Download or read book Photochemical Charge Transfer in Nanostructured Photocatalysts for Solar Hydrogen Production written by Jiarui Wang and published by . This book was released on 2015 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Solar energy is a promising sustainable energy source to reduce greenhouse gas emission from combustion of fossil fuels and slow down the global climate change. Solar hydrogen generation via photocatalytic water splitting is potentially the most cost-effective way to produce solar fuels, so the development of efficient photocatalysts is one of the most important targets for scientific research. However, the application of inorganic materials for solar water splitting is currently limited by our understanding of photochemical charge transfer on the nanoscale, where space charge layers are less effective for carrier separation. Therefore, this dissertation focuses on the preparation of well-defined photocatalysts for the water splitting reaction and on the characterization of photochemical charge transfer on their interfaces. This will be accomplished through the application of surface photovoltage and photoelectrochemical measurements, and with photocatalytic reactivity tests. Results from this study can guide the design of inorganic photocatalysts with improved efficiency for solar energy conversion into fuel. Chapter 2 describes surface photovoltage spectroscopy studies to measure the internal photovoltages in a hydrogen evolution photocatalyst, single crystalline platinum/ruthenium-modified Rh-doped SrTiO3 nanocrystals. Voltages of -0.88 V and -1.13 V are found between the light absorber and the Ru and Pt cocatalysts, respectively, and a voltage of -1.48 V for a Rh-doped SrTiO3 film on an Au substrate. The voltages shows that the Pt and Ru cocatalysts not only improve the redox kinetics but also aid charge separation in the absorber. The voltages with redox agents correlate well with the photocatalytic performance of the catalyst and are influenced by the built-in potentials of the donor-acceptor configurations, the physical separation of donors and acceptors, and the reversibility of the redox reaction. The photovoltage data also allow the identification of a photosynthetic system for hydrogen evolution (80 [mu]mol·g−11h−1) under visible light illumination (>400 nm) from 0.05 M aqueous K4[Fe(CN)6]. Chapter 3 shows that suspended p-Si nanowires obtained by etching of an Al-doped silicon wafer facilitate photochemical hydrogen evolution under visible light. The activity varies greatly between sacrificial donors and can be increased by attachment of MoS2 cocatalysts, which promote proton reduction and charge transfer at the silicon-MoS2 interface. Overall, the activity of suspended p-Si nanorods is limited by the stability of the material in neutral solutions. A basic or neutral environment with photo-excitation can lead to silicon corrosion. In 0.05 M ferrocyanide at pH 6.5, the hydrogen evolution rate for SiNW/MoS2 was as high as 106 [mu]mol (10mg)−1 h−1 accompanied by silicon corrosion. The rate without corrosion decreased to 0.64 [mu]mol (10mg)−1 h−1 at a lower pH of 4.7. With silicon corrosion, the rate also reached 117 [mu]mol (10mg)−1 h−1 in pH 6.5 0.05 M Na2SO3 solution and 678 [mu]mol (10mg)−1 h−1 in 0.1 M NaSH without pH control. Silicon corrosion was not found in formaldehyde and methanol solutions, but the rates of SiNW/MoS2 and SiNW were as low as 0.40 and 0.18 [mu]mol (10mg)−1 h−1 for methanol solution, and 0.71 and 0.27 [mu]mol (10mg)−1 h−1 for formaldehyde solution. The increased hydrogen evolution with silicon corrosion can be attributed to both electron donating of silicon and reduced charge transfer resistivity with the dissolution of surface oxide layer on silicon nanowires. These findings can improve the understanding of photochemistry of Si-MoS2 catalyst, and help avoiding silicon corrosion in photocatalysis.

