Download or read book Palladium and Platinum Complexes of Bis alkylthio alkanes written by Hugo Torrens M. and published by . This book was released on 1977 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Palladium and Platinum Complexes of Bis alkylthio Alkanes by Hugo Torrens M written by Hugo Torrens Miguel and published by . This book was released on 1977 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book One electron Chemistry of Palladium Platinum and Gold Bis phosphine Complexes written by Matthew J. G. Sinclair and published by . This book was released on 2022 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book The Chemistry of Platinum and Palladium with Particular Reference to Complexes of the Elements written by F. R. Hartley and published by . This book was released on 1973 with total page 570 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Higher Oxidation State Organopalladium and Platinum Chemistry written by Allan J. Canty and published by Springer. This book was released on 2011-02-25 with total page 195 pages. Available in PDF, EPUB and Kindle. Book excerpt: Kyle A. Grice, Margaret L. Scheuermann and Karen I. Goldberg: Five-Coordinate Platinum(IV) Complexes.- Jay A. Labinger and John E. Bercaw: The Role of Higher Oxidation State Species in Platinum-Mediated C-H Bond Activation and Functionalization.- Joy M. Racowski and Melanie S. Sanford: Carbon-Heteroatom Bond-Forming Reductive Elimination from Palladium(IV) Complexes.- Helena C. Malinakova: Palladium(IV) Complexes as Intermediates in Catalytic and Stoichiometric Cascade Sequences Providing Complex Carbocycles and Heterocycles.- Allan J. Canty and Manab Sharma: h1-Alkynyl Chemistry for the Higher Oxidation States of Palladium and Platinum.- David C. Powers and Tobias Ritter: Palladium(III) in Synthesis and Catalysis.- Marc-Etienne Moret: Organometallic Platinum(II) and Palladium(II) Complexes as Donor Ligands for Lewis-Acidic d10 and s2 Centers.
Download or read book Metal Complexes written by Peter Maitlis and published by Elsevier. This book was released on 2012-12-02 with total page 336 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Organic Chemistry of Palladium, Volume 1: Metal Complexes deals with the number of organic reactions that can be catalyzed by palladium, particularly as regards the structures bonding, and reactions of the metal complexes. The book discusses monodentate ligands which are either neutral (carbonyls, isonitriles, carbenes) or anionic (methyl, phenyl, ethynyl, hydride). The text also examines the complexes formed by 1,3-. 1,4-, and 1,5-diolefins where four carbon atoms are bound to the metal. Palladium (II) can undergo a reaction with the 1,3-dienes and results in a ?-allylic complexes where only three carbon atoms are coordinated to the metal. (The bonding situation in complexes 1,4- and 1,5-dienes, where no great interaction between the olefins are similar to that in monoolefin complexes, is straightforward), Olefins can also react with palladium chloride in protic solvents to produce ketones (or aldehydes) or organic coupling products. Some experiments conducted by Huttel et al shows that some palladium was precipitated from the reactions giving lower yields, resulting in various aldehydes and ketones as by products. The book also discusses cyclopentadienyl and benzene complexes. The text can prove beneficial for researchers, investigators and scientists whose works involve organic chemistry, analytical chemistry, physical chemistry and inorganic chemistry.
Download or read book Stoichiometric and Catalytic Chemistry of Platinum Palladium and Nickel Bis phosphine Alkyls and Hydrides written by Allen L. Seligson and published by . This book was released on 1991 with total page 534 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Bis allenylidene Complexes of Palladium and Platinum written by Florian Kessler and published by . This book was released on 2011 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Dioxygen Insertion Studies Into Platinum and Palladium Alkyl Complexes written by Allan Robertson Petersen and published by . This book was released on 2012 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Chapter 1 provides an overview of the oxidation of methane by platinum salts known as Shilov chemistry. This includes platinum complexes used for the selective oxidation of methane to methyl bisulfate. Attention is paid to model platinum complexes that have been synthesised to explore the oxidation of methane using dioxygen as the oxidant. Chapter 2 describes two sets of tridentate N donor ligands that have been synthesised. The first set contains 6,6"-disubsthuted-2,2/:6/,2"-terpyridine ligands, of these two new ligands 6,6"-di(methylamino)-2,2/:6/,2"-terpyridine and 6,6"-dimethoxy-2,2/:6/,2"-terpyridine have been synthesised and fully characterised. The second set contains non-terpyridine tridentate ligands. The synthesis and characterisation of novel cationic platinum(II) methyl complexes bearing these ligands is described in Chapter 3. The structures of some of these complexes have been determined by X-ray crystallography. Further, the reactivity of the complexes towards dioxygen is reported and how different reactivity is imparted by the different ligands is discussed. The ability of some of these platinum(II) methyl complexes to insert dioxygen into their M-Me bonds arises from the steric interaction between the Pt-Me ligand and the substituents in the 6- and 6"-positions on the terpyridine ligand. Chapter 4 describes a study into the mechanism of the insertion of dioxygen into a Pt-Me bond. This includes deuterium labelling experiments, which led to the discovery of the exchange of methyl ligands between platinum(II) and palladium(II) centres. A mechanism for this exchange involving the formation of a MII_MII dimer is proposed. In addition, the decomposition of a palladium(II) methylperoxo complex to give an intriguing new metallacyclic hemiacetal alkoxide complex is described. A possible mechanism for the formation of this new palladium(II) complex is discussed. The synthesis and characterisation of the new compounds discussed in Chapters 2-4 are reported in Chapter 5. 4.
Download or read book Synthesis and Electrochemistry Studies of Palladium and Platinum Complexes Containing Chiral C subscript 2 symmetric Bis oxazoline Ligands and Platinum Complexes of the Chiral C subscript 2 symmetric Bidentate Phosphine Ligand Diop written by Kara Leigh Cetto and published by . This book was released on 2003 with total page 268 pages. Available in PDF, EPUB and Kindle. Book excerpt: In an effort to design complexes in which electrochemical reduction does not result in loss of the chiral ligand, five different bis(oxazoline) ligands were prepared (3, 5, 7, 8 and 9). 3 was found to have poor solubility and an exceedingly negative reduction potential of Ep[subscript]c= -2.38 V. Chemical reduction studies of 5 revealed that the bis(oxazoline) ligand is ejected during the reduction process. Compound 7 was found to have a reduction potential of Ep[subscript]c= -1.12 V. However, ejection of the chiral ligand occurs when other bis(oxazoline) platinum and palladium dichloride complexes are reduced. Therefore, a neutral PdClMe complex (8) with a reduction potential of Ep[subscript]c= -2.97 V and a cationic Pd(CH[subscript]3CN)Me complex (9) (Ep[subscript]c= -1.38 V) were also prepared. A platinum complex of the bidentate phosphine ligand was then investigated. Electrochemistry studies revealed that 11 undergoes a two-electron reduction process in which the ligand remains bound to the metal. The synthesis of Pt(DIOP)(trans-stilbene) through the chemical and electrochemical reduction of 11 further demonstrated that DIOP remains bound to platinum after reduction of 11.
Download or read book Some Reactions of Platinum and Palladium Alkyl Complexes written by and published by . This book was released on 1976 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book The Preparation and Investigation of Cis bis alkyl Aryl Or Diiodo Bis triphenylarsine Platinum II Complexes written by Jon D. Blackman and published by . This book was released on 1968 with total page 78 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Paramagnetic Palladium II and Platinum II Complexes with Sterically Demanding Ethylenediamines and a Study of the Coordination Chemistry of 2 2 bis piperidino with Divalent Transition Metal Ions written by John Robert Hoover and published by . This book was released on 1976 with total page 308 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Bulletin of the Chemical Society of Japan written by Nihon Kagakkai and published by . This book was released on 1992 with total page 1140 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Abstracts of Papers written by American Chemical Society. Meeting and published by . This book was released on 1965 with total page 988 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Chemical Abstracts written by and published by . This book was released on 2002 with total page 2668 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Rodd s Chemistry of Carbon Compounds written by E. H. Rodd and published by . This book was released on 1964 with total page 368 pages. Available in PDF, EPUB and Kindle. Book excerpt:
