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Book Chemical Interactions of Polycyclic Organic Compounds with Coal Fly Ash and Related Solid Surfaces

Download or read book Chemical Interactions of Polycyclic Organic Compounds with Coal Fly Ash and Related Solid Surfaces written by and published by . This book was released on 1990 with total page 13 pages. Available in PDF, EPUB and Kindle. Book excerpt: The interactions of polycyclic aromatic hydrocarbons (PAHs) with particulate surfaces (especially those of coal fly ash) have been investigated, and the influence of coal ash surface properties on the photochemical transformation of adsorbed PAHs has been studied. The overall objective of the work has been to characterize the effects of adsorption onto atmospheric particulate matter on the chemical behavior of PAHs released into the atmosphere via combustion processes. Progress is reported in the following areas of effort: (a) Major emphasis has been devoted to the interactions of PAHs with the different particulate phases that are found in heterogeneous coal ash samples. Techniques have been developed and thoroughly characterized for the fractionation of coal ashes into carbonaceous, mineral-magnetic, and mineral-nonmagnetic subfractions. Heats of adsorption for pyrene on such subfractions have been measured by gas-solid chromatography, and the photoreactivity of pyrene and benz[a]anthracene on ash subfractions has been examined. Carbonaceous particles exhibit the highest affinity for vapor-phase PAHS; mineral magnetic particles usually exhibit the smallest tendency to sorb PAHs from the vapor phase. Adsorption of PAHs on carbonaceous particles suppresses, virtually completely, their tendency to undergo photochemical transformation. For coal ashes that contain few carbonaceous particles, the adsorption and photochemical transformation of PAHs tend to be dominated by the mineral nonmagnetic particles; PAHs adsorbed on these particles tend to exhibit relatively efficient phototransformation.

Book Chemical Interactions of Polycyclic Organic Compounds with Coal Fly Ash and Related Solid Surfaces  Final Report  July 1  1987  December 31  1989

Download or read book Chemical Interactions of Polycyclic Organic Compounds with Coal Fly Ash and Related Solid Surfaces Final Report July 1 1987 December 31 1989 written by and published by . This book was released on 1990 with total page 13 pages. Available in PDF, EPUB and Kindle. Book excerpt: The interactions of polycyclic aromatic hydrocarbons (PAHs) with particulate surfaces (especially those of coal fly ash) have been investigated, and the influence of coal ash surface properties on the photochemical transformation of adsorbed PAHs has been studied. The overall objective of the work has been to characterize the effects of adsorption onto atmospheric particulate matter on the chemical behavior of PAHs released into the atmosphere via combustion processes. Progress is reported in the following areas of effort: (a) Major emphasis has been devoted to the interactions of PAHs with the different particulate phases that are found in heterogeneous coal ash samples. Techniques have been developed and thoroughly characterized for the fractionation of coal ashes into carbonaceous, mineral-magnetic, and mineral-nonmagnetic subfractions. Heats of adsorption for pyrene on such subfractions have been measured by gas-solid chromatography, and the photoreactivity of pyrene and benz[a]anthracene on ash subfractions has been examined. Carbonaceous particles exhibit the highest affinity for vapor-phase PAHS; mineral magnetic particles usually exhibit the smallest tendency to sorb PAHs from the vapor phase. Adsorption of PAHs on carbonaceous particles suppresses, virtually completely, their tendency to undergo photochemical transformation. For coal ashes that contain few carbonaceous particles, the adsorption and photochemical transformation of PAHs tend to be dominated by the mineral nonmagnetic particles; PAHs adsorbed on these particles tend to exhibit relatively efficient phototransformation.

Book Photochemical and Supercritical Fluid Extraction Studies of Polycyclic Aromatic Hydrocarbons Adsorbed on Coal Stack Ash Fractions

Download or read book Photochemical and Supercritical Fluid Extraction Studies of Polycyclic Aromatic Hydrocarbons Adsorbed on Coal Stack Ash Fractions written by Robert Frank Mauldin and published by . This book was released on 1990 with total page 238 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Aquatic and Surface Photochemistry

Download or read book Aquatic and Surface Photochemistry written by George R. Helz and published by CRC Press. This book was released on 2018-01-10 with total page 571 pages. Available in PDF, EPUB and Kindle. Book excerpt: Aquatic and Surface Photochemistry provides a broad overview of current research in the emerging field of environmental aquatic and surface photochemistry. Selected reviews and current research articles are blended to provide an in-depth treatment of various aspects of this research area. The first part of the text deals with photochemistry in the environment, covering recent research on the following topics: aquatic photochemistry of organic pollutants and agrochemicals, photochemical cycling of carbon and transition metals (especially iron), photochemical formation of reactive oxygen species in natural waters, photoreaction in cloud and rain droplets, and photoreactions on environmental surfaces (soil, ash, metal, oxide). The second part provides discussions and data on both heterogeneous photocatalytic and homogeneous processes, with topics ranging from applications to mechanistic studies. These chapters illustrate the wide diversity of pollutant classes that are degradable by photochemical techniques and the effects of various reaction conditions on the rates and efficiency of the techniques. Current kinetic studies are presented, which provide new information about the role of adsorption and the nature of the reactive oxidizing species that mediate these photoremediation processes.This book will interest civil, chemical, and environmental engineers, as well as chemists, soil scientists, geochemists, and atmospheric chemists.

