Download or read book Polynuclear transition metal compounds with inorganic anions as bridging group written by Saskia Fennegina Keij and published by . This book was released on 1990 with total page 125 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Compounds of the Transition Elements Involving Metal Metal Bonds written by D. L. Kepert and published by Elsevier. This book was released on 2016-06-06 with total page 177 pages. Available in PDF, EPUB and Kindle. Book excerpt: Compounds of the Transition Elements Involving Metal-Metal Bonds focuses on compounds of the transition elements involving metal-metal bonds. Emphasis is on metal-metal bonds in coordination compounds and organometallic complexes, halides, and oxides. Factors that influence the formation, stability, and properties of such compounds, as well as their application in various fields of chemistry and physics, are discussed. This book is divided into four sections and begins with a classification of metal-metal bonds and some of the physical and chemical methods used to study them, including X-ray crystallography, magnetic susceptibility and electron spin resonance, nuclear spin resonance, Mössbauer measurements, infrared and Raman spectroscopy, visible and ultraviolet spectroscopy, mass spectrometry, electrical conductivity, electrochemistry, and chemical reactivity. Factors influencing the strength of metal-metal bonds in metals and compounds are also examined. The remaining sections deal with metal-metal bonds in coordination compounds and organometallic complexes, halides, and oxides. This monograph will be a useful resource for inorganic chemists.
Download or read book Transition Metals in Supramolecular Chemistry written by Jean-Pierre Sauvage and published by John Wiley & Sons. This book was released on 2008-04-30 with total page 426 pages. Available in PDF, EPUB and Kindle. Book excerpt: Perspectives in Supramolecular Chemistry will relate recent developments and new exciting approaches in supramolecular chemistry. In supramolecular chemistry, our aim is to understand molecular chemistry beyond the covalent bond - the series will concentrate on goal-orientated supramolecular chemistry. Perspectives in Supramolecular Chemistry will reflect research which develops supramolecular structures with specific new properties, such as recognition, transport and simulation of biosystems or new materials. The series will cover all areas from theoretical and modelling aspects through organic and inorganic chemistry and biochemistry to materials, solid-state and polymer sciences reflecting the many and varied applications of supramolecular structures in modern chemistry. Transition Metals in Supramolecular Chemistry Edited by Jean-Pierre Sauvage, Université Louis Pasteur, Strasbourg, France The chemistry of weak forces and non-covalent interactions as pioneered by Pedersen, Lehn and Cram is considered to be the origin of modern supramolecular chemistry. 30 years ago transition metals and their complexes were not regarded as important to this science. Transition Metals in Supramolecular Chemistry clearly demonstrates that today, transition metal complexes are routinely used to build large multicomponent architectures which display new and exciting applications including molecular switches, liquid crystals, and molecular magnets. Contents * Ligand and Metal Control of Self-Assembly in Supramolecular Chemistry * Bistability in Iron (II) Spin-Crossover Systems: A Supramolecular Function * Luminescent Sensors with and for Transition Metals * The Chirality of Polynuclear Transition Metal Complexes * Design and Serendipity in the Synthesis of Polynuclear Compounds of the 3d-metals * Rotaxanes: From Random to Transition Metal-Templated Threading of Rings at the Molecular Level * Metallomesogens - Supramolecular Organisation of Metal Complexes in Fluid Phases * Self-Assembly of Interlocked Structures with Cucurbituril Metal Ions and Metal Complexes Reflecting contemporary science, Transition Metals in Supramolecular Chemistry will inspire scientists and students interested in coordination chemistry, magnetochemistry, molecular sensors and switches, liquid crystals and artificial systems.
Download or read book Transition Metal Complexes of Phosphorus Arsenic and Antimony Ligands written by Charles Andrew McAuliffe and published by John Wiley & Sons. This book was released on 1973 with total page 458 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Macromolecules Containing Metal and Metal Like Elements Metal Coordination Polymers written by Alaa S. Abd-El-Aziz and published by Wiley-Interscience. This book was released on 2005-07-22 with total page 400 pages. Available in PDF, EPUB and Kindle. Book excerpt: This series provides a useful, applications-oriented forum for the next generation of macromolecules and materials. The fifth volume in this series provides useful descriptions of the transition metals and their applications. Transition Metals are covered in 2 volumes, the second part is covered in Volume 6.
