Download or read book Pore scale Analysis of Mixing controlled Calcium Carbonate Precipitation and Dissolution Kinetics in Microfluidic Experiments written by and published by . This book was released on 2013 with total page 18 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Pore scale Simulation of Mixing induced Calcium Carbonate Precipitation and Dissolution in a Microfluidic Pore Network written by and published by . This book was released on 2011 with total page 13 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Microfluidic Study of Calcium Carbonate Dissolution and Precipitation in Confinement written by Jianping Xu (Ph. D.) and published by . This book was released on 2023 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Calcium carbonate is the major carbon sink in the Earth system and its dissolution and precipitation are essential for carbon cycling between the geosphere, hydrosphere, and atmosphere. Given that the Earth is a rocky planet populated with life, often these dissolution and precipitation processes occur not in open waters, but in small confinement of rock and soil pores and cellular spaces in organisms. Examples include Karst dissolution and formation, rock weathering, soil carbonation, biomineralization, geologic carbon storage and petroleum reservoir acidizing. Fundamental understanding and control of dissolution and precipitation in confinement are still challenging due to the high complexity generated from multi-coupling between fluid transport, interfacial interactions, chemical reactions, and mineral phase transition. In this work, we fabricate glass microfluidic chips that house rock micropore-like confinements for the lab-on-a-chip investigations of calcium carbonate dissolution and precipitation. Optical transparency of the chips allows direct visualizations of pore-scale dynamic behaviors with high temporal and spatial resolutions, which is crucial for quantitative characterizations. First, through extensive experiments we discovered a series of novel regimes, patterns and mechanisms of calcium carbonate dissolution and precipitation confined in micrometer geometries. Previously unknown behaviors such as CO2 bubble breathing during carbonate dissolution, power-law particle size distribution of calcium carbonate precipitates, and the hydrodynamic instability induced by mineral phase transition are observed and quantified. Numerical and theoretical modeling are implemented to interpret the experimental results and demonstrate that small spatial confinement is actively shaping the mineral dissolution and precipitation dynamics. Second, novel experimental methodologies are developed to grow calcium carbonate in a glass microfluidic confinement either as scattered crystal particles or carbonate porous media. Utilizing the in situ grown carbonate porous media, we for the first time realize all the five classical carbonate rock dissolution regimes in a microfluidic chip. Extensive experiments are conducted to examine the effects of porous media heterogeneity and nonaqueous phases of oil and CO2 on the carbonate dissolution dynamics. Third, high-resolution microfluidic visualizations provide an analytical basis for tracking mineral surfaces and precise measurements of dissolution and precipitation rates. Therefore, the microfluidic approach can be utilized as a screening tool for faster carbonate mineralization, which is important for geologic carbon storage and other decarbonization technologies such as enhanced rock weathering and soil carbonation
Download or read book Pore scale Microstructure Mechanisms and Models for Subsurface Flow and Transport written by James E. McClure and published by Frontiers Media SA. This book was released on 2022-11-29 with total page 164 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Pore scale Investigation of Mixing induced Calcite Precipitation and Dissolution Kinetics in Micromodel Experiments written by and published by . This book was released on 2011 with total page 1 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Pore Scale Geochemical Processes written by Carl Steefel and published by Walter de Gruyter GmbH & Co KG. This book was released on 2015-09-25 with total page 496 pages. Available in PDF, EPUB and Kindle. Book excerpt: This RiMG (Reviews in Mineralogy & Geochemistry) volume includes contributions that review experimental, characterization, and modeling advances in our understanding of pore-scale geochemical processes. The volume had its origins in a special theme session at the 2015 Goldschmidt Conference in Prague. From a diversity of pore-scale topics that ranged from multi-scale characterization to modeling, this work summarizes the state-of-the-science in this subject. Topics include: modification of thermodynamics and kinetics in small pores. chemo-mechanical processes and how they affect porosity evolution in geological media. small angle neutron scattering (SANS) techniques. how isotopic gradients across fluid–mineral boundaries can develop and how these provide insight into pore-scale processes. Information on an important class of models referred to as "pore network" and much more. The material in this book is accessible for graduate students, researchers, and professionals in the earth, material, environmental, hydrological, and biological sciences. The pore scale is readily recognizable to geochemists, and yet in the past it has not received a great deal of attention as a distinct scale or environment that is associated with its own set of questions and challenges. Is the pore scale merely an environment in which smaller scale (molecular) processes aggregate, or are there emergent phenomena unique to this scale? Is it simply a finer-grained version of the "continuum" scale that is addressed in larger-scale models and interpretations? The scale is important because it accounts for the pore architecture within which such diverse processes as multi-mineral reaction networks, microbial community interaction, and transport play out, giving rise to new geochemical behavior that might not be understood or predicted by considering smaller or larger scales alone.
Download or read book FLUID FLOW SOLUTE MIXING AND PRECIPITATION IN POROUS MEDIA written by George D. Redden and published by . This book was released on 2006 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Reactions that lead to the formation of mineral precipitates, colloids or growth of biofilms in porous media often depend on the molecular-level diffusive mixing. For example, for the formation of mineral phases, exceeding the saturation index for a mineral is a minimum requirement for precipitation to proceed. Solute mixing frequently occurs at the interface between two solutions each containing one or more soluble reactants, particularly in engineered systems where contaminant degradation or modification or fluid flow are objectives. Although many of the fundamental component processes involved in the deposition or solubilization of solid phases are reasonably well understood, including precipitation equilibrium and kinetics, fluid flow and solute transport, the deposition of chemical precipitates, biofilms and colloidal particles are all coupled to flow, and the science of such coupled processes is not well developed. How such precipitates (and conversely, dissolution of solids) are distributed in the subsurface along flow paths with chemical gradients is a complex and challenging problem. This is especially true in systems that undergo rapid change where equilibrium conditions cannot be assumed, particularly in subsurface systems where reactants are introduced rapidly, compared to most natural flow conditions, and where mixing fronts are generated. Although the concept of dispersion in porous media is frequently used to approximate mixing at macroscopic scales, dispersion does not necessarily describe pore-level or molecular level mixing that must occur for chemical and biological reactions to be possible. An example of coupling between flow, mixing and mineral precipitation, with practical applications to controlling fluid flow or contaminant remediation in subsurface environments is shown in the mixing zone between parallel flowing solutions. Two- and three-dimensional experiments in packed-sand media were conducted where solutions containing calcium and carbonate ions came into contact along a parallel flow boundary and mixed by dispersion and diffusion. The result is the propagation of calcium carbonate precipitates along the solution-solution boundary in the direction of flow. As carbonate precipitates fill the pore space mixing of the two solutions is restricted and therefore precipitation, flow, and transport are coupled. The distribution of carbonate phases is a complex interaction involving precipitation and dissolution kinetics, which are functions of pore-scale saturation indices and solute ratios, heterogeneous vs. homogeneous nucleation and growth mechanisms and changes in porosity and flow. Experimental and modeling results illustrate challenges in understanding the macroscopic and microscopic phenomena that depend on solute mixing, the relevance of molecular and pore-scale processes to the macroscopic behavior, and potential impact on metal mobility in porous media. Mineral precipitation and changes in porosity are simulated at the pore-scale using the Smooth Particle Hydrodynamics method. Macroscopic simulations were performed using discretized, continuum-scale modeling with parameterization representing macroscopic media properties. One of the modeling goals is to use pore-scale simulations to provide the basis for parameterization of macroscopic (more practical) model predictions.
Download or read book Biomineralization written by Patricia M. Dove and published by Walter de Gruyter GmbH & Co KG. This book was released on 2018-12-17 with total page 396 pages. Available in PDF, EPUB and Kindle. Book excerpt: Volume 54 of Reviews in Mineralogy and Geochemistry focuses upon the various processes by which organisms direct the formation of minerals. Our framework of examining biominerals from the viewpoints of major mineralization strategies distinguishes this volume from most previous reviews. The review begins by introducing the reader to over-arching principles that are needed to investigate biomineralization phenomena and shows the current state of knowledge regarding the major approaches to mineralization that organisms have developed over the course of Earth history. By exploring the complexities that underlie the "synthesis" of biogenic materials, and therefore the basis for how compositions and structures of biominerals are mediated (or not), we believe this volume will be instrumental in propelling studies of biomineralization to a new level of research questions that are grounded in an understanding of the underlying biological phenomena.
Download or read book Pore scale Velocity Measurements in Microfluidic Pore Networks with Calcium Carbonate Precipitates written by and published by . This book was released on 2015 with total page 7 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Carbonates written by Richard J. Reeder and published by Walter de Gruyter GmbH & Co KG. This book was released on 2018-12-17 with total page 412 pages. Available in PDF, EPUB and Kindle. Book excerpt: Volume 11 of Reviews in Mineralogy attempts to synthesize our present understanding of certain aspects of the mineralogy and chemistry of the rock-forming carbonates. This review follows, by ten years, a major assessment of (sedimentary) carbonate minerals by Lippmann (1973). There is only minor overlap of subject material, and I hope that this difference reflects fairly how this field has developed. In this volume, some of the papers are general (i.e., those addressing crystal chemistry and phase relations), and they provide overviews of a fundamental nature and are of interest to many. Others are more specialized in coverage and generally reflect the different approaches used in carbonate geochemistry. The final chapter introduces transmission electron microscopy, a relatively new and powerful technique for mineralogical research that has great potential in carbonate research.
