Download or read book Photoionization of Rare Gas Clusters written by Huaizhen Zhang and published by . This book was released on 2009 with total page 182 pages. Available in PDF, EPUB and Kindle. Book excerpt: This thesis concentrates on the study of photoionization of van der Waals clusters[sic] with different cluster sizes. The goal of the experimental investigation is to understand the electronic structure of van der Waals clusters and the electronic dynamics. These studies are fundamental to understand the interaction between UV-X rays and clusters. The experiments were performed at the Advanced Light Source at Lawrence Berkeley National Laboratory. The experimental method employs angle-resolved time-of-flight photoelectron spectrometry, one of the most powerful methods for probing the electronic structure of atoms, molecules, clusters and solids. The van der Waals cluster photoionization studies are focused on probing the evolution of the photoelectron angular distribution parameter as a function of photon energy and cluster size. The angular distribution has been known to be a sensitive probe of the electronic structure in atoms and molecules. However, it has not been used in the case of van der Waals clusters. We carried out outer-valence levels, inner-valence levels and core-levels cluster photoionization experiments. Specifically, this work reports on the first quantitative measurements of the angular distribution parameters of rare gas clusters as a function of average cluster sizes. Our findings for xenon clusters is that the overall photon-energy-dependent behavior of the photoelectrons from the clusters is very similar to that of the corresponding free atoms. However, distinct differences in the angular distribution point at cluster-size-dependent effects were found. For krypton clusters, in the photon energy range where atomic photoelectrons have a high angular anisotropy, our measurements show considerably more isotropic angular distributions for the cluster photoelectrons, especially right above the 3d and 4p thresholds. For the valence electrons, a surprising difference between the two spin-orbit components was found. For argon clusters, we found that the angular distribution parameter values of the two-spin-orbit components from Ar2p clusters are slightly difference. When comparing the [Beta] values for Ar between atoms and clusters, we found different results between Ar 3s atoms and clusters, and between Ar 3p atoms and clusters. Argon cluster resonance from surface and bulk were also measure. Furthermore, the angular distribution parameters of Ar cluster photoelectrons and Ar atom photoelectrons in the 3s [rightwards arrow] np ionization region were obtained.
Download or read book Size Effects in Angle Resolved Photoelectron Spectroscopy of Free Rare Gas Clusters written by and published by . This book was released on 2007 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The photoionization of free Xe clusters is investigated by angle-resolved time-of-flight photoelectron spectroscopy. The measurements probe the evolution of the photoelectron angular distribution parameter as a function of photon energy and cluster size. While the overall photon-energy-dependent behavior of the photoelectrons from the clusters is very similar to that of the free atoms, distinct differences in the angular distribution point at cluster-size-dependent effects. Multiple scattering calculations trace their origin to elastic photoelectron scattering.
Download or read book Electron Impact Ionization Studies of Small Rare Gas Clusters written by Thomas Pflüger and published by . This book was released on 2012 with total page 158 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Rare Gas Clusters Containing Charged Atoms written by and published by . This book was released on 1992 with total page 58 pages. Available in PDF, EPUB and Kindle. Book excerpt: Three kinds of rare gas (R) containing clusters are considered in this article: (1) ionic clusters Rn+ and (R M)+, M being another atom or a molecule, (2) neutral rare gas-halogen n n clusters R n X with R X electron transfer, and (3) Rydberg excited R n clusters. These clusters have much in common, as all of them contain ions or ionic cores, with the positive charge delocalized mostly between some number of atoms. Such systems can be treated by the semiempirical diatomics-in-ionic-systems (DIIS) method. We present in this article a brief description of the DIIS method and the results of its applications to the kinds of clusters mentioned above. The article presents also discussions of results obtained by other theoretical methods and experimental studies.