Download or read book Polynuclear Transition Metal Complexes Containing Azido and Pyrazolinato Bridging Ligands written by Stephanos Organtzis and published by . This book was released on 2008 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Polynuclear Transition Metal Complexes Containing Azido and Pyrazolinato Bridging Ligands written by Stephanos Organtzis and published by . This book was released on 2008 with total page 220 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Rings Clusters and Polymers of Main Group and Transition Elements written by H. W. Roesky and published by Elsevier Publishing Company. This book was released on 1989 with total page 568 pages. Available in PDF, EPUB and Kindle. Book excerpt: The chemistry of rings, clusters and polymers is becoming an important branch of inorganic and organometallic chemistry. Although inorganic rings have been known for more than 150 years, they have only been structurally characterized within the last fifty years. Inorganic and organometallic clusters and polymers have recently become the subject of intense interest and study because of their unusual properties and their potential for applications in the areas of catalysis, electronics and ceramics. Transition metal clusters have been examined as models for heterogeneous catalysts. Both rings and clusters might function as potential building blocks for extended solid state systems. In comparison with organic polymers, however, general and versatile methods for the synthesis of inorganic and organometallic polymers are not readily available. In particular, the preparation of polymers containing transition metal atoms in the polymer backbone is a challenge to inorganic chemistry. This book describes the rapid development which has taken place in this field.
Download or read book Polynuclear Main Group and Transition Metal Complexes Containing the Tridentate Ligand Bis diphenylphosphinomethyl phenylarsine written by Philip Edward Reedy and published by . This book was released on 1987 with total page 614 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Inorganic Reactions and Methods The Formation of Bonds to N P As Sb Bi Part 2 written by A. D. Norman and published by John Wiley & Sons. This book was released on 2009-09-17 with total page 514 pages. Available in PDF, EPUB and Kindle. Book excerpt: For the first time the discipline of modern inorganic chemistry has been systematized according to a plan constructed by a council of editorial advisors and consultants, among them three Nobel laureates (E.O. Fischer, H. Taube and G. Wilkinson). Rather than producing a collection of unrelated review articles, the series creates a framework which reflects the creative potential of this scientific discipline. Thus, it stimulates future development by identifying areas which are fruitful for further research. The work is indexed in a unique way by a structured system which maximizes its usefulness to the reader. It augments the organization of the work by providing additional routes of access for specific compounds, reactions and other topics.
Download or read book Di and Polynuclear Compounds 5 written by Ulf Thewalt and published by Springer Science & Business Media. This book was released on 2013-12-11 with total page 432 pages. Available in PDF, EPUB and Kindle. Book excerpt: The present volume is the fifth and for the present moment last in a series of volumes on organotitanium compounds. It covers the literature to the end of 1987. The volume continues the treatment of titanium compounds with the dinuclear and polynuclear complexes. The main part of this volume deals with the dinuclear complexes and therein (+-C5H5)2TiCl 2 is the most frequently described compound. Another key compound in this volume is the presumably oligomeric +-C5H5TiCl2 n. This volume also deals with different "titanocenes" de- scribed in the literature. There are also well-defined tri- and tetranuclear compounds, one penta- and a few hexanuclear compounds. "Black titanocene" is described together with the oligonuclear compounds. Polymers containing (+-C5H5)2TiIV units conclude this volume. As in the preceding volumes of this series, compounds of debatable existence and postulated reaction intermediates are included for completeness. A Formula Index and a Ligand Formula Index for this volume are included.
Download or read book Spectroscopic Properties of Inorganic and Organometallic Compounds written by Jack Yarwood and published by Royal Society of Chemistry. This book was released on 2009-04-30 with total page 448 pages. Available in PDF, EPUB and Kindle. Book excerpt: Spectroscopic Properties of Inorganic and Organometallic Compounds: Techniques, Materials and Applications provides a unique source of information in an important area of chemistry.
