Download or read book Oscillations Waves and Chaos in Chemical Kinetics written by Stephen K. Scott and published by . This book was released on 1994 with total page 93 pages. Available in PDF, EPUB and Kindle. Book excerpt: The subject of nonlinear dynamics and the phenomenon of chaos, in particular, has become of great interest across of wide range of scientific disciplines in recent years. Chemical kineticists have been very much involved in these developments. Chemical reactions are exemplary nonlinear systems and have provided some of the most strikingly visual experimental evidence and some of the 'neatest' models for theoretical studies. This text sets out to provide a simple introduction to the excitement and relevance of nonlinear chemical kinetics to the chemical world in general.
Download or read book Oscillations Waves and Chaos in Chemical Kinetics written by Stephen K. Scott and published by Oxford University Press on Demand. This book was released on 1994 with total page 90 pages. Available in PDF, EPUB and Kindle. Book excerpt: This series of short texts provides accessible accounts of a range of essential topics in chemistry. Written with the needs of the student in mind, the Oxford Chemistry Primers offer just the right level of detail for undergraduate study, and will be invaluable as a source of material commonly presented in lecture courses yet not adequately covered in existing texts. All the basic principles and facts in a particular area are presented in a clear and straightforward style, to produce concise yet comprehensive accounts of topics covered in both core and specialist courses.
Download or read book Chemical Chaos written by Stephen K. Scott and published by Oxford University Press. This book was released on 1993 with total page 484 pages. Available in PDF, EPUB and Kindle. Book excerpt: Table of contents: 1. Introduction. 2. Mappings. 3. Flows. 1. Two-variable systems. 4. Flows II. Three-vairable systems. 5. Forced systems. 6. Coupled systems. 7.Experimental methods. 8. The Belousov-Zhabotinskii reaction and other solution-phase reactions. 9. Gas-phase reactions. 10. Heterogeneous catalysis. 11. Electrodissolution reactions. 12. Biochemical systems. Index.
Download or read book Chemical Oscillations and Instabilities written by Peter Gray and published by Oxford University Press on Demand. This book was released on 1994 with total page 453 pages. Available in PDF, EPUB and Kindle. Book excerpt: Scientists in many fields are now expressing considerable interest in non-linearity and the ideas of oscillations and chaos. Chemical reactions provide perfect examples of these phenomena, as oscillating reactions, explosions, ignition, travelling waves, patterns, quasiperiodicity, and chaosare all features of chemical kinetics.Now available in paperback, this book introduces non-linear phenomena in chemical kinetics using simple model schemes. These models involve chemical feedback, such as chain branching, autocatalysis, and self-heating. The emphasis is on physical and pictorial representation, and on identifying thosegross features which are essential. The experimental conditions under which such behaviour will occur can be predicted using simple mathematical recipes, and these are also included.The first part of the book begins with a discussion of long-lived oscillations for autocatalytic or exothermic reactions in closed vessels. Stationary states, bistability, and oscillations in continuous flow reactors and diffusion cells are then considered. This is followed by chemical wavepropagation and by pattern selection and oscillations. Complex oscillations, quasiperiodicity, and chemical chaos, either forced or spontaneous, are introduced. Part 2 deals with real experimental systems, describing observed experimental behaviour and its interpretation in terms of the underlyingchemical mechanisms or simplified models. The Belousov-Zhabotinskii reactions is discussed in some detail as the most extensively studied system, and the behaviour of important gas phase reactions is presented.
Download or read book Encyclopedia of Chemical Physics and Physical Chemistry written by John H. Moore and published by CRC Press. This book was released on 2023-07-03 with total page 986 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Encyclopedia of Physical Chemistry and Chemical Physics introduces possibly unfamiliar areas, explains important experimental and computational techniques, and describes modern endeavors. The encyclopedia quickly provides the basics, defines the scope of each subdiscipline, and indicates where to go for a more complete and detailed explanation. Particular attention has been paid to symbols and abbreviations to make this a user-friendly encyclopedia. Care has been taken to ensure that the reading level is suitable for the trained chemist or physicist. The encyclopedia is divided in three major sections: FUNDAMENTALS: the mechanics of atoms and molecules and their interactions, the macroscopic and statistical description of systems at equilibrium, and the basic ways of treating reacting systems. The contributions in this section assume a somewhat less sophisticated audience than the two subsequent sections. At least a portion of each article inevitably covers material that might also be found in a modern, undergraduate physical chemistry text. METHODS: the instrumentation and fundamental theory employed in the major spectroscopic techniques, the experimental means for characterizing materials, the instrumentation and basic theory employed in the study of chemical kinetics, and the computational techniques used to predict the static and dynamic properties of materials. APPLICATIONS: specific topics of current interest and intensive research. For the practicing physicist or chemist, this encyclopedia is the place to start when confronted with a new problem or when the techniques of an unfamiliar area might be exploited. For a graduate student in chemistry or physics, the encyclopedia gives a synopsis of the basics and an overview of the range of activities in which physical principles are applied to chemical problems. It will lead any of these groups to the salient points of a new field as rapidly as possible and gives pointers as to where to read about the topic in more detail.
Download or read book Kinetics of Multistep Reactions written by Friedrich G. Helfferich and published by Elsevier. This book was released on 2004-09-15 with total page 508 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book addresses primarily the engineer in industrial process development, the research chemist in academia and industry, and the graduate student intending to become a reaction engineer. In industry, competitive pressures put a premium on scale-up by large factors to cut development time. To be safe, such development should be based on "fundamental" kinetics that reflect the elementary steps of which the reaction consists. The book forges fundamental kinetics into a practical tool by presenting new, effective methods for elucidation of mechanisms and reduction of complexity without unacceptable sacrifice in accuracy: fewer equations (lesser computational load), fewer coefficients (fewer experiment to determine them). For network elucidation, new rules relating network configurations to observable kinetic behaviour allow incorrect networks to be ruled out by whole classes instead of one by one. For modelling, general equations and algorithms are given from which equations for specific networks can be recovered by simple substitutions. The procedures are illustrated with examples of industrial reactions including, among others, paraffin oxidation, ethoxylation, hydroformylation, hydrocyanation, shape-selective catalysis, ethane pyrolysis, styrene polymerization, and ethene oligomerization. Many of the rate equations have not been published before. The expanded edition of the 2001 title, Kinetics of Homogeneous Multistep Reactions includes new chapters on heterogeneous catalysis and periodic and chaotic re-actions; new sections on adsorption, statistical methods, and lumping; and other new detail. - Contains new chapters on heterogeneous catalysis, oscillations and chaos - Includes new sections on statistical methods, lumping adsorption and software and databases - Provides a better understanding of complex reaction mechanisms
Download or read book Physical and Chemical Processes in Gas Dynamicsphysical and Chemical Kinet Ics and Thermodynamics written by G. G. Chernyi and published by AIAA. This book was released on 2004 with total page 352 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Physical Chemistry for the Chemical and Biological Sciences written by Raymond Chang and published by University Science Books. This book was released on 2000-05-12 with total page 1048 pages. Available in PDF, EPUB and Kindle. Book excerpt: Hailed by advance reviewers as "a kinder, gentler P. Chem. text," this book meets the needs of an introductory course on physical chemistry, and is an ideal choice for courses geared toward pre-medical and life sciences students. Physical Chemistry for the Chemical and Biological Sciences offers a wealth of applications to biological problems, numerous worked examples and around 1000 chapter-end problems.
Download or read book Physical Chemistry for the Biosciences written by Raymond Chang and published by University Science Books. This book was released on 2005-02-11 with total page 706 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is ideal for use in a one-semester introductory course in physical chemistry for students of life sciences. The author's aim is to emphasize the understanding of physical concepts rather than focus on precise mathematical development or on actual experimental details. Subsequently, only basic skills of differential and integral calculus are required for understanding the equations. The end-of-chapter problems have both physiochemical and biological applications.
Download or read book Self Organized Biological Dynamics and Nonlinear Control written by Jan Walleczek and published by Cambridge University Press. This book was released on 2006-04-20 with total page 444 pages. Available in PDF, EPUB and Kindle. Book excerpt: The growing impact of nonlinear science on biology and medicine is fundamentally changing our view of living organisms and disease processes. This book introduces the application to biomedicine of a broad range of interdisciplinary concepts from nonlinear dynamics, such as self-organization, complexity, coherence, stochastic resonance, fractals and chaos. It comprises 18 chapters written by leading figures in the field and covers experimental and theoretical research, as well as the emerging technological possibilities such as nonlinear control techniques for treating pathological biodynamics, including heart arrhythmias and epilepsy. This book will attract the interest of professionals and students from a wide range of disciplines, including physicists, chemists, biologists, sensory physiologists and medical researchers such as cardiologists, neurologists and biomedical engineers.
Download or read book Growth and Form of Self organized Branched Crystal Pattern in Nonlinear Chemical System written by Rohit Srivastava and published by Springer. This book was released on 2016-04-12 with total page 79 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book introduces the oscillatory reaction and pattern formation in the Belousov-Zhabotinsky (BZ) reaction that became model for investigating a wide range of intriguing pattern formations in chemical systems. So many modifications in classic version of BZ reaction have been carried out in various experimental conditions that demonstrate rich varieties of temporal oscillations and spatio-temporal patterns in non- equilibrium conditions. Mixed-mode versions of BZ reactions, which comprise a pair of organic substrates or dual metal catalysts, have displayed very complex oscillating behaviours and novel space-time patterns during reaction processes. These characteristic spatio-temporal properties of BZ reactions have attracted increasing attention of the scientific community in recent years because of its comparable periodic structures in electrochemical systems, polymerization processes, and non-equilibrium crystallization phenomena. Instead, non-equilibrium crystallization phenomena which lead to development of novel crystal morphologies in constraint of thermodynamic equilibrium conditions have been investigated and are said to be stationary periodic structures. Efforts have continued to analyze insight mechanisms and roles of reaction-diffusion mechanism and self-organization in the growth of such periodic crystal patterns. In this book, non-equilibrium crystallization phenomena, leading to growth of some novel crystal patterns in dual organic substrate modes of oscillatory BZ reactions have been discussed. Efforts have been made to find out experimental parameters where transitions of the spherulitic crystal patterns take place. The book provides the scientific community and entrepreneurs with a thorough understanding and knowledge of the growth and form of branched crystal pattern in reaction-diffusion system and their morphological transition.
Download or read book Dynamical Systems with Applications Using Mathematica written by Stephen Lynch and published by Birkhäuser. This book was released on 2017-10-12 with total page 590 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides an introduction to the theory of dynamical systems with the aid of the Mathematica® computer algebra package. The book has a very hands-on approach and takes the reader from basic theory to recently published research material. Emphasized throughout are numerous applications to biology, chemical kinetics, economics, electronics, epidemiology, nonlinear optics, mechanics, population dynamics, and neural networks. Theorems and proofs are kept to a minimum. The first section deals with continuous systems using ordinary differential equations, while the second part is devoted to the study of discrete dynamical systems.
Download or read book Foundations Of Complex Systems Nonlinear Dynamics Statistical Physics Information And Prediction written by Gregoire Nicolis and published by World Scientific. This book was released on 2007-09-03 with total page 343 pages. Available in PDF, EPUB and Kindle. Book excerpt: Complexity is emerging as a post-Newtonian paradigm for approaching a large body of phenomena of concern at the crossroads of physical, engineering, environmental, life and human sciences from a unifying point of view. This book outlines the foundations of modern complexity research as it arose from the cross-fertilization of ideas and tools from nonlinear science, statistical physics and numerical simulation. It is shown how these developments lead to an understanding, both qualitative and quantitative, of the complex systems encountered in nature and in everyday experience and, conversely, how natural complexity acts as a source of inspiration for progress at the fundamental level.
Download or read book Physical Chemistry written by Harold H. Trimm and published by CRC Press. This book was released on 2011-04-15 with total page 359 pages. Available in PDF, EPUB and Kindle. Book excerpt: Physical chemistry covers diverse topics, from biochemistry to materials properties to the development of quantum computers. Physical chemistry applies physics and math to problems that interest chemists, biologists, and engineers. Physical chemists use theoretical constructs and mathematical computations to understand chemical properties and describe the behavior of molecular and condensed matter. Their work involves manipulations of data as well as materials. Physical chemistry entails extensive work with sophisticated instrumentation and equipment as well as state-of-the-art computers. This new volume presents a selection of articles on topics in the field.
Download or read book Complexity written by D.G. Bonchev and published by CRC Press. This book was released on 2003-01-23 with total page 223 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume covers the rapidly developing field of complexity studies with the underlying theme that complexity is to be found everywhere. The volume discusses many chemical applications and offers a comprehensive coverage of complexity and the ways in which it may be measured, complexity indices, complexity measures based on Shannon's information
Download or read book An Introduction to Nonlinear Chemical Dynamics written by Irving R. Epstein and published by Oxford University Press. This book was released on 1998-10-22 with total page 407 pages. Available in PDF, EPUB and Kindle. Book excerpt: Just a few decades ago, chemical oscillations were thought to be exotic reactions of only theoretical interest. Now known to govern an array of physical and biological processes, including the regulation of the heart, these oscillations are being studied by a diverse group across the sciences. This book is the first introduction to nonlinear chemical dynamics written specifically for chemists. It covers oscillating reactions, chaos, and chemical pattern formation, and includes numerous practical suggestions on reactor design, data analysis, and computer simulations. Assuming only an undergraduate knowledge of chemistry, the book is an ideal starting point for research in the field. The book begins with a brief history of nonlinear chemical dynamics and a review of the basic mathematics and chemistry. The authors then provide an extensive overview of nonlinear dynamics, starting with the flow reactor and moving on to a detailed discussion of chemical oscillators. Throughout the authors emphasize the chemical mechanistic basis for self-organization. The overview is followed by a series of chapters on more advanced topics, including complex oscillations, biological systems, polymers, interactions between fields and waves, and Turing patterns. Underscoring the hands-on nature of the material, the book concludes with a series of classroom-tested demonstrations and experiments appropriate for an undergraduate laboratory.
Download or read book Macroscopic Metaphysics written by Paul Needham and published by Springer. This book was released on 2018-01-08 with total page 234 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is about our ordinary concept of matter in the form of enduring continuants and the processes in which they are involved in the macroscopic realm. It emphasises what science rather than philosophical intuition tells us about the world, and chemistry rather than the physics that is more usually encountered in philosophical discussions. The central chapters dealing with the nature of matter pursue key steps in the historical development of scientific conceptions of chemical substance. Like many contemporary discussions of material objects, it relies heavily on mereology. The classical principles are applied to the mereological structure of regions of space, intervals of time, processes and quantities of matter. Quantities of matter, which don’t gain or lose parts over time, are distinguished from individuals, which are typically constituted of different quantities of matter at different times. The proper treatment of the temporal aspect of the features of material objects is a central issue in this book, which is addressed by investigating the conditions governing the application of predicates relating time and other entities. Of particular interest here are relations between quantities of matter and times expressing substance kind, phase and mixture. Modal aspects of these features are taken up in the final chapter.