Download or read book Photoionization and Photo Induced Processes in Mass Spectrometry written by Ralf Zimmermann and published by John Wiley & Sons. This book was released on 2021-07-06 with total page 448 pages. Available in PDF, EPUB and Kindle. Book excerpt: Provides comprehensive coverage of laser-induced ionization processes for mass spectrometry analysis Drawing on the expertise of the leading academic and industrial research groups involved in the development of photoionization methods for mass spectrometry, this reference for analytical scientists covers both the theory and current applications of photo-induced ionization processes. It places widely used techniques such as MALDI side by side with more specialist approaches such as REMPI and RIMS, and discusses leading edge developments in ultrashort laser pulse desorption, to give readers a complete picture of the state of the technology. Photoionization and Photo-Induced Processes in Mass Spectrometry: Fundamentals and Applications starts with a complete overview of the fundamentals of the technique, covering the basics of the gas phase ionization as well as those of laser desorption and ablation, pulse photoionization, and single particle ionization. Numerous application examples from different analytical fields are described that showcase the power and the wide scope of photo ionization in mass spectrometry. -The first general reference book on photoionization techniques for mass spectrometry -Examines technologies and applications of gas phase resonance-enhanced multiphoton ionization mass spectrometry (REMPI-MS) and gas phase resonance ionization mass spectrometry (RIMS) -Provides complete coverage of popular techniques like MALDI -Discusses the current and potential applications of each technology, focusing on process and environmental analysis Photoionization and Photo-Induced Processes in Mass Spectrometry: Fundamentals and Applications is an excellent book for spectroscopists, analytical chemists, photochemists, physical chemists, and laser specialists.
Download or read book Vacuum Ultraviolet Photoionization and Photodissociation of Molecules and Clusters written by Cheuk-Yiu Ng and published by World Scientific. This book was released on 1991 with total page 590 pages. Available in PDF, EPUB and Kindle. Book excerpt: This monograph reviews the recent progress in vacuum ultraviolet (VUV) photoionization and photodissociation processes. Photoionization, photoelectron, and fluorescence spectroscopic techniques have played an important role in revealing the photoionization and photodissociation dynamics of molecules in the vacuum ultraviolet region and in providing accurate energetic and spectroscopic information of ions as well as neutral molecules. The book represents the first detailed review of major experimental developments in the studies of single vacuum ultraviolet photon ionization and dissociation processes of gaseous molecules and clusters.
Download or read book The Physics and Chemistry of Nanosolids written by Frank J. Owens and published by John Wiley & Sons. This book was released on 2008-04-11 with total page 557 pages. Available in PDF, EPUB and Kindle. Book excerpt: A comprehensive textbook that addresses the recent interest in nanotechnology in the engineering, materials science, chemistry, and physics communities In recent years, nanotechnology has become one of the most promising and exciting fields of science, triggering an increasing number of university engineering, materials science, chemistry, and physics departments to introduce courses on this emerging topic. Now, Drs. Owens and Poole have revised, updated, and revamped their 2003 work, Introduction to Nanotechnology, to make it more accessible as a textbook for advanced undergraduate- and graduate-level courses on the fascinating field of nanotechnology and nanoscience. The Physics and Chemistry of Nanosolids takes a pedagogical approach to the subject and assumes only an introductory understanding of the physics and chemistry of macroscopic solids and models developed to explain properties, such as the theory of phonon and lattice vibrations and electronic band structure. The authors describe how properties depend on size in the nanometer regime and explain why these changes occur using relatively simple models of the physics and chemistry of the solid state. Additionally, this accessible book: Provides an introductory overview of the basic principles of solids Describes the various methods used to measure the properties of nanosolids Explains how and why properties change when reducing the size of solids to nano-dimensions, and what they predict when one or more dimensions of a solid has a nano-length Presents data on how various properties of solids are affected by nanosizing and examines why these changes occur Contains a chapter entirely devoted to the importance of carbon nanostructured materials and the potential applications of carbon nanostructures The Physics and Chemistry of Nanosolids is complete with a series of exercises at the end of each chapter for readers to enhance their understanding of the material presented, making this an ideal textbook for students and a valuable tutorial for technical professionals and researchers who are interested in learning more about this important topic.