Download or read book The Perfect Slime written by Hans-Curt Flemming and published by IWA Publishing. This book was released on 2016-09-15 with total page 336 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Perfect Slime presents the latest state of knowledge and all aspects of the Extracellular Polymeric Substances, (EPS) matrix – from the ecological and health to the antifouling perspectives. The book brings together all the current material in order to expand our understanding of the functions, properties and characteristics of the matrix as well as the possibilities to strengthen or weaken it. The EPS matrix represents the immediate environment in which biofilm organisms live. From their point of view, this matrix has paramount advantages. It allows them to stay together for extended periods and form synergistic microconsortia, it retains extracellular enzymes and turns the matrix into an external digestion system and it is a universal recycling yard, it protects them against desiccation, it allows for intense communication and represents a huge genetic archive. They can remodel their matrix, break free and eventually, they can use it as a nutrient source. The EPS matrix can be considered as one of the emergent properties of biofilms and are a major reason for the success of this form of life. Nevertheless, they have been termed the “black matter of biofilms” for good reasons. First of all: the isolation methods define the results. In most cases, only water soluble EPS components are investigated; insoluble ones such as cellulose or amyloids are much less included. In particular in environmental biofilms with many species, it is difficult to impossible isolate, separate the various EPS molecules they are encased in and to define which species produced which EPS. The regulation and the factors which trigger or inhibit EPS production are still very poorly understood. Furthermore: bacteria are not the only microorganisms to produce EPS. Archaea, Fungi and algae can also form EPS. This book investigates the questions, What is their composition, function, dynamics and regulation? What do they all have in common?
Download or read book Crystal Dissolution and Precipitation in Porous Media written by Cornelis Johannes Duijn and published by . This book was released on 2003 with total page 44 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Kinetics of Water Rock Interaction written by Susan Brantley and published by Springer Science & Business Media. This book was released on 2007-12-29 with total page 843 pages. Available in PDF, EPUB and Kindle. Book excerpt: Geochemical kinetics as a topic is now of importance to a wide range of geochemists in academia, industry, and government, and all geochemists need a rudimentary knowledge of the field. This book summarizes the fundamentals of geochemical kinetics with examples drawn especially from mineral dissolution and precipitation. It also encompasses discussion of high temperature processes and global geochemical cycle modeling. Analysis of textures of rocks, sediments, and mineral surfaces are incorporated throughout and provide a sub-theme of the book.
Download or read book Hydrogeophysics written by Yorum Rubin and published by Springer Science & Business Media. This book was released on 2006-05-06 with total page 518 pages. Available in PDF, EPUB and Kindle. Book excerpt: This ground-breaking work is the first to cover the fundamentals of hydrogeophysics from both the hydrogeological and geophysical perspectives. Authored by leading experts and expert groups, the book starts out by explaining the fundamentals of hydrological characterization, with focus on hydrological data acquisition and measurement analysis as well as geostatistical approaches. The fundamentals of geophysical characterization are then at length, including the geophysical techniques that are often used for hydrogeological characterization. Unlike other books, the geophysical methods and petrophysical discussions presented here emphasize the theory, assumptions, approaches, and interpretations that are particularly important for hydrogeological applications. A series of hydrogeophysical case studies illustrate hydrogeophysical approaches for mapping hydrological units, estimation of hydrogeological parameters, and monitoring of hydrogeological processes. Finally, the book concludes with hydrogeophysical frontiers, i.e. on emerging technologies and stochastic hydrogeophysical inversion approaches.
Download or read book Geochemical Self organization written by Peter J. Ortoleva and published by . This book was released on 1994 with total page 440 pages. Available in PDF, EPUB and Kindle. Book excerpt: This monograph offers an interdisciplinary approach to the analysis of geological systems which become spatially organized through the mediation of chemical processes. The treatment is based on a mathematical approach. The intended readership includes researchers and advanced undergraduate and graduate students in all branches of geology as well as scientists and mathematicians concerned with nonlinear dynamics, numerical analysis, self-organization, nonlinear waves and dynamics, and phase transition phenomena. The work could also serve as a basis for a special topics course in mathematics, chemistry or physics.
Download or read book Modeling Phenomena of Flow and Transport in Porous Media written by Jacob Bear and published by Springer. This book was released on 2018-01-25 with total page 761 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents and discusses the construction of mathematical models that describe phenomena of flow and transport in porous media as encountered in civil and environmental engineering, petroleum and agricultural engineering, as well as chemical and geothermal engineering. The phenomena of transport of extensive quantities, like mass of fluid phases, mass of chemical species dissolved in fluid phases, momentum and energy of the solid matrix and of fluid phases occupying the void space of porous medium domains are encountered in all these disciplines. The book, which can also serve as a text for courses on modeling in these disciplines, starts from first principles and focuses on the construction of well-posed mathematical models that describe all these transport phenomena.
Download or read book Energy Efficient Solvents for CO2 Capture by Gas Liquid Absorption written by Wojciech M. Budzianowski and published by Springer. This book was released on 2016-12-01 with total page 282 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book reviews and characterises promising single-compound solvents, solvent blends and advanced solvent systems suitable for CO2 capture applications using gas-liquid absorption. Focusing on energy efficient solvents with minimal adverse environmental impact, the contributions included analyse the major technological advantages, as well as research and development challenges of promising solvents and solvent systems in various sustainable CO2 capture applications. It provides a valuable source of information for undergraduate and postgraduate students, as well as for chemical engineers and energy specialists.
