Download or read book Phase Equilibria in Multicomponent Systems written by Lev Samoĭlovich Palatnik and published by . This book was released on 1964 with total page 472 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Phase equilibria in multicomponent systems written by Len Samoilovich Palatnik and published by . This book was released on with total page 454 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Phase Diagrams and Thermodynamic Modeling of Solutions written by Arthur D. Pelton and published by Academic Press. This book was released on 2018-09-19 with total page 401 pages. Available in PDF, EPUB and Kindle. Book excerpt: Phase Diagrams and Thermodynamic Modeling of Solutions provides readers with an understanding of thermodynamics and phase equilibria that is required to make full and efficient use of these tools. The book systematically discusses phase diagrams of all types, the thermodynamics behind them, their calculations from thermodynamic databases, and the structural models of solutions used in the development of these databases. Featuring examples from a wide range of systems including metals, salts, ceramics, refractories, and concentrated aqueous solutions, Phase Diagrams and Thermodynamic Modeling of Solutions is a vital resource for researchers and developers in materials science, metallurgy, combustion and energy, corrosion engineering, environmental engineering, geology, glass technology, nuclear engineering, and other fields of inorganic chemical and materials science and engineering. Additionally, experts involved in developing thermodynamic databases will find a comprehensive reference text of current solution models. Presents a rigorous and complete development of thermodynamics for readers who already have a basic understanding of chemical thermodynamics Provides an in-depth understanding of phase equilibria Includes information that can be used as a text for graduate courses on thermodynamics and phase diagrams, or on solution modeling Covers several types of phase diagrams (paraequilibrium, solidus projections, first-melting projections, Scheil diagrams, enthalpy diagrams), and more
Download or read book Critical Evaluation and Prediction of Phase Equilibria in Multicomponent Systems written by CODATA. and published by . This book was released on with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Phase Equilibria Phase Diagrams and Phase Transformations written by Mats Hillert and published by Cambridge University Press. This book was released on 2007-11-22 with total page 525 pages. Available in PDF, EPUB and Kindle. Book excerpt: Computational tools allow material scientists to model and analyze increasingly complicated systems to appreciate material behavior. Accurate use and interpretation however, requires a strong understanding of the thermodynamic principles that underpin phase equilibrium, transformation and state. This fully revised and updated edition covers the fundamentals of thermodynamics, with a view to modern computer applications. The theoretical basis of chemical equilibria and chemical changes is covered with an emphasis on the properties of phase diagrams. Starting with the basic principles, discussion moves to systems involving multiple phases. New chapters cover irreversible thermodynamics, extremum principles, and the thermodynamics of surfaces and interfaces. Theoretical descriptions of equilibrium conditions, the state of systems at equilibrium and the changes as equilibrium is reached, are all demonstrated graphically. With illustrative examples - many computer calculated - and worked examples, this textbook is an valuable resource for advanced undergraduates and graduate students in materials science and engineering.
Download or read book Thermodynamic Data Models and Phase Diagrams in Multicomponent Oxide Systems written by Olga Fabrichnaya and published by Springer Science & Business Media. This book was released on 2013-03-14 with total page 216 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book involves application of the Calphad method for derivation of a self consistent thermodynamic database for the geologically important system Mg0- Fe0-Fe203-Alz03-Si02 at pressures and temperatures of Earth's upper mantle and the transition zone of that mantle for Earth. The created thermodynamic database reproduces phase relations at 1 bar and at pressures up to 30 GPa. The minerals are modelled by compound energy formalism, which gives realistic descriptions of their Gibbs energy and takes into account crystal structure data. It incorporates a detailed review of diverse types of experimental data which are used to derive the thermodynamic database: phase equilibria, calorimetric stud ies, and thermoelastic property measurements. The book also contains tables of thermodynamic properties at 1 bar (enthalpy and Gibbs energy of formation from the elements, entropy, and heat capacity, and equation of state data at pressures from 1 bar to 30 GPa. Mixing parameters of solid solutions are also provided by the book. Table of Contents Introduction to the Series . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . V Acknowledgments . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . VII Preface . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . IX Table of Contents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . XI Co-Authors . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . XIII Vitae of Co-Authors . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . XV CODATA Task Group on Geothermodynamic Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . XXIII Chapter 1. Thermodynamics and Modeling . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 1. 1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 1. 2 Thermodynamic Modeling . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 1. 3 Experimental Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3 1. 4 Programs and Assessment. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4 System and Phases . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5 1. 5 Chapter 2. Experimental Phase Equilibrium Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7 The Si02 System . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7 2. 1 2. 2 The Fe-0 System . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8 2. 3 The Fe-Si-0 System . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10 2. 4 The Mg0-Si0 System . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Download or read book Thermodynamics and Chemistry written by Howard DeVoe and published by . This book was released on 2019 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Measurement of Phase Equilibria and Compressibility of Multicomponent Systems written by K. M. Gratwick and published by . This book was released on 1956 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Phase Equilibria in Multicomponent Systems written by Lev Samoĭlovich Palatnik and published by . This book was released on 1964 with total page 474 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Phase Equilibrium Engineering written by Esteban Brignole and published by Elsevier Inc. Chapters. This book was released on 2013-04-02 with total page 43 pages. Available in PDF, EPUB and Kindle. Book excerpt: Phase equilibrium knowledge is required for the design of all sorts of chemical processes that may involve separations, reactions, fluids flow, particle micronization, etc. Indeed, different phase behavior scenarios are required for a rational conceptual process design. The aim of this chapter is to present the possible fluid mixture phase behavior that can be found in binary, ternary, and multicomponent systems. Moreover, representation of phase behavior in terms of phase diagrams is discussed. Dealing with phase diagrams of complex mixtures is not an easy task for beginners; however, very simple concepts are behind the rules for their construction. Phase diagrams are essential tools for phase equilibrium engineering as they provide valuable hints to understand the process and to assess the feasible and optimum operating regions. In this chapter, the “phenomenological” meaning of each phase behavior and its relation with molecular properties is discussed. A special attention is given to binary system phase behavior. Even though, in practice we rarely found such simple mixtures, they furnish a great deal of information for the understanding of multicomponent systems.
Download or read book Modeling of Thermodynamic Properties and Phase Equilibria of Multicomponent Systems Related to the Oil and Gas Industry Using the PC SAFT Equation of State written by Sally Hisham Mohamed El Meragawi and published by . This book was released on 2015 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Equations of state (EoS) have proved to be a reliable tool in chemical engineering thermodynamics for modeling the physical properties of complex systems. Various types of EoS have been developed based on different theories. For various reasons, some have become more popular for use in industry and academia. Of the popular EoS, two were chosen for investigation in this thesis. The first one was the Perturbed Chain- Statistical Associating Fluid Theory (PC-SAFT), an equation derived based on statistical mechanics and the second was the Peng-Robinson (PR) EoS, a cubic EoS commonly used in industry. In this work, the prediction capabilities of these two EoS were compared for several properties. The analysis began with an evaluation of their use in the prediction of the saturation properties of pure components and derivative properties from ambient conditions to the supercritical range. The particular derivative properties studied include the isochoric and isobaric heat capacities, the speed of sound, and the isothermal compressibility. In general, it was concluded that PC-SAFT outperforms PR in all cases. Next, the same primary and derivative properties of several binary and a select ternary mixture were studied. To improve agreement with experimental data, a binary interaction parameter was introduced and fitted to binary mixture vapor - liquid equilibria (VLE) data. This procedure drastically improved the accuracy of the models compared to the case where no binary interaction parameter used for the case of VLE predictions. However, for the case of the derivative properties, the use of the binary interaction parameter to ensure a more accurate representation of the interactions between molecules had only a marginal effect on the prediction of these properties. Finally, phase equilibria of hydrates were studied. As EoS for fluids are not designed to predict the properties of solid phases, the van der Waals-Platteeuw model was incorporated to allow for the prediction of three-phase equilibrium conditions of various hydrate formers. Specifically, this work focused on the equilibrium of a water-rich liquid phase, a hydrate phase and a vapor phase rich in a hydrate former. In all cases, calculations of the solid hydrate phase properties are based on the Kihara potential. This potential requires three parameters to be defined; initial values for which were found through a review of the literature. The accuracy of the predictions of the three-phase equilibrium is highly dependent on the reliability of these parameters. Thus, one of the parameters, the so-called Îæ parameter, was fitted to hydrate equilibrium data and resulted in a significant improvement in the accuracy of predictions of both PC-SAFT and PR EoS. The new set of parameters was then used to predict the three-phase equilibrium of several binary, ternary and quaternary mixtures of hydrate forming agents. Several conclusions are drawn from this work, including the observation that the accuracy of the models is reduced when the number of components increases. The electronic version of this dissertation is accessible from http://hdl.handle.net/1969.1/155481
Download or read book Measurement and Evaluation of Phase Equilibria written by and published by . This book was released on 1990 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Thermodynamic Properties of Multicomponent Systems Multicomponent Phase Equilibria and Chemical Equilibria written by B. M. Goodwin and published by Amer Inst of Chemical Engineers. This book was released on 1982-01-01 with total page 46 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Phase Equilibria in Multicomponent Systems Translated by Scripta Technica Inc Edited by Joseph Joffe Etc written by Lev Samoilovich PALATNIK (and LANDAU (Aleksandr Isaakovich)) and published by . This book was released on 1964 with total page 454 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book AIChEMI Modular Instruction written by American Institute of Chemical Engineers and published by . This book was released on 1982 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Introduction to Phase Equilibria in Ceramic Systems written by Hummel and published by Routledge. This book was released on 2018-05-02 with total page 289 pages. Available in PDF, EPUB and Kindle. Book excerpt: Written by a leading practitioner and teacher in the field of ceramic science and engineering, this outstanding text provides advanced undergraduate- and graduate-level students with a comprehensive, up-to-date Introduction to Phase Equilibria in Ceramic Systems. Building upon a concise definition of the phase rule, the book logically proceeds from one- and two-component systems through increasingly complex systems, enabling students to utilize the phase rule in real applications. Unique because of its emphasis on phase diagrams, timely because of the rising importance of ceramic applications, practical because of its pedagogical approach, Introduction to Phase Equilibria in Ceramic Systems offers end-of-chapter review problems, extensive reading lists, a solid thermodynamic foundation and clear perspectives on the special properties of ceramics as compared to metals.This authoritative volume fills a broad gap in the literature, helping undergraduate- and graduate-level students of ceramic engineering and materials science to approach this demanding subject in a rational, confident fashion. In addition, Introduction to Phase Equilibria in Ceramic Systems serves as a valuable supplement to undergraduate-level metallurgy programs.
Download or read book Measurement and Evaluation of Phase Equilibria written by CODATA. and published by . This book was released on 1988 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