Download or read book Photo and Electro Catalytic Processes written by Jianmin Ma and published by John Wiley & Sons. This book was released on 2022-01-25 with total page 596 pages. Available in PDF, EPUB and Kindle. Book excerpt: Explore green catalytic reactions with this reference from a renowned leader in the field Green reactions—like photo-, photoelectro-, and electro-catalytic reactions—offer viable technologies to solve difficult problems without significant damage to the environment. In particular, some gas-involved reactions are especially useful in the creation of liquid fuels and cost-effective products. In Photo- and Electro-Catalytic Processes: Water Splitting, N2 Fixing, CO2 Reduction, award-winning researcher Jianmin Ma delivers a comprehensive overview of photo-, electro-, and photoelectron-catalysts in a variety of processes, including O2 reduction, CO2 reduction, N2 reduction, H2 production, water oxidation, oxygen evolution, and hydrogen evolution. The book offers detailed information on the underlying mechanisms, costs, and synthetic methods of catalysts. Filled with authoritative and critical information on green catalytic processes that promise to answer many of our most pressing energy and environmental questions, this book also includes: Thorough introductions to electrocatalytic oxygen reduction and evolution reactions, as well as electrocatalytic hydrogen evolution reactions Comprehensive explorations of electrocatalytic water splitting, CO2 reduction, and N2 reduction Practical discussions of photoelectrocatalytic H2 production, water splitting, and CO2 reduction In-depth examinations of photoelectrochemical oxygen evolution and nitrogen reduction Perfect for catalytic chemists and photochemists, Photo- and Electro-Catalytic Processes: Water Splitting, N2 Fixing, CO2 Reduction also belongs in the libraries of materials scientists and inorganic chemists seeking a one-stop resource on the novel aspects of photo-, electro-, and photoelectro-catalytic reactions.

Download or read book Solar Hydrogen Generation written by Krishnan Rajeshwar and published by Springer Science & Business Media. This book was released on 2008-02-21 with total page 329 pages. Available in PDF, EPUB and Kindle. Book excerpt: Given the backdrop of intense interest and widespread discussion on the prospects of a hydrogen energy economy, this book aims to provide an authoritative and up-to-date scientific account of hydrogen generation using solar energy and renewable sources such as water. While the technological and economic aspects of solar hydrogen generation are evolving, the scientific principles underlying various solar-assisted water splitting schemes already have a firm footing. This book aims to expose a broad-based audience to these principles. This book spans the disciplines of solar energy conversion, electrochemistry, photochemistry, photoelectrochemistry, materials chemistry, device physics/engineering, and biology.

Download or read book Photocatalytic Hydrogen Evolution written by Misook Kang and published by MDPI. This book was released on 2020-06-17 with total page 136 pages. Available in PDF, EPUB and Kindle. Book excerpt: Energy crises and global warming pose serious challenges to researchers in their attempt to develop a sustainable society for the future. Solar energy conversion is a remarkable, clean, and sustainable way to nullify the effects of fossil fuels. The findings of photocatalytic hydrogen production (PCHP) by Fujishima and Honda propose that “water will be the coal for the future”. Hydrogen is a carbon-free clean fuel with a high specific energy of combustion. Titanium oxide (TiO2), graphitic-carbon nitride (g-C3N4) and cadmium sulfide (CdS) are three pillars of water splitting photocatalysts owing to their superior electronic and optical properties. Tremendous research efforts have been made in recent years to fabricate visible or solar-light, active photocatalysts. The significant features of various oxide, sulfide, and carbon based photocatalysts for cost-effective hydrogen production are presented in this Special Issue. The insights of sacrificial agents on the hydrogen production efficiency of catalysts are also presented in this issue.

Download or read book Nanostructured Photocatalysts written by Van-Huy Nguyen and published by Elsevier. This book was released on 2021-06-25 with total page 594 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nanostructured Photocatalysts: From Fundamental to Practical Applications offers a good opportunity for academic, industrial researchers and engineers to gain insights on the fundamental principles and updated knowledge on the engineering aspects and various practical applications of photocatalysis. This book comprehensively and systematically reviews photocatalytic fundamental aspects, ranging from reaction mechanism, kinetic modeling, nanocatalyst synthesis and design, essential material characterization using advanced techniques, and novel reactor design and scale-up. Future perspectives, techno-economical evaluation and lifecycle assessment of photocatalytic processes are also provided. Finally, a wide range of practical, important and emerging photocatalytic applications, namely wastewater treatment, air pollution remediation, renewable and green energy generation, and vital chemical production are thoroughly covered, making this book useful and beneficial for engineers, scientists, academic researchers, undergraduates and postgraduates. - Provides a fundamental understanding of photocatalysis - Covers all aspects of recent developments in photocatalytic processes and photocatalytic materials - Focuses on advanced photocatalytic applications and future research advancements on energy, environment, biomedical, and other specialty fields - Contains contributions from leading international experts in photocatalysis - Presents a valuable reference for academic and industrial researchers, scientists and engineers