Book Energy Research Abstracts

Download or read book Energy Research Abstracts written by and published by . This book was released on 1993 with total page 490 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Photochemical Investigations of Surface Adsorbed Polycyclic Aromatic Hydrocarbons

Download or read book Photochemical Investigations of Surface Adsorbed Polycyclic Aromatic Hydrocarbons written by Anthony Dewayne Hipps and published by . This book was released on 1989 with total page 144 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Environmental Health Perspectives

Download or read book Environmental Health Perspectives written by and published by . This book was released on 1993 with total page 388 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Fossil Energy Update

Download or read book Fossil Energy Update written by and published by . This book was released on 1981 with total page 1002 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Environmental Chemistry

    Book Details:
  • Author : Eric Lichtfouse
  • Publisher : Springer Science & Business Media
  • Release : 2005
  • ISBN : 9783540228608
  • Pages : 818 pages

Download or read book Environmental Chemistry written by Eric Lichtfouse and published by Springer Science & Business Media. This book was released on 2005 with total page 818 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book describes advances in this new, fast developing science, which seeks to decipher fundamental mechanisms ruling the behaviour in water, soils, atmosphere, food and living organisms of toxic metals, fossil fuels, pesticides and other organic pollutants. Sections on eco-toxicology, green chemistry, and analytical chemistry round out this thorough survey of conditions and analytical techniques in an emerging specialty.

Book PAHs

    Book Details:
  • Author : Peter E. T. Douben
  • Publisher : John Wiley & Sons
  • Release : 2003-07-25
  • ISBN : 047086429X
  • Pages : 404 pages

Download or read book PAHs written by Peter E. T. Douben and published by John Wiley & Sons. This book was released on 2003-07-25 with total page 404 pages. Available in PDF, EPUB and Kindle. Book excerpt: Polycyclic aromatic hydrocarbons (PAHs), or polyarenes, are one of the largest and most structurally diverse class of organic molecules known. High percentages of polyarenes, representing a wide range of molecular sizes and structural types, are present in coal tars and petroleum residues. The major sources of PAHs are crude oil, coal and oil shale. The fuels produced from these fossil sources constitute the primary source of energy for the industrial nations of the world, and the petrochemicals from these raw materials are the basis of the synthetic fibre and plastics industries. PAHs are however, widespread pollutants and their impact on the environment and human health must be monitored and controlled. This book will review and assess our scientific understanding of the ecological exposure and effects PAHs have in different environments and habitats. It will accomplish this by taking the recipients of the pollution in the environment as starting points and working its way back through pathways to access what is required for our understanding of effects and rationale for control. Although this book will concentrate on ecological exposure of PAHs, the general impacts of PAHs on human populations will be touched upon. It is thought to be the first book to focus on the ecological aspects of PAHs.

Book Acid Precipitation

    Book Details:
  • Author :
  • Publisher :
  • Release : 1984
  • ISBN :
  • Pages : 428 pages

Download or read book Acid Precipitation written by and published by . This book was released on 1984 with total page 428 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Indexes

    Book Details:
  • Author : United States. Environmental Protection Agency
  • Publisher :
  • Release : 1983
  • ISBN :
  • Pages : 1760 pages

Download or read book Indexes written by United States. Environmental Protection Agency and published by . This book was released on 1983 with total page 1760 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Groundwater Chemicals Desk Reference

Download or read book Groundwater Chemicals Desk Reference written by John H. Montgomery and published by CRC Press. This book was released on 2010-12-12 with total page 1388 pages. Available in PDF, EPUB and Kindle. Book excerpt: The latest edition of the bestselling Groundwater Chemicals Desk Reference has been thoroughly updated and expanded. In addition to information concerning the environmental fate and transport in various media, organic priority pollutants and chemicals commonly found in the workplace and the environment, it includes toxicity information for mammals and aquatic species in a clear, consistent format.

Book Abstracts of Papers

    Book Details:
  • Author : American Chemical Society. Meeting
  • Publisher :
  • Release : 1986
  • ISBN :
  • Pages : 1222 pages

Download or read book Abstracts of Papers written by American Chemical Society. Meeting and published by . This book was released on 1986 with total page 1222 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Smoke in Food Processing

Download or read book Smoke in Food Processing written by Joseph A. Maga and published by CRC Press. This book was released on 2018-02-06 with total page 168 pages. Available in PDF, EPUB and Kindle. Book excerpt: Smoking was one of the first forms of food processing, and through the centuries the chemistry of smoke has slowly evolved.It is now known that wood and food composition can significantly influence smoke composition, as well as the resulting textual, sensory, nutritional, antioxidative, and antimicrobial properties of the smoked food.Aside from beneficial properties, one must also consider potential health concerns associated with certain woods and their resulting smoke.