Download or read book Oxidation in Organic Synthesis written by V. K. Ahluwalia and published by CRC Press. This book was released on 2012-02-13 with total page 323 pages. Available in PDF, EPUB and Kindle. Book excerpt: Oxidation plays a crucial role in organic synthesis. This volume presents the array of oxidizing agents and their applications in oxidations. The book describes in great detail a number of reagents of importance. The text includes oxidation of specific types of organic compounds including hydrocarbons, alcohols, phenols, ethers, carbonyl compounds, carboxylic acids, amides, hydrazides, nitro compounds, nitroso compounds, hydroxylamines, azo compounds, azides, hydrazo compounds, amines, phosphorus, arsenic and sulphur compounds. It also covers enzymatic or microbial oxidations as well as oxidations under benign conditions.
Download or read book Chromium Oxidations in Organic Chemistry written by G. Cainelli and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 272 pages. Available in PDF, EPUB and Kindle. Book excerpt: Chromium oxidation, well known and widely explored in organic chemistry since the very beginning of this science, is a topic of current interest for the organic chemist as evidenced by the continuous development of new techni ques and procedures reported in the literature. Chromium oxidation is a simple process which can be easily performed in the laboratory and scaled up in industry as well. Although almost every oxidizable organic functional group may undergo chromium oxidation, the most important fields of appli cation are the oxidation of alcohols, allylic and benzylic oxidation, oxidative degradation and oxidation of some organometallic compounds. A high degree of selectivity is often possible by choosing the most suitable reagent among those several ones now available. This book takes account of the various functional groups that undergo oxidation and the entire literature up to 1982. It has been written in the hope to help the synthetic organic chemist in his experimental work. For this purpose a number of tables comprising yields and references have been included; detailed descriptions of typical procedures are meant to show the experimental conditions and the scope of the reactions. We wish to thank Dr. Mario Orena for his valuable scientific and technical assistence and Prof. Bruno Camerino, who read the entire manuscript and corrected many of the errors. Bologna, February 1984 Gianfranco Cainelli Giuliana Cardillo Table of Contents I. Introduction . . . . . . . . . . .
Download or read book Oxidation and Antioxidants in Organic Chemistry and Biology written by Evgeny T. Denisov and published by CRC Press. This book was released on 2005-03-29 with total page 1020 pages. Available in PDF, EPUB and Kindle. Book excerpt: Providing a comprehensive review of reactions of oxidation for different classes of organic compounds and polymers, and biological processes mediated by free radicals, Oxidation and Antioxidants in Organic Chemistry and Biology puts the data and bibliographical information you need into one easy-to-use resource. You will find up-to-date information
Download or read book Oxidation and Reduction of Organic Compounds written by Kenneth L. Rinehart and published by Prentice Hall. This book was released on 1973 with total page 164 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Methods for the Oxidation of Organic Compounds written by Alan H. Haines and published by . This book was released on 1988 with total page 496 pages. Available in PDF, EPUB and Kindle. Book excerpt: Methods for Oxidation of Organic Compounds V2 ...
Download or read book Oxidation in Organic Chemistry 5 B written by Walter Trahanovsky and published by Elsevier. This book was released on 2012-12-02 with total page 263 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organic Chemistry, Volume 5-B: Oxidation in Organic Chemistry, Part B presents some of the most common and significant reactions in organic chemistry, which involves oxidation and reduction. This book provides detailed discussions of specific oxidants or topics concerning oxidation of organic compounds. Organized into four chapters, this volume begins with an overview of the specific oxidants, including thallium(III), cupric ion, and ruthenium tetroxide. This text then presents the scope and preparative use as well as the mechanistic aspects of the various oxidations. Other chapters consider the significance of phenolic oxidative coupling in nature's biosynthetic pathways. This book discusses as well the various mechanistic alternatives for the enzymic and non-enzymic reactions, which will lead to a fuller understanding of the enzymic mechanisms and the greater synthetic utility of this reaction. The final chapter deals with the oxidative coupling of phenols. This book is a valuable resource for organic chemists and research workers.
Download or read book Methods for Oxidation of Organic Compounds V1 written by Alan Haines and published by Elsevier. This book was released on 2012-12-02 with total page 409 pages. Available in PDF, EPUB and Kindle. Book excerpt: Methods for the Oxidation of Organic Compounds: Alkanes, Alkenes, Alkynes, and Arenes is an account of the different methods used for the controlled oxidation of alkanes, alkenes, alkynes, and arenes. Most of the oxidative techniques considered are illustrated with detailed experimental procedures taken from the literature. This book is comprised of five chapters and begins with a discussion on alkanes, alkyl groups, and hydrocarbon residues. The formation of alkenes, alcohols, hydroperoxides, dialkyl peroxides, cyclic peroxides, ethers, and esters as well as aldehydes, ketones, and carboxylic acids is described, together with the aromatization of cyclic systems. The following chapters are devoted to alkenes, alkynes, and arenes and focus on the formation of compounds ranging from 1,2-diols and oxiranes (1,2-epoxides) to 1,2-dicarbonyl compounds, phenols and their derivatives, and quinones. The formation of dialkynes by oxidative coupling of 1-alkynes is described, along with the oxidative cleavage of arenes and oxidative coupling of phenols. This monograph should be of interest to organic chemists and research students.
Download or read book Oxidation in Organic Chemistry written by Kenneth B. Wiberg and published by . This book was released on 1965 with total page 272 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book discusses the cupric ion, thallium (III), and rutherium tetroxide and the application of each to the oxidation of specific functional groups or types of organic compounds. One chapter is devoted to the oxidative coupling of phenols; it presents novel mechanistic views, and corrects common misconceptions about this very important reaction.
Download or read book Basic Principles of Organic Chemistry written by John D. Roberts and published by . This book was released on 1977 with total page 1596 pages. Available in PDF, EPUB and Kindle. Book excerpt: Introduction what is organic chemistry all about?; Structural organic chemistry the shapes of molecules functional groups; Organic nomenclature; Alkanes; Stereoisomerism of organic molecules; Bonding in organic molecules atomic-orbital models; More on nomenclature compounds other than hydrocarbons; Nucleophilic substitution and elimination reactions; Separation and purification identification of organic compounds by spectroscopic techniques; Alkenes and alkynes. Ionic and radical addition reactions; Alkenes and alkynes; Oxidation and reduction reactions; Acidity or alkynes.
Download or read book Methods for Oxidation of Organic Compounds V2 written by Alan Haines and published by Elsevier. This book was released on 2012-12-02 with total page 488 pages. Available in PDF, EPUB and Kindle. Book excerpt: Methods for the Oxidation of Organic Compounds: Alcohols, Alcohol Derivatives, Alkyl Halides, Nitroalkanes, Alkyl Azides, Carbonyl Compounds, Hydroxyarenes and Aminoarenes describes the different methods used for the controlled oxidation of alcohols, alcohol derivatives, alkyl halides, nitroalkanes, alkyl azides, carbonyl compounds, hydroxyarenes, and aminoarenes. Most of the oxidative techniques considered are illustrated with detailed experimental procedures taken from the literature. This book is comprised of eight chapters and begins with a discussion on the oxidation of alcohols, with particular emphasis on the formation of carbonyl compounds and carboxylic acids. The following chapters focus on the oxidation of esters and alkyl halides; ethers, acetals, and metal derivatives of alcohols; amines, nitro compounds, and azides; carbonyl compounds; 1,2-diols and related compounds; and hydroxyarenes, aminoarenes, dihydroxyarenes, diaminoarenes, and aminohydroxyarenes. Methods such as catalytic oxidation, catalytic dehydrogenation, and electrochemical and biochemical oxidation are mentioned. This monograph should be of interest to organic chemists and research students.
Download or read book Metal Catalyzed Oxidations of Organic Compounds written by Roger Sheldon and published by Elsevier. This book was released on 2012-12-02 with total page 447 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal-Catalyzed Oxidations of Organic Compounds: Mechanistic Principles and Synthetic focuses on the oxidative transformations of functional groups. This book explores oxidation as being extensively used in the laboratory synthesis of fine organic chemicals and in the manufacture of large-volume petrochemicals. Organized into two parts encompassing 13 chapters, this book starts with an overview of the mechanistic principles of oxidation–reduction in biochemical, organic, and inorganic systems. This text then proceeds with a discussion of the use of molecular oxygen, hydrogen peroxide, and alkyl hydroperoxides as primary oxidants. Other chapters explore stoichiometric oxidations with metal oxidants, which include permanganate and chromic acid. This book discusses as well the synthetic applications of catalytic oxidations as well as the technology of petrochemical oxidation. The final chapter deals with the autoxidations of sulfur, phosphorus, and nitrogen compounds. This book is intended for chemists involved in organic synthesis, catalysis, and organometallic chemistry, both in academic institutions and in industrial laboratories.
Download or read book Oxidation in Organic Chemistry 5 D written by Walter Trahanovsky and published by Elsevier. This book was released on 2012-12-02 with total page 377 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organic Chemistry, A Series of Monographs, Volume 5-D: Oxidation in Organic Chemistry is a four-chapter text that discusses the specific oxidants in oxidation reactions of organic compounds. Chapter I covers oxidations with lead tetraacetate, an oxidant that has been used widely for the selective oxidation of a variety of functional groups. Chapter II examines an oxidant that has a long and extensive history, the permanganate, with emphasis on phase transfer assisted permanganate oxidations. Chapter III discusses the intramolecular oxidative coupling of aromatic substrates, highlighting the utility of developed methods, such as vanadium oxytrifluoride oxidations, in the syntheses of complex natural products. Chapter IV describes the process of coal oxidation with emphasis on the selective oxidative degradation procedures as tools for characterization of coal structure. This text will be of value to organic chemists, researchers, teachers, and students who are interested in oxidation of organic compounds.
Download or read book Oxidation of Organic Compounds by Dioxiranes written by Waldemar Adam and published by John Wiley & Sons. This book was released on 2009-04-27 with total page 684 pages. Available in PDF, EPUB and Kindle. Book excerpt: A Comprehensive Monograph on Dioxirane Oxidations The oxidation of organic compounds is one of the most important methods for the introduction and manipulation of functional groups. Among the most modern of these transformations is the use of the fascinating family of oxidants known as dioxiranes. A dioxirane can, by transferring one of its oxygen atoms to organic substrates, effect a remarkable array of oxidative processes such as epoxidation, C-H insertion, and heteroatom (N, S, P, I) oxidation. In addition to their versatility, dioxiranes can be generated catalytically under mild conditions and produce no toxic waste stream as part of the oxidation process. Moreover, some of the most exciting recent developments involve the enantioselective introduction of oxygen atoms via chiral dioxiranes. This book represents the first single volume dedicated to the comprehensive coverage of the myriad of oxidations of organic compounds performed by dioxiranes. The contents of this book are extracted from comprehensive reviews of the topics contained in the Organic Reactions series and cover the oxidation of alkenes and the oxidation of all other organic substrates. In addition, updated lists of references for each of the chapters are provided, bringing the literature coverage up to June 2008. The authors of these chapters are among the pioneers of dioxirane chemistry and draw on extensive firsthand knowledge of the subject. As with all Organic Reactions content, the presentation emphasizes the preparative aspects of the reactions and pays particular attention throughout to substrate scope, limitations, structural and electronic influences, and stereochemical aspects. For the student or experienced practitioner, both general guidelines for carrying out the reactions as well as detailed experimental procedures are provided. Most importantly, all known examples of dioxirane oxidations have been compiled in easy-to-scan tables covering over 500 pages. Oxidation of Organic Compounds by Dioxiranes is an indispensable working resource for organic and medicinal chemists as well as anyone wishing to own the definitive treatise on this fascinating and useful class of oxidants.
Download or read book Oxidation in Organic Chemistry B written by Walter S. Trahanovsky and published by . This book was released on 1973 with total page 248 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Oxidation and Reduction in Organic Chemistry from the Standpoint of Potential Differences written by Frederic Stearns Granger and published by . This book was released on 1920 with total page 60 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Oxidation written by Barry M. Trost and published by Elsevier. This book was released on 1992-09-08 with total page 1039 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume covers all methods of oxidation for use in organic synthesis. Emphasis has been placed on selectivity and functional group compatibility together with practical utility and applications. The volume is broadly divided to cover oxidation of unactivated carbon-hydrogen bonds, oxidation of activated carbon-hydrogen bonds, that is to say those adjacent to activating substituents and adjacent to heteroatoms, and oxidation of carbon-carbon double bonds. The volume also covers oxidation of C-X bonds, carbon-carbon single bonds, heteroatom oxidation and a number of special topics such as electrochemical methods, oxidative rearrangements, solid supported reagents, electron transfer oxidation, and biological methods.
Download or read book Oxidation of Alcohols to Aldehydes and Ketones written by Gabriel Tojo and published by Springer Science & Business Media. This book was released on 2006-06-15 with total page 388 pages. Available in PDF, EPUB and Kindle. Book excerpt: The aim of this book is to help people performing routine operations in Organic Synthesis in a laboratory. This book, the first one in a series, focuses on the oxidation of alcohols to aldehydes and ketones. Probably, this is the most important routine operation in Organic Synthesis.