Download or read book Semiconductor Photocatalysis written by Horst Kisch and published by John Wiley & Sons. This book was released on 2015-04-20 with total page 264 pages. Available in PDF, EPUB and Kindle. Book excerpt: Focusing on the basic principles of semiconductor photocatalysis, this book also gives a brief introduction to photochemistry, photoelectrochemistry, and homogeneous photocatalysis. In addition, the author - one of the leading authorities in the field - presents important environmental and practical aspects. A valuable, one-stop source for all chemists, material scientists, and physicists working in this area, as well as novice researchers entering semiconductor photocatalysis.

Download or read book Nanostructured Photocatalysts written by Rabah Boukherroub and published by Elsevier. This book was released on 2020-06-06 with total page 301 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nanostructured Photocatalysts: From Materials to Applications in Solar Fuels and Environmental Remediation addresses the different properties of nanomaterials-based heterogeneous photocatalysis. Heterogeneous nanostructured photocatalysis represents an interesting and viable technique to address issues of climate change and global energy supply. Sustainable hydrogen (H2) fuel production from water via semiconductor photocatalysis, driven by solar energy, is regarded as a viable and sustainable solution to address increasing energy and environmental issues. Similarly, photocatalytic reduction of CO2 with water for the production of hydrocarbons could also be a viable solution. Sections cover band gap tuning, high surface area, the short diffusion path of carriers, and more. - Introduces the utilization of nanostructured materials in heterogeneous photocatalysis for hydrogen fuel production via water splitting - Explains preparation techniques for different nanomaterials and hybrid nanocomposites, enabling improved sunlight absorption efficiency and enhanced charge separation - Assesses the challenges that need to be addressed before this technology can be practically implemented, particularly of identifying cost-effective nanophotocatalysts

Download or read book Solar Fuels and Photocatalysts 4 written by N. Wu and published by The Electrochemical Society. This book was released on 2015-04-30 with total page 25 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book New and Future Developments in Catalysis written by Steven L Suib and published by Newnes. This book was released on 2013-07-19 with total page 493 pages. Available in PDF, EPUB and Kindle. Book excerpt: New and Future Developments in Catalysis is a package of seven books that compile the latest ideas concerning alternate and renewable energy sources and the role that catalysis plays in converting new renewable feedstock into biofuels and biochemicals. Both homogeneous and heterogeneous catalysts and catalytic processes will be discussed in a unified and comprehensive approach. There will be extensive cross-referencing within all volumes.The use of solar energy during various catalytic chemical processes for the production of an array of chemical products is the theme of this volume. Photocatalysis is a topic of increasing importance due to its essential role in many of today's environmental and energy source problems. The use of solar energy for catalytic reactions results in a carbon dioxide–neutral process. All photocatalytic processes and the future developments in this area are discussed, including an economic analysis of the various processes. - Offers in-depth coverage of all catalytic topics of current interest and outlines future challenges and research areas - A clear and visual description of all parameters and conditions, enabling the reader to draw conclusions for a particular case - Outlines the catalytic processes applicable to energy generation and design of green processes

Download or read book Nanostructured Semiconductors written by Serge Zhuiykov and published by Woodhead Publishing. This book was released on 2018-01-02 with total page 568 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nanostructured Semiconductors focuses on the development of semiconductor nanocrystals, their technologies and applications, including energy harvesting, solar cells, solid oxide fuel cells, and chemical sensors. Semiconductor oxides are used in electronics, optics, catalysts, sensors, and other functional devices. In their 2D form, the reduction in size confers exceptional properties, useful for creating faster electronics and more efficient catalysts. Since the first edition of the book, there has been significant progress in the development of new functional nanomaterials with unique and sometimes unpredictable quantum-confined properties within the class what it called two-dimensional (2D) semiconductors. These nanocrystals represent extremely thin nano-structures with thickness of just few nano-meters. Since that time, not only were 2D semiconductor oxides further developed, more importantly, 2D metal dichalcogenides, such as MoS2, MoSe2, WS2, WSe2 and others also progressed significantly in their development demonstrating their superior properties compared to their bulk and microstructural counterparts. The book has been expanded to include these advancements. The book begins with the structure and properties of semiconductor nanocrystals (chapter 1), addresses electronic device applications (chapter 2), discusses 2-Dimensional oxides and dichalcogenide semiconductors (chapters 3 through 5), and ends with energy, environment, and bio applications (chapters 6 through 8). - Focuses on the development of semiconductor nanocrystals and their technologies and applications, including energy harvesting, solar cells, solid oxide fuel cells and chemical sensors - Include other 2D materials, such as dichalcogenides to present a comprehensive resource on the latest advancements in nanostructured semiconductors - Reviews the fundamental physics of conductivity and electron arrangement before proceeding to practical applications - Contains a unique chapter dedicated to the new atomic layer deposition (ALD) technique which has the ability to develop 2D nanostructures with great precision

Download or read book Sustainable Hydrogen Production written by Ibrahim Dincer and published by Elsevier. This book was released on 2016-08-05 with total page 494 pages. Available in PDF, EPUB and Kindle. Book excerpt: Sustainable Hydrogen Production provides readers with an introduction to the processes and technologies used in major hydrogen production methods. This book serves as a unique source for information on advanced hydrogen generation systems and applications (including integrated systems, hybrid systems, and multigeneration systems with hydrogen production). Advanced and clean technologies are linked to environmental impact issues, and methods for sustainable development are thoroughly discussed. With Earth's fast-growing populations, we face the challenge of rapidly rising energy needs. To balance these we must explore more sustainable methods of energy production. Hydrogen is one key sustainable method because of its versatility. It is a constituent of a large palette of essential materials, chemicals, and fuels. It is a source of power and a source of heat. Because of this versatility, the demand for hydrogen is sure to increase as we aim to explore more sustainable methods of energy. Furthermore, Sustainable Hydrogen Production provides methodologies, models, and analysis techniques to help achieve better use of resources, efficiency, cost-effectiveness, and sustainability. The book is intellectually rich and interesting as well as practical. The fundamental methods of hydrogen production are categorized based on type of energy source: electrical, thermal, photonic, and biochemical. Where appropriate, historical context is introduced. Thermodynamic concepts, illustrative examples, and case studies are used to solve concrete power engineering problems. - Addresses the fundamentals of hydrogen production using electrical, thermal, photonic, and biochemical energies - Presents new models, methods, and parameters for performance assessment - Provides historical background where appropriate - Outlines key connections between hydrogen production methods and environmental impact/sustainable development - Provides illustrative examples, case studies, and study problems within each chapter

Download or read book Modern Electrochemical Methods in Nano Surface and Corrosion Science written by Mahmood Aliofkhazraei and published by BoD – Books on Demand. This book was released on 2014-06-11 with total page 354 pages. Available in PDF, EPUB and Kindle. Book excerpt: The basics and principles of new electrochemical methods and also their usage for fabrication and analysis of different nanostructures were discussed in this book. These methods consist of electrochemical methods in nanoscale (e.g. electrochemical atomic force microscopy and electrochemical scanning tunneling microscopy) and also electrochemical methods for fabrication of nanomaterials.

Download or read book Solar to Chemical Conversion written by Hongqi Sun and published by John Wiley & Sons. This book was released on 2021-04-29 with total page 480 pages. Available in PDF, EPUB and Kindle. Book excerpt: This comprehensive book systematically covers the fundamentals in solar energy conversion to chemicals, either fuels or chemical products. It includes natural photosynthesis with emphasis on artificial processes for solar energy conversion and utilization. The chemical processes of solar energy conversion via homogeneous and/or heterogeneous photocatalysis has been described with the mechanistic insights. It also consists of reaction systems toward a variety of applications, such as water splitting for hydrogen or oxygen evolution, photocatalytic CO2 reduction to fuels, and light driven N2 fixation, etc. This unique book offers the readers a broad view of solar energy utilization based on chemical processes and their perspectives for future sustainability.

Download or read book Semiconductor Photocatalysis written by Wenbin Cao and published by BoD – Books on Demand. This book was released on 2016-08-24 with total page 678 pages. Available in PDF, EPUB and Kindle. Book excerpt: Photocatalysis is a hot topic because it is an environmentally friendly approach toward the conversion of light energy into chemical energy at mild reaction environments. Also, it is well applied in several major areas such as water splitting, bacterial inactivation, and pollutants elimination, which is a possible solution to energy shortage and environmental issues. The fundamental knowledge and the frontier research progress in typical photocatalytic materials, such as TiO2-based and non-TiO2-based photocatalysts, are included in this book. Methods to improve the photocatalytic efficiency and to provide a hint for the rational design of the new photocatalysts are covered.

Download or read book Environmentally Benign Photocatalysts written by Masakazu Anpo and published by Springer Science & Business Media. This book was released on 2010-11-11 with total page 740 pages. Available in PDF, EPUB and Kindle. Book excerpt: Over the past few decades, mankind has observed an unprecedented and remarkable growth in industry, resulting in a more prosperous lifestyle for peoples of many countries. In developing countries, however, explosive industrial growth is just now beginning to raise the living standards of the people. Most industries, especially in these developing countries, are still powered by the burning of fossil fuels; con- quently, a lack of clean energy resources has caused environmental pollution on an unprecedented large and global scale. Toxic wastes have been relentlessly released into the air and water leading to serious and devastating environmental and health problems while endangering the planet and life itself with the effects of global warming. To address these urgent environmental issues, new catalytic and photocatalytic processes as well as open-atmospheric systems are presently being developed that can operate at room temperature while being totally clean and ef?cient and thus environmentally harmonious. Essential to technologies harnessing the abundant solar energy that reaches the earth are the highly functional photocatalytic proce- es that can utilize not only UV light, but also visible light.

Download or read book Conjugated Polymer Nanostructures for Energy Conversion and Storage Applications written by Srabanti Ghosh and published by John Wiley & Sons. This book was released on 2021-06-01 with total page 38 pages. Available in PDF, EPUB and Kindle. Book excerpt: A timely overview of fundamental and advanced topics of conjugated polymer nanostructures Conjugated Polymer Nanostructures for Energy Conversion and Storage Applications is a comprehensive reference on conjugated polymers for energy applications. Distinguished academic and editor Srabanti Ghosh offers readers a broad overview of the synthesis, characterization, and energy-related applications of nanostructures based on conjugated polymers. The book includes novel approaches and presents an interdisciplinary perspective rooted in the interfacing of polymer and synthetic chemistry, materials science, organic chemistry, and analytical chemistry. This book provides complete descriptions of conjugated polymer nanostructures and polymer-based hybrid materials for energy conversion, water splitting, and the degradation of organic pollutants. Photovoltaics, solar cells, and energy storage devices such as supercapacitors, lithium ion battery electrodes, and their associated technologies are discussed, as well. Conjugated Polymer Nanostructures for Energy Conversion and Storage Applications covers both the fundamental topics and the most recent advances in this rapidly developing area, including: The design and characterization of conjugated polymer nanostructures, including the template-free and chemical synthesis of polymer nanostructures Conjugated polymer nanostructures for solar energy conversion and environmental protection, including the use of conjugated polymer-based nanocomposites as photocatalysts Conjugated polymer nanostructures for energy storage, including the use of nanocomposites as electrode materials The presentation of different and novel methods of utilizing conjugated polymer nanostructures for energy applications Perfect for materials scientists, polymer chemists, and physical chemists, Conjugated Polymer Nanostructures for Energy Conversion and Storage Applications also belongs on the bookshelves of organic chemists and any other practicing researchers, academics, or professionals whose work touches on these highly versatile and useful structures.

Download or read book Green Photocatalytic Semiconductors written by Seema Garg and published by Springer Nature. This book was released on 2021-09-20 with total page 855 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book comprises a detailed overview on the role of photocatalysts for environmental remediation, hydrogen production and carbon dioxide reduction. Effective ways to enhance the photocatalytic activity of the material via doping, hybrid material, laser light and nanocomposites have been discussed in this book. The book also further elaborates the role of metal nanoparticles, rare earth doping, sensitizers, surface oxygen vacancy, interface engineering and band gap engineering for enhancing the photocatalytic activity. An approach to recover the photocatalytic material via immobilization is also presented. This book brings to light much of the recent research in the development of such semiconductor photocatalytic systems. The book will thus be of relevance to researchers in the field of: material science, environmental science & technology, photocatalytic applications, newer methods of energy generation & conversion and industrial applications.