Download or read book Trinuclear Compounds b written by and published by Springer. This book was released on 1992-06-16 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: The volume closes the gap that exists within the "C" series on polynuclear compounds. It describes the trinuclear organoiron compounds containing only ligands of the 1L type, i.e., those carbon ligands bonded to iron through one carbon atom per ligand such as terminal and bridging carbonyls, isocyanides, and various triply bridging carbon groups. Other trinuclear compounds with nL ligands of higher order (n = 2 or more) have already been treated in Organoiron Compounds C7, 1985. Volume C 6b describes Fe3(CO)n compounds in which n = 10 and 11. The great variety of cluster types originates in (a) the existence of noncarbon ligands with Group 16 to 13 elements acting as iron-bridging atoms, (b) many hydrogen-bridged clusters and their corresponding deprotonated anions, and (c) numerous derivatives with donor ligands (2D) replacing terminal carbonyl groups. In addition, there are compounds containing other transition metals (M) in an Fe3Mx skeleton. The ÄHFe3(CO)11Ü - and ÄFe3(CO)11Ü 2- anions, their properties and derivatives are described in detail as they play an important role in many preparations and reactions of trinuclear iron carbonyl complexes. Many of the typical cluster structures, determined by X-ray diffraction analyses, are illustrated. This present volume contains an Empirical Formula Index and Ligand Formula Index for all of the compounds in volumes C 6a and C 6b.
Download or read book Ytterbium II Group 6 7 Transition Metal Carbonyl Complexes written by Pavel V. Poplaukhin and published by . This book was released on 2006 with total page 202 pages. Available in PDF, EPUB and Kindle. Book excerpt: Abstract: New carbonyl complexes of divalent ytterbium and transition metals of groups 6, 7 of the periodic table have been prepared. The syntheses were carried out in systematic fashion with the aim of establishing general procedures suitable for preparation of a range of compounds of this type. The products obtained were characterized by means of IR spectroscopy and X-ray single crystal diffraction. Nineteen X-ray structures are reported herein, of which only one has been published before. The compounds studied can be divided into two major groups: the solvent-separated ion pairs, where the YbII cation is surrounded with solvent molecules acting as ligands, preventing interaction with the metal carbonylate anion; and complexes with the bridging carbonyl ligands (isocarbonyl ligands), where the cation and the anion are bound together through a -CO- link. New instances of condensation of the solvent-separated ion pairs into the isocarbonyl complexes have been discovered, and the mechanism for such transformation was proposed. The novel [Hg(W(CO)5)2]2− anion was discovered and characterized by X-ray single crystal diffraction. Its reactivity was briefly investigated.
Download or read book Nomenclature of Inorganic Chemistry written by International Union of Pure and Applied Chemistry and published by Royal Society of Chemistry. This book was released on 2005 with total page 379 pages. Available in PDF, EPUB and Kindle. Book excerpt: The 'Red Book' is the definitive guide for scientists requiring internationally approved inorganic nomenclature in a legal or regulatory environment.
Download or read book Chemistry of polynuclear metal complexes with bridging carebe or carbyne ligands part 90 written by Simon J. Davies and published by . This book was released on 1989 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Aliphatic Compounds written by S. Coffey and published by Elsevier. This book was released on 2016-06-03 with total page 330 pages. Available in PDF, EPUB and Kindle. Book excerpt: Rodd's Chemistry of Carbon Compounds: A Modern Comprehensive Treatise, Second Edition, Volume I, Part B: Monohydric Alcohols: Their Ethers and Esters, Sulfur Analogues, Nitrogen Derivatives, Organometallic Compounds focuses on the reactions, characteristics, transformations, and methodologies involved in halogeno- and nitroalkanols, singly-linked, mono-substituted, aliphatic hydrocarbons, and sulfur analogues of alcohols and their derivatives. The selection first offers information on the ethers and esters of monohydric alcohols and sulfur analogues of alcohols and their derivatives. Topics include alkyl peroxides, esters of mineral or organic acids, sulfides or thio-esters, alkyl polysulfides, alkylthiosulfuric acids, dialkyl sulfoxides or alkylsulphinylalkanes, and sulfones. The book also considers nitrogen derivatives of aliphatic hydrocarbons, as well as amines and quaternary ammonium compounds, nitro-and nitroso-compounds, and N-substituted derivatives of the alkylamines. The publication takes a look at aliphatic organometallic and organometalloidal compounds. Discussions focus on beryllium, magnesium, calcium, strontium, and barium, lithium, sodium, potassium, and rubidium, and boron, aluminum, gallium, indium, and thallium. The text is a valuable reference for readers interested in carbon compounds.
