action. While the living thing may easily be crushed by superior force, it none the less tries to turn the energies which act upon it into means of its own further existence. If it cannot do so, it does not just split into smaller pieces (at least in the higher forms of life), but loses its identity as a living thing. As long as it endures, it struggles to use surrounding energies in its own behalf. It uses light, air, moisture, and the material of soil. To say that it uses them is to say that it turns them into means of its own conservation. As long as it is growing, the energy it expends in thus turning the environment to account is more than compensated for by the return it gets: it grows. Understanding the word "control" in this sense, it may be said that a living being is one that subjugates and controls for its own continued activity the energies that would otherwise use it up. Life is a self-renewing process through action upon the environment.
Download or read book Biochar for Environmental Management written by Johannes Lehmann and published by Routledge. This book was released on 2012-05-16 with total page 450 pages. Available in PDF, EPUB and Kindle. Book excerpt: Biochar is the carbon-rich product when biomass (such as wood, manure or crop residues) is heated in a closed container with little or no available air. It can be used to improve agriculture and the environment in several ways, and its stability in soil and superior nutrient-retention properties make it an ideal soil amendment to increase crop yields. In addition to this, biochar sequestration, in combination with sustainable biomass production, can be carbon-negative and therefore used to actively remove carbon dioxide from the atmosphere, with major implications for mitigation of climate change. Biochar production can also be combined with bioenergy production through the use of the gases that are given off in the pyrolysis process. This book is the first to synthesize the expanding research literature on this topic. The book's interdisciplinary approach, which covers engineering, environmental sciences, agricultural sciences, economics and policy, is a vital tool at this stage of biochar technology development. This comprehensive overview of current knowledge will be of interest to advanced students, researchers and professionals in a wide range of disciplines.
Download or read book Scientific and Technical Aerospace Reports written by and published by . This book was released on 1987 with total page 1124 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Toxicological Profile for Polycyclic Aromatic Hydrocarbons written by and published by . This book was released on 1995 with total page 500 pages. Available in PDF, EPUB and Kindle. Book excerpt:
