Download or read book Oxidation of Organic Compounds by Dioxiranes written by Waldemar Adam and published by John Wiley & Sons. This book was released on 2009-04-27 with total page 684 pages. Available in PDF, EPUB and Kindle. Book excerpt: A Comprehensive Monograph on Dioxirane Oxidations The oxidation of organic compounds is one of the most important methods for the introduction and manipulation of functional groups. Among the most modern of these transformations is the use of the fascinating family of oxidants known as dioxiranes. A dioxirane can, by transferring one of its oxygen atoms to organic substrates, effect a remarkable array of oxidative processes such as epoxidation, C-H insertion, and heteroatom (N, S, P, I) oxidation. In addition to their versatility, dioxiranes can be generated catalytically under mild conditions and produce no toxic waste stream as part of the oxidation process. Moreover, some of the most exciting recent developments involve the enantioselective introduction of oxygen atoms via chiral dioxiranes. This book represents the first single volume dedicated to the comprehensive coverage of the myriad of oxidations of organic compounds performed by dioxiranes. The contents of this book are extracted from comprehensive reviews of the topics contained in the Organic Reactions series and cover the oxidation of alkenes and the oxidation of all other organic substrates. In addition, updated lists of references for each of the chapters are provided, bringing the literature coverage up to June 2008. The authors of these chapters are among the pioneers of dioxirane chemistry and draw on extensive firsthand knowledge of the subject. As with all Organic Reactions content, the presentation emphasizes the preparative aspects of the reactions and pays particular attention throughout to substrate scope, limitations, structural and electronic influences, and stereochemical aspects. For the student or experienced practitioner, both general guidelines for carrying out the reactions as well as detailed experimental procedures are provided. Most importantly, all known examples of dioxirane oxidations have been compiled in easy-to-scan tables covering over 500 pages. Oxidation of Organic Compounds by Dioxiranes is an indispensable working resource for organic and medicinal chemists as well as anyone wishing to own the definitive treatise on this fascinating and useful class of oxidants.
Download or read book Heterocyclic Chemistry written by Raj K. Bansal and published by New Age International. This book was released on 2020 with total page 508 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Oxirane Chemistry written by James Bonnar and published by CreateSpace. This book was released on 2014-03-27 with total page 102 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents a comprehensive survey of 300 organic chemical reactions involving oxiranes and the oxirane functional group. It is ideal for the purposes of learning the chemistry, synthesis planning, highly-profitable pharmaceutical and industrial research and retrosynthetic analysis of oxiranes, the oxirane functional group and its derivatives.
Download or read book Oxidation in Organic Chemistry 5 B written by Walter Trahanovsky and published by Elsevier. This book was released on 2012-12-02 with total page 263 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organic Chemistry, Volume 5-B: Oxidation in Organic Chemistry, Part B presents some of the most common and significant reactions in organic chemistry, which involves oxidation and reduction. This book provides detailed discussions of specific oxidants or topics concerning oxidation of organic compounds. Organized into four chapters, this volume begins with an overview of the specific oxidants, including thallium(III), cupric ion, and ruthenium tetroxide. This text then presents the scope and preparative use as well as the mechanistic aspects of the various oxidations. Other chapters consider the significance of phenolic oxidative coupling in nature's biosynthetic pathways. This book discusses as well the various mechanistic alternatives for the enzymic and non-enzymic reactions, which will lead to a fuller understanding of the enzymic mechanisms and the greater synthetic utility of this reaction. The final chapter deals with the oxidative coupling of phenols. This book is a valuable resource for organic chemists and research workers.
Download or read book Methods for Oxidation of Organic Compounds V1 written by Alan Haines and published by Elsevier. This book was released on 2012-12-02 with total page 409 pages. Available in PDF, EPUB and Kindle. Book excerpt: Methods for the Oxidation of Organic Compounds: Alkanes, Alkenes, Alkynes, and Arenes is an account of the different methods used for the controlled oxidation of alkanes, alkenes, alkynes, and arenes. Most of the oxidative techniques considered are illustrated with detailed experimental procedures taken from the literature. This book is comprised of five chapters and begins with a discussion on alkanes, alkyl groups, and hydrocarbon residues. The formation of alkenes, alcohols, hydroperoxides, dialkyl peroxides, cyclic peroxides, ethers, and esters as well as aldehydes, ketones, and carboxylic acids is described, together with the aromatization of cyclic systems. The following chapters are devoted to alkenes, alkynes, and arenes and focus on the formation of compounds ranging from 1,2-diols and oxiranes (1,2-epoxides) to 1,2-dicarbonyl compounds, phenols and their derivatives, and quinones. The formation of dialkynes by oxidative coupling of 1-alkynes is described, along with the oxidative cleavage of arenes and oxidative coupling of phenols. This monograph should be of interest to organic chemists and research students.
Download or read book Anodic Oxidation written by Sidney D. Ross and published by Elsevier. This book was released on 2013-10-22 with total page 353 pages. Available in PDF, EPUB and Kindle. Book excerpt: Anodic Oxidation covers the application of the concept, principles, and methods of electrochemistry to organic reactions. This book is composed of two parts encompassing 12 chapters that consider the mechanism of anodic oxidation. Part I surveys the theory and methods of electrochemistry as applied to organic reactions. These parts also present the mathematical equations to describe the kinetics of electrode reactions using both polarographic and steady-state conditions. Part II examines the anodic oxidation of organic substrates by the functional group initially attacked. This part particularly emphasizes the kinds of intermediates generated and the mechanisms leading to final products. This book is intended primarily to organic chemists and physical electrochemists.
Download or read book The Chemistry of Heterocycles written by Vishnu Ji Ram and published by Elsevier. This book was released on 2019-06-05 with total page 500 pages. Available in PDF, EPUB and Kindle. Book excerpt: Heterocycles are ubiquitously present in nature and occupy a unique place in organic chemistry as they are part of the DNA and haemoglobin that make life possible. The Chemistry of Heterocycles covers an introduction to the topic, followed by a chapter on the nomenclature of all classes of isolated, fused and polycyclic heterocycles. The third chapter delineates the highly strained three membered N,O and S containing aromatic and non-aromatic heterocycles with one and more than one similar and dissimilar heteroatom. The four-membered heterocycles are abundantly present in various natural and synthetic products of pharmacological importance. This chapter describes the natural abundance, synthesis, chemical reactivity, structural features and their medicinal importance. This class of compounds are present as sub-structures in penicillin and cytotoxic Taxol. Lastly, a chapter on the natural abundance, synthesis, chemical reactivity and pharmacological importance of 5-membered heterocycles with N,O,S heteroatom is covered. The chemistry of heterocycles with mixed heteroatom such as, N-S, N-O, N-S etc. is also described. Gives in-depth, clear information about various systems of nomenclature along with widely acceptable IUPAC system for naming various classes of heterocycles Provides complete information about natural occurrences, synthesis, chemical reactivity, pharmacological importance of heterocycles and their application in material science Highly relevant for graduate students and researchers, providing updated information about various isolated and fused N,O and,S containing heterocycles
Download or read book Chemical Processes in Atmospheric Oxidation written by Georges Le Bras and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 316 pages. Available in PDF, EPUB and Kindle. Book excerpt: Oxidation and removal of atmospheric constituents involve complex sequences of reactions which can lead to the production of photo-oxidants such as ozone. In order to understand and model these complex reaction sequences, it is necessary to have a comprehensive understanding of reaction mechanisms and accurate estimates of kinetic parameters for relevant gas-phase atmospheric reactions. This book presents recent advances in the field and includes the following topics: e.g. the oxidation of simple organic compounds, NOx kinetics and mechanisms, OH radical production and rate constants for the OH attack on more complex organic compounds, peroxy and alkoxy radical reactions, photo-oxidation of aromatic and biogenic compounds, and the interaction between radical species.
Download or read book Modern Oxidation Methods written by Jan-Erling Bäckvall and published by John Wiley & Sons. This book was released on 2011-08-02 with total page 500 pages. Available in PDF, EPUB and Kindle. Book excerpt: While rust is an unwanted oxidation reaction, there are also many other useful oxidation reactions that are extremely important and number among the most commonly used reactions in the chemical industry. This completely revised, updated second edition now includes additional sections on industrial oxidation and biochemical oxidation. Edited by one of the world leaders in the field, high-quality contributions cover every important aspect from classical to green chemistry methods: - Recent Developments in Metal-catalyzed Dihydroxylation of Alkenes - Transition Metal-Catalyzed Epoxidation of Alkenes - Organocatalytic Oxidation. Ketone-Catalyzed Asymmetric Epoxidation of Alkenes and Synthetic Applications - Catalytic Oxidations with Hydrogen Peroxide in Fluorinated Alcohol Solvents - Modern Oxidation of Alcohols using Environmentally Benign Oxidants - Aerobic Oxidations and Related Reactions Catalyzed by N-Hydro xyphthalimide - Ruthenium-Catalyzed Oxidation for Organic Synthesis - Selective Oxidation of Amines and Sulfides - Liquid Phase Oxidation Reactions Catalyzed by Polyoxometalates - Oxidation of Carbonyl Compounds - Manganese-Catalyzed Oxidation with Hydrogen Peroxide - Biooxidation with Cytochrome P450 Monooxygenases By providing an overview of this vast topic, the book represents an unparalleled aid for organic, catalytic and biochemists working in the field.
Download or read book Methods for Oxidation of Organic Compounds V2 written by Alan Haines and published by Elsevier. This book was released on 2012-12-02 with total page 488 pages. Available in PDF, EPUB and Kindle. Book excerpt: Methods for the Oxidation of Organic Compounds: Alcohols, Alcohol Derivatives, Alkyl Halides, Nitroalkanes, Alkyl Azides, Carbonyl Compounds, Hydroxyarenes and Aminoarenes describes the different methods used for the controlled oxidation of alcohols, alcohol derivatives, alkyl halides, nitroalkanes, alkyl azides, carbonyl compounds, hydroxyarenes, and aminoarenes. Most of the oxidative techniques considered are illustrated with detailed experimental procedures taken from the literature. This book is comprised of eight chapters and begins with a discussion on the oxidation of alcohols, with particular emphasis on the formation of carbonyl compounds and carboxylic acids. The following chapters focus on the oxidation of esters and alkyl halides; ethers, acetals, and metal derivatives of alcohols; amines, nitro compounds, and azides; carbonyl compounds; 1,2-diols and related compounds; and hydroxyarenes, aminoarenes, dihydroxyarenes, diaminoarenes, and aminohydroxyarenes. Methods such as catalytic oxidation, catalytic dehydrogenation, and electrochemical and biochemical oxidation are mentioned. This monograph should be of interest to organic chemists and research students.
Download or read book Oxidation written by Barry M. Trost and published by Elsevier. This book was released on 1992-09-08 with total page 1039 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume covers all methods of oxidation for use in organic synthesis. Emphasis has been placed on selectivity and functional group compatibility together with practical utility and applications. The volume is broadly divided to cover oxidation of unactivated carbon-hydrogen bonds, oxidation of activated carbon-hydrogen bonds, that is to say those adjacent to activating substituents and adjacent to heteroatoms, and oxidation of carbon-carbon double bonds. The volume also covers oxidation of C-X bonds, carbon-carbon single bonds, heteroatom oxidation and a number of special topics such as electrochemical methods, oxidative rearrangements, solid supported reagents, electron transfer oxidation, and biological methods.
Download or read book Active Oxygen in Chemistry written by Christopher S. Foote and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 355 pages. Available in PDF, EPUB and Kindle. Book excerpt: Taking an interdisciplinary approach, this book and its counterpart, Active Oxygen in Biochemistry, explore the active research area of the chemistry and biochemistry of oxygen. Complementary but independent, the two volumes integrate subject areas including medicine, biology, chemistry, engineering, and environmental studies.
Download or read book The Chemistry of Heterocycles written by Theophil Eicher and published by John Wiley & Sons. This book was released on 2013-02-25 with total page 659 pages. Available in PDF, EPUB and Kindle. Book excerpt: Das klassische Lehrbuch wurde überarbeitet und aktualisiert; mehr als 40 Prozent des Inhalts ist neu! Beibehalten wurde das bewährte Ordnungsschema (nach der Ringgröße); neue Kapitel befassen sich mit kondensierten Heterocyclen und speziellen Fragen der Nomenklatur. Enthält knapp 1000 neu aufgenommene Literaturhinweise.
Download or read book Oxidation in Organic Chemistry 5 C written by Walter Trahanovsky and published by Elsevier. This book was released on 2012-12-02 with total page 395 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organic Chemistry, A Series of Monographs, Volume 5-C: Oxidation in Organic Chemistry covers the preparative use and the mechanistic aspects of the various oxidation reactions. This book contains five chapters that particularly consider oxidations that involve organoselenium intermediates. Chapter I describes the developments of selenium in organic chemistry, particularly the organoselenium reagents for performing selective oxidative transformations under unusually mild conditions. Chapter II deals with the problems encountered in oxygenation reactions carried out by several microorganisms, with an emphasis on a variety of fermentation techniques. Chapter III examines the oxidation of various organic peroxy acids and other peroxides, while Chapter IV discusses the oxidation with nitric acid or nitrogen oxides. Chapter V focuses on the properties of various oxidants and their application to hypohalite oxidation. This text will be of value to organic chemists, researchers, teachers, and students who are interested in oxidation of organic compounds.
Download or read book Chemical Oxidation written by John A. Roth and published by CRC Press. This book was released on 2021-05-30 with total page 317 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book focuses on present state of the art chemical oxidation technologies with regard to various wastewater applications. It is a valuable aid to engineers and scientists engaged in developing cost-effective solutions to complex water quality problems in today's regulatory environment.
Download or read book Oxidation and Reduction of Organic Compounds written by Kenneth L. Rinehart and published by Prentice Hall. This book was released on 1973 with total page 164 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book The Determination of Epoxide Groups written by B. Dobinson and published by Elsevier. This book was released on 2013-10-22 with total page 88 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Determination of Epoxide Groups describes the advantages and limitations of the methods for determination of 1,2-epoxide groups of various kinds. Chapter 1 examines the chemical reactivities of different epoxides under various conditions, which is of fundamental importance in the choice of the analytical method to be used. Chapter 2 explores most of the analytical work on epoxides involving ring-opening with HCl or HBr. Chapter 3 deals with the alternative techniques involving quantitative rearrangement of epoxides, or ring-opening under non-acidic conditions. This chapter also contains descriptions of various miscellaneous analytical techniques, including very sensitive methods, as well as the use of infrared spectroscopic techniques for analysis of epoxides and the study of their reactions, particularly the cure of epoxy resins. Chapter 4 summarizes the advantages and limitations of the various methods, along with the main factors affecting choice of experimental. This book is of great value to analytical and organic chemists, researchers, and students.