Download or read book Electronic Excitations in Rare Gas Clusters the Evolution of Energy Levels from the Atom to the Solid h written by Thomas Möller and published by . This book was released on 1991 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Atomic and Molecular Clusters written by Roy L. Johnston and published by CRC Press. This book was released on 2002-04-25 with total page 258 pages. Available in PDF, EPUB and Kindle. Book excerpt: Cluster physics is the foundation of the increasingly important field of nanotechnology. Clusters, ranging in size from a few to many millions of atoms, constitute a fascinating field of research in physics, chemistry and materials science. They are formed by most of the elements of the Periodic Table, and the types of bonding and the resultant clusters are equally as varied. This book introduces atomic clusters, ranging from weakly-bonded clusters of argon to strongly-bonded carbon clusters and metal nano-particles. It includes worked examples to enable lecturers and students to gauge their understanding and progress. Atomic and Molecular Clusters describes the experimental generation, detection and interrogation of clusters and theoretical approaches developed to aid understanding of their physical properties. It classifies clusters according to their bonding types and gives examples of present and possible future applications of clusters in electronic, optical and magnetic devices.
Download or read book A Photoionization Study of Cluster Species Present in Gas Vapors and Those Created by Condensation in a Supersonic Molecular Beam written by James W. Taylor and published by . This book was released on 1976 with total page 9 pages. Available in PDF, EPUB and Kindle. Book excerpt: This interim report summarizes the results of studies on clusters sampled by and produced through a supersonic molecular beam sampling system. Photoionization cross section measurements were used to calibrate mass spectral ion signals and to study beam discrimination effects. Heats of formation data were obtained for clusters of carbon dioxide, methanol, methanol-d1, ethanol, and trifluoroethanol. (Author).
Download or read book Clusters and Small Particles written by Boris Mikhaĭlovich Smirnov and published by Springer Science & Business Media. This book was released on 2000-06-08 with total page 372 pages. Available in PDF, EPUB and Kindle. Book excerpt: Not merely a discussion of small particles or clusters of atoms, molecules, but also the systems they constitute. The goal is to analyse the properties of such finite aggregates and their behaviour in gases and plasmas, and to investigate processes that involve such clusters, based on lectures and seminar problems for graduates. The main part of the book includes more than 200 problems, covering collisions, charge transfer, chemical reactions, condensed systems and their structures, kinetics of cluster growth, excited clusters, the transition from clusters to bulk particles, and small particles, dust, and aerosols in plasmas. Reference data for corresponding parameters of systems under consideration is given in the appendices. Of interest to physicists, astrophysicists, and chemists.
Download or read book Physics and Chemistry of Small Clusters written by P. Jena and published by Springer. This book was released on 1987-08 with total page 984 pages. Available in PDF, EPUB and Kindle. Book excerpt: Recent advances in experimental techniques now enable researchers to produce in a laboratory clusters of atoms of desired composition from any of the elements of the periodic table. This has created a new area of research into novel materials since clusters cannot be regarded either as a "large" molecule or as a fragment of the bulk. Both experimental and theoretical studies are revealing unusual properties that are not ob served in solid state environments. The structures of micro-clusters are found to be significantly distorted from the most symmetric arrangement, some even exhibiting pentagonal symmetry commonly found in icosahedric structures. The unusual stability of certain clusters, now described as "magic number species", shows striking similarities with the nuclear shell structure. The relative stabilities of clusters depend not only on the composition of the clusters but also on their charged states. The studies on spontaneous fragmentation of mUltiply charged clusters, commonly referred to as Coulomb explosion, illustrate the role of electronic bonding mechanisms on stability of clusters. The effect of foreign atoms on geometry and stability of clusters and the interaction of gas atoms with clusters are showing promise for an indepth understanding of chemisorption and catalysis. The magnetic and optical properties are dependent not only on cluster size but also on its geometry. These findings have the potential for aiding industry in the area of micro-electronics and catalysis.
Download or read book Properties of Rare Gas Clusters and Cluster surface Impact written by Syargey Prasalovich and published by . This book was released on 2005 with total page 72 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Rare Gas Atoms and Cluster of Atoms Inside Microporous Solids written by Boyong Chen and published by . This book was released on 1997 with total page 336 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Cluster Models for Surface and Bulk Phenomena written by Gianfranco Pacchioni and published by Springer Science & Business Media. This book was released on 2013-03-08 with total page 683 pages. Available in PDF, EPUB and Kindle. Book excerpt: It is widely recognized that an understanding of the physical and chemical properties of clusters will give a great deal of important information relevant to surface and bulk properties of condensed matter. This relevance of clusters for condensed matter is one of the major motivations for the study of atomic and molecular clusters. The changes of properties with cluster size, from small clusters containing only a few atoms to large clusters containing tens of thousands of atoms, provides a unique way to understand and to control the development of bulk properties as separated units are brought together to form an extended system. Another important use of clusters is as theoretical models of surfaces and bulk materials. The electronic wavefunctions for these cluster models have special advantages for understanding, in particular, the local properties of condensed matter. The cluster wavefunctions, obtained with molecular orbital theory, make it possible to relate chemical concepts developed to describe chemical bonds in molecules to the very closely related chemical bonding at the surface and in the bulk of condensed matter. The applications of clusters to phenomena in condensed matter is a cross-disciplinary activity which requires the interaction and collaboration of researchers in traditionally separate areas. For example, it is necessary to bring together workers whose background and expertise is molecular chemistry with those whose background is solid state physics. It is also necessary to bring together experimentalists and theoreticians.
Download or read book Latest Advances In Atomic Clusters Collisions Fission Fusion Electron Ion And Photon Impact written by Jean-patrick Connerade and published by World Scientific. This book was released on 2004-11-24 with total page 398 pages. Available in PDF, EPUB and Kindle. Book excerpt: This comprehensive volume surveys the general aspects of atomic cluster science and outlines some of its important new challenges. It begins by detailing the recent advances in the understanding of structure and the essential properties of selected atomic cluster systems, fullerenes and confined atoms. Recent advances in the field of photo processes involving atomic clusters and fullerenes are discussed, and an entire chapter is devoted to the problem of fission dynamics of atomic clusters, presenting parallels with similar processes in nuclear physics.The book goes on to describe the problems of electron-cluster collisions with special emphasis on polarization and collective excitation effects. The important area of the behavior of atomic clusters in laser fields is considered; the ionization, collective dynamics of electrons in the system in the presence of the laser field, and the laser induced dynamics of molecules and clusters are thoroughly described.Finally, a broad spectrum of problems in the area of ionic collisions with fullerenes and metal clusters is covered — from both experimental and theoretical points of view — and the results of the most recent measurements are reported. The concluding chapter takes a careful look at the interaction of an atomic cluster with a surface. The problems of cluster deposition and formation at a surface as well as collision processes involving clusters deposited at a surface are considered through a number of illustrative examples./a
Download or read book Progress in Experimental and Theoretical Studies of Clusters written by Tamotsu Kondow and published by World Scientific. This book was released on 2003 with total page 293 pages. Available in PDF, EPUB and Kindle. Book excerpt: The cluster which is an ensemble of two thousands of atoms or molecules, has emerged as a completely new class of materials at the frontier of materials science. The frontier of cluster science extends so rapidly that the map of the science is renewed day by day. In order to provide basic knowledge and recent information on this growing field, 14 world-renowned scientists who are actively involved experimentally and theoretically in cluster science have written this book, which is concise, comprehensive, suitable for students at both the undergraduate and the graduate level, as well as people who work outside cluster science.
